We present the results of two ground-based radio-echo-sounding(RES) and GPS surveys performed in the vicinity of new Chinese Taishan station,Princess Elizabeth Land,East Antarctica,obtained in two austral summers du...We present the results of two ground-based radio-echo-sounding(RES) and GPS surveys performed in the vicinity of new Chinese Taishan station,Princess Elizabeth Land,East Antarctica,obtained in two austral summers during CHINARE 21(2004/2005) and CHINARE 29(2012/2013).The radar surveys measured ice thickness and internal layers using 60- and 150-MHz radar systems,and GPS measurements showed smooth surface slopes around the station with altitudes of 2607-2636 m above sea level(a.s.l.).Radar profiles indicate an average ice thickness of 1900 m,with a maximum of 1949 m and a minimum of 1856 m,within a square area measuring approximately 2 km × 2 km in the vicinity of the station.The ice thickness beneath the station site is 1870 m.The subglacial landscape beneath the station is quiet sharp and ranges from 662 to 770 m a.s.l.,revealing part of a mountainous topography.The ice volume in the grid is estimated to be 7.6 km^3.Along a 60-MHz radar profile with a length of 17.6 km at the region covering the station site,some disturbed internal layers are identified and traced;the geometry of internal layers within the englacial stratigraphy may imply a complex depositional process in the area.展开更多
Chromia-forming alloys have good resistance to oxidizing agents such as O2, CO2, … It is accepted that the protection of these alloys is always due to the chromia layer formed at the surface of the alloys, which acts...Chromia-forming alloys have good resistance to oxidizing agents such as O2, CO2, … It is accepted that the protection of these alloys is always due to the chromia layer formed at the surface of the alloys, which acts as a barrier between the oxidizing gases and the alloy substrates, forming a diffusion zone that limits the overall reaction rate and leads to parabolic kinetics. But this was not verified in the study devoted to Inconel®625 the oxidation in CO2 that was followed by TGA, with characterizations by XRD, EDS and FIB microscopy. Contrary to what was expected and accepted in similar studies on other chromia-forming alloys, it was shown that the diffusion step that governs the overall reaction rate is not located inside the chromia layer but inside the alloy, precisely inside a zone just beneath the interface alloy/chromia, this zone being depleted in chromium. The chromia layer, therefore, plays no kinetic role and does not directly protect the underlying alloy. This result was demonstrated using a simple test that consisted in removing the chromia layer from the surface of samples partially oxidized and then to continue the thermal treatment: insofar as the kinetics continued without any change in rate, this proved that this surface layer of oxide did not protect the substrate. Based on previous work on many chromia-forming alloys, the possibility of a similar reaction mechanism is discussed. If the chromia layer is not the source of protection for a number of chromia-forming alloys, as is suspected, this might have major consequences in terms of industrial applications.展开更多
A variety of techniques, such as chemical analysis, scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, were applied to characterize the adhesion protective layer formed below the blast...A variety of techniques, such as chemical analysis, scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, were applied to characterize the adhesion protective layer formed below the blast furnace taphole level when a certain amount of titanium-bearing burden was used. Samples of the protective layer were extracted to identify the chemical composition, phase assemblage, andistribution. Furthermore, the formation mechanism of the protective layer was determined after clarifying the source of each componenFinally, a technical strategy was proposed for achieving a stable protective layer in the hearth. The results show that the protective layemainly exists in a bilayer form in the sidewall, namely, a titanium-bearing layer and a graphite layer. Both the layers contain the slag phaswhose major crystalline phase is magnesium melilite(Ca2Mg Si2O7) and the main source of the slag phase is coke ash. It is clearly determinethat solid particles such as graphite, Ti(C,N) and Mg Al2O4play an important role in the formation of the protective layer, and the key factofor promoting the formation of a stable protective layer is reasonable control of the evolution behavior of coke.展开更多
AIM: To explore a new diagnostic index for differentiating the evaporative dry eye(EDE) subtypes by analysis of their respective clinical characteristics. METHODS: A cross-sectional study of 139 patients(139 eyes...AIM: To explore a new diagnostic index for differentiating the evaporative dry eye(EDE) subtypes by analysis of their respective clinical characteristics. METHODS: A cross-sectional study of 139 patients(139 eyes) with EDE who were enrolled and classified as obstructive meibomian gland dysfunction(MGD)(n=81) and non-obstructive MGD(n=58) EDE. All patients completed a Standard Patient Evaluation of Eye Dryness(SPEED) questionnaire and were evaluated for average lipid layer thickness(LLT), tear meniscus height measurements(TMH), tear break-up time(TBUT), ocular surface staining score, Schirmer I test(SIT), lid margin abnormalities, and meibomian gland function and morphology. RESULTS: Age, average LLT, TMH, scores of lid margin abnormalities, meibum quality, meibomian gland loss(MGL)(all P≤0.001), and TBUT(P=0.03) were all significantly different between obstructive MGD EDE patients and nonobstructive MGD EDE patients. Average LLT in obstructive MGD EDE was correlated with meibomian expressibility(r=-0.541, P≤0.001), lid margin abnormalities were marginally not significant(r=0.197, P=0.077), and TMH was correlated with MGL(total MGL: r=0.552, P≤0.001; upper MGL: r=0.438, P≤0.001; lower MGL: r=0.407, P≤0.001). Average LLT in non-obstructive MGD EDE, was correlated with meibomian expressibility and Oxford staining(r=-0.396, P=0.002; r=-0.461, P≤0.001). The efficiency of combining average LLT and TMH was optimal, with a sensitivity of 80.2% and a specificity of 74.1%. Obstructive MGD EDE patients had an average LLT≥69 nm and TMH≥0.25 mm, while non-obstructive MGD EDE patients had an average LLT〈69 nm and TMH〈0.25 mm.CONCLUSION: Obstructive MGD EDE and nonobstructive MGD EDE have significantly different clinical characteristics. Combining average LLT and TMH measurements enhanced their reliability for differentiating these two subtypes and provided guidance for offering more precise treatments for EDE subtypes.展开更多
