BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sin...BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.展开更多
分析了现有短路电流限制技术的发展现状,提出一种基于正温度系数(positive temperature coefficient,PTC)热敏电阻的可恢复型混合式短路限流装置的拓扑结构。通过将PTC热敏电阻与超快速分断开关并联,有效提高了限流装置的额定通流能力,...分析了现有短路电流限制技术的发展现状,提出一种基于正温度系数(positive temperature coefficient,PTC)热敏电阻的可恢复型混合式短路限流装置的拓扑结构。通过将PTC热敏电阻与超快速分断开关并联,有效提高了限流装置的额定通流能力,并充分利用PTC材料的电阻快速变化特性,提高装置限流能力,降低限流装置对于PTC材料额定通流要求。给出该型限流装置的检测判断原理及控制策略,分析其限流过程。完成基于PTC热敏电阻的混合式短路限流装置应用于蓄电池组电源短路限流的试验测试,通过不同设定电流值时的限流试验结果,证明所设计的装置能快速有效限制短路电流,具有良好的应用前景。展开更多
基金supported by the Research Funds of the Guangxi Key Laboratory of Information Materials at the School of Material Science and Engineering,China (Grant No. 0710908-07-Z)
文摘BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.
文摘分析了现有短路电流限制技术的发展现状,提出一种基于正温度系数(positive temperature coefficient,PTC)热敏电阻的可恢复型混合式短路限流装置的拓扑结构。通过将PTC热敏电阻与超快速分断开关并联,有效提高了限流装置的额定通流能力,并充分利用PTC材料的电阻快速变化特性,提高装置限流能力,降低限流装置对于PTC材料额定通流要求。给出该型限流装置的检测判断原理及控制策略,分析其限流过程。完成基于PTC热敏电阻的混合式短路限流装置应用于蓄电池组电源短路限流的试验测试,通过不同设定电流值时的限流试验结果,证明所设计的装置能快速有效限制短路电流,具有良好的应用前景。
