Molecular rotation-caused autocorrelation behaviors of thermal noise in water

The finite autocorrelation time of thermal noise is crucial to unidirectional transportation on the molecular scale.Therefore,it is important to understand the cause of the intrinsic picosecond autocorrelation time of thermal noise in water.In this work,we use molecular dynamics simulations to compare the autocorrelation behaviors of the thermal noise,hydrogen bonds,and molecular rotations found in water.We found that the intrinsic picosecond autocorrelation time for thermal noise is caused by finite molecular rotation relaxation,in which hydrogen bonds play the role of a bridge.Furthermore,the simulation results show that our method of calculating the autocorrelation of thermal noise,by observing the fiuctuating force on an oxygen atom of water,provides additional information about molecular rotations.Our findings may advance the understanding of the anomalous dynamic nanoscale behavior of particles,and the applications of terahertz technology in measuring the structural and dynamical information of molecules in solutions.

Towards Post-Quantum Cryptography Using Thermal Noise Theory and True Random Numbers Generation

The advent of quantum computers and algorithms challenges the semantic security of symmetric and asymmetric cryptosystems. Thus, the implementation of new cryptographic primitives is essential. They must follow the breakthroughs and properties of quantum calculators which make vulnerable existing cryptosystems. In this paper, we propose a random number generation model based on evaluation of the thermal noise power of the volume elements of an electronic system with a volume of 58.83 cm3. We prove through the sampling of the temperature of each volume element that it is difficult for an attacker to carry out an exploit. In 12 seconds, we generate for 7 volume elements, a stream of randomly generated keys of 187 digits that will be transmitted from source to destination through the properties of quantum cryptography.

TEMPERATURE PROFILES OF LOCAL THERMAL NONEQUILIBRIUM FOR THERMAL DEVELOPING FORCED CONVECTION IN POROUS MEDIUM PARALLEL PLATE CHANNEL

Based on the two-energy equation model, taking into account viscous dissipation due to the interaction between solid skeleton and pore fluid flow, temperature expressions of the solid skeleton and pore fluid flow are obtained analytically for the thermally developing forced convection in a saturated porous medium parallel plate channel, with walls being at constant temperature. It is proved that the temperatures of the two phases for the local thermal nonequilibrium approach to the temperature derived from the one-energy equation model for the local thermal equilibrium when the heat exchange coefficient goes to infinite. The temperature profiles are shown in figures for different dimensionless parameters and the effects of the parameters on the local thermal nonequilibrium are revealed by parameter study.

Numerical investigation on the flow characteristics of a reverse-polarity plasma torch by two-temperature thermal non-equilibrium modelling

A two-temperature(2 T)thermal non-equilibrium model is developed to address the thermal nonequilibrium phenomenon that inevitably exists in the reverse-polarity plasma torch(RPT)and applied to numerically investigate the plasma flow characteristics inside and outside the RPT.Then,a detailed comparison of the results of the 2 T model with those of the local thermal equilibrium(LTE)model is presented.Furthermore,the temperature of the plasma jet generated by a RPT and the RPT’s voltage are experimentally measured to compare and validate the result obtained by different models.The differences of the measured excitation temperature and the arc voltage between the 2 T model and experimental measurement are less than 13%and 8%,respectively,in all operating cases,validating the effectiveness of the 2 T model.The LTE model overestimates the velocity and temperature distribution of the RPT and its plasma jet,showing that thermal non-equilibrium phenomena cannot be neglected in the numerical modelling of the RPT.Unlike other common hot cathode plasma torches,the thermal non-equilibrium phenomenon is found even in the arc core of the RPT,due to the strong cooling effect caused by the big gas flow rate.

Determination of the thermal noise limit in test of weak equivalence principle with a rotating torsion pendulum

Thermal noise is one of the most fundamental limits to the sensitivity in weak equivalence principle test with a rotating torsion pendulum. Velocity damping and internal damping are two of many contributions at the thermal noise, and which one mainly limits the torsion pendulum in low frequency is difficult to be verified by experiment. Based on the conventional method of fast Fourier transform, we propose a developed method to determine the thermal noise limit and then obtain the precise power spectrum density of the pendulum motion signal. The experiment result verifies that the thermal noise is mainly contributed by the internal damping in the fiber in the low frequency torsion pendulum experiment with a high vacuum. Quantitative data analysis shows that the basic noise level in the experiment is about one to two times of the theoretical value of internal damping thermal noise.

