Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Values of macular ganglion cell-inner plexiform layer and 10-2 visual field measurements in detecting and evaluating glaucoma

AIM:To assess the performance of macular ganglion cell-inner plexiform layer thickness(mGCIPLT)and 10-2 visual field(VF)parameters in detecting early glaucoma and evaluating the severity of advanced glaucoma.METHODS:Totally 127 eyes from 89 participants(36 eyes of 19 healthy participants,45 eyes of 31 early glaucoma patients and 46 eyes of 39 advanced glaucoma patients)were included.The relationships between the optical coherence tomography(OCT)-derived parameters and VF sensitivity were determined.Patients with early glaucoma were divided into eyes with or without central 10°of the VF damages(CVFDs),and the diagnostic performances of OCT-derived parameters were assessed.RESULTS:In early glaucoma,the mGCIPLT was significantly correlated with 10-2 VF pattern standard deviation(PSD;with average mGCIPLT:β=-0.046,95%CI,-0.067 to-0.024,P<0.001).In advanced glaucoma,the mGCIPLT was related to the 24-2 VF mean deviation(MD;with average mGCIPLT:β=0.397,95%CI,0.199 to 0.595,P<0.001),10-2 VF MD(with average mGCIPLT:β=0.762,95%CI,0.485 to 1.038,P<0.001)and 24-2 VF PSD(with average mGCIPLT:β=0.244,95%CI,0.124 to 0.364,P<0.001).Except for the minimum and superotemporal mGCIPLT,the decrease of mGCIPLT in early glaucomatous eyes with CVFDs was more severe than that of early glaucomatous eyes without CVFDs.The area under the curve(AUC)of the average mGCIPLT(AUC=0.949,95%CI,0.868 to 0.982)was greater than that of the average circumpapillary retinal nerve fiber layer thickness(cpRNFLT;AUC=0.827,95%CI,0.674 to 0.918)and rim area(AUC=0.799,95%CI,0.610 to 0.907)in early glaucomatous eyes with CVFDs versus normal eyes.CONCLUSION:The 10-2 VF and mGCIPLT parameters are complementary to 24-2 VF,cpRNFLT and ONH parameters,especially in detecting early glaucoma with CVFDs and evaluating the severity of advanced glaucoma in group level.

Dual-function protective layer for highly reversible Zn anode

The thermodynamic instability of zinc anodes in aqueous electrolytes leads to issues such as corrosion,hydrogen evolution reactions(HER), and dendrite growth, severely hindering the practical application of zinc-based aqueous energy storage devices. To address these challenges, this work proposes a dualfunction zinc anode protective layer, composed of Zn-Al-In layered double oxides(ILDO) by rationally designing Zn-Al layered double hydroxides(Zn-Al LDHs) for the first time. Differing from previous works on the LDHs coatings, firstly, the ILDO layer accelerates zinc-ion desolvation and also captures and anchors SO_(4)^(2-). Secondly, the in-situ formation of the Zn-In alloy phase effectively lowers the nucleation energy barrier, thereby regulating zinc nucleation. Consequently, the zinc anode with the ILDO protective layer demonstrates long-term stability exceeding 1900 h and low voltage hysteresis of 7.5 m V at 0.5 m A cm^(-2) and 0.5 m A h cm^(-2). Additionally, it significantly enhances the rate capability and cycling performance of Zn@ILDO//MnO_(2) full batteries and Zn@ILDO//activated carbon zinc-ion hybrid capacitors.This simple and effective dual-function protective layer strategy offers a promising approach for achieving high-performance zinc-ion batteries.

Multi-Layer Tree Hierarchical Architecture Based on Web Service

To solve the problem of the information share and services integration in population information system, we propose a multi-layer tree hierarchical architecture. The command （Web Service Call） is recursively muhicast from top layer of tree to bottom layer of tree and statistical data are gatbered from bottom layer to top layer. We implemented the architecture by using Web Services technology. In our implementation, client program is the requestor of Web Services, and all leaf nodes of the last layer are only the provider of Web Services. For those nodes of intermediate layers, every node is not only the provider of Web Services, but also the dispatcher of Web Services. We take population census as an cxample to describe the working flow of the architecture.

