A layered multifunctional framework based on polyacrylonitrile and MOF derivatives for stable lithium metal anode

Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition behavior still occurs at the top of 3D frameworks owing to the local accumulation of Li ions.To promote uniform Li deposition without top dendrite growth,herein,a layered multifunctional framework based on oxidation-treated polyacrylonitrile(OPAN) and metal-organic framework(MOF) derivatives was proposed for rationally regulating the distribution of Li ions flux,nucleation sites,and electrical conductivity.Profiting from these merits,the OPAN/carbon nano fiber-MOF(CMOF) composite framework demonstrated a reversible Li plating/stripping behavior for 500 cycles with a stable Coulombic efficiency of around 99.0% at the current density of 2 mA/cm~2.Besides,such a Li composite anode exhibited a superior cycle lifespan of over 1300 h under a low polarized voltage of 18 mV in symmetrical cells.When the Li composite anode was paired with LiFePO_(4)(LFP) cathode,the obtained full cell exhibited a stable cycling over 500 cycles.Moreover,the COMSOL Multiphysics simulation was conducted to reveal the effects on homogeneous Li ions distribution derived from the above-mentioned OPAN/CMOF framework and electrical insulation/conduction design.These electrochemical and simulated results shed light on the difficulties of designing stable and safe Li metal anode via optimizing the 3D frameworks.

Large Eddy Simulation and Study of the Urban Boundary Layer

Based on a pseudo-spectral large eddy simulation (LES) model, an LES model with an anisotropy turbulent kinetic energy (TKE) closure model and an explicit multi-stage third-order Runge-Kutta scheme is established. The modeling and analysis show that the LES model can simulate the planetary boundary layer (PBL) with a uniform underlying surface under various stratifications very well. Then, similar to the description of a forest canopy, the drag term on momentum and the production term of TKE by subgrid city buildings are introduced into the LES equations to account for the area-averaged effect of the subgrid urban canopy elements and to simulate the meteorological fields of the urban boundary layer (UBL). Numerical experiments and comparison analysis show that: (1) the result from the LES of the UBL with a proposed formula for the drag coefficient is consistent and comparable with that from wind tunnel experiments and an urban subdomain scale model; (2) due to the effect of urban buildings, the wind velocity near the canopy is decreased, turbulence is intensified, TKE, variance, and momentum flux are increased, the momentum and heat flux at the top of the PBL are increased, and the development of the PBL is quickened; (3) the height of the roughness sublayer (RS) of the actual city buildings is the maximum building height (1.5-3 times the mean building height), and a constant flux layer (CFL) exists in the lower part of the UBL.

Influence of active constrained layer damping on the coupled vibration response of functionally graded magneto-electro-elastic plates with skewed edges

This article makes the first attempt in assessing the influence of active constrained layer damping(ACLD)treatment towards precise control of frequency responses of functionally graded skew-magneto-electroelastic(FGSMEE)plates by employing finite element methods.The materials are functionally graded across the thickness of the plate in terms of modest power-law distributions.The principal equations of motion of FGSMEE are derived via Hamilton’s principle and solved using condensation technique.The effect of ACLD patches are modelled by following the complex modulus approach(CMA).Additionally,distinctive emphasis is laid to evaluate the influence of geometrical skewness on the attenuation capabilities of the plate.The accuracy of the current analysis is corroborated with comparison of previous researches of similar kind.Additionally,a complete parametric study is directed to understand the combined impacts of various factors like coupling fields,patch location,fiber orientation of piezoelectric patch in association with skew angle and power-law index.

Influence of uniform momentum zones on frictional drag within the turbulent boundary layer

Based on a set of experimental databases of turbulent boundary layers obtained from particle image velocimetry in the streamwise-wall-normal plane at friction-velocity-based Reynolds number Reτ=612,the influence of uniform momentum zones(UMZs)on the skin-friction drag is investigated.The skin-friction drag is measured by the single-pixel ensemble correlation method.The results show that the velocity fields with the number of UMZs larger than the mean value have a relatively low skin-friction drag,while the velocity fields with the number of UMZs less than the mean value have a relatively high skin-friction drag.By analyzing the statistical characteristics of UMZs,the dynamic correlation between the UMZs and skin-friction drag is explored.The velocity fields with a low number of UMZs present a sweep event.These sweep motions intensify the small-scale Reynolds shear stress in the near-wall region by modulation effects.The enhancement of small-scale Reynolds shear stress is the direct reason for the high skin-friction drag.Increasing the proportion of velocity fields with high UMZs amount may be a direction to reduce the skin-friction drag within the TBL.

