Three-dimensional structural models,evolution and petroleum geological significances of transtensional faults in the Ziyang area,central Sichuan Basin,SW China

With drilling and seismic data of Transtensional(strike-slip)Fault System in the Ziyang area of the central Sichuan Basin,SW China plane-section integrated structural interpretation,3-D fault framework model building,fault throw analyzing,and balanced profile restoration,it is pointed out that the transtensional fault system in the Ziyang 3-D seismic survey consists of the northeast-trending F_(I)19 and F_(I)20 fault zones dominated by extensional deformation,as well as 3 sets of northwest-trending en echelon normal faults experienced dextral shear deformation.Among them,the F_(I)19 and F_(I)20 fault zones cut through the Neoproterozoic to Lower Triassic Jialingjiang Formation,presenting a 3-D structure of an“S”-shaped ribbon.And before Permian and during the Early Triassic,the F_(I)19 and F_(I)20 fault zones underwent at least two periods of structural superimposition.Besides,the 3 sets of northwest-trending en echelon normal faults are composed of small normal faults arranged in pairs,with opposite dip directions and partially left-stepped arrangement.And before Permian,they had formed almost,restricting the eastward growth and propagation of the F_(I)19 fault zone.The F_(I)19 and F_(I)20 fault zones communicate multiple sets of source rocks and reservoirs from deep to shallow,and the timing of fault activity matches well with oil and gas generation peaks.If there were favorable Cambrian-Triassic sedimentary facies and reservoirs developing on the local anticlinal belts of both sides of the F_(I)19 and F_(I)20 fault zones,the major reservoirs in this area are expected to achieve breakthroughs in oil and gas exploration.

Changes of structure and functional properties of rice protein in the fresh edible rice during the seed development

It has been reported that fresh edible rice has more bioactive compounds and its protein is easier to digest and has lower hypoallergenic than mature rice. In this paper, the changes in structure and functional properties of proteins at five different stages, including early milky stage(EMS), middle milky stage(MMS), late milky stage(LMS), waxy ripe stage(WS)and ripening stage(RS), during the seed development were investigated. It was found that with the seed developing, the molecular weight of fresh rice protein gradually become larger while the secondary structure changed from the highest content of disordered structure at MMS to the highest content of ordered structure at RS, which affect the surface hydrophobicity and then the functional properties of proteins, including foaming properties, emulsifying properties and oil holding capacity. Fresh rice protein at MMS has the strongest surface hydrophobicity while fresh edible rice protein at RS has the strongest oil holding capability. The results of our study can provide a theoretical basis for the application of fresh rice protein in the food industry and help to develop new fresh edible rice food.

Emerging structures and dynamic mechanisms ofγ-secretase for Alzheimer’s disease

γ-Secretase,called“the proteasome of the membrane,”is a membrane-embedded protease complex that cleaves 150+peptide substrates with central roles in biology and medicine,including amyloid precursor protein and the Notch family of cell-surface receptors.Mutations inγ-secretase and amyloid precursor protein lead to early-onset familial Alzheimer’s disease.γ-Secretase has thus served as a critical drug target for treating familial Alzheimer’s disease and the more common late-onset Alzheimer’s disease as well.However,critical gaps remain in understanding the mechanisms of processive proteolysis of substrates,the effects of familial Alzheimer’s disease mutations,and allosteric modulation of substrate cleavage byγ-secretase.In this review,we focus on recent studies of structural dynamic mechanisms ofγ-secretase.Different mechanisms,including the“Fit-Stay-Trim,”“Sliding-Unwinding,”and“Tilting-Unwinding,”have been proposed for substrate proteolysis of amyloid precursor protein byγ-secretase based on all-atom molecular dynamics simulations.While an incorrect registry of the Notch1 substrate was identified in the cryo-electron microscopy structure of Notch1-boundγ-secretase,molecular dynamics simulations on a resolved model of Notch1-boundγ-secretase that was reconstructed using the amyloid precursor protein-boundγ-secretase as a template successfully capturedγ-secretase activation for proper cleavages of both wildtype and mutant Notch,being consistent with biochemical experimental findings.The approach could be potentially applied to decipher the processing mechanisms of various substrates byγ-secretase.In addition,controversy over the effects of familial Alzheimer’s disease mutations,particularly the issue of whether they stabilize or destabilizeγ-secretase-substrate complexes,is discussed.Finally,an outlook is provided for future studies ofγ-secretase,including pathways of substrate binding and product release,effects of modulators on familial Alzheimer’s disease mutations of theγ-secretase-substrate complexes.Comprehensive understanding of the functional mechanisms ofγ-secretase will greatly facilitate the rational design of effective drug molecules for treating familial Alzheimer’s disease and perhaps Alzheimer’s disease in general.

