期刊文献+
共找到1,154篇文章
< 1 2 58 >
每页显示 20 50 100
Natural ventilation performance of single room building with fluctuating wind speed and thermal mass 被引量:3
1
作者 TAN Gang 《Journal of Central South University》 SCIE EI CAS 2012年第3期733-739,共7页
Natural ventilation is driven by either buoyancy forces or wind pressure forces or their combinations that inherit stochastic variation into ventilation rates. Since the ventilation rate is a nonlinear function of mul... Natural ventilation is driven by either buoyancy forces or wind pressure forces or their combinations that inherit stochastic variation into ventilation rates. Since the ventilation rate is a nonlinear function of multiple variable factors including wind speed, wind direction, internal heat source and building structural thermal mass, the conventional methods for quantifying ventilation rate simply using dominant wind direction and average wind speed may not accurately describe the characteristic performance of natural ventilation. From a new point of view, the natural ventilation performance of a single room building under fluctuating wind speed condition using the Monte-Carlo simulation approach was investigated by incorporating building facade thermal mass effect. Given a same hourly turbulence intensity distribution, the wind speeds with 1 rain frequency fluctuations were generated using a stochastic model, the modified GARCH model. Comparisons of natural ventilation profiles, effective ventilation rates, and air conditioning electricity use for a three-month period show statistically significant differences (for 80% confidence interval) between the new calculations and the traditional methods based on hourly average wind speed. 展开更多
关键词 natural ventilation fluctuating wind speed thermal mass GARCH model
下载PDF
Measuring Thermal Mass of Sustainable Concrete Mixes 被引量:1
2
作者 Omer Damdelen Costas Georgopoulos Mukesh Limbachiya 《Journal of Civil Engineering and Architecture》 2014年第2期213-220,共8页
Thermal mass is currently evaluated with "admittance" which is the ability of the element to exchange heat with the environment and is based on specific heat capacity, thermal conductivity and density. The aim of th... Thermal mass is currently evaluated with "admittance" which is the ability of the element to exchange heat with the environment and is based on specific heat capacity, thermal conductivity and density. The aim of this study is to evaluate the effect of thermal properties namely, density, specific heat capacity and thermal conductivity on thermal mass. The objective of the study is to carry out laboratory experiments by measuring such thermal properties of concrete mixes with various percentages of GGBS (ground granulated blast furnace slag), PFA (pulverized fuel ash), and SF (silica fume) and RCA (recycled coarse aggregates). The results obtained from these tests would contribute to the evaluation of how such thermal properties influence the thermal admittance and hence the thermal mass performance of sustainable concrete elements in a building system. 展开更多
关键词 thermal mass thermal admittance thermal properties sustainable concrete.
下载PDF
The Study of Thermal Mass as a Passive Design Technique for Building Comfort and Energy Efficiency
3
作者 Mohammad Arif Kamal 《Journal of Civil Engineering and Architecture》 2011年第1期84-88,共5页
The day/night (diurnal) changes in temperature and solar radiation pose challenges for maintaining human thermal comfort in buildings. Passive and energy-conserving buildings seek to manage the available thermal ene... The day/night (diurnal) changes in temperature and solar radiation pose challenges for maintaining human thermal comfort in buildings. Passive and energy-conserving buildings seek to manage the available thermal energy by lowering peaks and dampening the fluctuations in order to maintain conditions for human comfort. Appropriate use of thermal mass moderates the internal temperatures by averaging diurnal extremes. Thermal mass is one of the powerful tools which architects and designers can use to control temperature. It can be used to optimize the performance of energy-conserving buildings that rely primarily on mechanical heating and cooling strategies. Massive building envelopes-such as masonry, concrete, earth, and insulating concrete forms (ICFs) can be utilized as one of the simplest ways of reducing building heating and cooling loads. This article analyses the role and effectiveness of thermal mass as a strategy for providing indoor thermal comfort for passive solar and energy conserving buildings. 展开更多
关键词 thermal mass passive solar building comfort energy efficiency.
