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STRUCTURE AND THERMAL MECHANICAL PROPERTIES OF ORIENTED POLYIMIDE (PEI-E)
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作者 孙振华 庄宇钢 +2 位作者 李诗春 丁孟贤 冯之榴 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1992年第2期145-151,共7页
The strain induced crystallization behaviour in polyimide from 1,4-bis (3', 4'- dicarboxyphenoxy)benzene and 4,4'-oxydianiline (PEI-E)has been investigated by WAXD, DSC and FTIR. The results obtained show ... The strain induced crystallization behaviour in polyimide from 1,4-bis (3', 4'- dicarboxyphenoxy)benzene and 4,4'-oxydianiline (PEI-E)has been investigated by WAXD, DSC and FTIR. The results obtained show that crystallization in PEI-E did take place just after tensile yielding. Meanwhile, the effect of strain induced crystallization on the thermomechanical properties was studied by DMA and TMA, the results of which indicate that the crystallization and hot stretching have a certain influence on the dynamic mechanical properties, such as weakening the β relaxation and decreasing the glass transition temperature. The TMA results confirm the shifting of glass transition temperature to lower temperature region after hot stretching. This phenomenon could be well explained by the effect of residual stress according to Eyring's theory. 展开更多
关键词 POLYIMIDE Strain induced crystallization thermal mechanical property
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Composite Panels from the Combination of Rice Husk and Wood Chips with a Natural Resin Based on Tannins Reinforced with Sugar Cane Molasses Intended for Building Insulation: Physico-Mechanical and Thermal Properties
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作者 Paul Nestor Djomou Djonga Rosellyne Serewane Deramne +2 位作者 Gustave Assoualaye Ahmat Tom Tégawendé Justin Zaida 《Journal of Materials Science and Chemical Engineering》 2024年第2期19-30,共12页
The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips an... The objective of this work is to develop new biosourced insulating composites from rice husks and wood chips that can be used in the building sector. It appears from the properties of the precursors that rice chips and husks are materials which can have good thermal conductivity and therefore the combination of these precursors could make it possible to obtain panels with good insulating properties. With regard to environmental and climatic constraints, the composite panels formulated at various rates were tested and the physico-mechanical and thermal properties showed that it was essential to add a crosslinker in order to increase certain solicitation. an incorporation rate of 12% to 30% made it possible to obtain panels with low thermal conductivity, a low surface water absorption capacity and which gives the composite good thermal insulation and will find many applications in the construction and real estate sector. Finally, new solutions to improve the fire reaction of the insulation panels are tested which allows to identify suitable solutions for the developed composites. In view of the flame tests, the panels obtained are good and can effectively combat fire safety in public buildings. 展开更多
关键词 Composite Panels Tannins Reinforced Sugar Cane Molasses Building Insulation mechanical and thermal properties
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Chemical, mechanical, and thermal expansion properties of a carbon nanotube-reinforced aluminum nanocomposite 被引量:2
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作者 Manjula Sharma Vimal Sharma 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2016年第2期222-233,共12页
In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube(CNT)-based crystalline nano-aluminum(nano Al) composite were reported.The properties of nanocomposites wer... In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube(CNT)-based crystalline nano-aluminum(nano Al) composite were reported.The properties of nanocomposites were tailored by incorporating CNTs into the nano Al matrix using a physical mixing method.The elastic moduli and the coefficient of thermal expansion(CTE) of the nanocomposites were also estimated to understand the effects of CNT reinforcement in the Al matrix.Microstructural characterization of the nanocomposite reveals that the CNTs are dispersed and embedded in the Al matrix.The experimental results indicate that the incorporation of CNTs into the nano Al matrix results in the increase in hardness and elastic modulus along with a concomitant decrease in the coefficient of thermal expansion The hardness and elastic modulus of the nanocomposite increase by 21%and 20%,respectively,upon CNT addition.The CTE of CNT/A1 nanocomposite decreases to 70%compared with that of nano Al. 展开更多
