The composition and vertical profiles of low molecular-weight organic acids （LMWOAs） and the contribution of them to dissolved organic matter （DOM） in sediment porewaters in Bosten Lake, Xinjiang, China were inves...The composition and vertical profiles of low molecular-weight organic acids （LMWOAs） and the contribution of them to dissolved organic matter （DOM） in sediment porewaters in Bosten Lake, Xinjiang, China were investigated. The results showed that total concentration of LMWOAs was up to 94.5 μmol/L and their proportion in DOM was 5.6%, suggesting that LMWOAs were important chemical components in DOM in lake sediment porewaters. Among the seven LMWOAs, pyruvic and acetic acid had the highest concentrations with 26.30 and 8.31 μmol/L, accounting for 51.4% and 14.92% of LMWOAs, respectively. Trifluoroacetic and sorbic acid had the lowest concentrations, indicating that the compositions of LMWOAs in relative reducing environments were largely different from those reported in glacier, atmosphere and soils. The concentrations of lactic, acetic, formic, sorbic and oxalic acid decreased with increasing depth, probably relating to stronger microbial activities in the initial stage of early diagenesis. Trifluoroacetic acid was mainly anthropogenic with its concentration, showing a diusive trend from the surface to bottom sediments. The concentrations of lactic acid and nitrate generally showed a consistent profile. The increasing concentration of pyruvic acid in the vertical profile was just opposite to that of sulfate, revealing a significant negative relationship between them. Oxalic acid remained constant except for an obvious peak at 6 cm depth. The results indicated the diversities in sources and behaviors for various LMWOAs during early diagenesis in sediments.展开更多
At present,a growing number of consumer products contain engineered nanoparticle TiO2(nano⁃TiO2),which has resulted in the consequences of nano⁃TiO2 entering the aquatic environment directly or indirectly at some stag...At present,a growing number of consumer products contain engineered nanoparticle TiO2(nano⁃TiO2),which has resulted in the consequences of nano⁃TiO2 entering the aquatic environment directly or indirectly at some stage.The fate of nano⁃TiO2 in the aquatic environment has become the key factor which affects its safety application and nanoecotoxicology.This paper aims to investigate how the dissolved organic matters(DOM),especially the molecular weight fractions in the aquatic environment,affect the aggregation,stability,and fate of nano⁃TiO2,and the interaction mechanism of DOM and nano⁃TiO2.Results of dynamic light scattering(DLS)showed that the molecular weight of DOM molecules caused different aggregation rates of nano⁃TiO2 in aqueous solution.Fourier Transform infrared spectroscopy(FTIR)results indicated the molecular structure is characteristics of DOM fractions and the mechanisms of bonds formation between DOM and nano⁃TiO2.Results of three⁃dimensional excitation⁃emission matrices(3D⁃EEM)confirmed the FTIR results and implied the increase of the stability of theπ-πconjugated system in the presence of DOM.In addition,low molecular weight of DOM fractions appeared to show more affinity with nano⁃TiO2 than high molecular weight fractions.展开更多
The molecular weight distribution (MWD) of dissolved organic matter (DOM) in lake waters from Lake Hongfeng was examined using high performance size exclusion chromatography (HPSEC) with UV-vis absorbance and fluoresc...The molecular weight distribution (MWD) of dissolved organic matter (DOM) in lake waters from Lake Hongfeng was examined using high performance size exclusion chromatography (HPSEC) with UV-vis absorbance and fluorescence detection. The elution curves obtained by absorbance and fluorescence techniques expressed similar patterns, with the exception of diminishing of large fraction and the peaks behind several seconds in fluorescence chromatograms. According to its molecular weight (MW), DOM in water samples is divided into several fractions: large ({>3.5} kDa); medium-large ({3.5}-{2.0} kDa); medium ({2.0}-{1.0} kDa) and small ({<1.0} kDa). The average molecular weight was calculated using the elution curve detected by UV-vis absorbance and fluorescence detection techniques. The results showed that the weight-average molecular weight (Mw) and number-average molecular weight (Mn) calculated by UV-vis absorbance techniques range from 1750 to 2050 Dalton and from 1450 to 1850 Dalton, respectively. And the Mw and Mn obtained by fluorescence detection are lower by 50 to 400 Dalton. As a reference, the molecular weight of Fluka humic acid (FHA) is larger than that of water samples by about 200 Dalton. The average molecular weight of DOM for water samples collected in March and July was compared. The results revealed that the molecular weight is lower for water samples obtained in July than that obtained in March, indicating the ambient environment has an influence on the molecular weight, including photo-degradation and biological activity.展开更多