Effects of three-dimensional quality assessment nursing intervention on efficacy and disease management of patients undergoing esophageal cancer surgery

BACKGROUND Esophageal cancer is one of the most common malignant tumors.The three-dimensional quality structure model is a quality assessment theory that includes three dimensions:Structure,process,and results.AIM To investigate the effects of nursing interventions with three-dimensional quality assessment on the efficacy and disease management ability of patients undergoing esophageal cancer surgery.METHODS In this prospective study,the control group received routine nursing,and the intervention group additionally received a three-dimensional quality assessment intervention based on the above routine care.Self-efficacy and patient disease management abilities were evaluated using the General Self-Efficacy Scale(GSES)and Exercise of Self-Care Agency scale,respectively.IBM SPSS Statistics for Windows,version 17.0,was used for the data processing.RESULTS This study recruited 112 patients who were assigned to the control and experi-mental groups(n=56 per group).Before the intervention,there was no significant difference in GSES scores between the two groups(P>0.05).After the inter-vention,the GSES scores of both groups increased,with the experimental group showing higher values(P<0.05).At the time of discharge and three months after discharge,the scores for positive attitudes,self-stress reduction,and total score of health promotion in the experimental group were higher than those in the control group(P<0.05).CONCLUSION The implementation of a three-dimensional quality structure model for postoperative patients with esophageal cancer can effectively improve their self-management ability and self-efficacy of postoperative patients.

Unraveling structure and performance of protein a ligands at liquid–solid interfaces: A multi-techniques analysis

Oriented ligand immobilization is one of the most effective strategies used in the design and construction of a high-capacity protein A chromatography. In this work, cysteine was introduced as anchoring sites by substituting a specific residue on Helix Ⅰ, Ⅱ, and at C-terminus of antibody binding domain Z from protein A, respectively, to investigate structural evolution and binding behavior of protein A ligands at liquid-solid interfaces. Among the three affinity dextran-coated Fe_(3)O_(4) magnetic nanoparticles(Fe_(3)O_(4)@Dx MNPs), affinity MNPs with the immobilized ligand via N11C on Helix Ⅰ(Fe_(3)O_(4)@Dx-Z_(1) MNPs) had the highest helical content, and MNPs with the immobilized ligand via G29C on Helix Ⅱ(Fe_(3)O_(4)@Dx-Z_(2) MNPs) had the lowest helical content at the same pHs. It was attributed to less electrostatic attraction of ligand to negatively charged surface on Fe_(3)O_(4)@Dx-Z_(1) MNPs because of less positive charged residues on Helix Ⅰ(K6) than Helix Ⅱ(R27/K35). Among the three affinity MNPs, moreover, the highest affinity to immunoglobulin G(IgG) binding was observed on Fe_(3)O_(4)@Dx-Z_(1) MNPs in isothermal titration calorimetry measurement, further validating greater structural integrity of the ligand on Fe_(3)O_(4)@Dx-Z_(1) MNPs. Finally,the study of IgG binding on MNPs and 96-well plates showed that anchoring sites for ligand immobilization had distinct influences on IgG binding and IgG-mediated antigen binding. This work illustrated that anchoring sites of the ligands had a striking significance for the molecular structure of the ligand at liquid-solid interfaces and raised an important implication for the design and optimization of protein A chromatography and protein A-based immunoassay analysis.