关键词 metal matrix composites carbon nanotubes nanocomposites chemical properties thermal expansion mechanical properties
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Effect of nonuniform sintering on mechanical and thermal properties of silica-based ceramic cores 被引量:1
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作者 Zhi-ping Pan Jian-zheng Guo +1 位作者 Shuang-ming Li Xu-guang Li 《China Foundry》 SCIE CAS 2021年第5期457-462,共6页
During sintering of the silica-based ceramic core of turbine blades,a phenomenon called"nonuniform sintering"occurs that negatively affects the thermal and mechanical properties of the core.Standard samples ... During sintering of the silica-based ceramic core of turbine blades,a phenomenon called"nonuniform sintering"occurs that negatively affects the thermal and mechanical properties of the core.Standard samples of silica-based core were prepared by an injection molding method and sintered with alumina backfilling powder with different sodium contents.The effect of sodium content on the nonuniform sintering of silica-based cores and the thermal and mechanical properties was evaluated.Results show that the sintering level and the content ofα-cristobalite in the surface layer are significantly higher than that of the sample interior.A considerable number of microcracks are found in the surface layer due to theβtoα-phase transition of cristobalite.As the sodium content in the alumina powder decreases,the level of the nonuniform sintering and the amount of crystallized cristobalite in the surface layer decrease,which is beneficial to the thermal expansion and flexural strength at ambient temperature.The flexural strength and thermal deformation at high temperature are improved by reducing the surface cracks,but deteriorated with the decrease of the cristobalite crystallization when the surface cracks are macroscopically invisible. 展开更多
关键词 silica-based ceramic core non-uniform sintering alkali metal content mechanical and thermal properties
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Mechanical and Thermal Expansion Properties of SiCp/ZAlSi9Mg Composites Produced by Centrifugal Casting 被引量:2
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作者 王开 jiang tao +3 位作者 huang zhili xue hansong yang dazhuang zhu zizong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2016年第1期197-203,共7页
Centrifugal casting was applied to produce cylindrical castings using SiCp/Al composite slurry,which contained 20%SiC particles.The castings comprised a particle free zone and a particle rich zone.The amount of SiC pa... Centrifugal casting was applied to produce cylindrical castings using SiCp/Al composite slurry,which contained 20%SiC particles.The castings comprised a particle free zone and a particle rich zone.The amount of SiC particles had a dramatic transformation from the particle rich zone to the particle free zone,and the maximum content of SiC particles in the particle rich zone reached up to 40 vol%.The ultimate tensile strength(UTS) of the as-cast SiCp / Al composites in the particle rich zone was 143 MPa,and the fracture was caused by the desorption of SiC particles from matrix alloy.The coefficient of thermal expansion(CTE) of the SiC_p / Al composites in the range of 20 and 100 ℃ was determined as 16.67×10^(-6) s^(-1),and the experimental CTE was lower than the predicted data based on the Kerner's model.The results show that the decrease in CTE in the case of the composites at high temperature stage can be attributed to the solute concentration of Si in Al and the plastic deformation of the matrix alloy in the composites with void architecture. 展开更多
关键词 metal-matrix composites aluminum thermal expansion property mechanical property casting
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Mechanical, electrical, and thermal expansion properties of carbon nanotube-based silver and silver–palladium alloy composites 被引量:3
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作者 Hemant Pal Vimal Sharma 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第11期1132-1140,共9页
