Controlling Factors of Organic Nanopore Development: A Case Study on Marine Shale in the Middle and Upper Yangtze Region, South China

The Upper Ordovician Wufeng-Lower Silurian Longmaxi and the Lower Cambrian Qiongzhusi shales are the major targets for shale gas exploration and development in China.Although the two organic-rich shales share similar distribution ranges and thicknesses,they exhibit substantially different exploration and development results.This work analyzed the nanopore structures of the shale reservoirs in this region.Pore development of 51 shale samples collected from various formations and locations was compared using the petromineralogical,geochemical,structural geological and reservoir geological methods.The results indicate that the reservoir space in these shales is dominated by organic pores and the total pore volume of micropores,mesopores,macropores in different tectonic areas and formations show different trends with the increase of TOC.It is suggested that organic pores of shale can be well preserved in areas with simple structure and suitable preservation conditions,and the shale with smaller maximum ancient burial depth and later hydrocarbongeneration-end-time is also more conducive to pore preservation.Organic pore evolution models are established,and they are as follows:①Organic matter pore development stage,②Early stage of organic matter pore destruction,and③late stage of organic matter pore destruction.The areas conducive to pore development are favorable for shale gas development.Research results can effectively guide the optimization and evaluation of favorable areas of shale gas.

Sedimentary and Geochemical Characteristics of Sinian Cap Carbonates in the Upper Yangtze Region

A global\|scale glaciation occurred at about 600 Ma ago. As a result, the Earth became the "Snowball Earth". The glaciation came to the end abruptly when atmospheric carbon dioxide increased to such an extent as to be about 350 times the modern level because of subaerial volcanic degassing. The rapid termination of glaciation would have led to warming of the Snowball Earth and extreme greenhouse conditions would have been created. The transfer of atmospheric carbon dioxide to oceans would give rise to the rapid precipitation of calcium carbonate in warm surface seawaters, thus forming the cap carbonate rocks as observed worldwide today.\; Regionally persisting, thin layers of carbonate rocks directly and ubiquitously overlie Proterozoic glacial deposits almost on every continent, and are commonly referred to as cap carbonates. Their unusual litho\| fabrics, stratigraphically abrupt basal and upper\|level contacts and strongly negative carbonate isotopic signatures (\{δ\{\}\+\{13\}C\-\{carb.\}\} values range from -7.0‰-0‰) suggest a chemical oceanographic origin, the details of which remain unknown. It is proposed that these enigmatic deposits are related to the destabilization of gaseous hydrate in terrestrial permafrost following rapid postglacial warming and flooding of widely exposed continental shelves and internal basins.\; The authors carried out studies on the geochemistry, sedimentology and palaeontology of the Sinian cap carbonates in Guizhou and Hunan provinces, including the occurrence of cap carbonates of unusual fabrics, strongly negative carbon isotopic signatures, and a lot of bitumen nodules. From the results it is suggested that the cap carbonates were formed from solid methane seepage, and it is in agreement with Kennedy’s viewpoint (2001) that the cap carbonates resulted from the rapid precipitation of calcium carbonate in response to solid methane seepage.

Carbon Isotopic Evolution Characteristics and the Geological Significance of the Permian Carbonate Stratotype Section in the Northern Upper-Yangtze Region, Southern China

The Permian global mass extinction events and the eruption of the Emeishan flood basalts in the Upper Yangtze region should display certain responses during the evolution of carbon isotope. In this paper, the Permian carbon isotopic evolution in the Upper Yangtze region is examined through systematic stratotype section sampling and determination of 13 C in the northern Upper-Yangtze regions and Southern China. Additionally, the carbon isotopic evolution response characteristics of the geological events in the region are evaluated, comparing the sea-level changes in the Upper Yangtze region and the global sea-level change curves. Results of this study indicated that the carbon isotopic curves of the Permian in the Upper Yangtze region are characterized by higher background carbonisotope baseline values, with three distinct negative excursions, which are located at the Middle–Late Permian boundary and the late period and end of the Late Permian. The three distinct negative excursions provide an insightful record of the global Permian mass extinction events and the eruption of the Emeishan flood basalts in the Upper Yangtze region. The first negative excursion at the Middle–Late Permian boundary reflected the eruption of the Emeishan flood basalts, a decrease in sea level, and biological extinction events of different genera in varying degrees. The second negative excursion in the Late Permian included a decrease in sea level and large-scale biological replacement events. The third negative excursion of the carbon isotope at the end of the Permian corresponded unusually to a rise rather than a decrease in sea level, and it revealed the largest biological mass extinction event in history.