With XAD-series and ion exchange resins, dissolved organic matter （DOM） from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid （HA）, fulvic acid （FA）, hydrophobic neutra...With XAD-series and ion exchange resins, dissolved organic matter （DOM） from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid （HA）, fulvic acid （FA）, hydrophobic neutrals （HON）, hydrophilic acids （HIA）, hydrophilic bases （HIB） and hydrophilic neutrals （HIN）. Those fractions were characterized by high performance size exclusion chromatography, fluorescence spectroscopy and UV absorbance. Among the 6 fractions, FA was predominant and accounted for 51% of the total DOM. The weight-average （Mw） and number-averaged （Mn） molecular weight of these fractions ranged from 1688 to 2355 Da and from 1338 to 1928 Da, respectively. A strong correlation was observed between specific UV absorbance at 280 nm, E2/E3 （absorbance at 250 nm to 365 nm）, and the molecular weight for DOM fractions. UV-Vis fulvic-like fluorescence peaks were found in all fractions. Proteinlike fluorescence peaks existed in HON may indicate that microbial activity was severely in Lake Hongfeng. There was a significant relationship between fluorescence intensities and specific UV absorbance at 254 nm for those DOM fractions, suggesting their similar luminescence characteristics. The values of fluorescence index （f450/500） indicated that hydrophobic fractions may derive from terrestrial sources, and the hydrophilic fractions from microbial and terrestrial origins. Those results suggest that there were inter-relationships between molecular weight, fluorescence and absorbance characteristics, and also subtle consistencies between the hydrophilic and hydrophobic properties and the sources for these 6 fractions from Lake Hongfeng.展开更多
Rapid urbanization has led to extensive land-use changes,particularly in developing countries.This research is aimed to investigate the role of land use and its effect on soil and water quality in Ziarat watershed foc...Rapid urbanization has led to extensive land-use changes,particularly in developing countries.This research is aimed to investigate the role of land use and its effect on soil and water quality in Ziarat watershed focusing on four land uses:forest,pasture,cultivated and urban development.Soil samples were taken from a depth of 0-30 cm on each land use and were analyzed by completely randomized split-plot design in two geographical directions.Results showed that bulk density(BD),electrical conductivity(EC),pH,calcium carbonate equivalent(CCE),and soil particle density(DS) of the soil samples in pastures,cultivated and urban areas increased and the mean weight diameter(MWD),soil porosity(F),organic carbons(OC),total nitrogen(TN),exchangeable cations(Ca 2+,Mg 2+,K +,Na +),cation exchange capacity(CEC) and soil microbial respirations(SMR) decreased,respectively in comparison with the forest soils.For water quality evaluations,sodium adsorption ratio(SAR),electrical conductivity(EC),pH,total dissolved solids(TDS),bicarbonate(HCO 3),chloride(Cl),total hardness(TH),calcium(Ca 2+),potassium(K +),sodium(Na +) and magnesium(Mg 2+) were investigated in two areas:Nahrkhoran and Abgir stations.Results showed that the concentration of TDS,EC and HCO 3 in Naharkhoran station is higher than that in Abgir station.On the other hand,the concentration of TDS,EC and HCO 3 in Abgir station are the relatively higher due to its location.Total hardness had the same trend during the study years except in the last three years;however,TH showed an increase of 25% TH in Naharkhoran for the last two years.Cl,K + and SAR in Naharkhoran station increased by 61%,22%,78% and 56% respectively,in comparison with Abgir station.This study demonstrated that the trend of soil degradation and mismanagement of land use may increase the frequency of urban floods and human health problems.展开更多