The mechanical, electrical, and thermal expansion properties of carbon nanotube(CNT)-based silver and silver–palladium(10:1, w/w) alloy nanocomposites are reported. To tailor the properties of silver, CNTs were ... The mechanical, electrical, and thermal expansion properties of carbon nanotube(CNT)-based silver and silver–palladium(10:1, w/w) alloy nanocomposites are reported. To tailor the properties of silver, CNTs were incorporated into a silver matrix by a modified molecular level-mixing process. CNTs interact weakly with silver because of their non-reactive nature and lack of mutual solubility. Therefore, palladium was utilized as an alloying element to improve interfacial adhesion. Comparative microstructural characterizations and property evaluations of the nanocomposites were performed. The structural characterizations revealed that decorated type-CNTs were dispersed, embedded, and anchored into the silver matrix. The experimental results indicated that the modification of the silver and silver–palladium nanocomposite with CNT resulted in increases in the hardness and Young's modulus along with concomitant decreases in the electrical conductivity and the coefficient of thermal expansion(CTE). The hardness and Young's modulus of the nanocomposites were increased by 30%?40% whereas the CTE was decreased to 50%-60% of the CTE of silver. The significantly improved CTE and the mechanical properties of the CNT-reinforced silver and silver–palladium nanocomposites are correlated with the intriguing properties of CNTs and with good interfacial adhesion between the CNTs and silver as a result of the fabrication process and the contact action of palladium as an alloying element. 展开更多
关键词 metal matrix composites carbon nanotubes mechanical properties coefficient of thermal expansion electrical conductivity
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Influence of Yb_2O_3-MgO on Mechanical Properties and Thermal Conductivity of Silicon Nitride Ceramics via Gas Pressure Sintering 被引量:2
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作者 LIN Sen YAO Dongxu +3 位作者 XIA Yongfeng ZUO Kaihui YIN Jinwei ZENG Yuping 《China's Refractories》 CAS 2015年第3期34-39,共6页
In this work,Yb2O3 and Mg O were used as sintering aids in preparing silicon nitride ceramics by gas pressure sintering( 0. 6 MPa N2atmosphere) to investigate how the amounts of Yb2O3- Mg O influence the mechanical ... In this work,Yb2O3 and Mg O were used as sintering aids in preparing silicon nitride ceramics by gas pressure sintering( 0. 6 MPa N2atmosphere) to investigate how the amounts of Yb2O3- Mg O influence the mechanical properties and thermal conductivity of silicon nitride ceramics. The total contents of Yb2O3- Mg O added were 1 mol%,2 mol%,4 mol%,6 mol%,8 mol%,10 mol%,12 mol%,14 mol%,keeping the Yb2O3-Mg O molar ratio of 1 ∶ 1 steadily. Curves of the relative density,thermal conductivity and bending strength plotted against the aids content present a ‘mountain'shape with a maximum at nearly 10 mol% aids. The fracture toughness increased with the amounts of additives up to10 mol% and decreased slightly thereafter. The mechanical properties and thermal conductivity were almost proportional to the amount of the additives before10 mol%. When the content of aids exceeded 10 mol%,it would weaken the mechanical properties and thermal conductivity of the ceramics. The optimum content of Yb2O3- Mg O was 10 mol% by gas pressure sintering( 0. 6MPa) at 1 850 ℃ for 4 h,which led to a relative density of 98. 9%,a flexural strength of( 966 ± 38)MPa as well as a fracture toughness of( 6. 29 ± 0. 29)MPa·m1 /2and thermal conductivity of 82 W /( m·K). 展开更多
关键词 silicon nitride sintering mechanical properties thermal conductivity
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Thermal Expansion and Mechanical Properties of Middle Reinforcement Content SiCp/Al Composites Fabricated by PM Technology 被引量:1
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作者 郝世明 谢敬佩 +3 位作者 WANG Aiqin WANG Wenyan LI Jiwen SUN Haoliang 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第4期660-664,共5页
Middle reinforcement content SiCp/Al composites(Vp=30%, 35% and 40%) for precision optical systems applications were fabricated by powder metallurgy technology. The composites were free of porosity and SiC particles... Middle reinforcement content SiCp/Al composites(Vp=30%, 35% and 40%) for precision optical systems applications were fabricated by powder metallurgy technology. The composites were free of porosity and SiC particles distributed uniformly in the composites. The mean linear coefficients of thermal expansion(20-100 ℃) of SiCp/Al composites ranged from 11.6×10-6 to 13.3×10-6 K-1 and decreased with an increase in volume fraction of SiC content. The experimental coeffi cients of thermal expansion agreed well with predicted values based on Kerner's model. The Brinell hardness increased from 116 to 147, and the modulus increased from 99 to 112 GPa for the corresponding composites. The tensile strengths were higher than 320 MPa, but no signifi cant increasing trend between tensile strength and SiC content was observed. 展开更多
