Asymmetric aminocatalysis has become one of the most powerful strategies for the transformations of carbonyl substances over the past two decades.Here,we describe the research from our laboratory that significantly ex...Asymmetric aminocatalysis has become one of the most powerful strategies for the transformations of carbonyl substances over the past two decades.Here,we describe the research from our laboratory that significantly expands the horizon of aminocatalysis.It includes the development and application of cinchona-based primary amines,fruitful reactions based on HOMO-raising strategy,and the disclosure of amine/thiol double activation catalysis.展开更多
基金We are grateful for the financial support from the NSFC(21931006 and 21961132004)the Fundamental Research Funds for the Central Universities,and China Postdoctoral Science Foundation(2019M663488)Postdoctoral Foundation of Sichuan University(2020SCU12019).
文摘Asymmetric aminocatalysis has become one of the most powerful strategies for the transformations of carbonyl substances over the past two decades.Here,we describe the research from our laboratory that significantly expands the horizon of aminocatalysis.It includes the development and application of cinchona-based primary amines,fruitful reactions based on HOMO-raising strategy,and the disclosure of amine/thiol double activation catalysis.