RESEARCH ON DISTURBED MECHANISM OF THERMAL NOISES OF THE SURFACE IN ABRUPT GEOTHERMAL ANOMALY

Geothermal anomaly as a physical phenomenon of an active and latent volca nic area would be well recog-nized,and abrupt geothermal anomaly should also be understood.However,in practical work,thermal infrare d remote sensing techniques are frequently u sed to monitor geothermal flows of th e earth.But then,except for this typ e of thermal source in the surface thermal field,there still exist a lot of noises in th e area where the abrupt geothermal an omaly is generat-ed.By Analyzing the reason,we find t hat it is brought about by the non-bou ndless projection characteristics of objects.These noises may be divided into two c lasses:system noises and random noises.If disturbed noises have comparative sta-ble time sequence law and space sequence law,the noises are called system noises.And because system noises have a certain law,it is easy to remove the n oises.On the contrary,if disturbed noises have not law of time sequence a nd space sequence,the noises are called random noises.The random noises have the character of non-linearity,uncertainty and indeterminism.For this case,this p aper discusses the disturbed mechan ism of these noises as well as how to re move them..

Optimal estimation of the amplitude of signal with known frequency in the presence of thermal noise

In the torsion pendulum experiments, the thermal noise sets the most fundamental limit to the accurate estimation of the amplitude of the signal with known frequency. The variance of the conventional method can meet the limit only when the measurement time is much longer than the relaxation time of the pendulum. By using the maximum likelihood estimation and the equation-of-motion filter operator, we propose an optimal(minimum variance, unbiased) amplitude estimation method without limitation of the measurement time, where thermal fluctuation is the leading noise. While processing the experimental data tests of the Newtonian gravitational inverse square law, the variance of our method has been improved than before and the measurement time of determining the amplitude with this method has been reduced about half than before for the same uncertainty. These results are significant for the torsion experiment when the measurement time is limited.

Heat transfer enhanced inorganic phase change material compositing carbon nanotubes for battery thermal management and thermal runaway propagation mitigation

Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.

Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

Recently,azobenzene-4,4'-dicarboxylic acid(ADCA)has been produced gradually for use as an organic synthesis or pharmaceutical intermediate due to its eminent performance.With large quantities put into application in the future,the thermal stability of this substance during storage,transportation,and use will become quite important.Thus,in this work,the thermal decomposition behavior,thermal decomposition kinetics,and thermal hazard of ADCA were investigated.Experiments were conducted by using a SENSYS evo DSC device.A combination of differential iso-conversion method,compensation parameter method,and nonlinear fitting evaluation were also used to analyze thermal kinetics and mechanism of ADCA decomposition.The results show that when conversion rateαincreases,the activation energies of ADCA's first and main decomposition peaks fall.The amount of heat released during decomposition varies between 182.46 and 231.16 J·g^(-1).The proposed kinetic equation is based on the Avrami-Erofeev model,which is consistent with the decomposition progress.Applying the Frank-Kamenetskii model,a calculated self-accelerating decomposition temperature of 287.0℃is obtained.

Coupling effect on the thermal hazard assessment of hazardous chemical materials via calorimetric technologies and simulation approaches

The coupling effect of heat absorption and release exists in the thermal decomposition of a few chemical materials.However,the impact of the above coupling on thermal hazard assessment is not considered in the literature studies.In this work,nitroguanidine(NQ)and 1,3,5-trinitro-1,3,5-triazine(RDX)are selected as representative materials to explore the influence of the coupling effect on the thermal hazard assessment of chemical materials.The linear heating experiments of NQ and RDX are carried out by a microcalorimeter and synchronous thermal analyser.The thermal decomposition curves are decoupled by advanced thermokinetics software.The thermal decomposition and kinetic parameters before and after decoupling are calculated.The results of TG experiment show that both NQ and RDX began to lose mass during the endothermic stage.The endothermic melting and exothermic decomposition of NQ and RDX are coupled within this stage.The coupling effect has different degrees of influence on its initial decomposition temperature and safety parameters.Compared with the parameters in the coupling state,the initial decomposition temperature and adiabatic induction period after decoupling decrease.The self-accelerating decomposition temperature increases,and internal thermal runaway time decreases.In the thermal hazard assessment of chemical materials with coupling effects,the calculated parameters after decoupling should be taken as an important safety index。

