Monitoring of Large Size Solar Thermal Systems： Design and Data Analysis

This paper describes how to achieve an efficient design and management of a tele-monitoring system of several solar thermal plants. The system will be able to make an analysis that assures a more efficient management of each plant and of the whole system. In the first part of this study, the features of the monitoring system that allows to monitor the operating parameters and to discover the issues before they actually become dangerous for the plant have been identified. The data collected in the different solar thermal systems realized in Italian jails have been analyzed. The results of these elaborations allowed us both to find out some anomalies of functioning of the plants, and to optimize the management of the whole plant in a more efficient way.

Constrained nonlinear MPC for accelerated tracking piece-wise references and its applications to thermal systems

In this paper,we propose a model predictive control(MPC)strategy for accelerated offset-free tracking piece-wise constant reference signals of nonlinear systems subject to state and control constraints.Some special contractive constraints on tracking errors and terminal constraints are embedded into the tracking nonlinear MPC formulation.Then,recursive feasibility and closed-loop convergence of the tracking MPC are guaranteed in the presence of piece-wise references and constraints by deriving some sufficient conditions.Moreover,the local optimality of the tracking MPC is achieved for unreachable output reference signals.By comparing to traditional tracking MPC,the simulation experiment of a thermal system is used to demonstrate the acceleration ability and the effectiveness of the tracking MPC scheme proposed here.

Electrical and thermal performances of photovoltaic/thermal systems with magnetic nanofluids:A review

Enhancing solar photovoltaic and thermal conversion performances may help develop more environmentally friendly hybrid photovoltaic/thermal(PV/T)systems that can be used in applications ranging from household to industrial scales.Owing to their enhanced thermal and optical properties,nanofluids have proven to be good candidates for designing PV/T systems with superior performances.As smart nanofluids,magnetic nanofluids(MNFs)can further enhance the performances of PV/T systems under external magnetic fields.This paper reviews recent developments in enhancing the electrical and thermal performances of PV/T systems using magnetic nanofluids.Various parameters affecting the performances are highlighted,and some areas for further investigations are discussed.The reviewed literature shows that PV/T systems with MNFs are promising.However,their performances need further investigation before they can be used in applications.

Optimisation of Electrical Distribution System by Using Solar Thermal Powered Systems and Its Impact on Electrical Distribution Feeders

In this research, the performance of the solar thermal powered systems (STPS) is analyzed with different models (without inserts, with inserts and with Nano fluids with different concentrations) and its impact on the Electric load in a residential/Institutional Electrical Distribution system. For this purpose, the electrical and solar thermal water heater is tested and validated. Solar thermal powered systems and its impact on the Institutional electrical distribution feeders are tested and compared with the energy efficiency (EE) and cost optimization. The goal of this paper is to analyze the impact of solar thermal energy on electrical energy consumption in the electrical distribution feeder level. The electrical system cost and energy consumptions are tabulated and observed that there is a considerable savings.

Thermal Energy Storage Systems： Power-to-Heat Concepts in Solid Media Storage for High Storage Densities

The German Aerospace Center has merged a wide range of technological research and development for future cars in a project called ＂Next Generation Car＂. Within this large research project, three vehicle concepts for different applications （urban, regional and interurban） and with different powertrains （fuel-cell, battery and hybrid） will be developed. Research questions on different levels from conceptual question about vehicle modularity down to detailed technological aspects like combining hydrogen storage with cabin climatization and a systematic investigation of different thermal energy storage systems for electric vehicles concepts are covered by this project. To the latter, the contribution shows an overview about three thermal storage technologies--sensible solid media, metallic latent and thermochemical thermal energy storage systems--and details about the development of an electrically heated （power-to-heat） solid media storage system to achieve high storage densities and to allow flexible thermal discharging values. Central works target the identification of suitable thermal management solutions in future electric vehicle concepts to increase range, efficiency and flexibility.

Corrosion behavior of pure metals(Ni and Ti)and alloys(316H SS and GH3535)in liquid GaInSn

In this study,the interactions between a Ga-based liquid metal,GaInSn,and several metal materials,including pure metals(Ni and Ti)and alloys(316H stainless steel(SS)and GH3535),at 650℃were investigated.The aim was to evaluate the corrosion performance and select a suitable candidate material for use as a molten salt manometer diaphragm in thermal energy storage systems.The results indicated that the alloys(316H SS and GH3535)exhibited less corrosion than pure metals(Ni and Ti)in liquid GaInSn.Ga-rich binary intermetallic compounds were found to form on the surfaces of all the tested metal materials exposed to liquid GaInSn,as a result of the decomposition of liquid GaInSn and its reaction with the constituent elements of the metal materials.The corrosion mechanism for all the tested materials exposed to liquid GaInSn was also investigated and proposed,which may aid in selecting the optimal candidate material when liquid GaInSn is used as the pressure-sensing medium.