层台累榭--楚国建筑形制特征探讨

两周时期楚国作为南方长江流域的霸主国家独领风骚,楚文化源于北方中原的商周文化,发展壮大于南方楚地,得天独厚的自然环境是孕育楚文化的重要基础。基于此,该文首先分析了楚文化及其自然环境的独特特征。其次,推论影响楚建筑形制的因素,提出其在楚文化与楚地自然环境影响下产生发展了楚高台建筑与干阑建筑。最后以文献和考古记载中的楚宫建筑为例,探讨楚国建筑“层台累榭”之形制特征。

Architecture design and demand analysis on application layer of standard system for ubiquitous power Internet of Things

The ubiquitous power Internet of Things(UPIoT)is an intelligent service system with comprehensive state perception,efficient processing,and flexible application of information.It focuses on each link of the power system and makes full use of the mobile internet,artificial intelligence,and other advanced information and communication technologies in order to realize the inter-human interaction of all things in all links of the power system.This article systematically presents to the national and international organizations and agencies in charge of UPIoT layer standardization the status quo of the research on the Internet of Things(IoT)-related industry standards system.It briefly describes the generic standard classification methods,layered architecture,conceptual model,and system tables in the UPIoT application layer.Based on the principles of inheritance,innovation,and practicability,this study divides the application layer into customer service,power grid operation,integrated energy,and enterprise operation,emerging business and analyzes the standard requirements of these five fields.This study also proposes a standard plan.Finally,it summarizes the research report and provides suggestions for a follow-up work.

Trend judgment of abandoned channels and fine architecture characterization in meandering river reservoirs: A case study of Neogene Minhuazhen Formation NmⅢ2 layer in Shijiutuo bulge, Chengning uplift, Bohai Bay Basin, East China

Based on well logging responses,sedimentary patterns and sandstone thickness,the distribution characteristics of meandering river sedimentary sand body of Neogene Minghuazhen Formation NmⅢ2 layer in the west of Shijiutuo Bulge,Chengning Uplift,Bohai Bay Basin were investigated.A new approach to calculate the occurrence of the sand-mudstone interfaces using resistivity log of horizontal well was advanced to solve the multiple solution problem of abandoned channel’s orientation.This method uses the trigonometric function relationship between radius,dip and length of the resistivity log to calculate the occurrence qualitatively-quantitatively to help determine the true direction of the abandoned channels.This method can supplement and improve the architecture dissection technique for meandering river sandbodies.This method was used to study the dip angle and scale of the lateral accretion layers in point bar quantitatively to help determine the spatial distribution of lateral accretion layers.The fine architecture model of underground meandering river reservoir in the study area has been established.Different from traditional grids,different grid densities for lateral accretion layers and bodies were used in this model by non-uniform upscaling to establish the inner architecture model of point-bars and realize industrial numerical simulation of the whole study area.The research results can help us predict the distribution of remaining oil,tap remaining oil,and optimize the waterflooding in oilfields.

A Novel IoT Architecture, Assessment of Threats and Their Classification withMachine Learning Solutions

The Internet of Things(IoT)will significantly impact our social and economic lives in the near future.Many Internet of Things(IoT)applications aim to automate multiple tasks so inactive physical objects can behave independently of others.IoT devices,however,are also vulnerable,mostly because they lack the essential built-in security to thwart attackers.It is essential to perform the necessary adjustments in the structure of the IoT systems in order to create an end-to-end secure IoT environment.As a result,the IoT designs that are now in use do not completely support all of the advancements that have been made to include sophisticated features in IoT,such as Cloud computing,machine learning techniques,and lightweight encryption techniques.This paper presents a detailed analysis of the security requirements,attack surfaces,and security solutions available for IoT networks and suggests an innovative IoT architecture.The Seven-Layer Architecture in IoT provides decent attack detection accuracy.According to the level of risk they pose,the security threats in each of these layers have been properly categorized,and the essential evaluation criteria have been developed to evaluate the various threats.Also,Machine Learning algorithms like Random Forest and Support Vector Machines,etc.,and Deep Learning algorithms like Artificial Neural Networks,Q Learning models,etc.,are implemented to overcome the most damaging threats posing security breaches to the different IoT architecture layers.

