Aluminum coatings on Mg alloy AZ31 were fabricated using the thermal spraying technique, and then sealed with silane.The surface morphology and chemical groups were discerned using scanning electron microscopy and exa...Aluminum coatings on Mg alloy AZ31 were fabricated using the thermal spraying technique, and then sealed with silane.The surface morphology and chemical groups were discerned using scanning electron microscopy and examined using Fourier transformation infrared spectroscopy, respectively.The salt fog tests and the potentiodynamic electrochemical technique were applied to evaluate the influence of silane on corrosion of the AZ31 alloy with aluminum coatings.The results showed that the corrosion resistance of the aluminum-coated AZ31 alloy was superior to that of the substrate.The aluminum coating sealed with various silane layers led to a further increase in the corrosion resistance of the alloy.Double silane layers were more corrosion-resistant than the single one.Also, it was no longer significant for more than two silane layers to improve the corrosion resistance.It implied that the optimum choice for silane treatment on the aluminum coatings was two layers.展开更多
The effect of thermal shock, in an accelerated-corrosion environment spectrum, on the fatigue and corrosion behavior of 7B04-T6 aluminum alloy, was determined. The environment spectrum consists of two modules, namely...The effect of thermal shock, in an accelerated-corrosion environment spectrum, on the fatigue and corrosion behavior of 7B04-T6 aluminum alloy, was determined. The environment spectrum consists of two modules, namely: salt-spray corrosion and thermal shock. The effect of thermal shock on the mechanical properties was determined via tensile tests; SEM, DCS, and XRD were used to determine the effect of thermal shock on the corrosion products. In addition, the corrosion resistance of the products was ascertained through electrochemical testing. The results show that the mechanical properties and fatigue life of the aluminum alloy will decline with prolonged thermal shock time. The thermal shock process may result in denser surface corrosion products than those formed on the no thermal shock specimens, and transformation of some Al(OH)_3 into Al OOH. Al OOH may have resulted in improved corrosion resistance and hence a lower decrease in the fatigue life after corrosion, compared with that of the no thermal shock specimen. Repeated corrosion/thermal shock may have delayed further decease in the fatigue life. Therefore, selection of an appropriate equivalent thermal shock temperature and time was essential for designing the environmental spectrum.展开更多
In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corro...In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corrosion products.Open circuit potential(OCP),electrochemical impedance spectroscopy,and potentiodynamic studies were used to assess the corrosion characteristics of these coatings after exposure according to the Society of Automotive Engineers(SAE)J2334 solution of varying durations.This solution simulates an industrial environment and contains chloride and carbonate ions that induce corrosion of the deposited coatings.However,the Al–Mg alloy coating maintained an OCP of approximately-0.911 V versus Ag/Ag Cl in the SAE J2334 solution even after 792 h of exposure.This indicates that it protects the steel sacrificially,whereas the Al–Zn coating provides only barrier-type protection through the deposition of corrosion products.The Al–Mg coating acts as a self-healing coating and provides protection by forming Mg_6Al_2(OH)_(16)CO_3(Al–Mg layered double hydroxides).Mg_6Al_2(OH)_(16)CO_3has interlocking characteristics with a morphology of plate-like nanostructures and an ion-exchange ability that can improve the corrosion resistance properties of the coating.The presence of Zn in the corrosion products of the Al–Zn coating allows dissolution,but,at the same time,Zn_5(OH)_6(CO_3)_2and Zn_6Al_2(OH)_(16)CO_3are formed and act to reduce the corrosion rate.展开更多
Surface structure of C/C composites has been regulated through electrochemical corrosion at room temperature to modify the residual stress and improve the joining strength when brazed to Nb.The unique crevice corrosio...Surface structure of C/C composites has been regulated through electrochemical corrosion at room temperature to modify the residual stress and improve the joining strength when brazed to Nb.The unique crevice corrosion in C/C composites is investigated to reveal the change of corrosion depth and fiber size.The interlacing zone of carbon fiber reinforced brazing alloy replaces the reaction layer in the original joint.Joining area is increased dramatically and the continuous crack will be hindered.The interlacing zone eliminates the stress concentration and relieves the residual stress through reducing the property mismatch.All advantages contribute to the joining quality of C/C–Nb.Shear strength of C/C–Nb joint with 80μm depth reached 37.7 MPa,which was 1.2 times higher than that of original joint.Surface structure design of C/C composites not only expands the application in structure component,but also exhibits the promising application in energy field.展开更多