下载PDF
Model-based investigation on building thermal mass utilization and flexibility enhancement of air conditioning loads
4
作者 Yue Sun Tianyi Zhao Shan Lyu 《Building Simulation》 SCIE EI CSCD 2024年第8期1289-1308,共20页
Building air conditioning systems(ACs)can contribute to the stable operation of power grids by participating in peak load shaving programs,but the participants need a fast and accurate zone temperature prediction mode... Building air conditioning systems(ACs)can contribute to the stable operation of power grids by participating in peak load shaving programs,but the participants need a fast and accurate zone temperature prediction model,e.g.,the detailed room thermal-resistance(RC)model,to improve peak shaving effect and avoid obvious thermal discomfort.However,when applying the detailed room RC model to multi-zone buildings,conventional studies mostly consider the heat transfer among neighboring rooms,which contributes little to the prediction accuracy improvement,but leads to complicated model structure and heavy computation.Thus,a distributed RC model is developed for multi-zone buildings in this study.Compared to conventional models,the proposed model considers the total heat transfer between the building and the air,and ignores the heat transfer among indoor air in neighboring rooms through internal walls with heavy thermal mass,thereby having comparable temperature prediction accuracy,simpler structure,and stronger robustness.Based on the model,the effectiveness of passive pre-cooling strategies in reducing the air conditioning loads during peak periods is investigated.Results indicate that the thermal insulation performance of opaque building envelope is quite important to the flexibility enhancement of air conditioning loads.With an uninsulated building envelope,passive pre-cooling is useless for the peak load shaving.In comparison,well insulated opaque building envelope enables the building thermal mass to be utilized through passive pre-cooling,which leads to the air conditioning loads during peak periods being further reduced by about 12%. 展开更多
关键词 RC model passive pre-cooling internal thermal mass building energy flexibility
原文传递
THE INFLUENCE OF THERMAL RESISTANCE AND THERMAL MASS ON THE SEASONAL PERFORMANCE OF WALLING SYSTEMS IN AUSTRALIA
5
作者 Dariusz Alterman Adrian W.Page +2 位作者 Behdad Moghtaderi Congcong Zhang Trevor Moffiet 《Journal of Green Building》 2015年第4期107-126,共20页
This paper describes an experimental investigation of the thermal performance of four Australian domestic walling systems(cavity brick,insulated cavity brick,insulated brick veneer and insulated reverse brick veneer)h... This paper describes an experimental investigation of the thermal performance of four Australian domestic walling systems(cavity brick,insulated cavity brick,insulated brick veneer and insulated reverse brick veneer)having various combinations of thermal insulation and of thermal mass location within