The effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on the viscosity and structure of the CaO-Al_(2)O_(3)-SiO_(2)-6MgO-1.5ZrO_(2)-1.5CeO_(2) slag was investigated.The results show that with the increase in Al...The effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on the viscosity and structure of the CaO-Al_(2)O_(3)-SiO_(2)-6MgO-1.5ZrO_(2)-1.5CeO_(2) slag was investigated.The results show that with the increase in Al_(2)O_(3)/SiO_(2) mass ratio,the viscous flow units within the slag gradually change from Si-O-Si to Al-O-Al and Al-O-Si.Furthermore,the substitution of Al_(2)O_(3) for SiO_(2) leads to the transformation of Si-O bonds towards weaker Al-O bonds,which weaken the bond strength of the aluminosilicate networks,thus leading to a decrease in the viscosity of slag.The increase in CaO content effectively promotes the depolymerization of the aluminosilicate networks,resulting in a significant decrease in the viscosity of the slag.The slag with Al_(2)O_(3)/SiO_(2) of 0.7-1.5 and CaO of 30 wt.%shows promise as the reference slag system for the Fe-collection smelting of spent automotive catalysts due to its good comprehensive performance.展开更多
The factors influencing the crystallization ratio of mold flux were researched by rapid cooling technolo gy, and the factors affecting crystallization temperature were studied by single thermocouple technique. The res...The factors influencing the crystallization ratio of mold flux were researched by rapid cooling technolo gy, and the factors affecting crystallization temperature were studied by single thermocouple technique. The results showed that the crystallization ratio of mold flux increases with the basicity and the content of Na2O, CaF2, Li2O and NaF, and decreases with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. However, the crystallization temperature of mold flux rises with the basicity and the content of NaF, Na2O and CaF2, and reduces with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. But for Li2O, crystallization temperature decreases firstly to a minimum value at 2%, and then increases gradually with the increase of Li2O.展开更多
The coalescence behavior of two droplets with different viscosities in the funnel-typed expansion chamber in T-junction microchannel was investigated experimentally and compared with droplet coalescence of the same vi...The coalescence behavior of two droplets with different viscosities in the funnel-typed expansion chamber in T-junction microchannel was investigated experimentally and compared with droplet coalescence of the same viscosity.Four types of coalescence regimes were observed:contact non-coalescence,squeeze non-coalescence,two-droplet coalescence and pinch-off coalescence.For droplet coalescence of different viscosities,the operating range of non-coalescence becomes narrowed compared to the droplet coalescence of same viscosity,and it shrinks with increasing viscosity ratioηof two droplets,indicating that the difference in the viscosity of two droplets is conducive to coalescence,especially when1<η<6.Furthermore,the influences of viscosity ratio and droplet size on the film drainage time(Tdr)and critical capillary number(Ca)c)were studied systematically.It was found that the film drainage time declined with the increase of average droplet size,which abided by power-law relation with the size difference and viscosity ratio of the two droplets:Tdr~(ld)^(0.25±0.04)and Tdr~(η)^(﹣0.1±0.02).For droplet coalescence of same viscosity,the relation of critical capillary number with two-phase viscosity ratio and dimensionless droplet size is Cac=0.48λ^(0.26)l^(﹣2.64),while for droplet coalescence of different viscosities,the scaling of critical capillary number with dimensionless average droplet size,dimensionless droplet size difference and viscosity ratio of two droplets is Cac=0.11η^(﹣0.07)ls^(﹣2.23)l^(0.16)_(d).展开更多