关键词 metal-matrix composites particle-reinforcement coefficient of thermal expansion mechanical properties powder metallurgy
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The Thermal and Mechanical Properties of Ultra-High Molecular Weight Polyethylene/Montmorillonite (UHMWPE/MMT) Nanocomposites Hybrid Gel Using Pressure-Induced Flow (PIF) Processing
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作者 BABIKER Musa E 张森 +3 位作者 冯小玲 王广成 汤轶飞 余木火 《Journal of Donghua University(English Edition)》 EI CAS 2011年第2期158-164,共7页
Hybrid organic-inorganic polymer nanocomposites incorporating organically modified montmorillonite (MMT) and ultra-high molecular weight polyethylene (UHMWPE) were examined. UHMWPE/MMT hybrid nanocomposites were prepa... Hybrid organic-inorganic polymer nanocomposites incorporating organically modified montmorillonite (MMT) and ultra-high molecular weight polyethylene (UHMWPE) were examined. UHMWPE/MMT hybrid nanocomposites were prepared using gel and pressure-induced flow(PIF) processing methods at a gel weight concentration of 8% UHMWPE with various organoclay contents (0, 0.4, 0.8, 1.2, and 1.6 parts per hundred parts). The interlayer properties of the nanocomposites were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The thermal and mechanical interfacial properties of the nanocomposites were investigated through thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and the use of a universal test machine (UTM). TEM indicates that the nanocomposites are formed upon dispersion of MMT in the polymer matrix. From the DSC, TGA, and DMA results, we find that the thermal stability of the UHMWPE nanocomposites increases as the MMT content increases. The nanocomposites show higher tensile strengths than pure UHMWPE gel sheet. These findings indicate that the interfacial and mechanical properties are improved by the addition of MMT and PIF processing. 展开更多
关键词 UHMWPE/MMT clay nanocomposites gel processing pressure-induced flow PIF processing mechanical and thermal properties
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Comparison of the effect of carbon,halloysite and titania nanotubes on the mechanical and thermal properties of LDPE based nanocomposite films
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作者 Khaliq Majeed Mariam Al Ali AlMaadeed Moustafa M.Zagho 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第2期428-435,共8页
In this study, titania nanotubes (TNTs) were prepared by hydrothermal method with the aim to compare the properties of these one-dimensional tubular nanostructures' reinforced nanocomposites with the carbon and hal... In this study, titania nanotubes (TNTs) were prepared by hydrothermal method with the aim to compare the properties of these one-dimensional tubular nanostructures' reinforced nanocomposites with the carbon and halloysite nanotubes' (CNTs and HNTs, respectively) reinforced nanocomposites. Low density polyethylene (LDPE) was used as the matrix material. The prepared nanocomposites were characterized and compared by means of their morphological, mechanical and thermal properties. SEM results showed enhanced interracial interaction and better dispersion of TNTs and HNTs into LDPE with the incorporation of a MAPE compatibilizer, however, these interactions seem to be absent between CNTs and LDPE, and the CNTs remained agglomerated. Contact angle measurements revealed that CNT filled nanocomposites are more hydrophilic than HNT composites, and less than TNT composites. CNTs provided better tensile strength and Young's modulus than HNT and TNT nanocomposites, a 42% increase in tensile strength and Young's modulus is achieved compared to LDPE. Tear strength improvement was noticed in the TNT composites with a value of 35.4 N. mm -1, compared to CNT composites with a value of 25.5 N.mm 1 -s- 1. All the prepared nanocomposites are more thermally stable than neat LDPE and the best improvement in thermal stability was observed for CNT reinforced nanocomposites. CNTs depicted the best improvement in tensile and thermal properties and the MAPE compatibilizer effective- ness regarding morphological, mechanical and thermal properties was only observed for TNT and HNT systems. 展开更多
关键词 Hydrothermal Nanostructure Nanotube Nanocomposite mechanical properties thermal properties
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Microstructure,elastic/mechanical and thermal properties of CrTaO_(4):A new thermal barrier material?