the wall.This experimental analysis extends further the previous studies of the benefits of thermal mass on the overall thermal performance of building enclosures(Gregory et al.2008,Luo at al.2008,Alashaary et al.2009).The comparison is based on the time required to maintain thermal comfort for free-floating internal conditions.The results clearly show that internal comfort levels are influenced by both the thermal resistance of the walls as well as the extent and location of the thermal mass,with neither parameter being the sole predictor.The best thermal performance is therefore obtained by an appropriate combination of thermal mass and resistance,rather than focussing on the overall wall thermal resistance(R-value)alone.A new approach of density temperature plots for comparison of temperature variation is also used in the assessment of module thermal performance. 展开更多
关键词 thermal mass thermal performance thermal resistance building enclosure temperature plots
下载PDF
ENERGY EMBODIED IN,AND TRANSMITTED THROUGH,WALLS OF DIFFERENT TYPES WHEN ACCOUNTING FOR THE DYNAMIC EFFECTS OF THERMAL MASS
6
作者 Aidan Reilly Oliver Kinnane Richard O’Hegarty 《Journal of Green Building》 2020年第4期43-66,共24页
Embodied energy is a measure of the energy used in producing,transporting and assembling the materials for a building.Operational energy is the energy used to moderate the indoor environment to make it functional or c... Embodied energy is a measure of the energy used in producing,transporting and assembling the materials for a building.Operational energy is the energy used to moderate the indoor environment to make it functional or comfortable-primarily,to heat or cool the building.For many building geometries,the walls make the most significant contribution to the embodied energy of the building,and they are also the path of greatest heat loss or gain through the fabric,as they often have a greater surface area than the roof or floor.Adding insulation reduces the heat flow through the wall,reducing the energy used during operation,but this adds to the embodied energy.The operational energy is not only a function of the wall buildup,but also depends on the climate,occupancy pattern,and heating strategy,making an optimisation for minimum overall energy use non-trivial.This study presents a comparison of typical wall construction types and heating strategies in a temperate maritime climate.The transient energy ratio method is a means to abstract the heat flow through the walls(operational energy for heating),allowing assessment of the influence of walls in isolation(i.e.in a general sense,without being restricted to particular building geometries).Three retrofit scenarios for a solid wall are considered.At very low U-values,overall energy use can increase as the embodied energy can exceed the operational energy;current best practice walls coupled with low building lifetimes mean that this point may be reached in the near future.Substantial uncertainty is present in existing embodied energy data,and given its contribution to total energy use,this is a topic of urgent concern. 展开更多