AIM: To investigate the effects of different concentrations of artificial tears on lipid layer thickness (LLT) and blink rate (BR) in dry eye patients. METHODS: This study included 106 eyes of 58 patients with ...AIM: To investigate the effects of different concentrations of artificial tears on lipid layer thickness (LLT) and blink rate (BR) in dry eye patients. METHODS: This study included 106 eyes of 58 patients with dry eye. The lipid deficiency type was defined as the LLT baseline 〈75 nm. The LLT and BR were measured at baseline and 1, 5 and 15min after the instillation of 0.1% or 0.3% sodium hyaluronate (SH) eye drops by using the LipiView ocular surface interferometer. RESULTS: In the lipid deficiency group, the LLT increased from baseline at 1rain post instillation. The LLT after the instillation of 0.1% SH was significantly higher than that after the instillation of 0.3% SH (P〈0.001). The LLT returned to baseline at 15min post instillation of 0.1% SH and at 5min post instillation of 0.3% SH. In the non-lipid deficiency group, the LLT decreased from baseline at lmin and returned to baseline at 5rain for both treatments. The BRs were not significantly different at different time points for both treatments. CONCLUSION: SH eye drops induce a short-term increase in LLT of patients with lipid deficiency. A low concentration of artificial tears have a stronger effect than a high concentration of artificial tears on the increase in LLT. in comparison, SH eye drops induce a transient and slight decrease in LLT of patients without lipid deficiency. A low concentration of artificial tears might be better for patients with lipid deficiency.展开更多
Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, te...Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, temperature of liquid aluminium, temperture of tools and pressure on thickness of the intermetallic layer at the interface between steel and aluminium under solid-liquid pressure bonding of steel and aluminium perfectly. The optimum thickness has been determined according to the value of the optimum shearing strength.展开更多
A long campaign life of blast furnaces is heavily linked to the existence of a protective layer in their hearths. In this work, we conducted dissection studies and investigated damage in blast furnace hearths to estim...A long campaign life of blast furnaces is heavily linked to the existence of a protective layer in their hearths. In this work, we conducted dissection studies and investigated damage in blast furnace hearths to estimate the formation mechanism of the protective layer. The results illustrate that a significant amount of graphite phase was trapped within the hearth protective layer. Furthermore, on the basis of the thermodynamic and kinetic calculations of the graphite precipitation process, a precipitation potential index related to the formation of the graphite-rich protective layer was proposed to characterize the formation ability of this layer. We determined that, under normal operating conditions, the precipitation of graphite phase ~om hot metal was thermodynamically possible. Among elements that exist in hot metal, C, Si, and P favor graphite precipitation, whereas Mn and Cr inhibit this process. Moreover, at the same hot-face temperature, an increase of carbon concentration in hot metal can shorten the precipitation time. Finally, the results suggest that measures such as reducing the hot-face tem- perature and increasing the degree of carbon saturation in hot metal are critically important to improve the precipitation potential index.展开更多
Forests and grasslands in arid and semi-arid regions receive high-intensity ultraviolet(UV) radiation year-round. However, how the UV radiation affects the litter decomposition on the forest floor remains unclear. H...Forests and grasslands in arid and semi-arid regions receive high-intensity ultraviolet(UV) radiation year-round. However, how the UV radiation affects the litter decomposition on the forest floor remains unclear. Here, we conducted a field-based experiment in 2011 in the southeastern Horqin Sandy Land, Northeast China, to investigate the effects of UV radiation, litter layer thickness, and their interaction on the mass loss and chemical properties of decomposing litter from Xiaozhuan poplar(Populus × xiaozhuanica) and Mongolian pine(Pinus sylvestris var. mongolica) plantation trees. We found that UV radiation accelerated the decomposition rates of both the Xiaozhuan poplar litter and Mongolian pine litter. For both species, the thick-layered litter had a lower mass loss than the thin-layered litter. The interaction between UV radiation and litter layer thickness significantly affected the litter mass loss of both tree species. However, the effects of UV radiation on the chemical properties of decomposing litter differed between the two species, which may be attributed to the contrasting initial leaf litter chemical properties and morphology. UV radiation mostly had positive effects on the lignin concentration and lignin/N ratio of Xiaozhuan poplar litter, while it had negative effects on the N concentration of Mongolian pine litter. Moreover, litter layer thickness and its interaction with UV radiation showed mostly positive effects on the N concentration and lignin/N ratio of Xiaozhuan poplar litter and the ratios of C/N and lignin/N of Mongolian pine litter, and mostly negative effects on the C/N ratio of Xiaozhuan poplar litter and the N concentration of Mongolian pine litter. Together, these results reveal the important roles played by UV radiation and litter layer thickness in the process of litter decomposition in this semi-arid region, and highlight how changes in the litter layer thickness can exert strong influences on the photodegradation of litter in tree plantations.展开更多
The developing processes of stress and deformation fields of a protected layer after mining an upper-protective layer with a bow pseudo-incline technique were simulated to locate the protection region. The pressure re...The developing processes of stress and deformation fields of a protected layer after mining an upper-protective layer with a bow pseudo-incline technique were simulated to locate the protection region. The pressure relief of the protected layer was analyzed after mining the upper-protective layer. The pressure relief angle along the strike and incline were located according to the roles of protection of the deformation and stress pressure-relief of the protective layer after mining. This results show that the upper-protective layer with the bow pseudo-incline technique have an upper and downside pressure relief angle of 85 and 68 degrees respectively; the distribution of strike pressure relief angles along the pseudo-incline working face is uneven and their values range from 38.3 to 51 degrees. The pressure relief angle of the inclined middle location was the largest. The distribution of the protection region of the upper-protective layer with the bow pseudo-incline teelmique located by practical tests and numerical simulation is essentially consistent, compared with the results obtained by these methods.展开更多
