Nano-crystalline Ni1.0Co0.2Mn1.8O4 powders were synthesized via non-crystalloid precursor method. The results on the precursor by XRD and IR techniques show that the stable non-crystalloid precursor could be formed by...Nano-crystalline Ni1.0Co0.2Mn1.8O4 powders were synthesized via non-crystalloid precursor method. The results on the precursor by XRD and IR techniques show that the stable non-crystalloid precursor could be formed by adding oleic acide and adjusting the pH values. The dried precursor exhibited auto-catalytic combustion behavior. After being calcined at 800 ℃, the Ni1.0Co0.2Mn1.8O4 powders with spinel structure were obtained. It has been demonstrated that the synthesized powder is well dispersed and with higher sintering activity. The Model of non-crystalloid precursor has been suggested. The reaction mechanism has also been proposed.展开更多
文摘Nano-crystalline Ni1.0Co0.2Mn1.8O4 powders were synthesized via non-crystalloid precursor method. The results on the precursor by XRD and IR techniques show that the stable non-crystalloid precursor could be formed by adding oleic acide and adjusting the pH values. The dried precursor exhibited auto-catalytic combustion behavior. After being calcined at 800 ℃, the Ni1.0Co0.2Mn1.8O4 powders with spinel structure were obtained. It has been demonstrated that the synthesized powder is well dispersed and with higher sintering activity. The Model of non-crystalloid precursor has been suggested. The reaction mechanism has also been proposed.