关键词 energy use lifetime energy use embodied energy operational energy thermal mass heating intermittent occupancy transient energy ratio uncertainty
下载PDF
Study on thermal wave based on the thermal mass theory 被引量:3
7
作者 HU RuiFeng CAO BingYang 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第6期1786-1792,共7页
The conservation equations for heat conduction are established based on the concept of thermal mass.We obtain a general heat conduction law which takes into account the spatial and temporal inertia of thermal mass.The... The conservation equations for heat conduction are established based on the concept of thermal mass.We obtain a general heat conduction law which takes into account the spatial and temporal inertia of thermal mass.The general law introduces a damped thermal wave equation.It reduces to the well-known CV model when the spatial inertia of heat flux and temperature and the temporal inertia of temperature are neglected,which indicates that the CV model only considers the temporal inertia of heat flux.Numerical simulations on the propagation and superposition of thermal waves show that for small thermal perturbation the CV model agrees with the thermal wave equation based on the thermal mass theory.For larger thermal perturbation,however,the physically impossible phenomenon pre-dicted by CV model,i.e.the negative temperature induced by the thermal wave superposition,is eliminated by the general heat conduction law,which demonstrates that the present heat conduction law based on the thermal mass theory is more reasonable. 展开更多
关键词 thermal wave thermal mass theory non-Fourier heat conduction CV mode
原文传递
High Precision Thermal Ionization Mass Spectrometric Dating of Corals and Its Application to Paleo-Environmental Study
8
作者 王兆荣 张兆峰 +1 位作者 彭子成 马志邦 《Chinese Journal Of Geochemistry》 EI CAS 2001年第2期138-143,共6页
Global change has become a hot spot in Quaternary geology, and high\|precision, high\|sensitivity dating is also an urgent problem which needs to be solved. This paper presents some achievements in U\|series dating of... Global change has become a hot spot in Quaternary geology, and high\|precision, high\|sensitivity dating is also an urgent problem which needs to be solved. This paper presents some achievements in U\|series dating of marine corals by thermal ionization mass spectrometry (TIMS) and its application to the study of paleo\|environments. Recently, coral samples were determined for their ages on a MAT\|262 mass spectrometer and satisfactory results have been obtained. 展开更多
关键词 光谱分析 珊瑚 古环境 全球变化
下载PDF
Thermal Diffusion Effect on MHD Heat and Mass Transfer Flow past a Semi Infinite Moving Vertical Porous Plate with Heat Generation and Chemical Reaction 被引量:1
9
作者 Gurivireddy P. Raju M. C. +1 位作者 Mamatha B. Varma S. V. K. 《Applied Mathematics》 2016年第7期638-649,共12页
