Fretting Wear Behavior of Medium Carbon Steel Modified by Low Temperature Gas Multi-component Thermo-chemical Treatment

The introduction of surface engineering is expected to be an effective strategy against fretting damage. A large number of studies show that the low gas multi-component （such as carbon, nitrogen, sulphur and oxygen, etc） thermo-chemical treatment（LTGMTT） can overcome the brittleness of nitriding process, and upgrade the surface hardness and improve the wear resistance and fatigue properties of the work-pieces significantly. However, there are few reports on the anti-fretting properties of the LTGMTT modified layer up to now, which limits the applications of fretting. So this paper discusses the fretting wear behavior of modified layer on the surface of LZ50 （0.48%C） steel prepared by low temperature gas multi-component thermo-chemical treatment （LTGMTT） technology. The fretting wear tests of the modified layer flat specimens and its substrate （LZ50 steel） against 52100 steel balls with diameter of 40 mm are carried out under normal load of 150 N and displacement amplitudes varied from 2 μm to 40 μm. Characterization of the modified layer and dynamic analyses in combination with microscopic examinations were performed through the means of scanning electron microscope（SEM）, optical microscope（OM）, X-ray diffraction（XRD） and surface profilometer. The experimental results showed that the modified layer with a total thickness of 60 μm was consisted of three parts, i.e., loose layer, compound layer and diffusion layer. Compared with the substrate, the range of the mixed fretting regime（MFR） of the LTGMTT modified layer diminished, and the slip regime（SR） of the modified layer shifted to the direction of smaller displacement amplitude. The coefficient of friction（COF） of the modified layer was lower than that of the substrate in the initial stage. For the modified layer, the damage in partial slip regime（PSR） was very slight. The fretting wear mechanism of the modified layer both in MFR and SR was abrasive wear and delamination. The modified layer presented better wear resistance than the substrate in PSR and MFR; however, in SR, the wear resistance of the modified layer decreased with the increase of the displacement amplitudes. The experimental results can provide some experimental bases for promoting industrial application of LTGMTT modified layer in anti-fretting wear.

Enhanced anaerobic digestion of corn stover by thermo-chemical pretreatment

In order to solve the problem of lignocellulose degraded speedily and efficiently in anaerobic digestion,the thermo-chemical pretreatment was applied to enhance biogas production from corn stover.Corn stover was thermo-chemical pretreated with a fluidized bed pyrolysis reactor at 180℃,200℃ and 220℃,respectively.Lignin degradations during pretreatment were 15.07%,32.57% and 33.31%,respectively.The Scanning Electron Microscope(SEM)images and Fourier Transform Infrared Spectroscopy(FTIR)spectra confirm that the thermo-chemical pretreatment can change the structure of corn stover and make lignin content decrease.The thermo-chemical pretreated corn stover was digested using a 2-L fermentation reactor.Experimental results showed thermo-chemical pretreatment could improve biodegradability and enhance biogas production.The highest total biogas production was 23319 mL for 20 d which was 10.0% higher than that of the untreated corn stover.

Bi-functional particles for integrated thermo-chemical processes:Catalysis and beyond

Particulate materials possessing dual functionalities have received tremendous investigations in many fields,owing to their superiority over mono-functional counterparts and their potential for process integration and intensification.This review focuses on bi-functional catalytic particles which also serve as sorbents/adsorbents or heat suppliers in the scheme of various thermo-chemical processes,enabling inherent separation or energy conservation within single-step operation.Bi-functional particles applied for integration of reaction and separation including sorption-enhanced hydrogen production and integrated capture and catalytic conversion processes are reviewed in detail,providing insights into material design and key performance indicators.On the other hand,bi-functional particles applied for integration of reaction and non-thermal radiation heating,including electrothermal and photothermal assisted heterogeneously catalyzed reactions,are also reviewed,with emphasis on the material property and energy efficiency improvement.These bi-functional particles show broad adaptability and feasibility in various reactions operated in integrated and intensified schemes,affording huge potentials for further improving productivity and efficiency in thermo-chemical processes.

Investigation on the thermo-chemical reaction mechanism between yttria-stabilized zirconia （YSZ） and calciummagnesium-alumino-silicate （CMAS）

Thermal barrier coatings （TBCs） with Y2O3-stabilized ZrO2 （YSZ） top coat play a very important role in advanced turbine blades by considerably increasing the engine efficiency and improving the performance of highly loaded blades. However, at high temperatures, environment factors result in the failure of TBCs. The influence of calcium-magnesium-alumino-silicate （CMAS） is one of environment factors. Although thermo-physical effect is being paid attention to, the thermo-chemical reaction becomes the hot-spot in the research area of TBCs affected by CMAS. In this paper, traditional twolayered structured TBCs were prepared by electron beam physical vapor deposition （EB- PVD） as the object of study. TBCs coated with CMAS were heated at 1240℃ for 3 h. Additionally, 15 wt.% simulated molten CMAS powder and YSZ powder were mixed and heated at 1240℃ or 1350℃ for 48 h. SEM and EDS were adopted to detect morphology and elements distribution. According to XRD and TEM results, it was revealed that CMAS react with YSZ at high temperature and form ZrSiO4, Ca0.2Zr0.8O1.8 and Ca0.15Zr0.85O1.85 after reaction, as a result, leading to the failure of TBCs and decreasing the TBC lifetime.