Thermo-Economic Optimization of Solar Thermal Devices by Coherent Integration of Technologies

Radiation is a form of energy where the angular variable of the direction of its photons has a primary importance, particularly for radiation concentration processes, which are essential tools to reach high temperatures from radiation beams (as the solar ones) with moderate intensities. Solar radiation cannot be used directly to feed thermodynamic cycles, and optical concentration must be applied to that goal. In general, reflection from mirrors is preferred to refraction by lenses in this case, because they have less optical aberrations. Concentration conveys very high temperatures in the receiver. However, the higher the temperature, the lower the efficiency of the solar thermal apparatus. Besides that, economy also suffers quite a lot when going to very high concentration factors, which is one of the main burdens in the development of Solar Thermal Energy. A new configuration of solar radiation concentrator is presented. It includes a salient innovation in the way the mirrors are given the right curvature by mechanical forces. Those mirrors are originally flat and do not need any special thermal treatment for this purpose. The whole device concept has been guided by the principle of thermoeconomic coherence, which requires similar efforts in all degrees of freedom that have strong influence in the performance and cost of the system. The paper shows the decision tree that has oriented the project, following the principle of equilibrium in efforts, which leads to a design window of moderate values in the main variables. The prototype of this new configuration has already been built, and the first stage of research is considered to be finished, because the prototype has shown excellent conditions to include selected (fitting) technologies at a very low cost.

Performance Evaluation of New Two Axes Tracking PV-Thermal Concentrator

The overall problem with PV （photovoltaic） systems is the high cost for the photovoltaic modules. This makes it interesting to concentrate irradiation on the PV-module, thereby reducing the PV area necessary for obtaining the same amount of output power. The tracking capability of two-axes tracking unit driving a new concentrating paraboloid for electric and heat production have been evaluated. The reflecting optics consisting of flat mirrors provides uniform illumination on the absorber which is a good indication for optimised electrical production due to series connection of solar cells. The calculated optical efficiency of the system indicates that about 80% of the incident beam radiation is transferred to the absorber. Simulations of generated electrical and thermal energy from the evaluated photovoltaic thermal （PV/T） collector show the potential of obtaining high total energy efficiency.

Influence of Oxygen Pressure on Structural and Sensing Properties of β-Ga2O3 Nanomaterial by Thermal Evaporation

We prepare the gallium oxide （β-Ga2O3） nanomaterials from gallium and oxygen by thermal evaporation in the argon atmosphere and research their oxygen sensing under UV illumination with different oxygen pressures. X-ray diffraction reveals that the synthesized product is monoclinic gallium oxide, it is further confirmed by electron diffraction of transmission electron microscope, and its morphology through the observation using scanning electron microscope reveals thatβ-Ga2O3 nanobelts with a breadth less than lOOnm and length of severai micrometers are synthesized under low oxygen pressure, while the nano/microbelts are synthesized under high oxygen pressure. Room-temperature oxygen sensing is tested under at 254 nm illumination and it is found that the current decreases quickly first and then slowly with oxygen pressure from low to high.

Thermal Properties of Poly（vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate） （PVVH） Polymer and Its Application in ZnO Based Nanogenerators ：

A novel piezoelectricity based nano energy conversion device using vertically aligned ZnO nanowires/PVVH matrix as the working unit is proposed. Thermal energy is converted to electricity via the interaction of the PVVH polymer and ZnO nanowires. The thermal properties of PVVH ave studied using Raman spectroscopy under different temperatures. The results show that the structure of PVVH is sensitive to fluctuations of the environmental temperatures. With the increasing temperature, PVVH tends to be crystallized and stress can be developed inside the polymer. The stress is responsible for the deformation and voltage generation of the ZnO nanowires.