ZWY90/132-G型煤矿井下移动式瓦斯抽放泵站智能化设计

介绍了ZWY90/132-G型煤矿井下移动式瓦斯抽放泵站的构成以及智能监测、调控功能,并据此设计了现场设备层、现场控制层和过程监控层3层监控架构体系。提出了监控设备选型原则,开展了低功耗、自诊断、数字传输的监控设备选型。设计并实现了具有数据存储和查询功能、实时曲线和历史曲线显示功能、操作权限管理功能、故障报警和查询功能的监控中心站软件。最后,通过性能试验验证了各项试验项目均满足相关标准及技术要求,基本实现了ZWY90/132-G型煤矿井下移动式瓦斯抽放泵站的智能化,为最终实现无人化创造了条件。

3D Hierarchical Co–Al Layered Double Hydroxides with Long-Term Stabilities and High Rate Performances in Supercapacitors

Three-dimensional(3D) flower-like Co–Al layered double hydroxide(Co–Al-LDH) architectures composed of atomically thin nanosheets were successfully synthesized via a hydrothermal method in a mixed solvent of water and butyl alcohol. Owing to the unique hierarchical structure and modification by butyl alcohol, the electrochemical stability and the charge/mass transport of the Co–Al-LDHs was improved. When used in supercapacitors, the obtained Co–Al-LDHs deliver a high specific capacitance of 838 Fg^(-1) at a current density of 1 Ag^(-1)and excellent rate performance(753 Fg^(-1) at 30 Ag^(-1) and 677 Fg^(-1) at 100 Ag^(-1)), as well as excellent cycling stability with 95% retention of the initial capacitance even after 20,000 cycles at a current density of 5 Ag^(-1). This work provides a promising alternative strategy to enhance the electrochemical properties of supercapacitors.

Cognitive Intelligence Based 6G Distributed Network Architecture

5G is envisioned to guarantee high transmission rate,ultra-low latency,high reliability and massive connections.To satisfy the above requirements,the 5G architecture is designed with the properties of using service-based architecture,cloud-native oriented,adopting IT-based API interfaces and introduction of the Network Repository Function.However,with the wide commercialization of 5G network and the exploration towards 6G,the 5G architecture exposes the disadvantages of high architecture complexity,difficult inter-interface communication,low cognitive capability,bad instantaneity,and deficient intelligence.To overcome these limitations,this paper investigates 6G network architecture,and proposes a cognitive intelligence based distributed 6G network architecture.This architecture consists of a physical network layer and an intelligent decision layer.The two layers coordinate through flexible service interfaces,supporting function decoupling and joint evolution of intelligence services and network services.With the above design,the proposed 6G architecture can be updated autonomously to deal with the future unpredicted complex services.

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with copper interlayer sheet

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with a copper sheet as interlayer was carried out.Microstructures of the joint were studied by optical microscopy(OM),scanning electron microscopy(SEM) and X-ray diffractometry(XRD).In addition,the mechanical properties of the joint were evaluated by tensile test and the microhardness was measured.These two alloys were successfully welded by adding copper transition layer into the weld.Solid solution with a certain thickness was located at the interfaces between weld and base metal in both sides.Regions inside the weld and near the stainless steel were characterized by solid solution of copper with TiFe2 intermetallics dispersedly distributed in it.While weld near titanium alloy contained Ti-Cu and Ti-Fe-Cu intermetallics layer,in which the hardness of weld came to the highest value.Brittle fracture occurred in the intermetallics layer when the joint was stretched.

Layer regrouping for water-flooded commingled reservoirs at a high water-cut stage

Layer regrouping is to divide all the layers into several sets of production series according to the physical properties and recovery percent of layers at high water-cut stage, which is an important technique to improve oil recovery for high water-cut multilayered reservoirs. Dif- ferent regroup scenarios may lead to different production performances. Based on unstable oil-water flow theory, a multilayer commingled reservoir simulator is established by modifying the production split method. Taking into account the differences of layer properties, including per- meability, oil viscosity, and remaining oil saturation, the pseudo flow resistance contrast is proposed to serve as a characteristic index of layer regrouping for high water-cut multilayered reservoirs. The production indices of multi- layered reservoirs with different pseudo flow resistances are predicted with the established model in which the data are taken from the Shengtuo Oilfield. Simulation results show that the pseudo flow resistance contrast should be less than 4 when the layer regrouping is implemented. The K-means clustering method, which is based on the objec- tive function, is used to automatically carry out the layer regrouping process according to pseudo flow resistances. The research result is applied to the IV-VI sand groups of the second member of the Shahejie Formation in the Shengtuo Oilfield, a favorable development performance is obtained, and the oil recovery is enhanced by 6.08 %.

Desorption of Cl^(-) from Mg-Al layered double hydroxide intercalated with Cl^(-) using CO_(2) gas and water

Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).

Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment

The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.