Elucidation of the structure, antioxidant, and interfacial properties of flaxseed proteins tailored by microwave treatment

The microwave treatment is commonly applied to flaxseed to release nutrients, inactivate enzymes, remove cyanogens,and intensify flavors. The current study aimed to explore the influences of microwave exposure on the antioxidant and interfacial properties of flaxseed protein isolates(FPI), focusing on the altering composition and molecular structure.The results showed that after microwave exposure(700 W, 1–5 min), more compact assembly of storage proteins and subsequent permeation by membrane fragments of oil bodies occurred for cold-pressing flaxseed flours. Moreover, the particle sizes of FPI was progressively reduced with the decrement ranged from 37.84 to 60.66%(P<0.05), whereas the zeta potential values initially decreased and then substantially recovered during 1–5 min of microwave exposure. The conformation unfolding, chain cross-linking, and depolymerization were sequentially induced for FPI based on the analysis of fluorescence emission spectra, secondary structure, and protein subunit profiles, thereby affecting the dispersion or aggregation properties between albumin and globulin fractions in FPI. Microwave exposure retained specific phenolic acids and superior in vitro antioxidant activities of FPI. The inferior gas–water interface absorption and the loose/porous assembly structure were observed for the foams prepared by FPI, concurrent with obviously shrinking foaming properties upon microwave exposure. Improving oil–water interface activities of FPI produced the emulsion droplets with descending sizes and dense interface coating, which were then mildly destabilized due to the lipid leakage and weakened rheological behavior with microwave exposure extended to 5 min. Our findings elucidated that microwave treatment could tailor the application functionality of protein fractions in flaxseed based on their in situ structural remodeling.

Head Pursuit Variable Structure Guidance Law for Three-dimensional Space Interception

This article aims to develop a head pursuit （HP） guidance law for three-dimensional hypervelocity interception, so that the effect of the perturbation induced by seeker detection can be reduced. On the basis of a novel HP three-dimensional guidance model, a nonlinear variable structure guidance law is presented by using Lyapunov stability theory. The guidance law positions the interceptor ahead of the target on its tlight trajectory, and the speed of the interceptor is required to be lower than that of the target, A numerical example of maneuvering ballistic target interception verifies the rightness of the guidance model and the effectiveness of the proposed method.

Velocity-Free MS/AE Source Location Method for Three-Dimensional Hole-Containing Structures

Microseismic/acoustic emission(MS/AE)source localization method is crucial for predicting and controlling of potentially dangerous sources of complex structures.However,the locating errors induced by both the irregular structure and pre-measured velocity are poorly understood in existing methods.To meet the high-accuracy locating requirements in complex three-dimensional hole-containing structures,a velocity-free MS/AE source location method is developed in this paper.It avoids manual repetitive training by using equidistant grid points to search the path,which introduces A*search algorithm and uses grid points to accommodate complex structures with irregular holes.It also takes advantage of the velocity-free source location method.To verify the validity of the proposed method,lead-breaking tests were performed on a cubic concrete test specimen with a size of 10 cm10 cm10 cm.It was cut out into a cylindrical empty space with a size of/6cm10 cm.Based on the arrivals,the classical Geiger method and the proposed method are used to locate lead-breaking sources.Results show that the locating error of the proposed method is 1.20 cm,which is less than 2.02 cm of the Geiger method.Hence,the proposed method can effectively locate sources in the complex three-dimensional structure with holes and achieve higher precision requirements.

Observed spatiotemporal variation of three-dimensional structure and heat/salt transport of anticyclonic mesoscale eddy in Northwest Pacific

As in-situ observations are sparse,targeted observations of a specific mesoscale eddy are rare.Therefore,it is difficult to study the three-dimensional structure of moving mesoscale eddies.From April to September 2014,an anticyclonic eddy located at 135°E-155°E,26°N-42°N was observed using 17 rapidsampling Argo floats,and the spatiotemporal variations in the three-dimensional structure were studied.The results are as follows:(1)the eddy was identified and tracked using satellite altimeter data.It had a lifetime of 269 days and an average radius of 91.5 km.The lifetime of the eddy can be divided into three phases,i.e.,the initiation,maturity,and termination phases.The depth of its influence reached 1000 m;(2)the Argo profiles were divided into seven periods(approximately 20 days in each)for composite analysis,and the composite Argo profiles and CARS2009(CSIRO Atlas of Regional Seas)climatology data were merged following the data-interpolating variational analysis(DIVA)method to reconstruct the three-dimensional structure.The temperature and salinity anomaly cores of the anticyclonic mesoscale eddy are located from 400 to 600 m.From 800 to 900 m,there is an area of low salinity at the center of the eddy.A high concentration anomaly of dissolved oxygen was located at approximately 250 m;(3)to better understand the features of the eddy and its interaction with the surroundings,we calculated the anomalous velocity of the geostrophic flow and the heat,salt,dissolved oxygen transport anomaly,and discussed the eddy's origin and its adjustments to topography.The maximum heat,salt,and oxygen transport caused by eddy were 9.37×10^11 W,3.08×10^3 kg/s,and 2.70×10^2 kg/s,which all occurred during the termination phase.This study highlights the applicability of using Argo floats to understand the three-dimensional structure thermohaline features of eddies in the North Pacific.