Silicon(Si)has been attracting extensive attention for rechargeable lithium(Li)‐ion batteries due to its high theoretical capacity and low potential vs Li/Li+.However,it remains challenging and problematic to stabili...Silicon(Si)has been attracting extensive attention for rechargeable lithium(Li)‐ion batteries due to its high theoretical capacity and low potential vs Li/Li+.However,it remains challenging and problematic to stabilize the Si materials during electrochemical cycling because of the huge volume expansion,which results in losing electric contact and pulverization of Si particles.Consequently,the Si anode materials generally suffer from poor cycling,poor rate performance,and low coulomb efficiency,preventing them from practical applications.Up‐to‐date,there are numerous reports on the engineering of Si anode materials at microscale and nanoscale with significantly improved electrochemical performances.In this review,we will concentrate on various precisely designed protective layers for silicon‐based materials,including carbon layers,inorganic layers,and conductive polymer protective layer.First,we briefly introduced the alloying and failure mechanism of Si as anode materials upon electrochemical reactions.Following that,representative cases have been introduced and summarized to illustrate the purpose and advancement of protective coating layers,for instance,to alleviate pulverization and improve conductivity caused by volume expansion of Si particles during charge/discharge process,and maintain the surface stability of Si particles to form a stable solid‐electrolyte interphase layer.At last,possible strategies on the protective coating layer for stabilizing silicon anode materials that can be applied in the future have been indicated.展开更多
By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode wit...By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode with a maximum external quantum efficiency of 6.19% and a stable lifetime at a high initial current density of 0.0375 A/cm2. We demonstrate that the change in the thicknesses of organic layers affects the operating voltage and luminous efficiency greater than the lifetime. The lifetime being independent of thickness is beneficial in achieving high-quality full-colour display devices and white lighting sources with multi-emitters.展开更多
Ink layer thickness on the printing plate greatly influences uniformity of ink transferred to the substrates,which is an important indicator of printing quality,so the study of ink layer and its thickness is important...Ink layer thickness on the printing plate greatly influences uniformity of ink transferred to the substrates,which is an important indicator of printing quality,so the study of ink layer and its thickness is important for improving the quality of printing products. Ansys CFX is used here to build a model of ink fluid adhering to lower vibrator roller,form inking roller,and printing plate for analyzing ink transferring in inking process. Ink layer thickness on each position of the model is acquired to analyze the forming mechanism of ink layer on printing plate,as well as the influence of oscillation speed of lower vibrator roller and dot area percentage of plate on ink layer thickness of printing plate. It can be concluded that,in the case of fixed ink supplying amount,ink layer thickness increases along with the increasing of oscillation speed,and decreases when the dot area percentage is getting larger and the minimum is got when the dot area percentage is 100%. At last,experiment of plate inking on print ability tester verifies the correctness of the simulation analysis.展开更多
The thermoelastic behaviors of such as temperature distribution, displacements, and stresses in thermal barrier coatings (TBC) are seriously influenced by top coat thickness and edge conditions. The top coat of TBC sp...The thermoelastic behaviors of such as temperature distribution, displacements, and stresses in thermal barrier coatings (TBC) are seriously influenced by top coat thickness and edge conditions. The top coat of TBC specimens prepared with TriplexPro?-200 system was controlled by changing the processing parameter and feedstock, showing the various thicknesses and microstructures. A couple of governing partial differential equations were derived based on the thermoelastic theory. Since the governing equations were too involved to solve analytically, a finite volume method was developed to obtain approximations. The thermoelastic behaviors of TBC specimens with the various thicknesses and microstructures were estimated through mathematical approaches with different edge conditions. The results demonstrated that the microstructure and thickness of the top coat, and the edge condition in theoretical analysis were crucial factors to be considered in controlling the thermoelastic characteristics of plasma-sprayed TBCs.展开更多
The active layer thickness(ALT)in permafrost regions,which affects water and energy exchange,is a key variable for assessing hydrological processes,cold-region engineering,and climate change.In this study,the authors ...The active layer thickness(ALT)in permafrost regions,which affects water and energy exchange,is a key variable for assessing hydrological processes,cold-region engineering,and climate change.In this study,the authors analyzed the variation trends and relative changes of simulated ALTs using the Chinese Academy of Sciences Land Surface Model(CAS-LSM)and the Chinese Academy of Sciences Flexible Global Ocean-Atmosphere-Land System Model,gridpoint version 3(CAS-FGOALS-g3).Firstly,the simulated ALTs produced by CAS-LSM were shown to be reasonable by comparing them with Circumpolar Active Layer Monitoring observations.Then,the authors simulated the ALTs from 1979 to 2014,and their relative changes across the entire Northern Hemisphere from 2015 to 2100.It is shown that the ALTs have an increasing trend.From 1979 to 2014,the average ALTs and their variation trends over all permafrost regions were 1.08 m and 0.33 cm yr-1,respectively.The relative changes of the ALTs ranged from 1%to 58%,and the average relative change was 10.9%.The variation trends of the ALTs were basically consistent with the variation trends of the 2-m air temperature.By 2100,the relative changes of ALTs are predicted to be 10.3%,14.6%,30.1%,and 51%,respectively,under the four considered hypothetical climate scenarios(SSP-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5).This study indicates that climate change has a substantial impact on ALTs,and our results can help in understanding the responses of the ALTs of permafrost due to climate change.展开更多
Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) o...Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) of the multi-layered fabrics was measured by a TPP tester under flash fire. Results showed that the utilization of the PCM fabrics improved the thermal protective performance of the multi-layered fabrics. The fabric with a PCM add on of 41. 9% increased the thermal protection by 50. 6% and reduced the time to reach a second degree burn by 8. 4 s compared with the reference fabrics( without PCMs). The employment of the PCM fabrics also reduced the blackened areas on the inner layers. The PCM fabrics with higher PCM melting temperature could bring higher thermal protective performance.展开更多