The formation of a dynamic membrane(DM)was investigated using polyethylene glycol(PEG)(molecular weight of 35000 g/mol,concentration of 1 g/L).Two natural organic matters(NOM),Dongbok Lake NOM(DLNOM)and Suwannee River...The formation of a dynamic membrane(DM)was investigated using polyethylene glycol(PEG)(molecular weight of 35000 g/mol,concentration of 1 g/L).Two natural organic matters(NOM),Dongbok Lake NOM(DLNOM)and Suwannee River NOM(SRNOM)were used in the ultrafiltration experiments along with PEG.To evaluate the effects of the DM with PEG on ultrafiltration,various transport experiments were conducted,and the analyses of the NOM in the membrane feed and permeate were performed using high performance size exclusion chromatography,and the effective pore size distribution(effective PSD)and effective molecular weight cut off(effective MWCO)were determined.The advantages of DM formed with PEG can be summarized as follows:(1)PEG interferes with NOM transmission through the ultrafiltration membrane pores by increasing the retention coefficient of NOM in UF membranes,and(2)low removal of NOM by the DM is affected by external factors,such as pressure increases during UF membrane filtration,which decreases the effective PSD and effective MWCO of UF membranes.However,a disadvantage of the DM with PEG was severe flux decline;thus,one must be mindful of both the positive and negative influences of the DM when optimizing the UF performance of the membrane.展开更多
Dissolved organic matter (DOM) is one of the most interesting and difficult problems in recent years due to its important functions in the ecological and environmental system and the complexity of its chemical composi...Dissolved organic matter (DOM) is one of the most interesting and difficult problems in recent years due to its important functions in the ecological and environmental system and the complexity of its chemical composition and structure. It is well ac- cepted that fluorescence characteristics and mo- lecular weight distribution are two important pa- rameters in the DOM characterization. However, the relationship between them is still unknown. In this study, fluorescence and molecular weight distribution of DOM in Lake Hongfeng, Lake Baihua and their rivers, and their relationship were investigated using the combination of fluorescence spectroscopy and high-performance size exclusion chromatography (HPSEC) with on-line UV absorbance and fluores- cence detectors. The results show that there were two obvious humic-like fluorescence peaks (Peaks A and B) in DOM from lake water. But there was an- other obvious protein-like fluorescence peak (Peak C) in DOM from river water. The humic-like fluorescence material consisted of DOM fraction with smaller mo- lecular weight, ranging from 1.0 to 3.0 kDa, while the protein-like fluorescence material mainly consisted of DOM fraction with MW larger than 2.0 kDa. The cal- culation of MW using HPSEC was related to the UV absorbance wavelength chosen.展开更多
Understanding organic matter characteristics(e.g., amount and state) of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these cha...Understanding organic matter characteristics(e.g., amount and state) of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these characteristics are relatively expensive. This study attempted to evaluate the organic matter characteristics of littoral sediments by employing solely the loss on ignition(LOI)method, which is the most economical and accessible method in developing countries. Different types of sediments were first oven dried at 100℃ and then continuously burned at 200, 300, 400, 500, and 600℃ for 4 h at each temperature. The mass LOI at each temperature was calculated and compared with the 100℃ oven-dried weight. Our results suggested that the mass LOI across the temperature range of 200–300℃(LOI_(200-300)):mass LOI at 600℃(LOI_(600)) ratio(LOI_(200-300)/LOI_(600)) could represent different types of sediments as well as the organic matter:organic C ratio. Compared with the sediments unaffected by wastewater, the sediments that were more influenced by the inflow of domestic wastewater had a higher LOI_(200-300)/LOI_(600). Interestingly, LOI_(200-300)/LOI_(600) could also represent changes in the organic matter characteristics as a function of organic matter decomposition in sediments. In conclusion, the organic matter characteristics of littoral sediments could be evaluated using solely the LOI method, particularly with LOI_(200-300)/LOI_(600).展开更多
Potatoes have to be stored after harvest for a shorter or longer period in order to maintain even supply to the market throughout the year for direct human consumption as well as for the processing industry. The prese...Potatoes have to be stored after harvest for a shorter or longer period in order to maintain even supply to the market throughout the year for direct human consumption as well as for the processing industry. The present study focused on the storage potentialities of six exotic varieties of potato viz., Diamant, Cardinal, Granola, Felsina, Provento and Asterix at farmers’ condition. The experiment was conducted during winter (December to March) for cultivation, and spring and summer (March to August) for storage at Domar Foundation Seed Potato Production Farm, BADC, Nilphamari, Bangladesh. Results revealed that there were significant variations in storage behavior among the varieties of potato tubers. Asterix