Broadband third-order optical nonlinearities of layered franckeite towards mid-infrared regime

The study of nonlinear optical responses in the mid-infrared(mid-IR)regime is essential for advancing ultrafast mid-IR laser applications.However,nonlinear optical effects under mid-IR excitation are rarely reported due to the lack of suitable nonlinear optical materials.The natural van derWaals heterostructure franckeite,known for its narrow bandgap and stability in air,shows great potential for developing mid-IR nonlinear optical devices.We have experimentally demonstrated that layered franckeite exhibits a broadband wavelength-dependent nonlinear optical response in the mid-IR spectral region.Franckeite nanosheets were prepared using a liquid-phase exfoliation method,and their nonlinear optical response was characterized in the spectral range of 3000 nm to 5000 nm.The franckeite nanosheets exhibit broadband wavelengthdependent third-order nonlinearities,with nonlinear absorption and refraction coefficients estimated to be about 10^(-7)cm/W and 10^(-11)cm^(2)/W,respectively.Additionally,a passively Q-switched fluoride fiber laser operating around a wavelength of 2800 nm was achieved,delivering nanosecond pulses with a signal-to-noise ratio of 43.6 dB,based on the nonlinear response of franckeite.These findings indicate that layered franckeite possesses broadband nonlinear optical characteristics in the mid-IR region,potentially enabling new possibilities for mid-IR photonic devices.

Galerkin-Bernstein Approximations for the System of Third-Order Nonlinear Boundary Value Problems

This paper is devoted to find the numerical solutions of one dimensional general nonlinear system of third-order boundary value problems (BVPs) for the pair of functions using Galerkin weighted residual method. We derive mathematical formulations in matrix form, in detail, by exploiting Bernstein polynomials as basis functions. A reasonable accuracy is found when the proposed method is used on few examples. At the end of the study, a comparison is made between the approximate and exact solutions, and also with the solutions of the existing methods. Our results converge monotonically to the exact solutions. In addition, we show that the derived formulations may be applicable by reducing higher order complicated BVP into a lower order system of BVPs, and the performance of the numerical solutions is satisfactory. .

Nonlinear static characteristics of piezoelectric unimorph bending micro actuators

The nonlinear static characteristic of a piezoelectric unimorph cantilever micro actuator driven by a strong applied electric field is studied based on the couple stress theory.The cantilever actuator consists of a piezoelectric layer,a passive（elastic）layer and two electrode layers.First,the nonlinear static characteristic of the actuator caused by the electrostriction of the piezoelectric layer under a strong applied electric field is analyzed using the Rayleigh-Ritz method.Secondly,since the thickness of the cantilever beam is in micro scale and there exists a size effect,the size dependence of the deformation behavior is evaluated using the couple stress theory.The results show that the nonlinearities of the beam deflection increase along with the increase of the applied electric field which means that softening of the micro beam rigidity exists when a strong external electric field is applied.Meanwhile,the optimal value of the thickness ratio for the passive layer and the piezoelectric layer is not around 1.0 which is usually adopted by some previous researchers.Since there exists a size effect of the micro beam deflection,the optimal value of this thickness ratio should be greater than 1.0 in micro scale.

Nonlinear Current-Voltage Characteristics and Electroluminescence of cBN Crystal

The current-voltage（I-V） characteristics of cBN crystal sandwiched between two metallic electrodes are measured and found to be nonlinear. Over 20 samples are measured at room temperature with various electrodes, and the resulting curves are all similar in shape. When a voltage of about 560V is applied to the cBN crystal, the emitted light is visible to the naked eye in a dark room. We explain these phenomena by the space charge limited current and the electronic transition between the X and Г valleys of the conduction band.

