Thermodynamic Consistency and Thermomechanical Dynamics (TMD) for Nonequilibrium Irreversible Mechanism of Heat Engines

The irreversible mechanism of heat engines is studied in terms of thermodynamic consistency and thermomechanical dynamics (TMD) which is proposed for a method to study nonequilibrium irreversible thermodynamic systems. As an example, a water drinking bird (DB) known as one of the heat engines is specifically examined. The DB system suffices a rigorous experimental device for the theory of nonequilibrium irreversible thermodynamics. The DB nonlinear equation of motion proves explicitly that nonlinear differential equations with time-dependent coefficients must be classified as independent equations different from those of constant coefficients. The solutions of nonlinear differential equations with time-dependent coefficients can express emergent phenomena: nonequilibrium irreversible states. The couplings among mechanics, thermodynamics and time-evolution to nonequilibrium irreversible state are defined when the internal energy, thermodynamic work, temperature and entropy are integrated as a spontaneous thermodynamic process in the DB system. The physical meanings of the time-dependent entropy, T(t)dS(t), , internal energy, dƐ(t), and thermodynamic work, dW(t), are defined by the progress of time-dependent Gibbs relation to thermodynamic equilibrium. The thermomechanical dynamics (TMD) approach constitutes a method for the nonequilibrium irreversible thermodynamics and transport processes.

Thermodynamic Consistency of Plate and Shell Mathematical Models in the Context of Classical and Non-Classical Continuum Mechanics and a Thermodynamically Consistent New Thermoelastic Formulation

Inclusion of dissipation and memory mechanisms, non-classical elasticity and thermal effects in the currently used plate/shell mathematical models require that we establish if these mathematical models can be derived using the conservation and balance laws of continuum mechanics in conjunction with the corresponding kinematic assumptions. This is referred to as thermodynamic consistency of the mathematical models. Thermodynamic consistency ensures thermodynamic equilibrium during the evolution of the deformation. When the mathematical models are thermodynamically consistent, the second law of thermodynamics facilitates consistent derivations of constitutive theories in the presence of dissipation and memory mechanisms. This is the main motivation for the work presented in this paper. In the currently used mathematical models for plates/shells based on the assumed kinematic relations, energy functional is constructed over the volume consisting of kinetic energy, strain energy and the potential energy of the loads. The Euler’s equations derived from the first variation of the energy functional for arbitrary length when set to zero yield the mathematical model(s) for the deforming plates/shells. Alternatively, principle of virtual work can also be used to derive the same mathematical model(s). For linear elastic reversible deformation physics with small deformation and small strain, these two approaches, based on energy functional and the principle of virtual work, yield the same mathematical models. These mathematical models hold for reversible mechanical deformation. In this paper, we examine whether the currently used plate/shell mathematical models with the corresponding kinematic assumptions can be derived using the conservation and balance laws of classical or non-classical continuum mechanics. The mathematical models based on Kirchhoff hypothesis (classical plate theory, CPT) and first order shear deformation theory (FSDT) that are representative of most mathematical models for plates/shells are investigated in this paper for their thermodynamic consistency. This is followed by the details of a general and higher order thermodynamically consistent plate/shell thermoelastic mathematical model that is free of a priori consideration of kinematic assumptions and remains valid for very thin as well as thick plates/shells with comprehensive nonlinear constitutive theories based on integrity. Model problem studies are presented for small deformation behavior of linear elastic plates in the absence of thermal effects and the results are compared with CPT and FSDT mathematical models.

Two-flavor quark matter in the perturbation theory with full thermodynamic consistency

Direct extrapolation of the strong interaction between quarks in pure perturbative calculation has a problem of thermodynamic inconsistency. A new term determined by thermodynamic consistency requirement could resolve it. This new term plays an important role at lower density in describing the equation of state of quark matter, while it is negligible at high density. Accordingly, the density behavior of the sotmd velocity becomes more reasonable, and the maximum mass of quark stars can be as large as two times the solar mass.

A thermodynamic Approach to Rate Equations in Continuum Physics

The paper addresses the formulation of rate equations, via objective time derivatives, within continuum physics. The concept of objectivity is reviewed and distinction is made with material frame-indifference whose meaning is restricted to the invariance of the balance equations relative to Galilean frames. Objective time derivatives are defined to leave the tensor character of the appropriate field invariant within the set of Euclidean frames. Rate equations are required to involve objective time derivatives and to be consistent with the second law of thermodynamics. Here the general structure of objective time derivatives is established and the known derivatives of the physical literature are shown to be particular cases. Next, to fix ideas, a rate equation is considered for the model of heat conduction via a generalization of the Maxwell-Cattaneo equation with higher-order gradients as in the Guyer-Krumhansl equation. The thermodynamic restrictions are investigated and the expected effects, of the selected derivative of the heat flux, on the stress tensor are derived.