The Background of Regional Lead Isotopic Compositions and Its Application in the Lower and Middle Reaches of the Yangtze River and Neighbouring Areas

The paper systematically deals with the background of regional isotopic compo-sitions in the lower and middle reaches of the Yangtze River and neighbouring areas. It isshown that the lead isotopic compositions of different geological formations and units are con-trolled by the primary mantle heterogeneity, dynamic process of crust-mantle interchange,abundances of uraninm, thorium and lead of various layers of the earth and timing. Studies onthe background of regional isotopic compositions may offer significant information forgeochemical regionalization, tracing of sources of ore-forming materials, and regionalprognosis of ore deposits.

Large-scale Migration of Fluids toward Foreland Basins during Collisional Orogeny: Evidence from Triassic Anhydrock Sequences and Regional Alteration in the Middle-Lower Yangtze Area

The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.

The Late Triassic Sequence-Stratigraphic Framework of the Upper Yangtze Region,South China

In the transitional period between the Middle and the Late Triassic, the Indochina orogeny caused two tectonic events in South China：（1） the formation and uplift of the Qinling-Dabie orogenic belt along the northern margin of the South China Plate, due to its collision with the North China Plate; and 2） the development of a 1300-km-wide intra-continental orogen in the southeastern part of the South China Plate, which led to a northwestward movement of the foreland thrust-fold zone. These tectonic events resulted in the ending of the Yangtze Platform, and were a stable paleogeographic factor from the Eidacaran to the end of the Middle Triassic. This platform was characterized by the widespread development of shallow-water carbonates. After the end of the Yangtze Platform, the upper Yangtze foreland basin（or Sichuan foreland basin） was formed during the Late Triassic and became a accumulation site of fluvial deposits that are composed of related strata of the Xujiahe Formation. In western Sichuan Province, the Xujiahe Formation overlies the Maantang Formation shallow-water carbonate rocks of the Xiaotangzi Formation siliciclastic rocks（from shelf shales to littoral facies）. The sequence-stratigraphic framework of the Upper Triassic in the upper Yangtze foreland basin indicates a particular alluvial architecture, characterized by sequences composed of（1） successions of low-energy fluvial deposits of high-accommodation phases, including coal seams, and（2） high-energy fluvial deposits of low-accommodation phases, including amalgamated river-channel sandstones. The spatial distribution of these fluvial deposits belonging to the Xujiahe Formation and its relative strata is characterized by gradual thinning-out, overlapping, and pinching-out toward both the east and south. This sedimentary record therefore expresses a particular sequence-stratigraphic succession of fluvial deposits within the filling succession of the foreland basin. The sequence-stratigraphic framework for the Upper Triassic in the Upper Yangtze region provides a record of the end of the Yangtze Platform and the formation of the upper Yangtze foreland basin.

The SIA method for spatial analysis of precipitation in the upper-middle reaches of the Yangtze River

Using geographic information system (GIS) techniques and the newest seasonal and annual average precipitation data of 679 meteorological stations from 1971 to 2000, the multiple regressions equations of the precipitation and topographical variables are established to extract the effect of topography on the annual and seasonal precipitation in the upper-middle reaches of the Yangtze River. Then, this paper uses a successive interpolation approach (SIA), which combines GIS techniques with the multiple regressions, to improve the accuracy of the spatial interpolation of annual and seasonal rainfall. The results are very satisfactory in the case of seasonal rainfall, with the relative error of 6.86%, the absolute error of 13.07 mm, the average coefficient of variation of 0.070, and the correlation coefficient of 0.9675; in the case of annual precipitation, with the relative error of 7.34%, the absolute error of 72.1 mm, the average coefficient of variation of 0.092, and the correlation coefficient of 0.9605. The analyses of annual mean precipitation show that the SIA calculation of 3-5 steps considerably improves the interpolation accuracy, decreasing the absolute error from 211.0 mm to 62.4 mm, the relative error from 20.74% to 5.97%, the coefficient of variation from 0.2312 to 0.0761, and increasing the correlation coefficient from 0.5467 to 0.9619. The SIA iterative results after 50 steps identically converge to the observed precipitation.