Nonreciprocal thermal metamaterials:Methods and applications

Nonreciprocity of thermal metamaterials has significant application prospects in isolation protection,unidirectional transmission,and energy harvesting.However,due to the inherent isotropic diffusion law of heat flow,it is extremely difficult to achieve nonreciprocity of heat transfer.This review presents the recent developments in thermal nonreciprocity and explores the fundamental theories,which underpin the design of nonreciprocal thermal metamaterials,i.e.,the Onsager reciprocity theorem.Next,three methods for achieving nonreciprocal metamaterials in the thermal field are elucidated,namely,nonlinearity,spatiotemporal modulation,and angular momentum bias,and the applications of nonreciprocal thermal metamaterials are outlined.We also discuss nonreciprocal thermal radiation.Moreover,the potential applications of nonreciprocity to other Laplacian physical fields are discussed.Finally,the prospects for advancing nonreciprocal thermal metamaterials are highlighted,including developments in device design and manufacturing techniques and machine learning-assisted material design.

Controlled thermally-driven mass transport in carbon nanotubes using carbon hoops

Controlling mass transportation using intrinsic mechanisms is a challenging topic in nanotechnology.Herein,we employ molecular dynamics simulations to investigate the mass transport inside carbon nanotubes(CNT)with temperature gradients,specifically the effects of adding a static carbon hoop to the outside of a CNT on the transport of a nanomotor inside the CNT.We reveal that the underlying mechanism is the uneven potential energy created by the hoops,i.e.,the hoop outside the CNT forms potential energy barriers or wells that affect mass transport inside the CNT.This fundamental control of directional mass transportation may lead to promising routes for nanoscale actuation and energy conversion.

Efficient Electromagnetic Wave Absorption and Thermal Infrared Stealth in PVTMS@MWCNT Nano‑Aerogel via Abundant Nano‑Sized Cavities and Attenuation Interfaces

Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT aerogel structure shows nano-pore size(30-40 nm),high specific surface area(559 m^(2)g^(−1)),high void fraction(91.7%)and enhanced mechanical property:(1)the nano-pore size is beneficial for efficiently blocking thermal conduction and thermal convection via Knudsen effect(beneficial for infrared(IR)stealth);(2)the heterogeneous interface was beneficial for IR reflection(beneficial for IR stealth)and MWCNT polarization loss(beneficial for electromagnetic wave(EMW)attenuation);(3)the high void fraction was beneficial for enhancing thermal insulation(beneficial for IR stealth)and EMW impedance match(beneficial for EMW attenuation).Guided by the above theoretical design strategy,PVTMS@MWCNT nano-aerogel shows superior EMW absorption property(cover all Ku-band)and thermal IR stealth property(ΔT reached 60.7℃).Followed by a facial combination of the above nano-aerogel with graphene film of high electrical conductivity,an extremely high electromagnetic interference shielding material(66.5 dB,2.06 mm thickness)with superior absorption performance of an average absorption-to-reflection(A/R)coefficient ratio of 25.4 and a low reflection bandwidth of 4.1 GHz(A/R ratio more than 10)was experimentally obtained in this work.

The Negative Thermal Expansion Property of NdMnO_(3) Based on Pores Effect and Phase Transition

A novel negative thermal expansion(NTE) material NdMnO_(3) was synthesized by solid-state method at 1 523 K. The crystal structure, phase transition, pores effect and negative expansion properties of NdMnO_(3) were investigated by variable temperature X-ray diffraction(XRD), scanning electron microscope(SEM) and variable temperature Raman spectra. The compound exhibits NTE properties in the orderly O' phase crystal structure. When the temperature is from 293 to 759 K, the ceramic NdMnO_(3) shows negative thermal expansion of-4.7×10^(-6)/K. As temperature increases, the ceramic NdMnO_(3) presents NTE property range from 759 to 1 007 K. The average linear expansion coefficient is-18.88×10^(-6)/K. The physical mechanism of NTE is discussed and clarified through experiments.