showed minimum weight loss (7.10%) which was statistically identical with Cardinal (7.85%) while it was maximum in Felsina (18.83%) followed by Provento (13.41%) during four months storage conditions practicing by farmers (farmers’ conditions). In respect of rotting, significantly highest degree was found in Felsina (18.72%) followed by Provento (15.01%) and the lowest was in Asterix (2.02%) identically similar with Granola (2.22%). The highest percentage of water loss was found in Provento (27.01%) and the lowest was recorded in Asterix (17.03%). Dormancy period and sprouts per tuber were found highest in Asterix (70 days and 9.67) while the lowest dormancy was in Diamant (56 days) and the lowest sprouting was in Granola (2.50). Asterix was found to produce significantly highest amount of dry matter content (20.50%) along with higher amount of edible stored tubers (80.21%) compared to those of other varieties at the end of four months storage. Under the same condition, Diamant was the second highest producer of dry matter (20%) which was statistically similar with Asterix, and had good storage ability that retained 69.07% edible tubers, whereas Felsina contained the lowest amount of dry matter (16%) and showed poor storage ability retaining 55.85% edible tubers. Based on the results, Asterix possessed better keeping quality with long dormancy, minimum weight loss, higher tuber dry matter with edible tuber, excellent storage ability, low storage losses and rotting. However, the variety Asterix may be recommended for commercial storage under ordinary storage condition or farmers’ practice. Diamant ranked in second position considering the above circumstances, although showed better performances compared to the rest of the studied varieties.展开更多
Dissolved organic matter（DOM） plays an important role in the process of mercury release from water body.In this study,the influence of DOM from different sources（DOMR,DOMS and DOMH,extracted from rice straw,compost...Dissolved organic matter（DOM） plays an important role in the process of mercury release from water body.In this study,the influence of DOM from different sources（DOMR,DOMS and DOMH,extracted from rice straw,compost and humic soil respectively） on mercury reduction was investigated.The molecular weight distribution and chemical composition of DOM from each source were determined using ultrafiltration membrane technique and elemental analysis respectively.The result showed that mercury release from DOM-added samples was much lower than the control;the lowest mercury release flux was observed in the treatment of DOMH,25.02% of the control,followed by DOMS and DOMR,62.46% and 64.95% of the control,respectively.The higher saturation degree and lower molecular weight of DOMH was responsible for the highest inhibition degree on the mercury release.The link between DOMH,concentration and mercury flux was also estimated and the result showed that mercury flux was increased with DOMH at lower concentration,while decreased with DOMH at higher concentration.Different mechanism dominated the influence of DOM on mercury release with variation of DOM concentration.展开更多
Effluent organic matter （EfOM） is the major cause of fouling in the low pressure membranes process for wastewater reuse. Coagulation and oxidation of biological wastewater treatment effluent have been applied for th...Effluent organic matter （EfOM） is the major cause of fouling in the low pressure membranes process for wastewater reuse. Coagulation and oxidation of biological wastewater treatment effluent have been applied for the fouling control of microfiltration membranes. However, the change in EfOM structure by pre-treatments has not been clearly identified. The changes of EfOM characteristics induced by coagulation and ozonation were investigated through size exclusion chromatography, UV/Vis spectrophotometry, fluorescence spectrophotometry and titrimetric analysis to identify the mechanisms in the reduction of ultrafiltration （UF） membrane fouling. The results indicated that reduction of flux decline by coagulation was due to modified characteristics of dissolved organic carbon （DOC） content. Total concentration of DOC was not reduced by ozonation. However, the mass fraction of the molecules with molecular weight larger than 5 kDa, fluorescence intensity, aromaticity, highly condensed chromophores, average molecular weight and soluble microbial byproducts decreased greatly after ozonation. These results indicated that EfOM was partially oxidized by ozonation to low molecular weight, highly charged compounds with abundant electron- withdrawing functional groups, which are favourable for alleviating UF membrane flux decline.展开更多