From Basin Black Shales to Platform Carbonate Rocks:A Study on Sequence Stratigraphy for the Lower Cambrian of the Upper-Yangtze Region in South China

In the Upper-Yangtze region, especially in Guizhou Province and its adjacent areas, the Lower Cambrian is well developed and is marked by a succession from black shales of the basin facies to carbonate rocks of the platform facies. The drowning event of the platform occurring at the turn from Sinian to Cambrian resulted in a set of black shales, i.e. the Niutitang Formation, which makes up the bottom part of the Lower Cambrian. With the shoaling of the sedimentary environment, a set of carbonate rocks, i.e. the Qingxudong Formation, was formed in the top part of the Lower Cambrian. Thus, the Lower Cambrian in the study area makes up one second-order sequence that can be further subdivided into five third-order sequences, and forms a regularly cyclic succession of transgression-regression. There is a regularly vertical stacking pattern for the third-order sequences in the second-order sequence. From bottom to top, the succession of the ＂CS （condensed section） ＋HST （high-stand system tract）＂ of the third-order sequences is changed into the succession of the ＂TST （transgressive system tract）＋CS＋HST＂. Correspondingly, the drowning-type sequence boundary is changed into the exposure-type one. Therefore, both the second-order and the third-order sequences have similar sedimentary-facies architectures. A concomitant with these temporal changes, the Lower Cambrian with a thickness of 1000 m that contains five third-order sequences is changed into a condensed succession that cannot identify third-order sequences toward the southeast with the deepening of the sedimentary environment. According to the elementary features of the third-order sequences, i.e. the regularity o sedimentary-facies successions in space and the synchronism of sedimentary-environment changes in time, the detailed division of the third-order sequences at main logged sections in different paleogeographical background becomes the basis to establish the sequence-stratigraphic framework that can demonstrate two types of facies-changing surface and two types of diachronism in the stratigraphic records. This sequence-stratigraphic framework shows a growing process of the carbonate platform from the base of the condensed succession formed by black shales of basin facies. Resulting from the rapid transgression at the turn from Sinian to Cambrian the ecological space became open, which formed the antecedent condition of paleogeographical setting for ＂the Cambrian Biological Explosion＂. Ultimately, the genetic relationship between the depositional events and the biological-diversity events is very complex and there remain lots of problems that need further research in the future.

Geological Fluid Mapping in the Tongling Area:Implications for the Paleozoic Submarine Hydrothermal System in the Middle-Lower Yangtze Metallogenic Belt,East China

The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.

Research on Outcrop Sequence Stratigraphy of Permian in Middle-Lower Yangtze Region

According to the latest International Chronostratigraphic Scheme (ICS, 2000), the Permian in the Middle Lower Yangtze region of South China can be divided into three series and nine stages relevant to the traditional six stages of South China. From Assellian to Changxingian of Permian, 44 Ma in age range, the strata are composed of 14 third order sequences, each of which is 3.14 Ma in average age range. There is one third order sequence of Zisongian, equivalent to middle and upper Chuanshan Formation or equal to Asselian and two thirds of Sakmarian. There are two third order sequences, corresponding to Liang shan Formation or Zhenjiang Formation and upper Chuanshan Formation, which are assigned to Longlingian, coinciding with Artinskian and one third of Sakmarian. In addition, three third order sequences, equal to Qixia Formation, are attributed to Chihsian, corresponding to Kubergandian and one third of Roadian. Four third order sequences, comprising Gufeng, Maokou, Yanqiao, Yinping and Wuxue formations, are assigned to Maokouan, equivalent to two thirds of Roadian, Wordian and Capitanian. Two third order sequences, equal to Longtan Formation or Wujiaping Formation, are included in Wuchiapingian. Other two third order sequences, corresponding to Changxing Formation or Dalong Formation, are assigned to Changhsingian. In brief, these above third order sequences can be incorporated into 4 sequences sets.

GEOCHEMISTRY STUDY OF GOLD SILVER DEPOSITS IN THE MIDDLE UPPER PROTEROZOIC SUBERATHEM IN SOUTHERN QINLING METALLOGENETIC ZONE

According to Ihe combinations of mctallogcnetic elements and minerals assemblages,the Au-Ag deposits in the Middle-Upper Proterozoic Suberathcm of the middle of northern margin of Yangtze Platform could be classified into four types,(l)Au-Ag-Pb-Zn type,(2)Au-Ag-Te type,(3)Au-quartz vein type,(4)Au-Ag-Pb-Zn-Ba type.The Yangpin formation and the upper Dangyuhe subformation,which belong to Wudangshan group,are regarded as favorable strata for Au-Ag mineralization by systematic assessments for Au-Ag bearing ability of the strata,as well as the felsic rocks of Bikou group.The mctallogcnetic physicochemical conditions and the stable isotopic compositions(S.Pb,H.O,C)have been studied in this paper.The sources of metallogenetic materials,origins of fluids and genesis of various deposits have also been studied.