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作者 Shuang Zhang Xiaohui Wang +6 位作者 Chao Zhang Huimin Xiang Yingwei Li Cheng Fang Mingliang Li Hailong Wang Yanchun Zhou 《Journal of Advanced Ceramics》 SCIE EI CAS CSCD 2024年第3期373-387,共15页
CrTaO_(4)(or Cr_(0.5)Ta_(0.5)O_(2))has been unexpectedly found to play a decisive role in improving the oxidation resistance of Cr and Ta-containing refractory high-entropy alloys(RHEAs).This rarely encountered comple... CrTaO_(4)(or Cr_(0.5)Ta_(0.5)O_(2))has been unexpectedly found to play a decisive role in improving the oxidation resistance of Cr and Ta-containing refractory high-entropy alloys(RHEAs).This rarely encountered complex oxide can effectively prevent the outward diffusion of metal cations from the RHEAs.Moreover,the oxidation kinetics of CrTaO_(4)-forming RHEAs is comparable to that of the well-known oxidation resistant Cr_(2)O_(3)-and Al_(2)O_(3)-forming Ni-based superalloys.However,CrTaO_(4)has been ignored and its mechanical and thermal properties have yet to be studied.To fill this research gap and explore the untapped potential for its applications,here we report for the first time the microstructure,mechanical and thermal properties of CrTaO_(4)prepared by hot-press sintering of solid-state reaction synthesized powders.Using the HAADF and ABF-STEM techniques,rutile crystal structure was confirmed and short range ordering was directly observed.In addition,segregation of Ta and Cr was identified.Intriguingly,CrTaO_(4)exhibits elastic/mechanical properties similar to those of yttria stabilized zirconia(YSZ)with Young’s modulus,shear modulus,and bulk modulus of 268,107,and 181 GPa,respectively,and Vickers hardness,flexural strength,and fracture toughness of 12.2±0.44 GPa,142±14 MPa,and 1.87±0.074 MPa·m^(1/2).The analogous elastic/mechanical properties of CrTaO_(4)to those of YSZ has spurred inquiries to lucrative leverage it as a new thermal barrier material.The measured melting point of CrTaO_(4)is 2103±20 K.The anisotropic thermal expansion coefficients areα_(a)=(5.68±0.10)×10^(-6)K^(-1),α_(c)=(7.81±0.11)×10^(-6)K^(-1),with an average thermal expansion coefficient of(6.39±0.11)×10^(-6)K^(-1).The room temperature thermal conductivity of CrTaO_(4)is 1.31 W·m^(-1)·K^(-1)and declines to 0.66 W·m^(-1)·K^(-1)at 1473 K,which are lower than most of the currently well-known thermal barrier materials.From the perspective of matched thermal expansion coefficient,CrTaO_(4)pertains to an eligible thermal barrier material for refractory metals such as Ta,Nb,and RHEAs,and ultrahigh temperature ceramics.As such,this work not only provides fundamental microstructure,elastic/mechanical and thermal properties that are instructive for understanding the protectiveness displayed by CrTaO_(4)on top of RHEAs but also outreaches its untapped potential as a new thermal barrier material. 展开更多
关键词 MICROSTRUCTURE SYNTHESIS thermal conductivity thermal expansion coefficient melting point CrTaO_(4) mechanical and thermal properties
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Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand 被引量:3
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作者 Yan-lei Li Guo-hua Wu +3 位作者 Wen-cai Liu An-tao Chen Liang Zhang Ying-xin Wang 《China Foundry》 SCIE 2017年第2期128-137,共10页
In this work, the effects of reclaimed sand additions on the microstructure characteristics, mechanical properties and fracture behavior of furan no-bake resin sand have been investigated systematically within the tem... In this work, the effects of reclaimed sand additions on the microstructure characteristics, mechanical properties and fracture behavior of furan no-bake resin sand have been investigated systematically within the temperature range from 25 to 600 oC. The addition of 20%-100% reclaimed sand showed dramatic strength deterioration effect at the same temperature, which is associated with the formation of bonding bridges. Both the ultimate tensile strength(UTS) and compressive strength(CS) of the moulding sand initially increase with the increase of temperature, and then sharply decrease with the further increase of temperature, which is attributed to the thermal decomposition of furan resin. The addition amount of reclaimed sand has a remarkable effect on the room temperature fracture mode, i.e., with the addition of 0-20% reclaimed sand, the fracture mode was mainly cohesive fracture; the fracture mode converts to be mixture fracture mode as the addition of reclaimed sand increases to 35%-70%; further increasing the addition to 100% results in the fracture mode of typical adhesive fracture. The fracture surface of the bonding bridge changes from a semblance of cotton or holes to smooth with the increase of test temperature. 展开更多
关键词 reclaimed sand mechanical properties thermal decomposition fracture mode