The objective of present work is to study the thermo diffusion effect on an unsteady simultaneous convective heat and mass transfer flow of an incompressible, electrically conducting, heat generating/absorbing fluid a... The objective of present work is to study the thermo diffusion effect on an unsteady simultaneous convective heat and mass transfer flow of an incompressible, electrically conducting, heat generating/absorbing fluid along a semi-infinite moving porous plate embedded in a porous medium with the presence of pressure gradient, thermal radiation field and chemical reaction. It is assumed that the permeable plate is embedded in a uniform porous medium and moves with a constant velocity in the flow direction in the presence of a transverse magnetic field. It is also assumed that the free stream consists of a mean velocity, temperature and concentration over which are super imposed an exponentially varying with time. The equations of continuity, momentum, energy and diffusion, which govern the flow field, are solved by using a regular perturbation method. The behavior of the velocity, temperature, concentration, Skin-friction, rate of heat transfer and rate of mass transfer has been discussed for variations in the physical parameters. An increase in both Pr and R results a decrease in thermal boundary layer thickness. However, concentration decreases as Kr, Sc increase but it increases with an increase in both So and δ. 展开更多
关键词 Heat Generation/Absorption Chemical Reaction MHD thermal Radiation thermal Diffusion Heat and mass Transfer Semi-Infinite Vertical Plate
下载PDF
Spatial Thermal Crack Control in Mass Concrete
10
作者 Munishi Fred Abel ZHANG Shengdong LI Minying 《结构工程师》 北大核心 2012年第6期54-59,共6页
The finite element software,MIDAS is used to predict the distribution of temperatures and,analyzes the cracking control methods within a hydrating mass concrete.The temperature control of mass concrete has great signi... The finite element software,MIDAS is used to predict the distribution of temperatures and,analyzes the cracking control methods within a hydrating mass concrete.The temperature control of mass concrete has great significance in assuring the project quality.Adiabatic or semi adiabatic temperature measurement is mostly used for measuring and controlling the temperature fluctuation during construction.The temperature distribution produced by the finite element thermal analysis of the model is used to quantify the maximum allowable internal temperature difference before crack initiation on concrete.This study analyzes the data from one high-rise structure project in Shanghai are used to verify the finite element model developed.Results suggest that reliance on a limiting maximum temperature differential to control cracking in massive concrete applications should be supplemented with a requirement for analysis showing the calculated spatial temperature and stress response to the predicted temperature distribution within the concrete,to ensure that the induced tensile stresses will not exceed the tensile strength of the concrete and so minimize the risk of having thermal cracks at early age. 展开更多