Nonlinear Static and Dynamic Stiffness Characteristics of Support Hydraulic System of TBM

Full-face hard rock tunnel boring machines(TBM)are essential equipment in highway and railway tunnel engineering construction.During the tunneling process,TBM have serious vibrations,which can damage some of its key components.The support system,an important part of TBM,is one path through which vibrational energy from the cutter head is transmitted.To reduce the vibration of support systems of TBM during the excavation process,based on the structural features of the support hydraulic system,a nonlinear dynamical model of support hydraulic systems of TBM is established.The influences of the component structure parameters and operating conditions parameters on the stiffness characteristics of the support hydraulic system are analyzed.The analysis results indicate that the static stiffness of the support hydraulic system consists of an increase stage,stable stage and decrease stage.The static stiffness value increases with an increase in the clearances.The pre-compression length of the spring in the relief valve a ects the range of the stable stage of the static stiffness,and it does not a ect the static stiffness value.The dynamic stiffness of the support hydraulic system consists of a U-shape and reverse U-shape.The bottom value of the U-shape increases with the amplitude and frequency of the external force acting on the cylinder body,however,the top value of the reverse U-shape remains constant.This study instructs how to design the support hydraulic system of TBM.

Optimized analysis of sharpening characteristics of a compact RF pulse source based on a gyro-magnetic nonlinear transmission line for ultrawideband electromagnetic pulse application

We constructed a compact high-power RF pulse generator based on a gyro-magnetic nonlinear transmission line(GNLTL) to produce a high-voltage pulse with a sub-nanosecond rise time and a relatively high repetition rate, which shows great potential for application in the high-power ultrawideband electromagnetic effect, etc. The influence of incident pulse parameters(rise time and voltage amplitude) and line length on the sharpening characteristics of the GNLTL were investigated experimentally to optimize the rising rate of the modulated pulse front. Based on the GNLTL equivalent circuit model consisting of an LC ladder network, the rise time, the voltage conversion coefficient and the rising rate properties of a modulated pulse were also numerically analyzed in a wider range. The results show that a?>?90 k V RF pulse with a rise time of 350 ps and a repetition rate of 1 kHz in burst mode is produced by the GNLTL at an axial biasing magnetic field of 22 kA m^-1 and a line length of 30 cm under the condition of a 70 kV incident pulse. Applying a faster and higher incident pulse is conducive to improving the sharpening effect of the GNLTL. Furthermore, within a certain range, increasing the line length of the GNLTL not only reduces the rise time, but increases the voltage conversion coefficient and the rising rate of a modulated pulse. Furthermore, considering the energy loss of ferrite rings, there is an optimal line length to obtain the fastest rising rate of a modulated pulse front edge.

Nonlinear Dynamic Characteristics of the Vectored Thruster AUV in Complex Sea Conditions

The mobility of the vectored thruster AUV in different environment is the important premise of control system design. The new type of autonomous underwater vehicle (AUV) equipped with rudders and vectored thrusters which are combined to control the course is studied. Firstly, Euler angles representation and quaternion method are applied to establish six-DOF kinematic model respectively, then Newton second law and Lagrangian approach are used to deduce the vectored thruster AUV’s nonlinear dynamic equations with six degrees of freedom (DOF) respectively in complex sea conditions based on the random wave theory according to the structural and kinetic characteristics of the vectored thruster AUV in this paper. The kinematic models and dynamic models based on different theories have the same expression and conclusion, which shows that the kinematic models and dynamic models of the vectored thruster AUV are accurate. The Runge-Kutta arithmetic is used to solve the dynamic equations, which not only can simulate the motions such as cruise and hover but also can describe the vehicle’s low-frequency and high-frequency motion. The results of computation show that the mobility of the vectored thruster AUV in interference-free environment and the integrated signals including low-frequency motion signal and high-frequency motion signal in environmental disturbance accord with practical situation, which not only solve the problem of especial singularities when the pitch angle θ = ±90° but also clears up the difficulties of computation and display of the coupled nonlinear motion equations in complex sea conditions. Moreover, the high maneuverability of the vectored thruster AUV equipped with rudders and vectored thrusters is validated, which lays a foundation for the control system design.