Layer-block tectonics of Cenozoic basements and formation of intra-plate basins in Nansha micro-plate, southern South China Sea

Layer-block tectonics （LBT） concept, with the core of pluralistic geodynamic outlook and multilayer-sliding tectonic outlook, is one of new keys to study 3-dimensional solid and its 4-dimensional evolution history of global tectonic system controlled by global geodynamics system. The LBT concept is applied to study the lithospheric tectonics of the southern South China Sea （SCS）. Based on the analysis of about 30 000 km of geophysical and geological data, some layer-blocks in the Nansha micro-plate can be divided as Nansha ultra-crustal layer-block, Zengmu crustal layer-block, Nanwei （Rifleman bank）-Andu （Ardasier bank） and Liyue （Reed bank） North Palawan crustal layer-blocks, Andu-Bisheng and Liyue-Banyue basemental layer-blocks. The basic characteristics of the basemental layer-blocks have been dicussed, and three intra-plate basin groups are identified. The intra-plate basins within Nansha micro-plate can be divided into three basin groups of Nanwei- Andu, Feixin-Nanhua, and Liyue-North Palawan based on the different geodynamics. In the light of pluralistic geodynamic concept, the upheaving force induced by the mid-crust plastic layer is proposed as the main dynamical force which causes the formation of the intra-plate basins within the Nansha micro-plate. Finally, models of a face-to-face dip-slip detachment of basemental layerblock and a unilateral dip-slip-detachment of basemental layer-block are put forward for the forming mechanisms of the Nanwei Andu and Liyue-North Palawan intra-plate basin groups, respectively.

Similarity Solutions of Unsteady Convective Boundary Layer Flow along Isothermal Vertical Plate with Porous Medium

Similarity solution of unsteady convective boundary layer flow along isothermal vertical plate with porous medium is analyzed. The plate surface is reactive with the fluid and generates inert specie which diffuses inside the boundary. The flux of the specie at the plate is proportional to specie concentration at the plate. The governing equations of continuity, momentum, energy and specie diffusion are transformed into ordinary differential equation by using the similarity transformation and solved numerically by using free parameter method along with shooting technique. The dimensionless velocity, temperature and concentration profiles are obtained and presented through figures for different parameters entering into the problem. The local Skin-friction co-efficient, Nusselt number and Sherwood number at the plate for physical interest are also discussed through tables.

Similarity Solutions of Unsteady Mixed Convective Boundary Layer Flow of Viscous Incompressible Fluid along Isothermal Horizontal Plate

Unsteady mixed convective boundary layer flow of viscous incompressible fluid along isothermal horizontal plate is analyzed through Similarity Solutions. The governing partial differential equations are transformed into ordinary differential equations using the similarity transformation and solved numerically along with shooting technique. The flow field for the fluid velocity, temperature and concentration at the plate surface are significantly influenced by the governing parameters such as unsteadiness parameter, permeability parameter, Prandtl number, Schmidt number and the other driving parameters. The results show that both fluid velocity and temperature decrease but no significant effect on concentration for the increasing values of Prandtl number. It is also exposed that velocity and concentration is higher at lower Schmidt number for low Prandtl fluid. Finally, the dependency of the Skin-friction co-efficient, Nusselt number and Sherwood number, which are of physical interest, are also illustrated in tabular form for the governing parameters.

Structure and effects of electroless Ni-Sn-P transition layer during acid electroless plating on magnesium alloys

An electroless ternary Ni-Sn-P transition layer with high corrosion resistance was applied for acid electroless nickel plating on magnesium alloys. The surface morphologies and microstructure of the traditional alkaline electroless Ni-P and novel Ni-Sn-P transition layers were compared by SEM and XRD, and the bonding strengths between the transition layers and AZ31 magnesium alloys were tested. The corrosion resistance of the samples was analyzed by porosity test, potentiodynamic polarization, electrochemical impedance spectroscopy（EIS） in acid electroless solution at p H 4.5 and immersion test in 10% HCl. The results indicate that the transition layer is essential for acid electroless plating Ni-P coatings on magnesium alloys. Under the same thin thickness（-6 μm）, the electroless Ni-Sn-P transition layer possesses superior properties to the traditional Ni-P transition layer, including high amorphization, smooth and dense surface without pores, enhanced bonding strength and corrosion resistance. Most importantly, acid electroless Ni-P coatings can be successfully deposited on magnesium alloys by using Ni-Sn-P transition layer.