Lithofacies palaeogeography of the Late Permian Wujiaping Age in the Middle and Upper Yangtze Region,China

The lithofacies palaeogeography of the Late Permian Wujiaping Age in Middle and Upper Yangtze Region was studied based on petrography and the ＂single factor analysis and multifactor comprehensive mapping＂ method. The Upper Permian Wujiaping Stage in the Middle and Upper Yangtze Region is mainly composed of carbonate rocks and clastic rocks, with lesser amounts of siliceous rocks, pyroclastic rocks, volcanic rocks and coal. The rocks can be divided into three types, including clastic rock, clastic rock-limestone and limestone-siliceous rock, and four fundamental ecological types and four fossil assemblages are recognized in the Wujiaping Stage. Based on a petrological and palaeoecological study, six single factors were selected, namely, thickness （m）, content （%） of marine rocks, content （%） of shallow water carbonate rocks, content （%） of biograins with limemud, content （%） of thinbedded siliceous rocks and content （%） of deep water sedimentary rocks. Six single factors maps of the Wujiaping Stage and one lithofacies palaeogeography map of the Wujiaping Age were composed. Palaeogeographic units from west to east include an eroded area, an alluvial plain, a clastic rock platform, a carbonate rock platform where biocrowds developed, a slope and a basin. In addition, a clastic rock platform exists in the southeast of the study area. Hydro- carbon source rock and reservoir conditions were preliminarily analyzed based on lithofacies palaeogeography. Sedimentary environments have obvious controls over the development of the resource rocks. With regard to the abundance of organic matter, the hydrocarbon potential of the coastal swamp environment is the best, followed by the basin environment and the carbonate rock platform. The gas reservoir types of the Wujiaping Stage can be classified as conventional and unconventional gas reservoirs, like coal bed gas and shale gas; all of them have well exploration prospects.

Lithofacies palaeogeography of the Upper Permian Changxing Stage in the Middle and Upper Yangtze Region,China

Based on the petrological study,according to single factor analysis and multifactor comprehensive mapping method,the quantitative lithofacies palaeogeography of the Upper Permian Changxing Stage of the Middle and Upper Yangtze Region was studied.The Changxing Stage in the Middle and Upper Yangtze Region is mainly composed of carbonate rocks;in addition,clastic and siliceous rocks occur with rare coals and pyroclastic rocks.Lithofacies can be divided into five types,including clastic rock assemblage,clastic rock-limestone assemblage,limestone assemblage,limestone-siliceous rock assemblage,and siliceous rock-clastic rock assemblage.Four fundamental ecological types and five fossil assemblages were recognized in the Changxing Stage.On the basis of the petrological and palaeoecological study,eight single factors were chosen including thickness,content of marine rocks,content of shallow water carbonate rocks,content of bioclasts with limemud matrix,content of bioclasts with sparry cement,distribution of reefs,content of thin bedded siliceous rocks and content of deep water sedimentary rocks.And eight single factor maps and one lithofacies paleogeographic map of the Changxing Stage were compiled.Paleoenvironments from west to east include an erosional area,fluvial plain,clastic platform,carbonate platform and reefs that developed there,slope and basin,low energy organic banks,and high energy organic banks.Sedimentary environments have an obvious control on the development of the source rocks,and the excellent source rocks are developed in the Dalong Formation.Changxing Stage reservoirs should be dominated by the reef and platform surrounding the GuangyuanLiangping Basin rim area,and is the most favorable exploration area of the reef petroleum reservoirs of the Changxing Formation.