Oscillation Criteria for Third-order NonlinearNeutral Dynamic Equations on Time Scales

Many practical problems, such as those from electronic engineering, mechanicalengineering, ecological engineering, aerospace engineering and so on, need to bedescribed by dynamic equations on time scales, so it is important in theory andpractical significance to study these equations. In this paper, the oscillation andasymptotic behavior of third-order nonlinear neutral delay dynamic equations ontime scales are studied by using generalized Riccati transformation technique, integralaveraging methods and comparison theorems. The main purpose of this paperis to establish some new oscillation criteria for such dynamic equations. The newKamenev criteria and Philos criteria are given, and an example is considered toillustrate our main results.

Research on the nonlinear spherical percolation model with quadratic pressure gradient and its percolation characteristics

For bottom water reservoir and the reservoir with a thick oil formation, there exists partial penetration completion well and when the well products the oil flow in the porous media takes on spherical percolation. The nonlinear spheri-cal flow equation with the quadratic gradient term is deduced in detail based on the mass conservation principle, and then it is found that the linear percolation is the approximation and simplification of nonlinear percolation. The nonlinear spherical percolation physical and mathematical model under different external boundaries is established, considering the ef-fect of wellbore storage. By variable substitu-tion, the flow equation is linearized, then the Laplace space analytic solution under different external boundaries is obtained and the real space solution is also gotten by use of the nu-merical inversion, so the pressure and the pressure derivative bi-logarithmic nonlinear spherical percolation type curves are drawn up at last. The characteristics of the nonlinear spherical percolation are analyzed, and it is found that the new nonlinear percolation type curves are evidently different from linear per-colation type curves in shape and characteris-tics, the pressure curve and pressure derivative curve of nonlinear percolation deviate from those of linear percolation. The theoretical off-set of the pressure and the pressure derivative between the linear and the nonlinear solution are analyzed, and it is also found that the in-fluence of the quadratic pressure gradient is very distinct, especially for the low permeabil-ity and heavy oil reservoirs. The influence of the non-linear term upon the spreading of pressure is very distinct on the process of percolation, and the nonlinear percolation law stands for the actual oil percolation law in res-ervoir, therefore the research on nonlinear per-colation theory should be strengthened and reinforced.

NONLINEAR J-E CHARACTERISTICS IN THE ELECTRIC-THERMAL EQUILIBRIUM STATE FOR HIGH DENSITY POLYETHYLENE CONDUCTIVE COMPOSITES

The nonlinear J-E characteristics under self-heating equilibrium for conductive composites based on high density polyethylene were studied. The results show that there are identical conduction mechanisms under self-heating equilibrium for the composites with various initial resistivities determined by filler content or ambient temperature. The nonlinear conduction behavior was involved in the limited microstructure transformations of the conducting network induced by electrical field applied and the corresponding self-heating effect. A reversible thermal fuse (RTF) model was suggested to interpret the physical origin of the nonlinear J-E characteristics.

Characteristics of a Quasi-Zero-Stiffness Isolator Using a Double-Curved Beam as a Negative Stiffness Mechanism

In this paper,a new quasi-zero-stiffness(QZS)nonlinear isolation system using a double-curved beam(DCB)as a negative stiffness structure is proposed,and its performance is investigated.The negative stiffness provided by the DCB to the isolator in the equilibrium position reduces the isolator’s overall dynamic stiffness.Static and dynamic characteristics of the system are investigated.The amplitude-frequency characteristics and force transmissibility equation of the system were derived via the harmonic balance method.The effects of damping ratio and excitation force amplitude on amplitude-frequency and force transmissibility curves are examined,and the isolation performance is compared with that of an equivalent linear isolator supporting the same mass with the same static deflection as nonlinear isolators.Furthermore,MATLAB numerical simulation software is used to perform dynamic time analysis of the nonlinear isolation system.The results indicate that the amplitude-frequency curves of the nonlinear isolation system exhibit bending,accompanied by discontinuous jumps in frequency.The appropriate increase in the damping ratio or reduction in the excitation amplitude benefits the vibration isolation performance of the nonlinear vibration isolation system.Compared with the equivalent linear isolation system,the QZS isolation system exhibits a better low-frequency vibration isolation performance,which provides a theoretical basis for the design of low-frequency nonlinear isolators.