The uniform convergence of upwind schemes on layer-adapted meshes for a singularly perturbed Robin BVP

In this paper, we discuss the uniform convergence of the simple upwind scheme on the Shishkin mesh and the Bakhvalov-Shishkin mesh for solving a singularly perturbed Robin boundary value problem, and investigate the midpoint upwind scheme on the Shishkin mesh and the Bakhvalov-Shishkin mesh to achieve better uniform convergence. The elaborate ε-uniform pointwise estimates are proved by using the comparison principle and barrier functions. The numerical experiments support the theoretical results for the schemes on the meshes.

Stress and Strain Accumulation Due to a Long Dip-Slip Fault Movement in an Elastic-Layer over a Viscoelastic Half Space Model of the Lithosphere-Asthenosphere System

Most of the earthquake faults in North-East India, China, mid Atlantic-ridge, the Pacific seismic belt and Japan are found to be predominantly dip-slip in nature. In the present paper a dip-slip fault is taken situated in an elastic layer over a viscoelastic half space representing the lithosphere-asthenosphere system. A movement of the dip-slip nature across the fault occurs when the accumulated stress due to various tectonic reasons e.g. mantle convection etc., exceeds the local friction and cohesive forces across the fault. The movement is assumed to be slipping in nature, expressions for displacements, stresses and strains are obtained by solving associated boundary value problem with the help of integral transformation and Green’s function method and a suitable numerical methods is used for computation. A detailed study of these expressions may give some ideas about the nature of stress accumulation in the system, which in turn will be helpful in formulating an earthquake prediction programme.

Numerical Analysis of the Structure of High-Strength Double-Layer Steel Plate Concrete Shaft by Drilling Method of Water-Bearing Weak Rock Formation

In order to ensure the safety of coal mine shaft construction, a double-layer steel plate concrete composite shaft wall structure was proposed. However, fewer studies were conducted on this structure, which made engineers too confused to fully recognize its feasibility of this structure. Hence, based on the previous experimental research on the Taohutu mine construction project in Ordos in Inner Mongolia, this research paper aims to provide a widely deep numerical analysis by the usage of the finite element software, in fact, to establish the corresponding numerical analysis model and make a comparison with the experimental data to get the rationality of the verified model. The influence of the composite characteristics of the steel plate and concrete on the ultimate bearing capacity and stress field of the shaft wall structure is studied here through the method of multi-factor analysis. Also, the optimal design scheme of the double-layer steel plate and concrete composite shaft wall structure is proposed in this research paper.

NONLINEAR VIBRATION OF CIRCULAR SANDWICH PLATE UNDER THE UNIFORMED LOAD

The differential equations of the axisymmetric large amplitude free vibration for circular sandwich plates under static load are derived, and a set of nonlinearly coupled algebraic and differential eigenvalue equations of the problem are formulated following an assumed time mode approach suggested. The analytic solutions are presented and a relation for amplitude frequency-load of the plates with edge clamped is derived by modified iteration method. The effects of static load on vibrations of plates are investigated.

THE PROBLEMS OF NONLINEAR BENDING FOR ORTHOTROPIC RECTANGULAR PLATE WITH FOUR CLAMPED EDGES

In this paper,under the non-uniformtransverse load,the problems of nonlinear bending for orthotropic rectangular plate are studied by using'the method of twovariable'[1]and 'the method of mixing perturbation'[2].The uniformly valid asymptotic solutions of Nth-order for ε1 and Mth-order for ε2 for ortholropic rectangular plale with four clamped edges are oblained.

Mathematical Analysis of Unsteady MHD Blood Flow through Parallel Plate Channel with Heat Source

In the present study, a mathematical model of unsteady blood flow through parallel plate channel under the action of an applied constant transverse magnetic field is proposed. The model is subjected to heat source. Analytical expressions are obtained by choosing the axial velocity;temperature distribution and the normal velocity of the blood depend on y and t only to convert the system of partial differential equations into system of ordinary differential equations under the conditions defined in our model. The model has been analyzed to find the effects of various parameters such as, Hartmann number, heat source parameter and Prandtl number on the axial velocity, temperature distribution and the normal velocity. The numerical solutions of axial velocity, temperature distributions and normal velocity are shown graphically for better understanding of the problem. Hence, the present mathematical model gives a simple form of axial velocity, temperature distribution and normal velocity of the blood flow so that it will help not only people working in the field of Physiological fluid dynamics but also to the medical practitioners.