关键词 温度分布 混凝土 施工技术 应力
下载PDF
硼同位素的正热电离质谱法测定新进展
11
作者 张宁 程原原 +6 位作者 李峥岩 邓丽 周晴 罗家馨 周江迪 贺茂勇 文雪琴 《地球化学》 CAS CSCD 北大核心 2024年第3期417-425,共9页
在不同环境下, B具有不同的^(11)B/^(10)B值。因此, B同位素作为一种灵敏的示踪剂被广泛应用于地球化学、环境化学和食品科学等领域。正热电离质谱法(PTIMS)因测试精度高,是测定B同位素组成最精确的方法。本文详细总结了PTIMS测定B同位... 在不同环境下, B具有不同的^(11)B/^(10)B值。因此, B同位素作为一种灵敏的示踪剂被广泛应用于地球化学、环境化学和食品科学等领域。正热电离质谱法(PTIMS)因测试精度高,是测定B同位素组成最精确的方法。本文详细总结了PTIMS测定B同位素组成的基本原理、带材料选择、石墨影响、石墨涂样顺序、点样形式、同质异位素的干扰以及离子峰接收方式,尤其是近几年在静态双接收测定B同位素上取得的成果和最新进展,以促进B同位素地球化学研究的进一步发展。 展开更多
关键词 B同位素 正热电离质谱法 测定 进展
下载PDF
Tidal Effects on the Bottom Thermal Front of North Yellow Sea Cold Water Mass near Zhangzi Island in Summer 2009
12
作者 XIA Yingying BAO Xianwen +3 位作者 SONG Dehai DING Yang WAN Kai YAN Yuhan 《Journal of Ocean University of China》 SCIE CAS CSCD 2019年第4期751-760,共10页
Three seabed-mounted TD/CTD chains and two upward-looking acoustic Doppler current profilers (ADCPs) in the southwest of Zhangzi Island are used and a simultaneous cruise observation in the northern North Yellow Sea (... Three seabed-mounted TD/CTD chains and two upward-looking acoustic Doppler current profilers (ADCPs) in the southwest of Zhangzi Island are used and a simultaneous cruise observation in the northern North Yellow Sea (NYS) is conducted to study temperature variation in the bottom thermal front zone of the NYS Cold Water Mass (NYSCWM) during the summer of 2009. In the flood-ebb tidal cycles, the bottom temperature decreases (increases) during flood (ebb) tides, which are dominated by the tidal-current induced horizontal advection. The ebb tide-induced temperature increase is larger than the flood tide-induced tempera- ture decrease due to seasonal warming. In the spring-neap tidal cycles, the temperature and the vertical temperature structure show notable fortnightly variation from 16 July to 25 August. The bottom temperature increases from neap to spring tides and decreases from spring to neap. The Richardson number demonstrates strengthened vertical mixing during spring tides but enhanced stratifica- tion during neap tides. The spring-neap variation in vertical shear caused by tidal current is the dominant factor that induces the fort- nightly variation in vertical mixing and thus bottom temperature. 展开更多
关键词 TIDAL effect NORTH YELLOW Sea Cold Water mass temperature variation Zhangzi ISLAND thermal front
下载PDF
Geologic-Geophysical Indicators of the Deep Structure of Zones of Geothermal Anomalies for Allocation of Channels of the Deep Heat and Mass Transfer 被引量:4
13
作者 R. A. Umurzakov H. A. Abidov G. Yu. Yuldashev 《Open Journal of Geology》 2017年第9期1452-1463,共12页