基金supported by the National Basic Research Program (973) of China (No. 2008CB418200)the National Natural Science Foundation of China (No.U0833603, 40632011, 40873080)
文摘The composition and vertical profiles of low molecular-weight organic acids （LMWOAs） and the contribution of them to dissolved organic matter （DOM） in sediment porewaters in Bosten Lake, Xinjiang, China were investigated. The results showed that total concentration of LMWOAs was up to 94.5 μmol/L and their proportion in DOM was 5.6%, suggesting that LMWOAs were important chemical components in DOM in lake sediment porewaters. Among the seven LMWOAs, pyruvic and acetic acid had the highest concentrations with 26.30 and 8.31 μmol/L, accounting for 51.4% and 14.92% of LMWOAs, respectively. Trifluoroacetic and sorbic acid had the lowest concentrations, indicating that the compositions of LMWOAs in relative reducing environments were largely different from those reported in glacier, atmosphere and soils. The concentrations of lactic, acetic, formic, sorbic and oxalic acid decreased with increasing depth, probably relating to stronger microbial activities in the initial stage of early diagenesis. Trifluoroacetic acid was mainly anthropogenic with its concentration, showing a diusive trend from the surface to bottom sediments. The concentrations of lactic acid and nitrate generally showed a consistent profile. The increasing concentration of pyruvic acid in the vertical profile was just opposite to that of sulfate, revealing a significant negative relationship between them. Oxalic acid remained constant except for an obvious peak at 6 cm depth. The results indicated the diversities in sources and behaviors for various LMWOAs during early diagenesis in sediments.
基金the National Natural Science Foundation of China(Grant No.51408162)the Special Financial Grant from the China Postdoctoral Science Foundation(Grant No.2016T90303)+1 种基金the China Postdoctoral Science Foundation(Grant No.2014M551258)the Heilongjiang Province Postdoctoral Science Foundation(Grant No.LBH-Z14077)。
文摘At present,a growing number of consumer products contain engineered nanoparticle TiO2(nano⁃TiO2),which has resulted in the consequences of nano⁃TiO2 entering the aquatic environment directly or indirectly at some stage.The fate of nano⁃TiO2 in the aquatic environment has become the key factor which affects its safety application and nanoecotoxicology.This paper aims to investigate how the dissolved organic matters(DOM),especially the molecular weight fractions in the aquatic environment,affect the aggregation,stability,and fate of nano⁃TiO2,and the interaction mechanism of DOM and nano⁃TiO2.Results of dynamic light scattering(DLS)showed that the molecular weight of DOM molecules caused different aggregation rates of nano⁃TiO2 in aqueous solution.Fourier Transform infrared spectroscopy(FTIR)results indicated the molecular structure is characteristics of DOM fractions and the mechanisms of bonds formation between DOM and nano⁃TiO2.Results of three⁃dimensional excitation⁃emission matrices(3D⁃EEM)confirmed the FTIR results and implied the increase of the stability of theπ-πconjugated system in the presence of DOM.In addition,low molecular weight of DOM fractions appeared to show more affinity with nano⁃TiO2 than high molecular weight fractions.
文摘The molecular weight distribution (MWD) of dissolved organic matter (DOM) in lake waters from Lake Hongfeng was examined using high performance size exclusion chromatography (HPSEC) with UV-vis absorbance and fluorescence detection. The elution curves obtained by absorbance and fluorescence techniques expressed similar patterns, with the exception of diminishing of large fraction and the peaks behind several seconds in fluorescence chromatograms. According to its molecular weight (MW), DOM in water samples is divided into several fractions: large ({>3.5} kDa); medium-large ({3.5}-{2.0} kDa); medium ({2.0}-{1.0} kDa) and small ({<1.0} kDa). The average molecular weight was calculated using the elution curve detected by UV-vis absorbance and fluorescence detection techniques. The results showed that the weight-average molecular weight (Mw) and number-average molecular weight (Mn) calculated by UV-vis absorbance techniques range from 1750 to 2050 Dalton and from 1450 to 1850 Dalton, respectively. And the Mw and Mn obtained by fluorescence detection are lower by 50 to 400 Dalton. As a reference, the molecular weight of Fluka humic acid (FHA) is larger than that of water samples by about 200 Dalton. The average molecular weight of DOM for water samples collected in March and July was compared. The results revealed that the molecular weight is lower for water samples obtained in July than that obtained in March, indicating the ambient environment has an influence on the molecular weight, including photo-degradation and biological activity.