Voxel-based canopy profiling is commonly used to determine small-scale leaf area.Layer thickness and voxel size impact accuracy when using this method.Here,we determined the optimal combination of layer thickness and ...Voxel-based canopy profiling is commonly used to determine small-scale leaf area.Layer thickness and voxel size impact accuracy when using this method.Here,we determined the optimal combination of layer thickness and voxel size to estimate leaf area density accurately.Terrestrial LiDAR Stonex X300 was used to generate point cloud data for Masson pines(Pinus massoniana).The canopy layer was stratified into 0.10-1.00-m-thick layers,while voxel size was 0.01-0.10 m.The leaf area density of individual trees was estimated using leaf area indices for the upper,middle,and lower canopy and the overall canopy.The true leaf area index,obtained by layered harvesting,was used to verify the inversion results.Leaf area density was inverted by nine combinations of layer thickness and voxel size.The average relative accuracy and mean estimated accuracy of these combined inversion results exceeded 80%.When layer thickness was 1.00 m and voxel size 0.05 m,inversion was closest to the true value.The average relative accuracy was 92.58%,mean estimated accuracy 98.00%,and root mean square error 0.17.The combination of leaf area density and index was accurately retrieved.In conclusion,nondestructive voxel-based canopy profiling proved suitable for inverting the leaf area density of Masson pine in Hetian Town,Fujian Province.展开更多
In order to prevent coal and methane outbursts, mining protective layers is an effective means, yet no precedents of mining multiple protective layers is discoveried in seams which includes several seams are prone to ...In order to prevent coal and methane outbursts, mining protective layers is an effective means, yet no precedents of mining multiple protective layers is discoveried in seams which includes several seams are prone to outburst like Xinzhuangzi Mine. This paper perfected the related theories through analyzing mining multiple upper protective layers. By means of examining several parameters, it synthetically analyzed and ascer- tains the protected effectiveness and scope and reasonable parameters, finally obtained the specific indexes and effectiveness of mining multiple protective layers in coal seams cluster.展开更多
Land reclamation is a process of ecosystem reconstruction, for which it is very important to keep co-adaptation between plants and the below ground habitat. In order to keep the co-adaptation among plant species, thic...Land reclamation is a process of ecosystem reconstruction, for which it is very important to keep co-adaptation between plants and the below ground habitat. In order to keep the co-adaptation among plant species, thickness of covering soil and medium of covering soil to establish a self-regulating ecosystem, the thickness of covering soil of land reclamation for plants in different living forms by synusia structure of plant below-ground habitat and medium of covering soil by ecological factors of plant below-ground habitat were studied. Synusia structure of plant below-ground habitat was recognized through investigation on structure and root of plant community, and ecological factors were determined through soil profile investigation. The thickness and medium of covering soil of land reclamation for the tree, the shrub and the herb were proposed.展开更多
In order to understand the effect of mining height and floor lithology at the upper protective layer face on the pressure relief of protected coal seams, this paper uses a numerical simulation method to model the pres...In order to understand the effect of mining height and floor lithology at the upper protective layer face on the pressure relief of protected coal seams, this paper uses a numerical simulation method to model the pressure changes at protected coal seam during mining upper protective layer. The results show that the taller the mining height at the upper protective layer face, the greater the protection on protected coal seam due to the higher level of pressure release; the upper protective layer face with hard rock floor impedes the pressure release at the protected coal seam, which affects the overall effect of the pressure release at protected coal seam using the protective layer mining method.展开更多
Prediction of methane emissions at the stage of longwall planning constitutes the basis for the determination of the appropriate method and parameters of ventilation and selection of prevention means including the met...Prediction of methane emissions at the stage of longwall planning constitutes the basis for the determination of the appropriate method and parameters of ventilation and selection of prevention means including the methane drainage technol- ogy. The growth of methane saturation of coal seams with the extraction depth, with simultaneously increasing output concen- tration, contributes to the increase of the quantity of methane emitted into longwall areas. The subject matter of the article has been directed at the predicted quantity of methane emissions into planned longwalls with roof caving in the layer of seams adjacent to the roof of large thickness. The performed prognostic calculations of methane emissions into the longwall working were referred to two sources, i.e. methane liberated during coal mining by means of a cutter-loader and methane originating from the degasification of the floor layer destressed by the longwall conducted in the close-to-roof layer. The calculations of predictions allow to refer to the planned longwall, on account of the emitting methane, with possible and safe output quantity. Planning of extraction in the close-to-roof layer of a seam of large thickness with roof caving is especially important in con- ditions of increasing methane saturation with the depth of deposition and should be preceded by a prognostic analysis for de- termining the extraction possibilities of the planned longwall.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant No.41376192,40906101)the National Basic Research Program of China(973 Program)(Grant No.2013CBA01804 and 2012CB957702)+2 种基金the Foreign Cooperation Support Program of Chinese Arctic and Antarctic Administration,SOA,China(Grand No.IC201214)the Natural Science Foundation of Shanghai,China(Grand No.13ZR1445300)the Chinese Polar Environment Comprehensive Investigation&Assessment Programmes(CHINARE2014-01-01)
文摘We present the results of two ground-based radio-echo-sounding(RES) and GPS surveys performed in the vicinity of new Chinese Taishan station,Princess Elizabeth Land,East Antarctica,obtained in two austral summers during CHINARE 21(2004/2005) and CHINARE 29(2012/2013).The radar surveys measured ice thickness and internal layers using 60- and 150-MHz radar systems,and GPS measurements showed smooth surface slopes around the station with altitudes of 2607-2636 m above sea level(a.s.l.).Radar profiles indicate an average ice thickness of 1900 m,with a maximum of 1949 m and a minimum of 1856 m,within a square area measuring approximately 2 km × 2 km in the vicinity of the station.The ice thickness beneath the station site is 1870 m.The subglacial landscape beneath the station is quiet sharp and ranges from 662 to 770 m a.s.l.,revealing part of a mountainous topography.The ice volume in the grid is estimated to be 7.6 km^3.Along a 60-MHz radar profile with a length of 17.6 km at the region covering the station site,some disturbed internal layers are identified and traced;the geometry of internal layers within the englacial stratigraphy may imply a complex depositional process in the area.