Structural deformation and fluid flow from East Sichuan to the northwestern periphery of the Xuefeng Uplift,China

Hydrocarbon preservation conditions have restricted exploration in the Middle and Upper Yangtze,and structural deformation and fluid activity have played an important role in the origin and preservation of oil and gas.In order to study that how the deformation and fluid activity impact the hydrocarbon preservation,we did some field work and collected some calcite vein samples for analysis of deformation periods using acoustic emission and fluid inclusions.Combined with previous studies,the strata distribution,tectonic deformation and fluid characteristics show that there are three structural belts in the study area：East Sichuan,West Hunan and Hubei and the northwestern periphery of the Xuefeng Uplift,and that their tectonic deformation style,fluid inclusion characteristics and hydrocarbon preservation are different.The breakthrough thrusts were well developed in the anticline core,and a lot of hydrocarbon inclusions were found in calcite veins around the thrusts in East Sichuan.The breakthrough thrusts were only in the syncline core in West Hunan and Hubei,and the brine inclusions did not contain hydrocarbon in calcite veins around the thrusts.Many breakthrough thrusts were found in the northwestern periphery of the Xuefeng Uplift,where there were only rare calcite veins.The deformation and hydrocarbon inclusion indicated that when there was no fault breakthrough in East Sichuan,the Paleozoic covered by the Triassic regional cap was good for hydrocarbon preservation.The strata above the Lower Paleozoic were denuded,and lots of brine inclusions and deep infiltration of surface water were found in the West Hunan and Hubei,so only the part of the syncline area with a well developed Silurian regional cap had good preservation conditions.Intense tectonic movements and denudation were widely developed in the northwestern periphery of the Xuefeng Uplift,where there were only paleo-reservoirs,non-hydrocarbon fluid activity and poor preservation conditions.

ANALYSIS OF THE MICROPHYSICAL STRUCTURE OF RADIATION FOG IN XUANEN MOUNTAINOUS REGION OF HUBEI,CHINA

Based on data of radiation fog events in Xuanen, Hubei province, 2010, this paper analyzes the microphysical process and evolution characteristics of radiation fogs with complicated substrate in the upper and middle reaches of the Yangtze River, and compares them with findings in other areas. Results are as follows: radiation fog in Xuanen is evidently weaker in droplet number concentration and liquid water content than land fogs in other areas. Its liquid water content fluctuates obviously, 0.01g/m3 with visibility of 1,000 meters, which is quite different from that in urban areas, but similar to the Nanling Mountains. Bi-modal droplet distribution is likely to occur in Xuanen mountain radiation fog(MRF) events. Statistical analysis shows that the observed droplet size distribution can be piecewise described well by the Gamma distribution. There is a positive correlation between liquid water content, fog droplet concentration and mean radius, especially in the development and dissipation stage. Condensation growth and droplet evaporation are major processes of Xuanen MRF. The dissipation time coincided with the time when the grass temperature reached the peak value, which indicated that dew evaporation is a key role in maintaining Xuanen MRF. In the early stage of dense fog's growth, droplets with diameter of over 20 micrometers can be observed with visibility of800-1,000 m, which might be caused by the transportation of low cloud droplets to earth's surface by turbulence. Big droplets in the initial stage correspond to higher water content, leading to the higher observed value of water content of Xuanen MRF.

Quartz Cementation in the Lower Paleozoic Shales,Middle Yangtze Region,South China:Implications for Shale Reservoir Properties

As one of the most important constitutes of shales/mudstones,quartz has received increasing interests in the last decades,because productive shale gas successions are generally rich in quartz content.This study critically documents quartz types,silica source for quartz cementation and effect of quartz cementation on reservoir quality in the Lower Paleozoic shales,Middle Yangtze region,South China,including the Lower Cambrian Niutitang Formation and the Upper Ordovician-Lower Silurian Wufeng-Longmaxi formations.Our results suggest that high-resolution scanning electron microscopy combined with cathodoluminescene techniques are necessary for identifying quartz types in shales.Integrations of high-resolution imaging technique and detailed geochemical analysis are able to document silica source for quartz cementation and silica diagenetic processes.Six types of quartz can be identified in the Paleozoic shales,primarily including detrital quartz silt,siliceous skeletons,quartz overgrowth,microcrystalline quartz(matrix-dispersed microquartz and aggregated microquartz),silica nanospheres and fracture-filling quartz veins.Dissolution of siliceous skeletons provides the principal silica sources for authigenic quartz formation in the Paleozoic shales.Authigenic quartz has dual effects on porosity development.Quartz overgrowth definitely occupies interparticle pores and possibly squeeze spaces,whereas aggregated microquartz can form rigid framework that is favorable for generating and preserving intercrystalline pores and organic pores.