Three-dimensional simulation of a Ka-band relativistic Cherenkov source with metal photonic-band-gap structures

This paper presents a three-dimensional particle-in-cell （PIC） simulation of a Ka-band relativistic Cherenkov source with a slow wave structure （SWS） consisting of metal photonic band gap （PBG） structures. In the simulation, a perfect match layer boundary is employed to absorb passing band modes supported by the PBG lattice with an artificial metal boundary. The simulated axial field distributions in the cross section and surface of the SWS demonstrate that the device operates in the vicinity of the π point of a TM01-1ike mode. The Fourier transformation spectra of the axial fields as functions of time and space show that only a single frequency appears at 36.27 GHz, which is in good agreement with that of the intersection of the dispersion curve with the slow space charge wave generated on the beam. The simulation results demonstrate that the SWS has good mode selectivity.

The three-dimensional structure and seasonal variation of the North Pacific meridional overturning circulation

The three-dimensional structure and the seasonal variation of the North Pacific meridional overturning circulation （NPMOC） are analyzed based on the Simple Ocean Data Assimilation data and Argo profiling float data. The NPMOC displays a multi-cell structure with four cells in the North Pacific altogether. The TC and the STC are a strong clockwise meridional cell in the low latitude ocean and a weaker clockwise meridional cell between 7°N and 18°N, respectively, while the DTC and the subpolar cell are a weaker anticlockwise meridional cell between 3°N and 15°N and a weakest anticlockwise meridional cell between 35°N and 50°N, respectively. The DTC, the TC and the STC are all of very strong seasonal variations. As to the DTC, the southward transport is strongest in fall and weakest in spring. For the TC, the northward transport is strongest in winter and weakest in spring, while the southward transport is strongest in fall and weakest in spring, which is associated with the strong southward fiow of the DTC in fall. As the STC, the northward transport is strongest in winter and weakest in summer, while the southward transport is strongest in summer and weakest in spring. This seasonal difference may be associated with the DTC. The zonal wind stress and the east-west slope of sea level play important roles in the seasonal variations of the TC, the STC and the DTC.

Three-dimensional Computational Fluid Dynamics Modeling of Two-phase Flow in a Structured Packing Column

Characterizing the complex two-phase hydrodynamics in structured packed columns requires a power- ful modeling tool. The traditional two-dimensional model exhibits limitations when one attempts to model the de- tailed two-phase flow inside the columns. The present paper presents a three-dimensional computational fluid dy- namics （CFD） model to simulate the two-phase flow in a representative unit of the column. The unit consists of an CFD calculations on column packed with Flexipak 1Y were implemented within the volume of fluid （VOF） mathe- matical framework. The CFD model was validated by comparing the calculated thickness of liquid film with the available experimental data. Special attention was given to quantitative analysis of the effects of gravity on the hy- drodynamics. Fluctuations in the liquid mass flow rate and the calculated pressure drop loss were found to be quali- tatively in agreement with the experimental observations.

[(n-C_4H_9)_3SnO_2C(CH_2)_2CO_2Sn(C_4H_9-n)_3]: A Novel Three-dimensional Framework Structure of Organotin Complex

The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) Angstrom, V = 7446(2) Angstrom(3), Z = 8, D-c = 1.242 g/cm(3), mu = 1.365 mm(-1), F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.