文摘Chromia-forming alloys have good resistance to oxidizing agents such as O2, CO2, … It is accepted that the protection of these alloys is always due to the chromia layer formed at the surface of the alloys, which acts as a barrier between the oxidizing gases and the alloy substrates, forming a diffusion zone that limits the overall reaction rate and leads to parabolic kinetics. But this was not verified in the study devoted to Inconel®625 the oxidation in CO2 that was followed by TGA, with characterizations by XRD, EDS and FIB microscopy. Contrary to what was expected and accepted in similar studies on other chromia-forming alloys, it was shown that the diffusion step that governs the overall reaction rate is not located inside the chromia layer but inside the alloy, precisely inside a zone just beneath the interface alloy/chromia, this zone being depleted in chromium. The chromia layer, therefore, plays no kinetic role and does not directly protect the underlying alloy. This result was demonstrated using a simple test that consisted in removing the chromia layer from the surface of samples partially oxidized and then to continue the thermal treatment: insofar as the kinetics continued without any change in rate, this proved that this surface layer of oxide did not protect the substrate. Based on previous work on many chromia-forming alloys, the possibility of a similar reaction mechanism is discussed. If the chromia layer is not the source of protection for a number of chromia-forming alloys, as is suspected, this might have major consequences in terms of industrial applications.
基金financially supported by the Natural Science Foundation of China(No.51304014)the Natural Science Foundation of China and Baosteel(No.51134008)the National Basic Research Program of China(No.2012CB720401)
文摘A variety of techniques, such as chemical analysis, scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, were applied to characterize the adhesion protective layer formed below the blast furnace taphole level when a certain amount of titanium-bearing burden was used. Samples of the protective layer were extracted to identify the chemical composition, phase assemblage, andistribution. Furthermore, the formation mechanism of the protective layer was determined after clarifying the source of each componenFinally, a technical strategy was proposed for achieving a stable protective layer in the hearth. The results show that the protective layemainly exists in a bilayer form in the sidewall, namely, a titanium-bearing layer and a graphite layer. Both the layers contain the slag phaswhose major crystalline phase is magnesium melilite(Ca2Mg Si2O7) and the main source of the slag phase is coke ash. It is clearly determinethat solid particles such as graphite, Ti(C,N) and Mg Al2O4play an important role in the formation of the protective layer, and the key factofor promoting the formation of a stable protective layer is reasonable control of the evolution behavior of coke.
基金Supported by the Provincial Frontier and Key Technology Innovation Special Fund of Guangdong Province(No.2015B020227001)the Guangzhou Science and Technology Plan Scientific Research Projects(No.201504010023)
文摘AIM: To explore a new diagnostic index for differentiating the evaporative dry eye(EDE) subtypes by analysis of their respective clinical characteristics. METHODS: A cross-sectional study of 139 patients(139 eyes) with EDE who were enrolled and classified as obstructive meibomian gland dysfunction(MGD)(n=81) and non-obstructive MGD(n=58) EDE. All patients completed a Standard Patient Evaluation of Eye Dryness(SPEED) questionnaire and were evaluated for average lipid layer thickness(LLT), tear meniscus height measurements(TMH), tear break-up time(TBUT), ocular surface staining score, Schirmer I test(SIT), lid margin abnormalities, and meibomian gland function and morphology. RESULTS: Age, average LLT, TMH, scores of lid margin abnormalities, meibum quality, meibomian gland loss(MGL)(all P≤0.001), and TBUT(P=0.03) were all significantly different between obstructive MGD EDE patients and nonobstructive MGD EDE patients. Average LLT in obstructive MGD EDE was correlated with meibomian expressibility(r=-0.541, P≤0.001), lid margin abnormalities were marginally not significant(r=0.197, P=0.077), and TMH was correlated with MGL(total MGL: r=0.552, P≤0.001; upper MGL: r=0.438, P≤0.001; lower MGL: r=0.407, P≤0.001). Average LLT in non-obstructive MGD EDE, was correlated with meibomian expressibility and Oxford staining(r=-0.396, P=0.002; r=-0.461, P≤0.001). The efficiency of combining average LLT and TMH was optimal, with a sensitivity of 80.2% and a specificity of 74.1%. Obstructive MGD EDE patients had an average LLT≥69 nm and TMH≥0.25 mm, while non-obstructive MGD EDE patients had an average LLT〈69 nm and TMH〈0.25 mm.CONCLUSION: Obstructive MGD EDE and nonobstructive MGD EDE have significantly different clinical characteristics. Combining average LLT and TMH measurements enhanced their reliability for differentiating these two subtypes and provided guidance for offering more precise treatments for EDE subtypes.