Ti–Al mixed powder(Ti:Al = 3:1 in atomic ratio) and Ti3 Al intermetallic alloy powder mechanically clad hexagonal BN to fabricate Ti Al/BN and Ti3Al/BN composite powders. The corresponding porous abradable seal c...Ti–Al mixed powder(Ti:Al = 3:1 in atomic ratio) and Ti3 Al intermetallic alloy powder mechanically clad hexagonal BN to fabricate Ti Al/BN and Ti3Al/BN composite powders. The corresponding porous abradable seal coatings(named as TAC-1 and TAC-2, respectively) were deposited using vacuum plasma spray(VPS) technology, and their corrosion behavior was studied via salt spray corrosion and electrochemical tests. Phase compositions and microstructures of these coatings before and after corrosion were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM) facilitated with energy dispersive X-ray spectrometer(EDS). The results showed that spontaneous passivation of TAC-1 and TAC-2 granted the coatings excellent corrosion resistance than that of commercial Al/BN coating. Additionally, TAC-2 exhibited higher corrosion potential(Ecorr) and breakdown potential(Ebp) but a lower corrosion current density(icorr) than TAC-1. A small quantity of the corrosion product(Al(OH)3and Al O) could be detected on the surface of TAC-1, while no corrosion product appeared in TAC-2. The non-uniform elements distribution in the metal matrix of TAC-1 resulted in localized corrosion and relatively poor corrosion resistance compared to TAC-2.展开更多
For corrosion protection of carbon steel in a marine environment,cold arc thermal spray coating was applied to the surface with Al and Al-Mg alloy wires.The surface hardness of Al and Al-Mg thermal spray coatings incr...For corrosion protection of carbon steel in a marine environment,cold arc thermal spray coating was applied to the surface with Al and Al-Mg alloy wires.The surface hardness of Al and Al-Mg thermal spray coatings increased with Mg content.And the various electrochemical experiments were carried out to evaluate corrosion damage characteristics of the thermal spray coating layers.The Al and Al-Mg thermal spray coating layers presented negative potentials compared to carbon steel in corrosion potential measurements.And an anodic polarization experiment revealed a tendency of activation polarization with no passivation.Furthermore,the corrosion damage of the thermal spray coating layer in galvanostatic experiment was observed mainly at the defect area,and the Al-3Mg thermal spray coating layer presented less surface damages than others.In addition,the Al-3Mg thermal spray coating layer showed the lowest corrosion rate while having a sufficient driving voltage for cathodic corrosion protection.Therefore,it is an optimal thermal spray material for sacrificial anode.展开更多
基金supported by the Key Technologies Research & Development Program of Chongqing Science and Technology Commission (CSTC) (Nos. 2007AC4073 and 2009AB4008)the Natural Science Foundation of CSTC, China (No. 2008BB0063)
文摘Aluminum coatings on Mg alloy AZ31 were fabricated using the thermal spraying technique, and then sealed with silane.The surface morphology and chemical groups were discerned using scanning electron microscopy and examined using Fourier transformation infrared spectroscopy, respectively.The salt fog tests and the potentiodynamic electrochemical technique were applied to evaluate the influence of silane on corrosion of the AZ31 alloy with aluminum coatings.The results showed that the corrosion resistance of the aluminum-coated AZ31 alloy was superior to that of the substrate.The aluminum coating sealed with various silane layers led to a further increase in the corrosion resistance of the alloy.Double silane layers were more corrosion-resistant than the single one.Also, it was no longer significant for more than two silane layers to improve the corrosion resistance.It implied that the optimum choice for silane treatment on the aluminum coatings was two layers.
文摘The effect of thermal shock, in an accelerated-corrosion environment spectrum, on the fatigue and corrosion behavior of 7B04-T6 aluminum alloy, was determined. The environment spectrum consists of two modules, namely: salt-spray corrosion and thermal shock. The effect of thermal shock on the mechanical properties was determined via tensile tests; SEM, DCS, and XRD were used to determine the effect of thermal shock on the corrosion products. In addition, the corrosion resistance of the products was ascertained through electrochemical testing. The results show that the mechanical properties and fatigue life of the aluminum alloy will decline with prolonged thermal shock time. The thermal shock process may result in denser surface corrosion products than those formed on the no thermal shock specimens, and transformation of some Al(OH)_3 into Al OOH. Al OOH may have resulted in improved corrosion resistance and hence a lower decrease in the fatigue life after corrosion, compared with that of the no thermal shock specimen. Repeated corrosion/thermal shock may have delayed further decease in the fatigue life. Therefore, selection of an appropriate equivalent thermal shock temperature and time was essential for designing the environmental spectrum.