Reactive molecular dynamics insight into the thermal decomposition mechanism of 2,6-Bis(picrylamino)-3,5-dinitropyridine

2,6-bis(picrylamino)-3,5-dinitropyridine(PYX)has excellent thermostability,which makes its thermal decomposition mechanism receive much attention.In this paper,the mechanism of PYX thermal decomposition was investigated thoroughly by the ReaxFF-lg force field combined with DFT-B3LYP(6-311++G)method.The detailed decomposition mechanism,small-molecule product evolution,and cluster evolution of PYX were mainly analyzed.In the initial stage of decomposition,the intramolecular hydrogen transfer reaction and the formation of dimerized clusters are earlier than the denitration reaction.With the progress of the reaction,one side of the bitter amino group is removed from the pyridine ring,and then the pyridine ring is cleaved.The final products produced in the thermal decomposition process are CO_(2),H_(2)O,N_(2),and H_(2).Among them,H_(2)O has the earliest generation time,and the reaction rate constant(k_(3))is the largest.Many clusters are formed during the decomposition of PYX,and the formation,aggregation,and decomposition of these clusters are strongly affected by temperature.At low temperatures(2500 K-2750 K),many clusters are formed.At high temperatures(2750 K-3250 K),the clusters aggregate to form larger clusters.At 3500 K,the large clusters decompose and become small.In the late stage of the reaction,H and N in the clusters escaped almost entirely,but more O was trapped in the clusters,which affected the auto-oxidation process of PYX.PYX's initial decomposition activation energy(E_(a))was calculated to be 126.58 kJ/mol.This work contributes to a theoretical understanding of PYX's entire thermal decomposition process.

Coaxial Wet Spinning of Boron Nitride Nanosheet‑Based Composite Fibers with Enhanced Thermal Conductivity and Mechanical Strength

Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric properties.However,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron nitride,thereby limiting their performance in applications such as thermal management.In this study,we present a coaxial wet spinning approach for the fabrication of BNNSs/polymer composite fibers with high nanosheet orientation.The composite fibers were prepared using a superacid-based solvent system and showed a layered structure comprising an aramid core and an aramid/BNNSs sheath.Notably,the coaxial fibers exhibited significantly higher BNNSs alignment compared to uniaxial aramid/BNNSs fibers,primarily due to the additional compressive forces exerted at the core-sheath interface during the hot drawing process.With a BNNSs loading of 60 wt%,the resulting coaxial fibers showed exceptional properties,including an ultrahigh Herman orientation parameter of 0.81,thermal conductivity of 17.2 W m^(-1)K^(-1),and tensile strength of 192.5 MPa.These results surpassed those of uniaxial fibers and previously reported BNNSs composite fibers,making them highly suitable for applications such as wearable thermal management textiles.Our findings present a promising strategy for fabricating high-performance composite fibers based on BNNSs.

Formation of Natural Melanin/TiO_(2) Nanostructure Hybrids with Enhanced Optical,Thermal and Magnetic Properties as a Soft Material

The natural Melanin/TiO_(2) was synthesized by the use of ultrasonication under UV radiation.The influence of natural melanin on the structural,optical and thermal properties of TiO_(2) nanoparticles was investigated by using Fourier transform infrared spectroscopy,thermogravimetric analysis and UV-Vis spectroscopy.It was observed that incorporating natural melanin on TiO_(2) nanoparticles(TiO_(2)-Mel)occurred at 2.01 eV with a low value of Urbach energy around 100 meV indicating improvement in the crystalline structure.Magnetic measurement at room temperature showed diamagnetic behavior.Furthermore,thermal results showed that TiO_(2)-Mel is stable even at temperatures up to 400℃.According to the results obtained by the thermal stability of melanin with titanium dioxide,it can be a good candidate in many applications such as solar cells and optoelectronics.