Synthesis of Poly (3-acetylpyrrolyl methine) with Azobenzene Side Groups and Study on Its Third-order Nonlinear Optical Property

A novel soluble π-conjugated polymer, poly [（3-acetylpyrrole-2, 5-diyl） p-（N, N-dimethylamino） azobenzylidene] （PAPDMAABE）, was synthesized by condensation of 3-acetylpyrrole with 4-aldehyde-4＇-dimethylaminoazobenzene （ADMAA）. The chemical structure of PAPDMAABE was characterized by Fourier transform infrared spectroscopy （FTIR）, ^1H-NMR, and UV-Vis-NIR spectra. Transmission electron microscope （TEM） analysis for PAPDMAABE indicates that part of PAPDMAABE is in crystal state, due to the short-range order of the polymer. Thermogravimetric analysis （TGA） curve shows that the polymer has good thermal stability and its decomposition temperature is 248℃. The optical band gap of PAPDMAABE obtained from the optical absorption spectrum is about 1.73 eV. The resonant third-order nonlinear optical property of PAPDMAABE at 532 nm was studied using degenerate four-wave mixing （DFWM） technique. The resonant third-order nonlinear optical susceptibility of the polymer is about 7.48×10^-8 esu.

The Third-Order Nonlinear Optical Properties in Cobalt-Doped ZnO Films

We quantitatively investigate the third-order optical nonlinear response of Co-doped ZnO thin films prepared by magnetron sputtering using the Z-scan method. The two-photon absorption and optical Kerr effect are revealed to contribute to the third-order nonlinear response of the Co-doped ZnO films. The nonlinear absorption coefficient β is determined to be approximately 8.8 × 10-5 cm/W and the third-order nonlinear susceptibility X（3） is 2.93 × 10-6 esu. The defect-associated energy levels within the band gap are suggested to be responsible for the enhanced nonlinear response observed in Co-doped ZnO films.

Giant and light modifiable third-order optical nonlinearity in a free-standing h-BN film

Recently,hexagonal boron nitride(h-BN)has become a promising nanophotonic platform for on-chip information devices due to the practicability in generating optically stable,ultra-bright quantum emitters.For an integrated information-processing chip,high optical nonlinearity is indispensable for various fundamental functionalities,such as all-optical modulation,high order harmonic generation,optical switching and so on.Here we study the third-order optical nonlinearity of free-standing h-BN thin films,which is an ideal platform for on-chip integration and device formation without the need of transfer.The films were synthesized by a solution-based method with abundant functional groups enabling high third-order optical nonlinearity.Unlike the highly inert pristine h-BN films synthesized by conventional methods,the free-standing h-BN films could be locally oxidized upon tailored femtosecond laser irradiation,which further enhances the third-order nonlinearity,especially the nonlinear refraction index,by more than 20 times.The combination of the free-standing h-BN films with laser activation and patterning capability establishes a new promising platform for high performance on-chip photonic devices with modifiable optical performance.

UV-Vis Spectrum and the Third-order Nonlinear Optical Properties of the Chiral Camphorderived β-diketonate Platinum Complexes

UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G＊ level. The results showed that the introduction of electron-drawing group -CF3 and -C3F7 on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of -OC2H5 on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the -C2H3 was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down.

Nonlinear dynamic characteristics model of labyrinth seal based on Muszynska model

An accurate seal forces model is the foundation to analyze the rotor-seal systems. In this paper, the Navier-Stokes equation and energy equation are solved to simulate the interior flow field in the labyrinth seal gap. The leakage rate is compared with the experimental results in the literatures. The ：4maximum error is 4% , which proves that the method of employing CFD to simulate the interior flow field of labyrinth seal gap is reliable. Based on this, the interior flow field and fluid exciting force of stage teeth labyrinth seal are studied. By coupling with the Muszynska model, the method of defining the experience loss parameters in Muszynska model is proposed. The results indicate that the experience parameters obtained by the proposed method can depict the nonlinear exciting force of labyrinth seal better.