基金supported by the China’s Na-tional Basic Research Program (No. 2008CB418200)the National Knowledge Innovation Program of Chinese Academy of Sciences (No. kzcx2-yw-102)the Nation-al Natural Science Foundation of China (No. U0833603,40873079, 40703022).
文摘With XAD-series and ion exchange resins, dissolved organic matter （DOM） from Lake Hongfeng in Southwestern China Plateau was isolated into 6 fractions, i.e., humic acid （HA）, fulvic acid （FA）, hydrophobic neutrals （HON）, hydrophilic acids （HIA）, hydrophilic bases （HIB） and hydrophilic neutrals （HIN）. Those fractions were characterized by high performance size exclusion chromatography, fluorescence spectroscopy and UV absorbance. Among the 6 fractions, FA was predominant and accounted for 51% of the total DOM. The weight-average （Mw） and number-averaged （Mn） molecular weight of these fractions ranged from 1688 to 2355 Da and from 1338 to 1928 Da, respectively. A strong correlation was observed between specific UV absorbance at 280 nm, E2/E3 （absorbance at 250 nm to 365 nm）, and the molecular weight for DOM fractions. UV-Vis fulvic-like fluorescence peaks were found in all fractions. Proteinlike fluorescence peaks existed in HON may indicate that microbial activity was severely in Lake Hongfeng. There was a significant relationship between fluorescence intensities and specific UV absorbance at 254 nm for those DOM fractions, suggesting their similar luminescence characteristics. The values of fluorescence index （f450/500） indicated that hydrophobic fractions may derive from terrestrial sources, and the hydrophilic fractions from microbial and terrestrial origins. Those results suggest that there were inter-relationships between molecular weight, fluorescence and absorbance characteristics, and also subtle consistencies between the hydrophilic and hydrophobic properties and the sources for these 6 fractions from Lake Hongfeng.
文摘Rapid urbanization has led to extensive land-use changes,particularly in developing countries.This research is aimed to investigate the role of land use and its effect on soil and water quality in Ziarat watershed focusing on four land uses:forest,pasture,cultivated and urban development.Soil samples were taken from a depth of 0-30 cm on each land use and were analyzed by completely randomized split-plot design in two geographical directions.Results showed that bulk density(BD),electrical conductivity(EC),pH,calcium carbonate equivalent(CCE),and soil particle density(DS) of the soil samples in pastures,cultivated and urban areas increased and the mean weight diameter(MWD),soil porosity(F),organic carbons(OC),total nitrogen(TN),exchangeable cations(Ca 2+,Mg 2+,K +,Na +),cation exchange capacity(CEC) and soil microbial respirations(SMR) decreased,respectively in comparison with the forest soils.For water quality evaluations,sodium adsorption ratio(SAR),electrical conductivity(EC),pH,total dissolved solids(TDS),bicarbonate(HCO 3),chloride(Cl),total hardness(TH),calcium(Ca 2+),potassium(K +),sodium(Na +) and magnesium(Mg 2+) were investigated in two areas:Nahrkhoran and Abgir stations.Results showed that the concentration of TDS,EC and HCO 3 in Naharkhoran station is higher than that in Abgir station.On the other hand,the concentration of TDS,EC and HCO 3 in Abgir station are the relatively higher due to its location.Total hardness had the same trend during the study years except in the last three years;however,TH showed an increase of 25% TH in Naharkhoran for the last two years.Cl,K + and SAR in Naharkhoran station increased by 61%,22%,78% and 56% respectively,in comparison with Abgir station.This study demonstrated that the trend of soil degradation and mismanagement of land use may increase the frequency of urban floods and human health problems.