基金Supported by Provincial Frontier and Key Technology Innovation Special Fund of Guangdong Province(No.2015B020227001)Guangzhou Science and Technology Plan Scientific Research Projects(No.201504010023)Fundamental Research Funds of State Key Laboratory of Ophthalmology of China,and Five Five Cultivation Project of Ophthalmic Center,Sun Yat-sen University
文摘AIM: To investigate the effects of different concentrations of artificial tears on lipid layer thickness (LLT) and blink rate (BR) in dry eye patients. METHODS: This study included 106 eyes of 58 patients with dry eye. The lipid deficiency type was defined as the LLT baseline 〈75 nm. The LLT and BR were measured at baseline and 1, 5 and 15min after the instillation of 0.1% or 0.3% sodium hyaluronate (SH) eye drops by using the LipiView ocular surface interferometer. RESULTS: In the lipid deficiency group, the LLT increased from baseline at 1rain post instillation. The LLT after the instillation of 0.1% SH was significantly higher than that after the instillation of 0.3% SH (P〈0.001). The LLT returned to baseline at 15min post instillation of 0.1% SH and at 5min post instillation of 0.3% SH. In the non-lipid deficiency group, the LLT decreased from baseline at lmin and returned to baseline at 5rain for both treatments. The BRs were not significantly different at different time points for both treatments. CONCLUSION: SH eye drops induce a short-term increase in LLT of patients with lipid deficiency. A low concentration of artificial tears have a stronger effect than a high concentration of artificial tears on the increase in LLT. in comparison, SH eye drops induce a transient and slight decrease in LLT of patients without lipid deficiency. A low concentration of artificial tears might be better for patients with lipid deficiency.
文摘Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, temperature of liquid aluminium, temperture of tools and pressure on thickness of the intermetallic layer at the interface between steel and aluminium under solid-liquid pressure bonding of steel and aluminium perfectly. The optimum thickness has been determined according to the value of the optimum shearing strength.
基金supported the National Science Foundation for Young Scientists of China (No. 51304014)the Open Foundation of the State Key Laboratory of Advanced Metallurgy (No. 41603007)
文摘A long campaign life of blast furnaces is heavily linked to the existence of a protective layer in their hearths. In this work, we conducted dissection studies and investigated damage in blast furnace hearths to estimate the formation mechanism of the protective layer. The results illustrate that a significant amount of graphite phase was trapped within the hearth protective layer. Furthermore, on the basis of the thermodynamic and kinetic calculations of the graphite precipitation process, a precipitation potential index related to the formation of the graphite-rich protective layer was proposed to characterize the formation ability of this layer. We determined that, under normal operating conditions, the precipitation of graphite phase ~om hot metal was thermodynamically possible. Among elements that exist in hot metal, C, Si, and P favor graphite precipitation, whereas Mn and Cr inhibit this process. Moreover, at the same hot-face temperature, an increase of carbon concentration in hot metal can shorten the precipitation time. Finally, the results suggest that measures such as reducing the hot-face tem- perature and increasing the degree of carbon saturation in hot metal are critically important to improve the precipitation potential index.
基金supported by the National Natural Science Foundation of China (31270668,41373038)the National Basic Research Program of China (2012CB416902)the China Postdoctoral Science Foundation (2016M601342)
文摘Forests and grasslands in arid and semi-arid regions receive high-intensity ultraviolet(UV) radiation year-round. However, how the UV radiation affects the litter decomposition on the forest floor remains unclear. Here, we conducted a field-based experiment in 2011 in the southeastern Horqin Sandy Land, Northeast China, to investigate the effects of UV radiation, litter layer thickness, and their interaction on the mass loss and chemical properties of decomposing litter from Xiaozhuan poplar(Populus × xiaozhuanica) and Mongolian pine(Pinus sylvestris var. mongolica) plantation trees. We found that UV radiation accelerated the decomposition rates of both the Xiaozhuan poplar litter and Mongolian pine litter. For both species, the thick-layered litter had a lower mass loss than the thin-layered litter. The interaction between UV radiation and litter layer thickness significantly affected the litter mass loss of both tree species. However, the effects of UV radiation on the chemical properties of decomposing litter differed between the two species, which may be attributed to the contrasting initial leaf litter chemical properties and morphology. UV radiation mostly had positive effects on the lignin concentration and lignin/N ratio of Xiaozhuan poplar litter, while it had negative effects on the N concentration of Mongolian pine litter. Moreover, litter layer thickness and its interaction with UV radiation showed mostly positive effects on the N concentration and lignin/N ratio of Xiaozhuan poplar litter and the ratios of C/N and lignin/N of Mongolian pine litter, and mostly negative effects on the C/N ratio of Xiaozhuan poplar litter and the N concentration of Mongolian pine litter. Together, these results reveal the important roles played by UV radiation and litter layer thickness in the process of litter decomposition in this semi-arid region, and highlight how changes in the litter layer thickness can exert strong influences on the photodegradation of litter in tree plantations.