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Effect of microstructure on the mechanical, thermal, and electronic property measurement of ceramic coatings
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作者 Xiaojuan Lu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第11期1127-1131,共5页
Ceramic materials were investigated as thermal barrier coatings and electrolytes. Electrophoretic deposition(EPD) and physical vapor deposition(PVD) were employed to fabricate samples, and the mechanical propertie... Ceramic materials were investigated as thermal barrier coatings and electrolytes. Electrophoretic deposition(EPD) and physical vapor deposition(PVD) were employed to fabricate samples, and the mechanical properties and microstructure were examined by nanoindentation and microscopy, respectively. Yttria-stabilized zirconia/alumina(YSZ/Al2O3) composite coatings, a candidate for thermal barrier coatings, yield a kinky, rather than smooth, load–displacement curve. Scanning electron microscope(SEM) examination reveals that the kinky curve is because of the porous microstructure and cracks are caused by the compression of the indenter. Li0.34La0.51 Ti O2.94(LLTO) on Si/Sr Ru O3(Si/SRO) substrates, an ionic conductor in nature, demonstrates electronic performance. Although SEM images show a continuous and smooth microstructure, a close examination of the microstructure by transmission electron microscopy(TEM) reveals that the observed spikes indicate electronic performance. Therefore, we can conclude that ceramic coatings could serve multiple purposes but their properties are microstructure-dependent. 展开更多
关键词 ceramic coatings mechanical properties thermal properties electronic properties microstructure electron microscopy
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A novel route to enhance high-temperature mechanical property and thermal shock resistance of low-carbon Mgo-C bricks by introducing ZrSiO_(4)
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作者 Chun-hui Sun Ling-ling Zhu +6 位作者 Hao Yan Wei Zhao Jing-xuan Liu Lin Ren Xian-tang Zhao Xiao-song Tong Shu-wen Yu 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2024年第6期1436-1448,共13页
Conventional MgO-C bricks(graphite content>14 wt.%)produce a great deal of greenhouse gas emission,while low-carbon MgO-C bricks have serious thermal shock resistance during high-temperature service.To enhance the ... Conventional MgO-C bricks(graphite content>14 wt.%)produce a great deal of greenhouse gas emission,while low-carbon MgO-C bricks have serious thermal shock resistance during high-temperature service.To enhance the high-temperature mechanical property and thermal shock resistance of low-carbon MgO-C bricks,a novel route of introducing ZrSiO_(4) powder into low-carbon MgO-C bricks was reported in such refractories with 2 wt.% flaky graphite.The results indicate that the low-carbon MgO-C brick with 0.5 wt.%ZrSiO_(4) addition has the maximum hot modulus of rupture at 1400℃ and the corresponding specimen fired in the carbon embedded atmosphere has the maximum residual strength ratio(98.6%)after three thermal shock cycles.It is found that some needle-like AlON and plate-like Al_(2)O_(3)-ZrO_(2) composites were in situ formed in the matrices after the low-carbon MgO-C bricks were coked at 1400℃,which can enhance the high-temperature mechanical property and thermal shock resistance due to the effect of fiber toughening and particle toughening.Moreover,CO_(2) emission of the newly developed low-carbon MgO-C bricks is reduced by 58.3% per ton steel after using them as the working lining of a 90 t vacuum oxygen decarburization ladle. 展开更多
关键词 Low-carbon MgO-C brick ZrsiO_(4) Synergistic toughening effect High-temperature mechanical property thermal shock resistance Vacuum oxygen decarburization ladle
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Photopolymerization of Dendritic Acrylated Aromatic/Aliphatic Polyesters and Properties of Their Cured Films
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作者 XU Gang LIANG Hong-bo +1 位作者 SHI Wen-fang BAO Jin-wen 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2002年第3期354-357,共4页
The radiative curable dendritic acrylated aromatic/aliphatic polyesters based on pentaerythritol, 1,2,4 benzenetricaboxylic anhydride and epoxy propane modified with acryloyl chloride were synthesized via a diver... The radiative curable dendritic acrylated aromatic/aliphatic polyesters based on pentaerythritol, 1,2,4 benzenetricaboxylic anhydride and epoxy propane modified with acryloyl chloride were synthesized via a divergent procedure, and their photopolymerization kinetics was studied by photo differential scanning calorimetry. The mechanical properties and the morphology of the fracture surface of the cured dendritic polyester films were investigated by means of dynamic mechanical thermal analysis and scanning electron microscopy, respectively. 展开更多