The emergence, development and regional differences of mixed farming of rice and millet in the upper and middle Huai River Valley, China

Mixed farming of rice and millet is one of the basic agricultural modes in the upper and middle Huai River Valley(HRV). According to the latest data, this agricultural mode appeared during the middle and late Peiligang Culture(7.8–7.0 ka BP) in the upper HRV, and then became a common subsistence economy in the end of the Neolithic(5.0–4.0 ka BP) in both the upper and middle HRV. However, it is still not clear how this mixed farming developed in the upper HRV after its occurrence, nor are the regional differences in the development of mixed farming between the upper and middle HRV during the Neolithic completely understood. In this paper, flotation and starch analyses were conducted on samples from eight archaeological sites in the upper and middle HRV. The results indicate that the mixed farming of rice and millet first appeared in the later phase of the middle Neolithic in the regions of the Peiligang Culture, then developed quite rapidly in the late Neolithic(6.8–5.0 ka BP), finally becoming the main subsistence economy at the end of the Neolithic in the upper HRV. However, there are obvious differences in the emergence and development of agriculture between the middle and upper HRV. Rice farming was the only agricultural system during the middle Neolithic, lasting until the end of the Neolithic, when mixed farming appeared in the middle HRV. Furthermore, although mixed farming appeared in both the upper and middle HRV during the end of the Neolithic, the roles of rice, foxtail millet and broomcorn millet in the subsistence economy were not the same. In general, millet was more widely cultivated than rice in the upper HRV, but rice occupied the same or a slightly more prominent position in the middle HRV at the end of the Neolithic. These results are significant for understanding the process of agricultural development and transformation, as well as human adaptation to climatic and cultural variability duringthe Neolithic.

Changhsingian sea level changes and brachiopod diversity in the upper Yangtze region

Sedimentary environment and distribution of brachiopods during the Changhsingian in Xingwen, Si-chuan Province of the upper Yangtze region, are statistically analyzed. Changing regularity in diversity of brachiopod is synthetically investigated based on qualitative and quantitative analysis of transgres-sion-regression cycles. The results show that the diversity of brachiopods in this region in the trans-gression (aggradation) sequence is higher than that in the regression (progradation) sequence. The brachiopods in this area began to diversify in the early Changhsingian. And the species diversity had four peak stages which are respectively in the middle Early Changhsingian, late Early Changhsingian, early Late Changhsingian and late Late Changhsingian. The species diversity reached its highest in the late Late Changhsingian but this is followed by a sharp decrease at the end-hanghsingian, indicating the mass extinction of most brachiopod species which were prosperous in the Late Paleozoic.

Seismic tomography of Yunnan region using short-period surface wave phase velocity

利用云南数字地震台网23个台站记录的短周期(1～18s)面波资料，用双台窄带通滤波互相关方法，测定了在209条路径上的基阶瑞利波相速度频散曲线，并通过层析成像反演得到各周期的相速度分布图象．给出了沿24°N，25°N，26°N及27°N和100．5°E的相速度频散剖面图．结果表明：云南地区的相速度分布图象具有强烈的横向变化，短周期段的相速度分布与沉积层厚度密切相关，中甸、丽江东部区域在约25km深度存在着明显的低速层，而畹町、云县、思茅一带在该深度范围是一明显的大面积高速区域．小江断裂与红河断裂围成的川滇菱形块体南段为低相速度区域．云南地区强震震中位置主要分布在相速度高速与低速过渡的区域．

Seismic tomography of Yunnan region using short-period surface wave phase velocity

The data of short-period (1~18 s) surface waves recorded by 23 stations belonging to the digital seismic network of Yunnan Province of China are used in this paper. From these data, the dispersion curves of phase velocities of the fundamental mode Rayleigh wave along 209 paths are determined by using the two-station narrowband filtering cross-correlation method. Adopting tomography method, the distribution maps of phase velocities at various peri-ods in Yunnan region are inverted. The maps of phase velocities on profiles along 24N, 25N, 26N, 27N and 100.5E and the distribution maps of phase velocities at 3 periods in the study region are given. The results show that the phase velocity distribution in Yunnan region has strong variations in horizontal direction, and the phase velocity distribution in short-period range is closely related to the thickness of sedimentary layers in the shallow crust. The phase velocity in southern part of the Sichuan-Yunnan rhombic block encircled by the Honghe fault and Xiaojiang fault is obviously lower than that in surrounding areas. The epicentral locations of strong earthquakes in Yunnan region are mainly distributed in transitional zones between low and high phase velocities.