Infl uencing Mechanism and Interaction of Muscovite on Thermal Decomposition of Ammonium Polyphosphate

The interaction mechanism and phase evolution of ammonium polyphosphate（APP）mixed with muscovite（APP/muscovite）were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates（AlPO_4 and K_5P_3O_（10））compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.

An Application of the Modified Shear Lag Model to Study the Influence of Thermal Residual Stresses on the Stiffness and Yield Strength of Short Fiber Reinforced Metal Matrix Composites

The modified shear lag model proposed recently was applied to calculate thermal residual stresses and subsequent stress distributions under tensile and compressive loadings. The expressions for the elastic moduli and the yield strengths under tensile and compressive loadings were derived which take account of thermal residual stresses. The asymmetries in the elastic modulus and the yield strength were interpreted using the derived expressions and the obtained results of the stress calculations. The model predictions have exhibited good agreements with the experimental results and also with the other theoretical predictions

Numerical simulation of a buried hot crude oil pipeline during shutdown

In this paper a mathematical model is built for a buried hot crude oil pipeline during shutdown, and an unstructured grid and polar coordinate grid are respectively applied to generating grids for the soil region and the three layers in the pipe （wax layer, pipe wall, and corrosion-inhibiting coating）. The governing equations are discretized using the finite volume method. The variations in temperatures of static oil and soil were investigated during pipeline shutdown in both summer and winter, in which some important parameters of the soil and crude oils of a Northeast pipeline are employed.

Simulation of heat transfer performance using middle-deep coaxial borehole heat exchangers by FEFLOW

Due to its large heat transfer area and stable thermal performance,the middledeep coaxial borehole heat exchanger(CBHE)has become one of the emerging technologies to extract geothermal energy.In this paper,a numerical modeling on a three-dimensional unsteady heat transfer model of a CBHE was conducted by using software FEFLOW,in which the model simulation was compared with the other studies and was validated with experimental data.On this basis,a further simulation was done in respect of assessing the influencing factors of thermal extraction performance and thermal influence radius of the CBHE.The results show that the outlet temperature of the heat exchanger decreases rapidly at the initial stage,and then tended to be stable;and the thermal influence radius increases with the increase of borehole depth.The heat extraction rate of the borehole increases linearly with the geothermal gradient.Rock heat capacity has limited impact on the heat extraction rate,but has a great influence on the thermal influence radius of the CBHE.When there is groundwater flow in the reservoir,the increase of groundwater velocity will result in the rise of both outlet temperature and heat extraction rate.The heat affected zone extends along with the groundwater flow direction;and its influence radius is increasing along with flow velocity.In addition,the material of the inner pipe has a significant effect on the heat loss in the pipe,so it is recommended that the material with low thermal conductivity should be used if possible.

Influence of alkali metal ions on thermal stability of Bi-activated NIR-emitting alkali-aluminoborosilicate glasses

We study the influence of alkali oxides on the near-infrared（NIR）-emitting thermal stability of Bi-doped R2O–Si O2–B2O3–Al2O3（R = Li, Na, K） glasses below Tg. Results show that undergoing heat treatment, remarkable luminescence quenching occurs for the glasses containing Na2 O and K2 O due to the formation of Bi metallic colloids, whereas the glass with Li2 O shows much better thermal stability. These changes can be understood by the tendency of modifier cations with lower mobility and higher tightness network to restrain the transport of Bi-related NIR-emitting centers. The results provide a scientific reference for composition design of Bi-doped optical fiber.