关键词 Dendritic polyester Radiation curing Photopolymerization kinetics thermal mechanical property
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Thermal Characterization of Lauric Acid and Stearic Acid Binary Eutectic Mixture in Latent Heat Thermal Storage Systems with Tube and Fins
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作者 丁磊 WANG Lixiong +2 位作者 Georgios Kokogiannakis Lü Yajun 周卫兵 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第4期753-759,共7页
In order to obtain the suitable phase change material(PCM) with low phase change temperature and improve its heat transfer rate, experimental investigation was conducted. Firstly, different mass ratios of lauric aci... In order to obtain the suitable phase change material(PCM) with low phase change temperature and improve its heat transfer rate, experimental investigation was conducted. Firstly, different mass ratios of lauric acid(LA) and stearic acid(SA) eutectic mixtures were prepared and characterized by differential scanning calorimetry(DSC). Then, the performance of eutectic mixture during charging process under different fin widths in vertical condition, and performance during charging and discharging processes under different inlet temperature heat transfer fluid(HTF) in horizontal condition were investigated, respectively. The results revealed that the LA-SA eutectic mixture had the suitable phase change temperature and desired latent heat for low-temperature water floor heating system. Wide fins and high inlet temperature HTF significantly enhanced the transfer rate and decreased the melting time. 展开更多
关键词 LA-SA binary eutectic mixture thermal properties heat exchanger heat transfer mechanism
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Thermal,physical and mechanical properties of hydrogenated dimer acid-based Nylon 636/Nylon 66 copolymers 被引量:4
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作者 Feng Jia Jin-Long Mao +2 位作者 Xue-Yun Yang Yan Ma Cheng Yao 《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第7期654-658,共5页
Hydrogenated dimer acid-based Nylon 636/Nylon 66 copolymers were synthesized by in situ polymerization. The effects of Nylon 66 contents on the copolymers were characterized by intrinsic viscosity measurements, attenu... Hydrogenated dimer acid-based Nylon 636/Nylon 66 copolymers were synthesized by in situ polymerization. The effects of Nylon 66 contents on the copolymers were characterized by intrinsic viscosity measurements, attenuated total reflection-Fourier transform infrared spectroscopy, X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis and mechanical tests. The results showed that incorporation of Nylon 66 into hydrogenated dimer acid-based Nylon had no significant effect on the glass transition or melting temperatures. However, the crystallization temperature, crystallinity degree and the maximum rate of decomposition temperature from derivative thermogravimetry measurements vary. Mechanical testing data revealed that with increasing Nylon 66 concentrations, the tensile strength of copolymers increased, while the elongation at break point and notched izod impact strength decreased. The physical and mechanical properties of HN-40, HN-50 and HN-60 are similar to those of the current PAl 1, PAl212, and PAlll 1 Nylon products. 展开更多
关键词 Nylon Hydrogenated dimer acid thermal properties mechanical properties
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Synthesis and Characterization of Fluorinated Polyurethane Containing Carborane in the Main Chain: Thermal, Mechanical and Chemical Resistance Properties 被引量:5
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作者 Ning Li Fang-Lei Zeng +5 位作者 Yu Wang De-Zhi Qu Chun Zhang Juan Li Jin-Zhao Huo Yong-Ping Bai 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2018年第1期85-97,共13页
In this study, two fluorinated polyurethanes(FPU) containing carborane groups in the main chains were firstly designed and synthesized via the reaction of hexamethylene diisocyanate trimer(HDI trimer) with fluorin... In this study, two fluorinated polyurethanes(FPU) containing carborane groups in the main chains were firstly designed and synthesized via the reaction of hexamethylene diisocyanate trimer(HDI trimer) with fluorinated polyesters(CFPETs) having hydroxyl-terminated carborane groups at room temperature. The structures of carborane fluorinated polyesters(CFPETs) and polyurethanes(CFPUs) were characterized by gel permeation chromatography(GPC), Fourier transform infrared(FTIR) spectroscopy and nuclear magnetic resonance(NMR) measurements. The thermal stability, mechanical properties, Shore A hardness, solvent resistance and acid-alkali resistance of the carborane fluorinated polyurethane films were also studied. Thermogravimetric analysis(TGA) tests manifested that the introduction of carborane