Local thermal conductivity of inhomogeneous nano-fluidic films:A density functional theory perspective

Combining the mean field Pozhar-Gubbins(PG)theory and the weighted density approximation,a novel method for local thermal conductivity of inhomogeneous fluids is proposed.The correlation effect that is beyond the mean field treatment is taken into account by the simulation-based empirical correlations.The application of this method to confined argon in slit pore shows that its prediction agrees well with the simulation results,and that it performs better than the original PG theory as well as the local averaged density model(LADM).In its further application to the nano-fluidic films,the influences of fluid parameters and pore parameters on the thermal conductivity are calculated and investigated.It is found that both the local thermal conductivity and the overall thermal conductivity can be significantly modulated by these parameters.Specifically,in the supercritical states,the thermal conductivity of the confined fluid shows positive correlation to the bulk density as well as the temperature.However,when the bulk density is small,the thermal conductivity exhibits a decrease-increase transition as the temperature is increased.This is also the case in which the temperature is low.In fact,the decrease-increase transition in both the small-bulk-density and low-temperature cases arises from the capillary condensation in the pore.Furthermore,smaller pore width and/or stronger adsorption potential can raise the critical temperature for condensation,and then are beneficial to the enhancement of the thermal conductivity.These modulation behaviors of the local thermal conductivity lead immediately to the significant difference of the overall thermal conductivity in different phase regions.

Identification of thermal front dynamics in the northern Malacca Strait using ROMS 3D-model

The thermal front in the oceanic system is believed to have a significant effect on biological activity.During an era of climate change,changes in heat regulation between the atmosphere and oceanic interior can alter the characteristics of this important feature.Using the simulation results of the 3D Regional Ocean Modelling System(ROMS),we identified the location of thermal fronts and determined their dynamic variability in the area between the southern Andaman Sea and northern Malacca Strait.The Single Image Edge Detection(SIED)algorithm was used to detect the thermal front from model-derived temperature.Results show that a thermal front occurred every year from 2002 to 2012 with the temperature gradient at the location of the front was 0.3°C/km.Compared to the years affected by El Ni?o and negative Indian Ocean Dipole(IOD),the normal years(e.g.,May 2003)show the presence of the thermal front at every selected depth(10,25,50,and 75 m),whereas El Ni?o and negative IOD during 2010 show the presence of the thermal front only at depth of 75 m due to greater warming,leading to the thermocline deepening and enhanced stratification.During May 2003,the thermal front was separated by cooler SST in the southern Andaman Sea and warmer SST in the northern Malacca Strait.The higher SST in the northern Malacca Strait was believed due to the besieged Malacca Strait,which trapped the heat and make it difficult to release while higher chlorophyll a in Malacca Strait is due to the freshwater conduit from nearby rivers(Klang,Langat,Perak,and Selangor).Furthermore,compared to the southern Andaman Sea,the chlorophyll a in the northern Malacca Strait is easier to reach the surface area due to the shallower thermocline,which allows nutrients in the area to reach the surface faster.

Phonon resonance modulation in weak van der Waals heterostructures:Controlling thermal transport in graphene-silicon nanoparticle systems

The drive for efficient thermal management has intensified with the miniaturization of electronic devices.This study explores the modulation of phonon transport within graphene by introducing silicon nanoparticles influenced by van der Waals forces.Our approach involves the application of non-equilibrium molecular dynamics to assess thermal conductivity while varying the interaction strength,leading to a noteworthy reduction in thermal conductivity.Furthermore,we observe a distinct attenuation in length-dependent behavior within the graphene-nanoparticles system.Our exploration combines wave packet simulations with phonon transmission calculations,aligning with a comprehensive analysis of the phonon transport regime to unveil the underlying physical mechanisms at play.Lastly,we conduct transient molecular dynamics simulations to investigate interfacial thermal conductance between the nanoparticles and the graphene,revealing an enhanced thermal boundary conductance.This research not only contributes to our understanding of phonon transport but also opens a new degree of freedom for utilizing van der Waals nanoparticle-induced resonance,offering promising avenues for the modulation of thermal properties in advanced materials and enhancing their performance in various technological applications.