Experimental test of a building thermal system for preventive maintenance based on thermoeconomic analysis

An analysis of the sectorial structure of energy consumption shows that residential and tertiary sector buildings are the third-highest consumers,responsible for 29.5%of a city’s final energy consumption.The Building Quality Control Laboratory of the Basque Government aims to promote quality,innovation,and sustainability in buildings.To accomplish this goal,it has constructed an experimental facility with different energy generation technologies and a very versatile control system for testing different energy systems and operation modes.In this study,we tested a facility for supplying domestic hot water and heating for a multi-family house by means of a condensing boiler and an aerothermal heat pump(together with the corresponding control).This installation could reproduce the thermal demands required to be satisfied by the generation equipment through a programmed operation of the installation based on real demands.Additionally,this installation was analyzed using thermoeconomics(TE)to solve problems unable to be solved using traditional energy analyses based on the First Law of Thermodynamics.These problems include:(1)Determining the costs of the products of the installation based on physical criteria,(2)detecting the places where losses actually occur,evaluating their costs,and proposing cost-effective improvements,and(3)diagnosing issues in the installation.As a result,this paper suggests a solution to the preventive maintenance problems confronting the technical maintenance personnel for thermal installations in buildings by applying TE knowledge and using real data collected from sensors.

Influence of materials’hygric properties on the hygrothermal performance of internal thermal insulation composite systems

Internal thermal insulation composite system(ITICS)can be an important measure for the energy-saving retrofitting of buildings.However,ITICS may cause harmful effects on the hygrothermal performance of building envelopes.This work investigated the influence of the materials’hygric properties on the hygrothermal perfor-mance of a typical ITICS in different climate conditions in China.Two base wall materials,the traditional concrete and a new type aerated concrete,were tested and compared for their hygric properties firstly.The influence of the hygroscopicity of exterior plasters,the permeability of insulation materials and the climate conditions were then analyzed with WUFI simulations.The hygrothermal performance was evaluated with consideration of the total water content(TWC)of the walls and the moisture flux strength,the relative humidity(RH)and the mould growth risk at the interface between the base wall and the insulation layer(B-I interface).The numerical analysis implies that the TWC of internal insulated walls depends mainly on the hygroscopicity of exterior plaster and the wind-driven rain intensity.The upper limits for the water absorption coefficient of exterior plasters used in Bei-jing,Shanghai and Fuzhou are 1e-9,1e-10,1e-10 m^(2)/s respectively.When such limits are guaranteed,a vapour tight system created by using insulation materials with a large vapour resistance factor or adding a vapour barrier can improve the hygrothermal performance of ITICS,especially for concrete walls in cold climate.

Quasi-optimal control of a solar thermal system via neural networks✩

The optimal control of complex thermal energy systems is a challenge due to their dynamic behavior andconstantly changing boundary conditions. To maximize the energy efficiency of such a dynamic system, optimaltrajectories for the controlled variables are needed. Extensive system knowledge is required to model the systemaccurately enough to be able to compute optimal trajectories. The high computational cost of computingoptimal control solutions with traditional approaches, especially with changing boundary conditions, oftenmakes this approach unusable for applications with limited computational power, such as real-time applicationson electronic control units (ECUs). This study investigates a possible solution to this challenge using a simplifiedexample system. Optimal control solutions for different boundary and initial conditions are generated forthe selected solar thermal system using a direct multiple shooting algorithm. Based on Bellman’s optimalityprinciple, the generated solutions are transformed into a data set of optimal state–action pairs. On this basis,different types of neural networks are trained, specifically a feed-forward, a recurrent, and a radial basisfunction network. Thus, data generation and training can be performed offline, and the required online computations are significantly reduced since the evaluation of a trained neural network requires comparatively lowcentral processing unit (CPU) power. The trained neural network controllers are tested for their ability to outputnear-optimal control actions based on the current system state. The feed-forward and recurrent neural networksshow promising initial results in this regard. Open questions and the need for improvements are discussed.

Analytic estimation and numerical modeling of actively cooled thermal protection systems with nickel alloys

Actively cooled thermal protection system has great influence on the engine of a hypersonic vehicle, and it is significant to obtain the thermal and stress distribution in the system. So an analytic estimation and numerical modeling are performed in this paper to investigate the behavior of an actively cooled thermal protection system. The analytic estimation is based on the electric analogy method and finite element analysis（FEA） is applied to the numerical simulation. Temperature and stress distributions are obtained for the actively cooled channel walls with three kinds of nickel alloys with or with no thermal barrier coating（TBC）. The temperature of the channel wall with coating has no obvious difference from the one with no coating, but the stress with coating on the channel wall is much smaller than that with no coating. Inconel X-750 has the best characteristics among the three Ni-based materials due to its higher thermal conductivity, lower elasticity module and greater allowable stress. Analytic estimation and numerical modeling results are compared with each other and a reasonable agreement is obtained.