基金Projects PLN0610 supported by the Open Fund of State Key Lab of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University)HKLGF200706 by the Opening Project of Henan Key Laboratory of Coal Mine Methane and Fire Prevention+3 种基金50334060, 50474025 and 50774106 by the National Natural Science Foundation of China2005CB221502 by the National Basic Research Program of China50621403 by the Natural Science Innova-tion Group Foundation of ChinaCSTC, 2006BB7147, 2006AA7002 by the Natural Science Foundation of Chongqing
文摘The developing processes of stress and deformation fields of a protected layer after mining an upper-protective layer with a bow pseudo-incline technique were simulated to locate the protection region. The pressure relief of the protected layer was analyzed after mining the upper-protective layer. The pressure relief angle along the strike and incline were located according to the roles of protection of the deformation and stress pressure-relief of the protective layer after mining. This results show that the upper-protective layer with the bow pseudo-incline technique have an upper and downside pressure relief angle of 85 and 68 degrees respectively; the distribution of strike pressure relief angles along the pseudo-incline working face is uneven and their values range from 38.3 to 51 degrees. The pressure relief angle of the inclined middle location was the largest. The distribution of the protection region of the upper-protective layer with the bow pseudo-incline teelmique located by practical tests and numerical simulation is essentially consistent, compared with the results obtained by these methods.
基金Japan Society for the Promotion of Science,Grant/Award Number:18H03869National Natural Science Foundation of China,Grant/Award Numbers:51872333,51874357。
文摘Silicon(Si)has been attracting extensive attention for rechargeable lithium(Li)‐ion batteries due to its high theoretical capacity and low potential vs Li/Li+.However,it remains challenging and problematic to stabilize the Si materials during electrochemical cycling because of the huge volume expansion,which results in losing electric contact and pulverization of Si particles.Consequently,the Si anode materials generally suffer from poor cycling,poor rate performance,and low coulomb efficiency,preventing them from practical applications.Up‐to‐date,there are numerous reports on the engineering of Si anode materials at microscale and nanoscale with significantly improved electrochemical performances.In this review,we will concentrate on various precisely designed protective layers for silicon‐based materials,including carbon layers,inorganic layers,and conductive polymer protective layer.First,we briefly introduced the alloying and failure mechanism of Si as anode materials upon electrochemical reactions.Following that,representative cases have been introduced and summarized to illustrate the purpose and advancement of protective coating layers,for instance,to alleviate pulverization and improve conductivity caused by volume expansion of Si particles during charge/discharge process,and maintain the surface stability of Si particles to form a stable solid‐electrolyte interphase layer.At last,possible strategies on the protective coating layer for stabilizing silicon anode materials that can be applied in the future have been indicated.
基金Project supported by the Science Fund of Science and Technology Commission of Shanghai Municipality,China (GrantNo. 10dz1140502)the Innovation Key Project of Education Commission of Shanghai Municipality,China (Grant No. 12ZZ091)the National Natural Science Foundation of China (Grant Nos. 61006005 and 61136003)
文摘By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode with a maximum external quantum efficiency of 6.19% and a stable lifetime at a high initial current density of 0.0375 A/cm2. We demonstrate that the change in the thicknesses of organic layers affects the operating voltage and luminous efficiency greater than the lifetime. The lifetime being independent of thickness is beneficial in achieving high-quality full-colour display devices and white lighting sources with multi-emitters.
基金Supported by the National Key Technology Research and Development Program of China(No.2012BAF13B05-1)National Natural Science Foundation of China(No.51105009)
文摘Ink layer thickness on the printing plate greatly influences uniformity of ink transferred to the substrates,which is an important indicator of printing quality,so the study of ink layer and its thickness is important for improving the quality of printing products. Ansys CFX is used here to build a model of ink fluid adhering to lower vibrator roller,form inking roller,and printing plate for analyzing ink transferring in inking process. Ink layer thickness on each position of the model is acquired to analyze the forming mechanism of ink layer on printing plate,as well as the influence of oscillation speed of lower vibrator roller and dot area percentage of plate on ink layer thickness of printing plate. It can be concluded that,in the case of fixed ink supplying amount,ink layer thickness increases along with the increasing of oscillation speed,and decreases when the dot area percentage is getting larger and the minimum is got when the dot area percentage is 100%. At last,experiment of plate inking on print ability tester verifies the correctness of the simulation analysis.
文摘The thermoelastic behaviors of such as temperature distribution, displacements, and stresses in thermal barrier coatings (TBC) are seriously influenced by top coat thickness and edge conditions. The top coat of TBC specimens prepared with TriplexPro?-200 system was controlled by changing the processing parameter and feedstock, showing the various thicknesses and microstructures. A couple of governing partial differential equations were derived based on the thermoelastic theory. Since the governing equations were too involved to solve analytically, a finite volume method was developed to obtain approximations. The thermoelastic behaviors of TBC specimens with the various thicknesses and microstructures were estimated through mathematical approaches with different edge conditions. The results demonstrated that the microstructure and thickness of the top coat, and the edge condition in theoretical analysis were crucial factors to be considered in controlling the thermoelastic characteristics of plasma-sprayed TBCs.
基金supported by the National Key R&D Program of China[grant number 2018YFC1506602]the Key Research Program of Frontier Sciences,CAS[grant number QYZDY-SSW-DQC012]the National Natural Science Foundation of China[grant number 41830967]。
文摘The active layer thickness(ALT)in permafrost regions,which affects water and energy exchange,is a key variable for assessing hydrological processes,cold-region engineering,and climate change.In this study,the authors analyzed the variation trends and relative changes of simulated ALTs using the Chinese Academy of Sciences Land Surface Model(CAS-LSM)and the Chinese Academy of Sciences Flexible Global Ocean-Atmosphere-Land System Model,gridpoint version 3(CAS-FGOALS-g3).Firstly,the simulated ALTs produced by CAS-LSM were shown to be reasonable by comparing them with Circumpolar Active Layer Monitoring observations.Then,the authors simulated the ALTs from 1979 to 2014,and their relative changes across the entire Northern Hemisphere from 2015 to 2100.It is shown that the ALTs have an increasing trend.From 1979 to 2014,the average ALTs and their variation trends over all permafrost regions were 1.08 m and 0.33 cm yr-1,respectively.The relative changes of the ALTs ranged from 1%to 58%,and the average relative change was 10.9%.The variation trends of the ALTs were basically consistent with the variation trends of the 2-m air temperature.By 2100,the relative changes of ALTs are predicted to be 10.3%,14.6%,30.1%,and 51%,respectively,under the four considered hypothetical climate scenarios(SSP-2.6,SSP2-4.5,SSP3-7.0,and SSP5-8.5).This study indicates that climate change has a substantial impact on ALTs,and our results can help in understanding the responses of the ALTs of permafrost due to climate change.