On the basis of the analysis of field thermogeochemical data along abnormal zones of a thermal stream in the Bukhara-Khiva, oil-and-gas region of the Turan (Tegermen, Chagakul, Shimoly Alat, Beshtepa) was succeeded to... On the basis of the analysis of field thermogeochemical data along abnormal zones of a thermal stream in the Bukhara-Khiva, oil-and-gas region of the Turan (Tegermen, Chagakul, Shimoly Alat, Beshtepa) was succeeded to obtain important data on a deep structure of sites. Data of gas-chemical and geothermal observations show about confinedness of abnormal concentration of methane to zones of the increased values of the temperature field the measured values of temperatures (Tegermen Square and others). On geoelectric section mines 2-D of inversion of the MT-field depth of 4000 m are lower, among very high-resistance the chemogenic and carbonate deposits of the Paleozoic is traced the subvertical carrying-out abnormal zone. This zone is identified as the channel of a deep heat and mass transfer with which hydrocarbon (HC) deposits are connected. It is shown that electro-investigation when using a geophysical complex can and has to become “advancing” at exploration by oil and gas. 展开更多
关键词 Anomaly of the thermal Field Thermogeochemical Data JUVENILE Gases Channel Heat and mass Transfer DEEP Structure GEOELECTRIC Section Deposits of Oil and Gas
下载PDF
双流路顶空热脱附-气相色谱质谱联用测定水中土臭素和二甲基异莰醇
14
作者 王炼 侯雯倩 +1 位作者 陈相 何洪志 《化学研究与应用》 CAS 北大核心 2024年第9期2203-2209,共7页
建立双流路顶空热脱附-气相色谱质谱联用测定水中土臭素和2-甲基异莰醇的方法。采用双流路顶空提取针将顶空气体进行连续吹扫至冷阱吸附,快速升温解吸,载气反向将待测组分送入气相色谱质谱联用仪分析。对恒温时间、温度等实验条件进行... 建立双流路顶空热脱附-气相色谱质谱联用测定水中土臭素和2-甲基异莰醇的方法。采用双流路顶空提取针将顶空气体进行连续吹扫至冷阱吸附,快速升温解吸,载气反向将待测组分送入气相色谱质谱联用仪分析。对恒温时间、温度等实验条件进行了优化,内标法定量,土臭素和2-甲基异莰醇在2.0~100ng·L^(-1)线性回归相关系数≥0.999,方法最低检出浓度为0.74ng·L^(-1)和1.50ng·L^(-1),5ng·L^(-1)、20ng·L^(-1)和100ng·L^(-1)三个浓度加标回收率在90.3~105%,精密度在1.76~6.91%。方法简便、灵敏、重现性好,可用于环境水和生活饮用水中土臭素和2-甲基异莰醇检测。 展开更多
关键词 顶空热脱附 气相色谱质谱联用 土臭素 2-甲基异莰醇
下载PDF
铁棍山药片热风干燥过程中传热传质规律
15
作者 庞凌云 袁志华 +2 位作者 詹丽娟 李瑜 潘思轶 《食品与机械》 CSCD 北大核心 2024年第8期157-165,共9页
[目的]探明热风干燥过程中铁棍山药片的传质情况,以及干燥空间和山药片的传热情况。[方法]选用7种薄层干燥数学模型对山药片热风干燥曲线进行拟合,找出最适传质动力学模型;测定不同温度下山药的导热系数和比热容,在此基础上利用ANSYS软... [目的]探明热风干燥过程中铁棍山药片的传质情况,以及干燥空间和山药片的传热情况。[方法]选用7种薄层干燥数学模型对山药片热风干燥曲线进行拟合,找出最适传质动力学模型;测定不同温度下山药的导热系数和比热容,在此基础上利用ANSYS软件模拟热风干燥过程中干燥空间温度场变化和山药片温度变化。[结果]Modified Page模型能准确预测不同热风温度条件下山药片的水分变化情况(R2为0.998 96~0.999 86)。热风干燥过程中干燥室空间温度总体呈水平面上距进出风口近处温度高,远处温度稍低,竖直面上呈上高下低的状态,但温差均不大。热风干燥过程中山药片中心处温度最低,外表面温度最高,内外层温差逐渐缩小,前期温度变化较快而后期缓慢,实测值与模拟值间的温差最大达7.75℃,最小仅为0.07℃,说明模拟结果准确度较高。[结论]Modified Page模型和ANSYS软件能够准确模拟热风干燥过程中山药片的传热传质。 展开更多
关键词 铁棍山药 热风干燥 导热系数 比热容 传热与传质
下载PDF
大口径异型方管风量测量数值仿真分析及试验验证
16
作者 贾露 曾永忠 +2 位作者 刘小兵 余志顺 肖文卓 《计量学报》 CSCD 北大核心 2024年第2期199-206,共8页
针对1 m以上大口径异型方管转弯部分长度较短、前后段没有较长的直管,管道内部流场复杂、需准确测量管道流量的问题,进行了数值模拟分析。提出了一种基于变差系数的平均速度评价方法,选出多点最接近管道平均流速的位置,明确传感器插入... 针对1 m以上大口径异型方管转弯部分长度较短、前后段没有较长的直管,管道内部流场复杂、需准确测量管道流量的问题,进行了数值模拟分析。提出了一种基于变差系数的平均速度评价方法,选出多点最接近管道平均流速的位置,明确传感器插入深度和多个测量点的权重系数,拟合出1个以截面平均速度为函数,流场中多点的流速值为自变量的计算公式。在风洞实验台进行流量测量试验,并与数值分析拟合的公式计算值进行比较,满量程相对误差小于0.54%。 展开更多
关键词 流量测量 风洞实验 数值模拟 变差系数法 热质流量计 异型方管
下载PDF
基于代谢组学的绿茶热加工过程中化学成分变化规律解析 被引量:1