Thermodynamically consistent model for diblock copolymer melts coupled with an electric field

We present a thermodynamically consistent model for diblock copolymer melts coupled with an electric field derived using the Onsager linear response theory.We compare the model with the thermodynamically inconsistent one previously used for the coupled system to highlight their differences in describing transient dynamics.

Finite Deformation, Finite Strain Nonlinear Dynamics and Dynamic Bifurcation in TVE Solids

This paper presents the mathematical model consisting of conservation and balance laws (CBL) of classical continuum mechanics (CCM) and the constitutive theories derived using entropy inequality and representation theorem for thermoviscoelastic solids (TVES) matter without memory. The CBL and the constitutive theories take into account finite deformation and finite strain deformation physics. This mathematical model is thermodynamically and mathematically consistent and is ideally suited to study nonlinear dynamics of TVES and dynamic bifurcation and is used in the work presented in this paper. The finite element formulations are constructed for obtaining the solution of the initial value problems (IVPs) described by the mathematical models. Both space-time coupled as well as space-time decoupled finite element methods are considered for obtaining solutions of the IVPs. Space-time coupled finite element formulations based on space-time residual functional (STRF) that yield space-time variationally consistent space-time integral forms are considered. This approach ensures unconditional stability of the computations during the entire evolution. In the space-time decoupled finite element method based on Galerkin method with weak form for spatial discretization, the solutions of nonlinear ODEs in time resulting from the decoupling of space and time are obtained using Newmark linear acceleration method. Newton’s linear method is used to obtain converged solution for the nonlinear system of algebraic equations at each time step in the Newmark method. The different aspects of the deformation physics leading to the factors that influence nonlinear dynamic response and dynamic bifurcation are established using the proposed mathematical model, the solution method and their validity is demonstrated through model problem studies presented in this paper. Energy methods and superposition techniques in any form including those used in obtaining solutions are neither advocated nor used in the present work as these are not supported by calculus of variations and mathematical classification of differential operators appearing in nonlinear dynamics. The primary focus of the paper is to address various aspects of the deformation physics in nonlinear dynamics and their influence on dynamic bifurcation phenomenon using mathematical models strictly based on CBL of CCM using reliable unconditionally stable space-time coupled solution methods, which ensure solution accuracy or errors in the calculated solution are always identified. Many model problem studies are presented to further substantiate the concepts presented and discussed in the paper. Investigations presented in this paper are also compared with published works when appropriate.

Deformable Permanent Ferroelectric or Ferromagnetic Media

In the framework of continuum mechanics, one of possible consistent definitions of deformable permanent magnets is introduced and explored. Similar model can be used for ferroelectric substances. Based on the suggested definition, we establish the key kinematic relationship for the deformable permanent magnet and suggest the simplest master system, allowing to analyze behavior of such substances.

On thermodynamic self-consistency of generic axiomatic-nonextensive statistics

Generic axiomatic-nonextensive statistics introduces two asymptotic properties,to each of which a scaling function is assigned.The first and second scaling properties are characterized by the exponents c and d,respectively.In the thermodynamic limit,a grand-canonical ensemble can be formulated.The thermodynamic properties of a relativistic ideal gas of hadron resonances are studied,analytically.It is found that this generic statistics satisfies the requirements of the equilibrium thermodynamics.Essential aspects of the thermodynamic self-consistency are clarified.Analytical expressions are proposed for the statistical fits of various transverse momentum distributions measured in most-central collisions at different collision energies and colliding systems.Estimations for the freezeout temperature（T_（ch）） and the baryon chemical potential（μ_b） and the exponents c and d are determined.The earlier are found compatible with the parameters deduced from Boltzmann-Gibbs（BG） statistics（extensive）,while the latter refer to generic nonextensivities.The resulting equivalence class（c,d） is associated with stretched exponentials,where Lambert function reaches its asymptotic stability.In some measurements,the resulting nonextensive entropy is linearly composed on extensive entropies.Apart from power-scaling,the particle ratios and yields are excellent quantities to highlighting whether the particle production takes place（non）extensively.Various particle ratios and yields measured by the STAR experiment in central collisions at 200,62.4 and 7.7 GeV are fitted with this novel approach.We found that both c and d 〈 1,i.e.referring to neither BG-nor Tsallis-type statistics,but to（c,d）-entropy,where Lambert functions exponentially rise.The freezeout temperature and baryon chemical potential are found comparable with the ones deduced from BG statistics（extensive）.We conclude that the particle production at STAR energies is likely a nonextensive process but not necessarily BG or Tsallis type.

Magnetized strange quark matter in a mass-density-dependent model

We investigate the properties of strange quark matter （SQM） in a strong magnetic field with quark confinement by the density dependence of quark masses considering the total baryon number conservation, charge neutrality and chemical equilibrium. It is found that an additional term should appear in the pressure expression to maintain thermodynamic consistency. At fixed density, the energy density of magnetized SQM varies with the magnetic field strength. By increasing the field strength an energy minimum exists located at about 6×10^19 Gauss when the density is fixed at two times the normal nuclear saturation density.