基金the National Research Laboratory Program by the Korea Science and Engineering Foundation(NOM Lab:R0A-2007-000-20055-0).
文摘The formation of a dynamic membrane(DM)was investigated using polyethylene glycol(PEG)(molecular weight of 35000 g/mol,concentration of 1 g/L).Two natural organic matters(NOM),Dongbok Lake NOM(DLNOM)and Suwannee River NOM(SRNOM)were used in the ultrafiltration experiments along with PEG.To evaluate the effects of the DM with PEG on ultrafiltration,various transport experiments were conducted,and the analyses of the NOM in the membrane feed and permeate were performed using high performance size exclusion chromatography,and the effective pore size distribution(effective PSD)and effective molecular weight cut off(effective MWCO)were determined.The advantages of DM formed with PEG can be summarized as follows:(1)PEG interferes with NOM transmission through the ultrafiltration membrane pores by increasing the retention coefficient of NOM in UF membranes,and(2)low removal of NOM by the DM is affected by external factors,such as pressure increases during UF membrane filtration,which decreases the effective PSD and effective MWCO of UF membranes.However,a disadvantage of the DM with PEG was severe flux decline;thus,one must be mindful of both the positive and negative influences of the DM when optimizing the UF performance of the membrane.
基金supported by the National Natural Science Foundation of China(Grant Nos.40525011,40403011)973 Projects(Grant No.2002CB412300)the National Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.KZCX2-W1).
文摘Dissolved organic matter (DOM) is one of the most interesting and difficult problems in recent years due to its important functions in the ecological and environmental system and the complexity of its chemical composition and structure. It is well ac- cepted that fluorescence characteristics and mo- lecular weight distribution are two important pa- rameters in the DOM characterization. However, the relationship between them is still unknown. In this study, fluorescence and molecular weight distribution of DOM in Lake Hongfeng, Lake Baihua and their rivers, and their relationship were investigated using the combination of fluorescence spectroscopy and high-performance size exclusion chromatography (HPSEC) with on-line UV absorbance and fluores- cence detectors. The results show that there were two obvious humic-like fluorescence peaks (Peaks A and B) in DOM from lake water. But there was an- other obvious protein-like fluorescence peak (Peak C) in DOM from river water. The humic-like fluorescence material consisted of DOM fraction with smaller mo- lecular weight, ranging from 1.0 to 3.0 kDa, while the protein-like fluorescence material mainly consisted of DOM fraction with MW larger than 2.0 kDa. The cal- culation of MW using HPSEC was related to the UV absorbance wavelength chosen.
基金the Grantin-Aid for Science Research from the Japan Society for the Promotion of Science (Nos.26820204 and 26630229)
文摘Understanding organic matter characteristics(e.g., amount and state) of sediments is necessary for evaluating both the sediment and water environments; however, methods that have been proposed to investigate these characteristics are relatively expensive. This study attempted to evaluate the organic matter characteristics of littoral sediments by employing solely the loss on ignition(LOI)method, which is the most economical and accessible method in developing countries. Different types of sediments were first oven dried at 100℃ and then continuously burned at 200, 300, 400, 500, and 600℃ for 4 h at each temperature. The mass LOI at each temperature was calculated and compared with the 100℃ oven-dried weight. Our results suggested that the mass LOI across the temperature range of 200–300℃(LOI_(200-300)):mass LOI at 600℃(LOI_(600)) ratio(LOI_(200-300)/LOI_(600)) could represent different types of sediments as well as the organic matter:organic C ratio. Compared with the sediments unaffected by wastewater, the sediments that were more influenced by the inflow of domestic wastewater had a higher LOI_(200-300)/LOI_(600). Interestingly, LOI_(200-300)/LOI_(600) could also represent changes in the organic matter characteristics as a function of organic matter decomposition in sediments. In conclusion, the organic matter characteristics of littoral sediments could be evaluated using solely the LOI method, particularly with LOI_(200-300)/LOI_(600).