基金Fundamental Research Funds for the Central Universities,China(No.14D110715/17/18)Start up Fund by Shanghai University of Engineering Science(No.2015-69)Young Teacher Training Program by Shanghai,China(No.ZZGCD15051))
文摘Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) of the multi-layered fabrics was measured by a TPP tester under flash fire. Results showed that the utilization of the PCM fabrics improved the thermal protective performance of the multi-layered fabrics. The fabric with a PCM add on of 41. 9% increased the thermal protection by 50. 6% and reduced the time to reach a second degree burn by 8. 4 s compared with the reference fabrics( without PCMs). The employment of the PCM fabrics also reduced the blackened areas on the inner layers. The PCM fabrics with higher PCM melting temperature could bring higher thermal protective performance.
基金This research was funded by Fujian University Industry-University Cooperation Project(grant number 2019N5012)Remote Sensing Quantitative Simulation of Rainfall Erosion Reduction Function of Forest Vertical Structure(grant number 31770760).
文摘Voxel-based canopy profiling is commonly used to determine small-scale leaf area.Layer thickness and voxel size impact accuracy when using this method.Here,we determined the optimal combination of layer thickness and voxel size to estimate leaf area density accurately.Terrestrial LiDAR Stonex X300 was used to generate point cloud data for Masson pines(Pinus massoniana).The canopy layer was stratified into 0.10-1.00-m-thick layers,while voxel size was 0.01-0.10 m.The leaf area density of individual trees was estimated using leaf area indices for the upper,middle,and lower canopy and the overall canopy.The true leaf area index,obtained by layered harvesting,was used to verify the inversion results.Leaf area density was inverted by nine combinations of layer thickness and voxel size.The average relative accuracy and mean estimated accuracy of these combined inversion results exceeded 80%.When layer thickness was 1.00 m and voxel size 0.05 m,inversion was closest to the true value.The average relative accuracy was 92.58%,mean estimated accuracy 98.00%,and root mean square error 0.17.The combination of leaf area density and index was accurately retrieved.In conclusion,nondestructive voxel-based canopy profiling proved suitable for inverting the leaf area density of Masson pine in Hetian Town,Fujian Province.
文摘In order to prevent coal and methane outbursts, mining protective layers is an effective means, yet no precedents of mining multiple protective layers is discoveried in seams which includes several seams are prone to outburst like Xinzhuangzi Mine. This paper perfected the related theories through analyzing mining multiple upper protective layers. By means of examining several parameters, it synthetically analyzed and ascer- tains the protected effectiveness and scope and reasonable parameters, finally obtained the specific indexes and effectiveness of mining multiple protective layers in coal seams cluster.
文摘Land reclamation is a process of ecosystem reconstruction, for which it is very important to keep co-adaptation between plants and the below ground habitat. In order to keep the co-adaptation among plant species, thickness of covering soil and medium of covering soil to establish a self-regulating ecosystem, the thickness of covering soil of land reclamation for plants in different living forms by synusia structure of plant below-ground habitat and medium of covering soil by ecological factors of plant below-ground habitat were studied. Synusia structure of plant below-ground habitat was recognized through investigation on structure and root of plant community, and ecological factors were determined through soil profile investigation. The thickness and medium of covering soil of land reclamation for the tree, the shrub and the herb were proposed.
文摘In order to understand the effect of mining height and floor lithology at the upper protective layer face on the pressure relief of protected coal seams, this paper uses a numerical simulation method to model the pressure changes at protected coal seam during mining upper protective layer. The results show that the taller the mining height at the upper protective layer face, the greater the protection on protected coal seam due to the higher level of pressure release; the upper protective layer face with hard rock floor impedes the pressure release at the protected coal seam, which affects the overall effect of the pressure release at protected coal seam using the protective layer mining method.
文摘Prediction of methane emissions at the stage of longwall planning constitutes the basis for the determination of the appropriate method and parameters of ventilation and selection of prevention means including the methane drainage technol- ogy. The growth of methane saturation of coal seams with the extraction depth, with simultaneously increasing output concen- tration, contributes to the increase of the quantity of methane emitted into longwall areas. The subject matter of the article has been directed at the predicted quantity of methane emissions into planned longwalls with roof caving in the layer of seams adjacent to the roof of large thickness. The performed prognostic calculations of methane emissions into the longwall working were referred to two sources, i.e. methane liberated during coal mining by means of a cutter-loader and methane originating from the degasification of the floor layer destressed by the longwall conducted in the close-to-roof layer. The calculations of predictions allow to refer to the planned longwall, on account of the emitting methane, with possible and safe output quantity. Planning of extraction in the close-to-roof layer of a seam of large thickness with roof caving is especially important in con- ditions of increasing methane saturation with the depth of deposition and should be preceded by a prognostic analysis for de- termining the extraction possibilities of the planned longwall.