17
作者 于帅 许继业 +5 位作者 胡争艳 高健健 陈丹 谭俊峰 林智 戴伟东 《食品科学》 EI CAS CSCD 北大核心 2024年第12期165-175,共11页
为探究高火功绿茶品质的形成机理,基于超高效液相色谱-四极杆轨道阱质谱代谢组学方法对绿茶加工过程样进行分析,重点关注杀青、干燥和焙火等热加工过程中化学成分差异及变化规律。在绿茶不同热加工过程样中共鉴定出125种化合物,包括10... 为探究高火功绿茶品质的形成机理,基于超高效液相色谱-四极杆轨道阱质谱代谢组学方法对绿茶加工过程样进行分析,重点关注杀青、干燥和焙火等热加工过程中化学成分差异及变化规律。在绿茶不同热加工过程样中共鉴定出125种化合物,包括10种黄烷醇类、14种二聚儿茶素类、19种黄酮醇-O-糖苷类、5种黄酮-C-糖苷类、8种N-乙基-2-吡咯烷酮取代的儿茶素(N-ethyl-2-pyrrolidinone-substituted flavan-3-ols,EPSF)类、16种氨基酸类、13种酚酸类、4种有机酸类、11种生物碱类、13种脂类、4种香气糖苷类和8种其他类化合物。偏最小二乘判别分析和热图分析结果表明,绿茶热加工过程中内含成分变化明显,筛选出114种具有显著差异的化合物(P<0.05)。在杀青、干燥、焙火等过程中,大部分儿茶素、二聚儿茶素类化合物含量下降,EPSF类、黄酮-C-糖苷类和脂类化合物含量明显上升;香气糖苷类化合物(苯乙醇樱草糖苷、芳樟醇樱草糖苷和芳樟醇氧化物樱草糖苷等)含量在杀青过程中增加了439%~2497%;N-1-脱氧-D-果糖酰茶氨酸含量在干燥过程中增加了820%~1290%;黄酮醇-O-糖苷类化合物(杨梅素-3-半乳糖苷、山柰酚-3-半乳糖苷、山柰酚-3-阿拉伯糖苷、杨梅素-3-葡萄糖苷和山柰酚-3-葡萄糖苷等)含量在焙火过程中明显下降。本研究可为后续进一步提升绿茶品质提供理论参考。 展开更多
关键词 绿茶 热加工过程 代谢组学 液相色谱-质谱联用 化学成分
下载PDF
热分析质谱技术在微塑料检测领域的应用
18
作者 刘禹慧 韩卓 +2 位作者 巢静波 周涛 宋善军 《中国无机分析化学》 CAS 北大核心 2024年第8期1166-1176,共11页
微塑料作为一种日益受到关注的新型污染物,已被证实广泛存在于全球各地,并随食物链在生态系统中不断富集,对生物安全和人体健康产生风险。热分析质谱技术基于对塑料热解产物的准确测定可以实现复杂基质中微塑料高效的定性定量分析,所提... 微塑料作为一种日益受到关注的新型污染物,已被证实广泛存在于全球各地,并随食物链在生态系统中不断富集,对生物安全和人体健康产生风险。热分析质谱技术基于对塑料热解产物的准确测定可以实现复杂基质中微塑料高效的定性定量分析,所提供的质量浓度数据在一致性和可比性上有着显著优势。热分析质谱技术近年来已逐渐成为微塑料检测中应用最普遍的方法之一。对当前几种常见的热分析质谱方法,如热裂解-气相色谱质谱(Pyr-GC-MS)、热重-质谱(TGA-MS)、热吸附-解吸气相色谱质谱(TED-GC-MS)进行了综述,对其基本原理,应用场景进行总结讨论。通过梳理,提出目前热分析质谱技术仍存在的主要技术挑战,并对热分析质谱技术检测微塑料这一领域的未来研究方向进行了展望。 展开更多
关键词 微塑料 热分析质谱 环境分析 新型污染物
下载PDF
磁质谱高丰度灵敏度阻滞过滤器研制与性能测试
19
作者 袁祥龙 沈小攀 +5 位作者 翟利华 李飞腾 邓虎 徐江 冯磊 李志明 《质谱学报》 EI CAS CSCD 北大核心 2024年第5期600-608,共9页
阻滞过滤器是商用磁质谱仪提高丰度灵敏度的关键部件。本研究基于离子光学基本原理,利用离子光学仿真软件SIMION8.1设计了由5个电极构成的阻滞过滤器,其结构小巧,尺寸仅为(40×50×50) mm3。在能量筛选基础上,该阻滞过滤器还具... 阻滞过滤器是商用磁质谱仪提高丰度灵敏度的关键部件。本研究基于离子光学基本原理,利用离子光学仿真软件SIMION8.1设计了由5个电极构成的阻滞过滤器,其结构小巧,尺寸仅为(40×50×50) mm3。在能量筛选基础上,该阻滞过滤器还具备方向筛选功能,极大地增强了对杂散离子的滤滞能力。将该阻滞过滤器应用于国产热表面电离质谱仪,并进行不同电压条件下传输效率和丰度灵敏度的测试。结果表明,在不影响主离子束传输效率和峰形的基础上,该阻滞过滤器成功将该仪器的丰度灵敏度指标从<2×10^(-6)提升至<5×10^(-9),丰度灵敏度极限为2×10^(-9),优于目前商用热表面电离质谱仪。本文所设计的阻滞过滤器可为国产高性能磁质谱仪的研制提供重要的技术支撑。 展开更多
关键词 热表面电离质谱(TIMS) 丰度灵敏度 阻滞过滤器 杂散离子 传输效率
下载PDF
磷灰石ID-TIMS高精度U-Pb定年方法
20
作者 涂家润 周红英 +3 位作者 崔玉荣 李国占 耿建珍 张健 《岩矿测试》 CAS CSCD 北大核心 2024年第4期533-545,共13页
磷灰石晶体结构呈六方晶系,具有相对高的封闭温度(350~550℃),能够容纳多种元素置换进入晶格内部,是火成岩、沉积岩、变质岩和矿床研究的重要定年矿物。然而,由于磷灰石通常具有较低铀含量和高普通铅含量,精准测定其年龄仍是当前U-Pb测... 磷灰石晶体结构呈六方晶系,具有相对高的封闭温度(350~550℃),能够容纳多种元素置换进入晶格内部,是火成岩、沉积岩、变质岩和矿床研究的重要定年矿物。然而,由于磷灰石通常具有较低铀含量和高普通铅含量,精准测定其年龄仍是当前U-Pb测年技术的一大挑战。本文基于^(208)Pb-^(235)U混合稀释剂,通过优化样品清洗、溶解以及柱色谱分离纯化U和Pb等化学前处理流程,建立了磷灰石同位素稀释-热电离质谱(ID-TIMS)高精度U-Pb定年方法,并准确测定了磷灰石标样MAD2和MAP-3的年龄,其^(206)Pb/^(238)U年龄加权平均值分别为474.6±1.7Ma和800.7±1.2Ma,单点定年精度优于0.4%,为磷灰石微区原位标样研发以及样品年龄精准测定提供技术支撑。采用MAP-3作为微区原位校正标样,对磷灰石Durango和Otter Lake进行LA-ICP-MS U-Pb测年分析,通过Tera-Wasserburg谐和图图解法扣除普通铅,获得下交点年龄分别为32.1±0.6Ma(MSWD=1.3,n=36)和910±13Ma(MSWD=1.6,n=36),与前人研究结果在误差范围内一致,进一步证实普通铅含量极低的MAP-3,是一个理想的磷灰石微区原位测年标样。与高普通铅的磷灰石标样相比,使用MAP-3作为外标能直接在数据处理软件中进行数据校正,有效地简化了数据处理过程,提高磷灰石微区原位U-Pb测年结果的可靠性。 展开更多
关键词 同位素稀释-热电离质谱法 U-PB定年 稀释剂 普通铅 标样
下载PDF
上一页 1 2 58 下一页 到第
使用帮助 返回顶部