Preparation of High-Density Nanocrystalline Bulk Selenium by Rapid Compressing of Melt

The melt＇s solidification behavior of elemental selenium is investigated by a series of experiments including rapid compressing to 2.8 and 3.5 GPa within 20ms respectively, slow compressing to 2.8 GPa for 20 min and natural cooling at ambient pressure. Based on the x-ray diffraction, scanning electron microscope and transmission electron microscope results of the recovered samples, it is clearly shown that homogenous nanostructures are formed only by the rapid compression processes, and that the average crystal sizes are about 18.7 and 19.0 nm in the samples recovered from 2.8 and 3.5 GPa, respectively. The relative density of the nanocrystalline bulk reaches 98.17% of the theoretical value. It is suggested that rapid compression could induce pervasive nucleation and restrain grain growth during the solidification, which is related to fast supercooling, higher viscosity of the melt and lower diffusivity of atoms under high pressure.

Synthesis and Properties of Magnetic Composites of Carbon Nanotubes/Fe Nanoparticle

Magnetic composites of carbon nanotubes （CNTs） are synthesized by the in situ catalytic decomposition of benzene at temperatures as low as 400℃ over Fe nanoparticles （mean grain size = 26 nm） produced by sol-gel fabrication and hydrogen reduction. The yield of CNT composite is up to about 3025% in a run of 6 h. FE- SEM and HRTEM investigations reveal that one-dimensional carbon species are produced in a large quantity. A relatively high value of magnetization is observed for the composite due to the encapsulation of ferromagnetic Fe3 C and/or α-Fe. The method is suitable for the mass-production of CNT composites that contain magnetic nanoparticles.

A Unified Guide to Two Opposite Size Effects in Nano Elastic Materials

The microstructural variation near surface of nano elastic materials is analyzed based on different potentials. The atomic/molecular mechanism underlying the variation and its effect on elastic modulus are such that the nature of long-range interactions （attractive or repulsive） in the atomic/molecular potentials essentially governs the variation near surface （looser or tighter） and results in two opposite size effects （decreasing or increasing modulus） with decreasing size.

Production of ZnO Nanobelts and Meso-Scale Study of Mechanical Properties

We investigate a peculiar phenomenon by processing ZnO nanobelts with an atomic force microscope （AFM）. In the contact mode of AFM, peculiar bending occurs in meso-scale when the nanobelt is applied with force in lateral direction. We study the mechanical properties of ZnO nanobelts under the influence of small size effect, with finite element analysis and mathematical analysis by means of Matlab. Based on this abnormal effect, a novel measuring method is proposed, which allows the surface morphology and surface properties to be characterized at the same time.

Growth of Pure Zinc Blende GaAs Nanowires： Effect of Size and Density of Au Nanoparticles

Pure zinc blende GaAs nanowires were grown by metal organic chemical vapor deposition on GaAs（111）B substrates via Au catalyzed vapor-liquid-solid mechanism. The diameter, size distribution, and density of Au particles can be changed by varying the Au film thickness. We find that the grown nanowires are of rod-like shapes and pure zinc blende structure; moreover, the growth rate depends on the density of Au particles and it is independent of its diameters. It can be concluded that the nanowire was grown with main contributions from the direct impingement of vapor species onto the Au-Ga droplets and contributions from adatom diffusion can be negligible. The results indicate that the droplet acts as a catalyst rather than an adatom collector.

Raman Spectrum of Epitaxial Graphene on SiC （0001） by Pulsed Electron Irradiation

We report new Raman features of epitaxial graphene （EG） on Si-face 4H-SiC prepared by pulsed electron irradiation （PEI）. With increasing graphene layers, frequencies of G and 2D peaks show blue-shifts and approach those of bulk highly-oriented pyrolytic graphite. It is indicated that the EG is slightly tension strained and tends to be strain-free. Meanwhile, single Lorentzian line shapes are well fitted to the 2D peaks of EG on SiC（O001） and their full widths at half maximum decrease with the increasing graphene layers, which indicates that the multilayer EG on Si-face can also contain turbostratic stacking by our PEI route instead of only AB Bernal stacking by a traditional thermal annealing method. It is worth noting that the stacking style plays an important role on the charge carrier mobility. Therefore our findings will be a candidate for growing quality graphene with high carrier mobility both on the Si- and C-terminated SiC substrate. Mechanisms behind the features are studied and discussed.