groups into the main chain of fluorinated polyurethane endowed the obtained fluorinated polyurethane with excellent thermal stability. The thermal decomposition temperature of carborane fluorinated polyurethane(CFPU) increased by 190 °C compared with that of the carborane-free fluorinated polyurethane(FPU). Even at 800 °C, CFPU showed the char yield of 66.5%, which was higher than that of FPU(34.3%). The carborane-containing fluorinated polyurethanes also showed excellent chemical resistance and prominent mechanical property even after the cured films being immersed into Jet aircraft oil or 37% HCl for 168 h or at high temperature(700 °C). It is found that the structural characteristics of carborane group and the compacted structure of CFPU effectively improve the thermal stability, mechanical property, solvent resistance and acid-alkali resistance of the carborane-free fluorinated polyurethane. These excellent properties make CFPU as the useful raw materials to prepare the high temperature resistant coatings or adhesives for automotive engines, engine or fuel tank of aircraft and other equipment working in high-temperature or high concentrations of acid-alkali environments. 展开更多
关键词 Fluorinated polyurethane Carborane thermal stability mechanical property Chemical resistance
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Simultaneous Improvements of Thermal Stability and Mechanical Properties of Poly(propylene carbonate) via Incorporation of Environmental-friendly Polydopamine 被引量:2
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作者 Yu-han Li Mi Zhou +2 位作者 Cheng-zhen Geng 陈枫 傅强 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2014年第12期1724-1736,共13页
Inspired by the photoprotection, radical scavenging of melanin together with versatile adhesive ability of mussel proteins, polydopamine(PDA) nanoparticles were successfully prepared and incorporated into environmen... Inspired by the photoprotection, radical scavenging of melanin together with versatile adhesive ability of mussel proteins, polydopamine(PDA) nanoparticles were successfully prepared and incorporated into environmentally friendly polymer, poly(propylene carbonate)(PPC) via solvent blending. The prepared composites exhibited excellent thermal stability in air and nitrogen atmosphere and extraordinary mechanical properties. The composites displayed eminent increase of temperature at 5% weight loss(T5%) by 30-100 K with 0.3 wt%-2.0 wt% loadings, meanwhile, the tensile strength and Young's modulus were significantly improved from 11.5 MPa and 553.7 MPa to 40.5 MPa and 2411.2 MPa, respectively. The kinetic calculation indicated that improvement of T5% is presumably derived from suppressing chain-end unzipping. The glass transition temperature(Tg) of the PPC/PDA composites increased by 8-10 K. This is probably due to hydrogen bonding interaction since the abundant proton donors along PDA chains would interact with proton acceptors like C = O and C―O―C in PPC which would cause restriction of segmental motion of PPC chains. 展开更多
关键词 Biodegradable polymers Reinforcements mechanical properties thermal properties Free radical scavenging
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MORPHOLOGY, CRYSTALLIZATION AND MECHANICAL PROPERTIES OF POLY(ε-CAPROLACTONE)/GRAPHENE OXIDE NANOCOMPOSITES 被引量:2
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作者 Guang-shuo Wang 魏志勇 +4 位作者 Lin Sang Guang-yi Chen Wan-xi Zhang Xu-feng Dong 齐民 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2013年第8期1148-1160,共13页
A series of nanocomposites based on poly(ε-caprolactone) (PCL) and graphene oxide (GO) were prepared by in situ polymerization. Scanning electron microscopy observation revealed not only a well dispersion of GO... A series of nanocomposites based on poly(ε-caprolactone) (PCL) and graphene oxide (GO) were prepared by in situ polymerization. Scanning electron microscopy observation revealed not only a well dispersion of GO but also a strong interfacial interaction between GO and the PCL matrix, as evidenced by the presence of some GO nanosheets embedded in the matrix. Effects of GO nanofillers on the crystal structure, crystallization behavior and spherulitic morphology of the PCL matrix were investigated in detail. The results showed that the crystallization temperature of PCL enhanced significantly due to the presence of GO in the nanocomposites, however, the addition of GO did not affect the crystal structure greatly. Thermal stability of PCL remarkably increased with the addition of GO nanosheets, compared with that of pure PCL. Incorporation of GO greatly improved the tensile strength and Young's modulus of PCL without a significant loss of the elongation at break. 展开更多
关键词 Poly(ε-caprolactone) Graphene oxide MORPHOLOGY thermal and mechanical properties.
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