In this paper, we have considered a fully developed flow of a viscous incompressible fluid in a rectangular porous duct saturated with the same fluid. The duct is heated from the bottom for forced and mixed convection...In this paper, we have considered a fully developed flow of a viscous incompressible fluid in a rectangular porous duct saturated with the same fluid. The duct is heated from the bottom for forced and mixed convection. The Brinkman model is used to simulate the momentum transfer in the porous duct. Using the momentum and thermal energy equations, the entropy generation has been obtained due to the heat transfer, viscous and Darcy dissipations. It is found from the mathematical analysis that the entropy generation is double when the viscous as well as the Darcy dissipations terms are taken in the thermal energy equation in comparison when the viscous as well as the Darcy dissipations terms are not taken in the thermal energy equation. This result clearly shows that there is no need of taking the viscous and Darcy dissipations terms in the thermal energy equation to obtain the entropy generation.展开更多
二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗...二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗费时间和成本。为了从微观角度深入理解CO_(2)地质封存过程中的渗流行为,提高CO_(2)地质埋存量,基于追踪两相界面动态变化的VOF(Volume of Fluid)方法,分别建立了2D和3D模型,开展了超临界CO_(2)-水两相流动数值模拟研究,对比了不同润湿性、毛细管数、黏度比条件下的CO_(2)团簇分布特征、CO_(2)饱和度变化规律,揭示了孔隙尺度CO_(2)埋存的内在机理。研究结果表明:①随着岩石对CO_(2)润湿性增加,CO_(2)波及范围扩大,同时CO_(2)团簇的卡断频率减少,CO_(2)埋存量增加;②随着毛细管数的增加,驱替模式由毛细指进转变为稳定驱替,CO_(2)埋存量增加;③随着注入超临界CO_(2)黏度逐渐接近水的黏度,两相流体之间的流动阻力降低,促进了“润滑效应”,CO_(2)相的渗流能力提高,CO_(2)埋存量增加;④润湿性、毛细管数、黏度比在不同维度多孔介质模型中对CO_(2)饱和度的影响程度不同。结论认为,基于VOF方法的CO_(2)-水两相渗流模拟研究在孔隙尺度上揭示了CO_(2)地质封存过程中的渗流机理,对CCUS技术的发展有指导意义,也为更大尺度的CO_(2)地质封存研究提供了理论指导和技术支撑。展开更多
气化炉灰渣比(合成气携带走的飞灰与沉积至壁面的熔渣的质量比)是影响后续合成气净化设备寿命的关键因素,优化烧嘴偏转角度是控制气化炉灰渣比的有效方法。采用数值模拟方法,研究了HNCERI(Huaneng Clean Energy Research Institute)气...气化炉灰渣比(合成气携带走的飞灰与沉积至壁面的熔渣的质量比)是影响后续合成气净化设备寿命的关键因素,优化烧嘴偏转角度是控制气化炉灰渣比的有效方法。采用数值模拟方法,研究了HNCERI(Huaneng Clean Energy Research Institute)气化炉一段四烧嘴偏转角度对气化炉灰渣比、壁面渣层及耐火材料的影响。数值模拟结果表明,烧嘴偏转角度由0°增加至4.5°,灰渣比由2.0降低至0.8,液态渣层平均停留时间减少31.5%。偏转角度增加,渣口位置液/固态渣层厚度均增加;H=4.45~5.07 m位置固态渣层厚度下降,液态渣层厚度则增加。液态渣层流速与黏度呈负相关,与厚度呈正相关,液态渣层厚度主要受流速和颗粒沉积率影响。偏转角度增加,烧嘴平面上方耐火材料表面平均温度升高,烧嘴平面下方耐火材料表面平均温度降低,偏转角度为3.5°时耐火材料需要承受的最高温度取得最低值。在有效降低灰渣比前提下,为减少气化炉堵渣、渣层脱落和耐火材料烧蚀概率,HNCERI气化炉烧嘴偏转角度建议取3.5°。展开更多
基金supported by the National Natural Science Foundation of China(No.52374409)the National Key Research and Development Program of China(No.2022YFB3504304).
文摘The effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on the viscosity and structure of the CaO-Al_(2)O_(3)-SiO_(2)-6MgO-1.5ZrO_(2)-1.5CeO_(2) slag was investigated.The results show that with the increase in Al_(2)O_(3)/SiO_(2) mass ratio,the viscous flow units within the slag gradually change from Si-O-Si to Al-O-Al and Al-O-Si.Furthermore,the substitution of Al_(2)O_(3) for SiO_(2) leads to the transformation of Si-O bonds towards weaker Al-O bonds,which weaken the bond strength of the aluminosilicate networks,thus leading to a decrease in the viscosity of slag.The increase in CaO content effectively promotes the depolymerization of the aluminosilicate networks,resulting in a significant decrease in the viscosity of the slag.The slag with Al_(2)O_(3)/SiO_(2) of 0.7-1.5 and CaO of 30 wt.%shows promise as the reference slag system for the Fe-collection smelting of spent automotive catalysts due to its good comprehensive performance.
文摘The factors influencing the crystallization ratio of mold flux were researched by rapid cooling technolo gy, and the factors affecting crystallization temperature were studied by single thermocouple technique. The results showed that the crystallization ratio of mold flux increases with the basicity and the content of Na2O, CaF2, Li2O and NaF, and decreases with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. However, the crystallization temperature of mold flux rises with the basicity and the content of NaF, Na2O and CaF2, and reduces with the increase of the content of Al2O3, MgO, BaO, MnO and B2O3. But for Li2O, crystallization temperature decreases firstly to a minimum value at 2%, and then increases gradually with the increase of Li2O.