Three-dimensional crustal P-wave velocity structure in the Yangbi and Eryuan earthquake regions, Yunnan, China

A magnitude 5.5 earthquakes occurred in Eryuan County,Dali Bai Autonomous Prefecture,Yunnan Province,China,on March 3.And a magnitude 5.0 earthquake occurred in the same place on April 17,2013,i.e.,45 days later.Then,on May 21,2021,multiple earthquakes,one with magnitude 6.4 and several at 5.0 or above,occurred in Yangbi County,Dali Bai Autonomous Prefecture,Yunnan Province,China.All of these occurred in the Weixi-QiaohouWeishan fault zone.In this study,1,874 seismic events in Yangbi and Eryuan counties were identified by automatic micro-seismic identification technology and the first arrivals were picked up manually.Following this,a total of 11,968 direct P-wave absolute arrivals and 73,987 high-quality Pwave relative arrivals were collected for joint inversion via the double difference tomography method.This was done to obtain the regional three-dimensional fine crustal P-wave velocity structure.The results show that the travel time residuals before and after inversion decreased from the initial–0.1–0.1 s to–0.06–0.06 s.The upper crust in the study area,which exhibited a low-velocity anomaly,corresponded to the basin region;this indicated that the low-velocity anomaly in the shallow part of the study area was affected by the basin.Results also showed some correlation between the distribution of the earthquakes and velocity structure,as there was a lowvelocity body Lv1 with a wide distribution at depths ranging from 15–20 km in the Yangbi and Eryuan earthquake regions.In addition,earthquakes occurred predominantly in the highlow velocity abnormal transition zone.The low-velocity body in the middle and lower crust may be prone to concentrating upper crustal stress,thus leading to the occurrence of earthquakes.

Three-dimensional visualization of soil pore structure using computed tomography

The geometric and spatial characteristics of pore structures determine the permeability and water retention of soils, which have important effects on soil functional diversity and ecological restoration. Until recently, there have not been tools and methods to visually and quantitatively describe the characteristics of soil pores. To solve this problem, this research reconstructs the geometry and spatial distribution of soil pores by the marching cubes method, texture mapping method and the ray casting method widely used in literature. The objectives were to explore an optimal method for three-dimensional visualization of soil pore structure by comparing the robustness of the three methods on soil CT images with single pore structure and porosity ranging from low (2–5%) to high (12–18%), and to evaluate the reconstruction performance of the three methods with different geometric features. The results demonstrate that there are aliases (jagged edges) and deficiency at the boundaries of the model reconstructed by the marching cubes method and pore volumes are smaller than the ground truth, whereas the results of the texture mapping method lack the details of pore structures. For all the soil images, the ray casting method is preferable since it better preserves the pore characteristics of the ground truth. Furthermore, the ray casting method produced the best soil pore model with higher rendering speed and lower memory consumption. Therefore, the ray casting method provides a more advanced method for visualization of pore structures and provides an optional technique for the study of the transport of moisture and the exchange of air in soil.

The Shengli I Point Bar on the Yellow River Delta: Three-Dimensional Structures and Their Evolution

Point bars are well developed on the Yellow River delta, an~ which theShengli I point bar is the most typical. The point bar, being about 4 km in length and several tensto more than 100 meters in width, is located on the south side of the Shengli Bridge in KenliCounty, Dongying, Shandong. It is a typical fine-grained point bar with silt, which is predominant,some clay and minor plant debris and clay boulders. The Shengli I Point bar has complicated 3-Dstructures. Firstly, in a plane view, it comprises mainly eight sedimentary units, bar edge, baredge, bar platform, bar plain, bar channel, bar gully, bar pond and bar bay, developing side by sideand superimposed one by one m a complex way. Secondly, its vertical structures are very complex dueto the partial superimposition of the 8 sedimentary units. Besides hydatogenesis, very intensivewind erosion, eolian, ice and meltwater actions are also visible on the Shengli I point bar. Thecomplex form is made even more complicated because of the above co-actions.