基金supported by the research fund of Hanyang University (No. HY-2014-P)
文摘In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corrosion products.Open circuit potential(OCP),electrochemical impedance spectroscopy,and potentiodynamic studies were used to assess the corrosion characteristics of these coatings after exposure according to the Society of Automotive Engineers(SAE)J2334 solution of varying durations.This solution simulates an industrial environment and contains chloride and carbonate ions that induce corrosion of the deposited coatings.However,the Al–Mg alloy coating maintained an OCP of approximately-0.911 V versus Ag/Ag Cl in the SAE J2334 solution even after 792 h of exposure.This indicates that it protects the steel sacrificially,whereas the Al–Zn coating provides only barrier-type protection through the deposition of corrosion products.The Al–Mg coating acts as a self-healing coating and provides protection by forming Mg_6Al_2(OH)_(16)CO_3(Al–Mg layered double hydroxides).Mg_6Al_2(OH)_(16)CO_3has interlocking characteristics with a morphology of plate-like nanostructures and an ion-exchange ability that can improve the corrosion resistance properties of the coating.The presence of Zn in the corrosion products of the Al–Zn coating allows dissolution,but,at the same time,Zn_5(OH)_6(CO_3)_2and Zn_6Al_2(OH)_(16)CO_3are formed and act to reduce the corrosion rate.
基金supported by the National Natural Science Foundation of China(nos.51575135,51622503,U1537206 and 51621091)the Natural Science Foundation of Heilongjiang Province of China(No.YQ2019E023).
文摘Surface structure of C/C composites has been regulated through electrochemical corrosion at room temperature to modify the residual stress and improve the joining strength when brazed to Nb.The unique crevice corrosion in C/C composites is investigated to reveal the change of corrosion depth and fiber size.The interlacing zone of carbon fiber reinforced brazing alloy replaces the reaction layer in the original joint.Joining area is increased dramatically and the continuous crack will be hindered.The interlacing zone eliminates the stress concentration and relieves the residual stress through reducing the property mismatch.All advantages contribute to the joining quality of C/C–Nb.Shear strength of C/C–Nb joint with 80μm depth reached 37.7 MPa,which was 1.2 times higher than that of original joint.Surface structure design of C/C composites not only expands the application in structure component,but also exhibits the promising application in energy field.
基金financially supported by the Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS (No. MPCS-2012-A-06)the Natural Science Foundation of Jiangsu Province, China (No. BK2011452)
文摘Ti–Al mixed powder(Ti:Al = 3:1 in atomic ratio) and Ti3 Al intermetallic alloy powder mechanically clad hexagonal BN to fabricate Ti Al/BN and Ti3Al/BN composite powders. The corresponding porous abradable seal coatings(named as TAC-1 and TAC-2, respectively) were deposited using vacuum plasma spray(VPS) technology, and their corrosion behavior was studied via salt spray corrosion and electrochemical tests. Phase compositions and microstructures of these coatings before and after corrosion were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM) facilitated with energy dispersive X-ray spectrometer(EDS). The results showed that spontaneous passivation of TAC-1 and TAC-2 granted the coatings excellent corrosion resistance than that of commercial Al/BN coating. Additionally, TAC-2 exhibited higher corrosion potential(Ecorr) and breakdown potential(Ebp) but a lower corrosion current density(icorr) than TAC-1. A small quantity of the corrosion product(Al(OH)3and Al O) could be detected on the surface of TAC-1, while no corrosion product appeared in TAC-2. The non-uniform elements distribution in the metal matrix of TAC-1 resulted in localized corrosion and relatively poor corrosion resistance compared to TAC-2.
基金a part of the project titled "Construction of eco-friendly Al ship with painting,and maintenance/repairment free," funded by the Ministry of Oceans and Fisheries,Korea
文摘For corrosion protection of carbon steel in a marine environment,cold arc thermal spray coating was applied to the surface with Al and Al-Mg alloy wires.The surface hardness of Al and Al-Mg thermal spray coatings increased with Mg content.And the various electrochemical experiments were carried out to evaluate corrosion damage characteristics of the thermal spray coating layers.The Al and Al-Mg thermal spray coating layers presented negative potentials compared to carbon steel in corrosion potential measurements.And an anodic polarization experiment revealed a tendency of activation polarization with no passivation.Furthermore,the corrosion damage of the thermal spray coating layer in galvanostatic experiment was observed mainly at the defect area,and the Al-3Mg thermal spray coating layer presented less surface damages than others.In addition,the Al-3Mg thermal spray coating layer showed the lowest corrosion rate while having a sufficient driving voltage for cathodic corrosion protection.Therefore,it is an optimal thermal spray material for sacrificial anode.