AI_4C_3 Hydration Thermochemical Analysis for Burned Carbon-containing Refractories with Al

In this paper, X-ray diffractogram analysis and SEM observation of Al$ C$ formed at high temperature from carbon-containing refractories ivith Al have been carried out. Aluminum added to carbon-containing refractories reacts with C（s） to form Al^ C^（s） gradually during heating from 600 ’C to 1200^0 . It is considered that the interlocked structure of Al^ C-$ plate crystals promotes the outstanding increase of hot modulus of rupture of carbon-containing refractories with Al. The HMOR of carbon-containing refractories added with Al additive from 0 to 5wt% increases by 2.8 times being from 6.5MPa to 18.2MPa. After a thermochemical calculation for hydration reaction processes ofAl^C^ and H^O （g）, the equilibrium partial pressure chart ofH^O （g） in H^O-A^C^-Al^ OH)} system vs various temperatures has been attained . The H2 0 （g） partial pressure in the air needed for the Al^ C3 hydration reaction is no more than 10;18 atm at the temperature below 120t . It is considered that the burned carbon-containing re

Development and experimental validation of kinetic models for the hydrogenation/dehydrogenation of Mg/Al based metal waste for energy storage

With the increased use of renewable energy sources,the need to store large amounts of energy will become increasingly important in the near future.A cost efficient possibility is to use the reaction of recycled Mg waste with hydrogen as thermo-chemical energy storage.Owing to the high reaction enthalpy,the moderate pressure and appropriate temperature conditions,the broad abundance and the recyclability,the Mg/Al alloy is perfectly suitable for this purpose.As further development of a previous work,in which the performance of recycled Mg/Al waste was presented,a kinetic model for hydro-and dehydrogenation is derived in this study.Temperature and pressure dependencies are determined,as well as the rate limiting step of the reaction.First experiments are carried out in an autoclave with a scaled-up powder mass,which is also used to validate the model by simulating the geometry with the scaled-up experiments at different conditions.

Gasification of Municipal Solid Waste for Power Generation in Brazil, a Review of Available Technologies and Their Environmental Benefits

This article reviews the literature on thermochemical processing of municipal solid waste as the final disposal in Brazil, explores recent publications in the field of solid waste generated, its origin, characteristics and removal mechanisms currently employed, in the same way, available technologies for the thermochemical treatment of MSW with an emphasis on gasification and clean technology are evaluated, highlighting the current technical and reported in the literature in order to identify indicators of efficiency and flexibility of the technology. From the review it is concluded that gasification is a technically feasible option for the thermochemical conversion of municipal solid waste and subsequent power generation, besides being a technology that meets the applicable emission limits. Some of the main advantages of gasification of municipal solid waste are： （a） the sharp reduction in the waste mass （about 70-80%） and volume （approximately 80-90%）; （b） the drastic reduction in land use, 1：3000; （c） destruction of organic pollutants and other halogenated hydrocarbons; （d） concentration and immobilisation of inorganic contaminants so that they can be used effectively and safely removed; （e） use recyclables, such as ferrous metals, ferrous ash and slag materials; （f） reducing emissions of greenhouse gases by anaerobic decomposition of organic waste and （g） power generation.

Conservative Residual Distribution Method for Viscous Double Cone Flows in Thermochemical Nonequilibrium

Amulti-dimensionally upwind conservative ResidualDistribution algorithm for simulating viscous axisymmetric hypersonic flows in thermo-chemical nonequilibrium on unstructured grids is presented and validated in the case of the complex flowfield over a double cone configuration.The resulting numerical discretization combines a state-of-the-art nonlinear quasi-monotone second order blended scheme for distributing the convective residual and a standard Galerkin formulation for the diffusive residual.The physical source terms are upwinded together with the convective fluxes.Numerical results show an excellent agreement with experimental measurements and available literature.

Variable High-Order Multiblock Overlapping Grid Methods for Mixed Steady and Unsteady Multiscale Viscous Flows,Part II:Hypersonic Nonequilibrium Flows

The variable high-order multiblock overlapping(overset)grids method of Sj¨ogreen&Yee[CiCP,Vol.5,2009]for a perfect gas has been extended to nonequilibrium flows.This work makes use of the recently developed high-order well-balanced shock-capturing schemes and their filter counterparts[Wang et al.,J.Comput.Phys.,2009,2010]that exactly preserve certain non-trivial steady state solutions of the chemical nonequilibrium governing equations.Multiscale turbulence with strong shocks and flows containing both steady and unsteady components is best treated by mixing of numerical methods and switching on the appropriate scheme in the appropriate subdomains of the flow fields,even under the multiblock grid or adaptive grid refinement framework.While low dissipative sixth-or higher-order shock-capturing filter methods are appropriate for unsteady turbulence with shocklets,second-and thirdorder shock-capturing methods are more effective for strong steady or nearly steady shocks in terms of convergence.It is anticipated that our variable high-order overset grid framework capability with its highly modular design will allow for an optimum synthesis of these new algorithms in such a way that the most appropriate spatial discretizations can be tailored for each particular region of the flow.In this paper some of the latest developments in single block high-order filter schemes for chemical nonequilibrium flows are applied to overset grid geometries.The numerical approach is validated on a number of test cases characterized by hypersonic conditions with strong shocks,including the reentry flow surrounding a 3D Apollo-like NASA Crew Exploration Vehicle that might contain mixed steady and unsteady components,depending on the flow conditions.