Three-dimensional discrete element numerical simulation of Paleogene salt structures in the western Kuqa foreland thrust belt

Taking the Paleogene salt strata in the west of Kuqa foreland thrust belt as study object, the deformation features of salt structure in the compression direction and perpendicular to the compression direction were examined to find out the control factors and formation mechanisms of the salt structures. By using the three-dimensional discrete element numerical simulation method, the formation mechanisms of typical salt structures of western Kuqa foreland thrust belt in Keshen and Dabei work areas were comprehensively analyzed. The simulation results show that the salt deformation in Keshen and Dabei work areas is of forward spread type, with deformation concentrated in the piedmont zone;the salt deformation is affected by the early uplift near the compression end, pre-existing basement faults, synsedimentary process and the initial salt depocenter;in the direction perpendicular to the compression direction, salt rocks near the compression end have strong lateral mobility with the velocity component moving towards the middle part, and the closer to the middle, the larger the velocity will be, so that salt rocks will aggregate towards the middle and deform intensely, forming complex folds and separation of salt structures from salt source, and local outcrop with thrust faults. Compared with 2 D simulation, 3 D simulation can analyze salt structures in the principal stress direction and direction perpendicular to the principal stress, give us a full view of the formation mechanisms of salt structures, and guide the exploration of oil and gas reservoirs related to salt structures.

Three-dimensional structure of an observed cyclonic mesoscale eddy in the Northwest Pacific and its assimilation experiment

Mesoscale eddies play an important role in modulating the ocean circulation.Many previous studies on the threedimensional structure of mesoscale eddies were mainly based on composite analysis,and there are few targeted observations for individual eddies.A cyclonic eddy surveyed during an oceanographic cruise in the Northwest Pacific Ocean is investigated in this study.The three-dimensional structure of this cyclonic eddy is revealed by observations and simulated by the four-dimensional variational data assimilation(4 DVAR)system combined with the Regional Ocean Modeling System.The observation and assimilation results together present the characteristics of the cyclonic eddy.The cold eddy has an obvious dual-core structure of temperature anomaly.One core is at 50–150 m and another is at 300–550 m,which both have the average temperature anomaly of approximately-3.5℃.The salinity anomaly core is between 250 m and 500 m,which is approximately-0.3.The horizontal velocity structure is axis-asymmetric and it is enhanced on the eastern side of the cold eddy.In the assimilation experiment,sea level anomaly,sea surface temperature,and in situ measurements are assimilated into the system,and the results of assimilation are close to the observations.Based on the high-resolution assimilation output results,the study also diagnoses the vertical velocity in the mesoscale eddy,which reaches the maximum of approximately 10 m/d.The larger vertical velocity is found to be distributed in the range of 0.5 to 1 time of the normalized radius of the eddy.The validation of the simulation result shows that the 4 DVAR method is effective to reconstruct the three-dimensional structure of mesoscale eddy and the research is an application to study the mesoscale eddy in the Northwest Pacific by combining observation and assimilation methods.

Three-dimensional P velocity structure in Beijing area

A detail three-dimensional P wave velocity structure of Beijing, Tianjin and Tangshan area (BTT area) was deter-mined by inverting local earthquake data. In total 16 048 P wave first arrival times from 16048 shallow and mid-depth crustal earthquakes, which occurred in and around the BTT area from 1992 to 1999 were used. The first arrival times are recorded by Northern China United Telemetry Seismic Network and Yanqing-Huailai Digital Seismic Network. Hypocentral parameters of 1 132 earthquakes with magnitude ML=1.7~6.2 and the three-dimensional P wave velocity structure were obtained simultaneously. The inversion result reveals the com-plicated lateral heterogeneity of P wave velocity structure around BTT area. The tomographic images obtained are also found to explain other seismological observations well.

Synthesis and Crystal Structure of a Three-dimensional Mn(Ⅱ) Coordination Polymer with 3-(Pyrazin-2-yloxy)-pyridine and Azide Anion as Mixed Bridge Ligand

A three-dimensional coordination polymer [Mn2（μ1.3-N3）4（μ-PP）2]n （PP = 3-（pyrazin-2-yloxy）-pyridine） has been synthesized with 3-（pyrazin-2-yloxy）-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data： triclinic system, space group P1, with a = 6.794（4）, b = 9.885（6）, c = 9.947（6） A, α = 64.170（6）, β= 84.190（8）, γ= 85.319（8）°, V = 597.7（6）A^3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm^3, F（000） = 314 and μ = 1.117 mm^-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn（Ⅱ） ions connect into a two-dimensional sheet on the ab plane, then 3-（pyrazin-2-yloxy）-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along