Electronic Absorption Spectra and Third-Order Nonlinear Optical Property of Dinaphtho[2,3-b:2’,3’-d]Thiophene-5,7,12,13- Tetraone (DNTTRA) and Its Phenyldiazenyl Derivatives: DFT Calculations

Third-order nonlinear optical (NLO) materials have broad application prospects in high-density data storage, optical computer, modern laser technology, and other high-tech industries. The structures and frequencies of Dinaphtho[2,3-b:2’,3’-d]thiophene-5,7,12,13-tetraone (DNTTRA) and its 36 derivatives containing azobenzene were calculated by using density functional theory B3LYP and M06-2X methods at 6-311++g(d, p) level, respectively. Besides, the atomic charges of natural bond orbitals (NBO) were analyzed. The frontier orbitals and electron absorption spectra of A-G5 molecule were calculated by TD-DFT (TD-B3LYP/6-311++g(d, p) and TD-M06-2X/6-311++g(d, p)). The NLO properties were calculated by effective finite field FF method and self-compiled program. The results show that 36 molecules of these six series are D-π-A-π-D structures. The third-order NLO coefficients γ (second-order hyperpolarizability) of the D series molecules are the largest among the six series, reaching 107 atomic units (10-33 esu) of order of magnitude, showing good third-order NLO properties. Last, the third-order NLO properties of the azobenzene ring can be improved by introducing strong electron donor groups (e.g. -N(CH3)2 or -NHCH3) in the azobenzene ring, so that the third-order NLO materials with good performance can be obtained.

Performance characteristics a nonlinear diode and optimal analysis of refrigerator

This paper establishes a model of a nonlinear diode refrigerator consisting of two diodes switched in the opposite directions and located in two heat reservoirs with different temperatures. Based on the theory of thermal fluctuations, the expressions of the heat flux absorbed from the heat reservoirs are derived. After the heat leak between the two reservoirs is considered, the cooling rate and the coefficient of performance are obtained analytically. The influence of the heat leak and the temperature ratio on the performance characteristics of the refrigerator is analysed in detail.

The retrieval of the nonlinear random waves from the non-Gaussian characteristics of the sea surface elevation distribution

In this paper, without recourse to the nonlinear dynamical equations of the waves, the nonlinear random waves are retrieved from the non-Gaussian characteristic of the sea surface elevation distribution. The question of coincidence of the nonlinear wave profile, spectrum and its distributions of maximum (or minimum) values of the sea surface elevation with results derived from some existing nonlinear theories is expounded under the narrow-band spectrum condition. Taking the shoaling sea wave as an example, the nonlinear random wave process and its spectrum in shallow water are retrieved from both the non-Gaussian characteristics of the sea surface elevation distribution in shallow water and the normal sea waves in deep water and compared with the values actually measured. Results show that they can coincide with the actually measured values quite well, thus, this can confirm that the method proposed in this paper is feasible.

Ultrashort pulse breaking in optical fiber with third-order dispersion and quintic nonlinearity

The optical wave breaking （OWB） characteristics in terms of the pulse shape, spectrum, and frequency chirp, in the normal dispersion regime of an optical fiber with both the third-order dispersion （TOD） and quintic nonlinearity （QN） are numerically calculated. The results show that the TOD causes the asymmetry of the temporal- and spectral-domain, and the chirp characteristics. The OWB generally appears near the pulse center and at the trailing edge of the pulse, instead of at the two edges of the pulse symmetrically in the case of no TOD. With the increase of distance, the relation of OWB to the TOD near the pulse center increases quickly, leading to the generation of ultra-short pulse trains, while the OWB resulting from the case of no TOD at the trailing edge of the pulse disappears gradually. In addition, the positive （negative） QN enhances （weakens） the chirp amount and the fine structures, thereby inducing the OWB phenomena to appear earlier （later）. Thus, the TOD and the positive （negative） QN are beneficial （detrimental） to the OWB and the generation of ultra-short pulse trains.