MICROSTRUCTURE AND MECHANISM OF A NEW TYPE OF Ni－Fe－W－P－S WEAR－RESISTANT BRUSH PLATING LAYER

A new type of Ni-Fe-W-P-S wear-resistant brush plating layer isdeveloped, and its microstructure is investigated at different temperatures by usingX-ray diffractometer, transmission electron microscope and surface analytical appa-ratus. The results revealed that the plating layer is composed of amorphous and mi-crocrystalline matrix and intermetallic compounds. Such a microstructure is verybeneficial to improving its wear-resistance.This new type of plating layer can replacethe chromium plating technique which is very poisonous for human health and harm-ful to the agricultural production.

NUMERICAL METHOD FOR THE SYSTEM OF REACTION-DIFFUSION EQUATIONS WITH A SMALL PARAMETER

This paper deals with the numerical method for the system of reaction-diffusion equations with a small parameter. It is difficult to solve the problems of this kind numerically because of the boundary layer efect Besed on singular perturbed theory and Greens function, we have established the difference scheme that is suited for the solution to the problems. We introduce an idea of feasitbe equidistant degree a here. And this proves that if a>2 the scheme converges in norm with speed uniformly.

APPLICATION OF THE MODIFIED METHOD OF MULTIPLE SCALES TO THE BENDING PROBLEMS FOR CIRCULAR THIN PLATE AT VERY LARGE DEFLECTION ANDTHE ASYMPTOTICS OF SOLUTIONS (Ⅰ)

In this paper, the modified method of multiple scales is applied to study the bending problems for circular thin plate with large deflection under the hinged and simply supported edge conditions. Theseries solutions are constructed, the boundary layer effects are analysed and their asymptotics are proved.

Layered Ag-graphene films synthesized by Gamma ray irradiation for stable lithium metal ano des in carb on ate-based electrolytes

Lithium metal batteries are considered as high energy density battery systems with very promising prospects and have bee n widely studied.However,The uncon trollable plating/strippi ng behavior,infinite volume change and den drites formation of lithium metal anode restrict the applicati on.The unc on trolled n ucleati on of lithium caused by the non uniform multi-physical field distributions,can lead to the undesirable lithium deposition.Herein,a graphene composite uniformly loaded with Ag nano-particles(Ag NPs)is prepared through a facile Gamma ray irradiation method and assembled into self-supported film with layered structure(Ag-rGO film).Whe n such film is used as a lithium metal an ode host,the uncontrolled deposition is converted into a highly nucleation-induced process.On one hand,the Ag NPs distributed between the in terlayers of graphe ne can preferentially induce lithium nu cleati on and en able uniform deposition morphology of lithium between interlayers.On the other hand,the stable layered graphene structure can accommodate volume change,stabilize the interface between anode and electrolyte and inhibit dendrites formation.Therefore,the layered Ag-rGO film as anode host can reach a high Coulombic efficiency over 93.3% for 200 cycle(786 h)at a current density of 1 mA cm^(-2) for 2 mAh cm^(-2) in carbonate-based electrolyte.This work proposes a facile Gamma ray irradiation method to prepare metal/3D-skeleton structure as lithium anode host and demonstrates the potential to regulate the lithium metal deposition behaviors via manipulating the distribution of lithiophilic metal(e.g.Ag)in 3D frameworks.This may offer a practicable thinking for the subsequent design of the lithium metal anode.

THE PROBLEM OF THE NON-LINEAR UNSYMMETRICAL BENDING FOR CYLINDRICALLY ORTHOTROPIC CIRCULAR THIN PLATE WITH VARIABLE THICKNESS

To begin with, in this paper, the governing equations of the problem of the non-linear unsymmetrical bending for cylindrically orthotropic circular thin plate with variable thickness are derived. By using 'the method of two-variable' and introducing four small parameters, the problem of the non-linear unsymmetrical bending for cylindrically orthotropic circular thin plate with linear variable thickness are studied, and the uniformly valid asymptotic solution of Nth-order for epsilon(1) and Mth-order for epsilon(2) are obtained.