Performance Analysis of Physical Layer Security over α-η-κ-μ Fading Channels

In this paper, we consider the secure data transmission over α-η-κ-μ fading channels, which are recently proposed to encompass nearly all the well-known statistical models adopted in the literature. In particular, we address the secrecy performance in terms of the average secrecy capacity(ASC) and the secrecy outage probability(SOP), for which novel analytical expressions are derived. Simulation results verify the analysis and demonstrate the impact of the physical parameters on the secrecy performance of this new channel fading model.

Developing architecture of a traveler information system for dynamic equilibrium in traffic networks

Having criticized the current architecture of Advanced Traveler Information Systems （ATISs）, this work discusses a new base of requirements to develop a new paradigm for traffic information systems. It mainly integrates three dimensions within a traffic system： drivers＇ pattern of behavior and preferences, urban traffic desires, and capabilities of traffic information service providers. Based on the above, functional segments from several related backgrounds are brought together to structure a new architecture, called Interactive Traveler Information System （ITIS）. The main interactive feature of this new architecture is a two-way communication track between drivers and the traffic information system provider-in fact, a decision on choosing a road at a particular time for an individual will be made based on the utility of both sides. This new configuration consists of driver-side smartphone application, centric traffic prediction, and decision-maker units, which will shape a new approach of decision-making processes. These all work together to satisfy the designated goal of ITIS, which is preserving the Wardrop equilibrium condition in the traffic network level. Finally, we concentrate on a comparison study, which shows a differentiation between performance of the proposed ITIS and the current ATIS model in a real situation. This has been done with simulations of analogical scenarios. The most noticeable advantage of the proposed architecture is not being limited to a saturation limit, and the positive effect of increasing system penetration in the performance of the newly introduced information system. In conclusion, new research subjects are suggested to be carried out.

Dynamics of low-speed streak evolution and interaction in laminar boundary layer

The present paper presents an experimental effort on the regeneration process of two low-speed laminar streaks in a zero-pressure-gradient laminar boundary layer. Two vertical thin wires separated by a spanwise distance of 30 mm are used to introduce disturbances of two rolls of transitional Karmain vortex street to the downstream boundary layer. Both hydrogen bubble visualization and particle image velocimetry （PIV） measurement show that two lowspeed streaks are induced through leading-edge receptivity process. As these streaks develop in the downstream, two additional low-speed streaks begin to appear outboard of the flank of the original two, together with complex dynamics of streak splitting and merging. A flow pattern of four streaks aligned along the spanwise direction occurs finally in the far downstream. It is found that besides the mechanisms of streak breakdown, the streak interaction is also an important factor characterizing the instability of low speed streaks and their regeneration process.

Promoting surface reconstruction of NiFe layered double hydroxides via intercalating[Cr(C_(2)O_(4))_(3)]^(3-)for enhanced oxygen evolution

Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.

A double-layer covered architecture with spinel phase induced by LiPP for Co-free Li-rich cathode with high-rate performance and long lifespan

Co-free Li-rich Mn-based layered oxides are promising candidates for next-generation lithium-ion batteries(LIBs)due to their high specific capacity,high voltage,low cost.However,their commercialization is hindered by limited cycle life and poor rate performance.Herein,an in-situ simple and low-cost strategy with a nanoscale double-layer architecture of lithium polyphosphate(LiPP)and spinel phase covered on top of the bulk layered phase,is developed for Li_(1.2)Mn_(0.6)Ni_(0.2)O_(2)(LMNO)using Li^(+)-conductor LiPP(denoted as LMNO@S-LiPP).With such a double-layer covered architecture,the half-cell of LMNO@S-LiPP delivers an extremely high capacity of 202.5 mAh·g^(−1)at 1 A·g^(−1)and retains 85.3%of the initial capacity after 300 cycles,so far,the best highrate electrochemical performance of all the previously reported LMNOs.The energy density of the full-cell assembled with commercial graphite reaches 620.9 Wh·kg^(−1)(based on total weight of active materials in cathode and anode).Mechanism studies indicate that the superior electrochemical performance of LMNO@S-LiPP is originated from such a nanoscale double-layer covered architecture,which accelerates Li-ion diffusion,restrains oxygen release,inhibits interfacial side reactions,suppresses structural degradation during cycling.Moreover,this strategy is applicable for other high-energy-density cathodes,such as LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2),Li_(1.2)Ni_(0.13)Co_(0.13)Mn_(0.54)O_(2),LiCoO_(2).Hence,this work presents a simple,cost-effective,scalable strategy for the development of high-performance cathode materials.