基金supported by the National Natural Science Foundation of China(92034303,91834303 and 21776200)the aid of Program of Introducing Talents of Discipline to Universities(BP0618007)。
文摘The coalescence behavior of two droplets with different viscosities in the funnel-typed expansion chamber in T-junction microchannel was investigated experimentally and compared with droplet coalescence of the same viscosity.Four types of coalescence regimes were observed:contact non-coalescence,squeeze non-coalescence,two-droplet coalescence and pinch-off coalescence.For droplet coalescence of different viscosities,the operating range of non-coalescence becomes narrowed compared to the droplet coalescence of same viscosity,and it shrinks with increasing viscosity ratioηof two droplets,indicating that the difference in the viscosity of two droplets is conducive to coalescence,especially when1<η<6.Furthermore,the influences of viscosity ratio and droplet size on the film drainage time(Tdr)and critical capillary number(Ca)c)were studied systematically.It was found that the film drainage time declined with the increase of average droplet size,which abided by power-law relation with the size difference and viscosity ratio of the two droplets:Tdr~(ld)^(0.25±0.04)and Tdr~(η)^(﹣0.1±0.02).For droplet coalescence of same viscosity,the relation of critical capillary number with two-phase viscosity ratio and dimensionless droplet size is Cac=0.48λ^(0.26)l^(﹣2.64),while for droplet coalescence of different viscosities,the scaling of critical capillary number with dimensionless average droplet size,dimensionless droplet size difference and viscosity ratio of two droplets is Cac=0.11η^(﹣0.07)ls^(﹣2.23)l^(0.16)_(d).
文摘In this paper, we have considered a fully developed flow of a viscous incompressible fluid in a rectangular porous duct saturated with the same fluid. The duct is heated from the bottom for forced and mixed convection. The Brinkman model is used to simulate the momentum transfer in the porous duct. Using the momentum and thermal energy equations, the entropy generation has been obtained due to the heat transfer, viscous and Darcy dissipations. It is found from the mathematical analysis that the entropy generation is double when the viscous as well as the Darcy dissipations terms are taken in the thermal energy equation in comparison when the viscous as well as the Darcy dissipations terms are not taken in the thermal energy equation. This result clearly shows that there is no need of taking the viscous and Darcy dissipations terms in the thermal energy equation to obtain the entropy generation.
文摘二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗费时间和成本。为了从微观角度深入理解CO_(2)地质封存过程中的渗流行为,提高CO_(2)地质埋存量,基于追踪两相界面动态变化的VOF(Volume of Fluid)方法,分别建立了2D和3D模型,开展了超临界CO_(2)-水两相流动数值模拟研究,对比了不同润湿性、毛细管数、黏度比条件下的CO_(2)团簇分布特征、CO_(2)饱和度变化规律,揭示了孔隙尺度CO_(2)埋存的内在机理。研究结果表明:①随着岩石对CO_(2)润湿性增加,CO_(2)波及范围扩大,同时CO_(2)团簇的卡断频率减少,CO_(2)埋存量增加;②随着毛细管数的增加,驱替模式由毛细指进转变为稳定驱替,CO_(2)埋存量增加;③随着注入超临界CO_(2)黏度逐渐接近水的黏度,两相流体之间的流动阻力降低,促进了“润滑效应”,CO_(2)相的渗流能力提高,CO_(2)埋存量增加;④润湿性、毛细管数、黏度比在不同维度多孔介质模型中对CO_(2)饱和度的影响程度不同。结论认为,基于VOF方法的CO_(2)-水两相渗流模拟研究在孔隙尺度上揭示了CO_(2)地质封存过程中的渗流机理,对CCUS技术的发展有指导意义,也为更大尺度的CO_(2)地质封存研究提供了理论指导和技术支撑。
文摘气化炉灰渣比(合成气携带走的飞灰与沉积至壁面的熔渣的质量比)是影响后续合成气净化设备寿命的关键因素,优化烧嘴偏转角度是控制气化炉灰渣比的有效方法。采用数值模拟方法,研究了HNCERI(Huaneng Clean Energy Research Institute)气化炉一段四烧嘴偏转角度对气化炉灰渣比、壁面渣层及耐火材料的影响。数值模拟结果表明,烧嘴偏转角度由0°增加至4.5°,灰渣比由2.0降低至0.8,液态渣层平均停留时间减少31.5%。偏转角度增加,渣口位置液/固态渣层厚度均增加;H=4.45~5.07 m位置固态渣层厚度下降,液态渣层厚度则增加。液态渣层流速与黏度呈负相关,与厚度呈正相关,液态渣层厚度主要受流速和颗粒沉积率影响。偏转角度增加,烧嘴平面上方耐火材料表面平均温度升高,烧嘴平面下方耐火材料表面平均温度降低,偏转角度为3.5°时耐火材料需要承受的最高温度取得最低值。在有效降低灰渣比前提下,为减少气化炉堵渣、渣层脱落和耐火材料烧蚀概率,HNCERI气化炉烧嘴偏转角度建议取3.5°。