文摘Potatoes have to be stored after harvest for a shorter or longer period in order to maintain even supply to the market throughout the year for direct human consumption as well as for the processing industry. The present study focused on the storage potentialities of six exotic varieties of potato viz., Diamant, Cardinal, Granola, Felsina, Provento and Asterix at farmers’ condition. The experiment was conducted during winter (December to March) for cultivation, and spring and summer (March to August) for storage at Domar Foundation Seed Potato Production Farm, BADC, Nilphamari, Bangladesh. Results revealed that there were significant variations in storage behavior among the varieties of potato tubers. Asterix showed minimum weight loss (7.10%) which was statistically identical with Cardinal (7.85%) while it was maximum in Felsina (18.83%) followed by Provento (13.41%) during four months storage conditions practicing by farmers (farmers’ conditions). In respect of rotting, significantly highest degree was found in Felsina (18.72%) followed by Provento (15.01%) and the lowest was in Asterix (2.02%) identically similar with Granola (2.22%). The highest percentage of water loss was found in Provento (27.01%) and the lowest was recorded in Asterix (17.03%). Dormancy period and sprouts per tuber were found highest in Asterix (70 days and 9.67) while the lowest dormancy was in Diamant (56 days) and the lowest sprouting was in Granola (2.50). Asterix was found to produce significantly highest amount of dry matter content (20.50%) along with higher amount of edible stored tubers (80.21%) compared to those of other varieties at the end of four months storage. Under the same condition, Diamant was the second highest producer of dry matter (20%) which was statistically similar with Asterix, and had good storage ability that retained 69.07% edible tubers, whereas Felsina contained the lowest amount of dry matter (16%) and showed poor storage ability retaining 55.85% edible tubers. Based on the results, Asterix possessed better keeping quality with long dormancy, minimum weight loss, higher tuber dry matter with edible tuber, excellent storage ability, low storage losses and rotting. However, the variety Asterix may be recommended for commercial storage under ordinary storage condition or farmers’ practice. Diamant ranked in second position considering the above circumstances, although showed better performances compared to the rest of the studied varieties.
基金supported by the National Natural Science Foundation of China(No.40673063,40973079)the Construction Project of Chongqing Engineering Research Center(CSTC)(No.2010CB7008)the Ecology National Key Discipline of Southwest University
文摘Dissolved organic matter（DOM） plays an important role in the process of mercury release from water body.In this study,the influence of DOM from different sources（DOMR,DOMS and DOMH,extracted from rice straw,compost and humic soil respectively） on mercury reduction was investigated.The molecular weight distribution and chemical composition of DOM from each source were determined using ultrafiltration membrane technique and elemental analysis respectively.The result showed that mercury release from DOM-added samples was much lower than the control;the lowest mercury release flux was observed in the treatment of DOMH,25.02% of the control,followed by DOMS and DOMR,62.46% and 64.95% of the control,respectively.The higher saturation degree and lower molecular weight of DOMH was responsible for the highest inhibition degree on the mercury release.The link between DOMH,concentration and mercury flux was also estimated and the result showed that mercury flux was increased with DOMH at lower concentration,while decreased with DOMH at higher concentration.Different mechanism dominated the influence of DOM on mercury release with variation of DOM concentration.
基金supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (No. 2012R1A1B3002152, 2013R1A2A2A03016095)
文摘Effluent organic matter （EfOM） is the major cause of fouling in the low pressure membranes process for wastewater reuse. Coagulation and oxidation of biological wastewater treatment effluent have been applied for the fouling control of microfiltration membranes. However, the change in EfOM structure by pre-treatments has not been clearly identified. The changes of EfOM characteristics induced by coagulation and ozonation were investigated through size exclusion chromatography, UV/Vis spectrophotometry, fluorescence spectrophotometry and titrimetric analysis to identify the mechanisms in the reduction of ultrafiltration （UF） membrane fouling. The results indicated that reduction of flux decline by coagulation was due to modified characteristics of dissolved organic carbon （DOC） content. Total concentration of DOC was not reduced by ozonation. However, the mass fraction of the molecules with molecular weight larger than 5 kDa, fluorescence intensity, aromaticity, highly condensed chromophores, average molecular weight and soluble microbial byproducts decreased greatly after ozonation. These results indicated that EfOM was partially oxidized by ozonation to low molecular weight, highly charged compounds with abundant electron- withdrawing functional groups, which are favourable for alleviating UF membrane flux decline.
