Three-in-one fire-retardant poly(phosphate)-based fast ion-conductor for all-solid-state lithium batteries

The development of flame retardant or nonflammable electrolytes is the key to improve the safety of lithium batteries,owing to inflammable organic solvents and polymer matrix in common liquid and polymer electrolytes regarded as the main cause of battery fire.Herein,a series of solid-state polyphosphate oligomers(SPPO)as a three-in-one electrolyte that integrated the roles of lithium salt,dissociation matrix,and flame retardant were synthesized.The well-designed SPPO electrolytes showed an optimal ionic conductivity of 5.5×10^(-4)S cm-1at 30℃,an acceptable electrochemical window up to 4.0 V vs.Li/Li+,and lithium ion transference number of 0.547.Stable Li-ion stripping/plating behavior for 500 h of charge-discharge cycles without internal short-circuit in a Li|SPPO|Li cell was confirmed,together with outstanding interface compatibility between the SPPO electrolyte and lithium foil.The optimal Li|SPPO|LiFePO4cell presented good reversible discharge capacity of 149.4 mA h g-1at 0.1 C and Coulombic efficiency of 96.4%after 120 cycles.More importantly,the prepared SPPO cannot be ignited by the lighter fire and show a limited-oxygen-index value as high as 35.5%,indicating splendid nonflammable nature.The SPPO could be a promising candidate as a three-in-one solid-state electrolyte for the improved safety of rechargeable lithium batteries.

Minimizing Carbon Content with Three-in-One Functionalized Nano Conductive Ceramics:Toward More Practical and Safer S Cathodes of Li-S Cells

Using porous carbon hosts in cathodes of Li-S cells can disperse S actives and offset their poor electrical conductivity.However,such reservoirs would in turn absorb excess electrolyte solvents to S-unfilled regions,causing the electrolyte overconsumption,specific energy decline,and even safety hazards for battery devices.To build better cathodes,we propose to substitute carbons by In-doped SnO_(2)(ITO)nano ceramics that own three-in-one functionalities:1)using conductive ITO enables minimizing the total carbon content to an extremely low mass ratio(~3%)in cathodes,elevating the electrode tap density and averting the electrolyte overuse;2)polar ITO nanoclusters can serve as robust anchors toward Li polysulfide(LiPS)by electrostatic adsorption or chemical bond interactions;3)they offer catalysis centers for liquid–solid phase conversions of S-based actives.Also,such ceramics are intrinsically nonflammable,preventing S cathodes away from thermal runaway or explosion.These merits entail our configured cathodes with high tap density(1.54 g cm^(−3)),less electrolyte usage,good security for flame retardance,and decent Li-storage behaviors.With lean and LiNO_(3)-free electrolyte,packed full cells exhibit excellent redox kinetics,suppressed LiPS shuttling,and excellent cyclability.This may trigger great research enthusiasm in rational design of low-carbon and safer S cathodes.

Boosting High-Voltage and Ultralong-Cycling Performance of Single-Crystal LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) Cathode Materials via Three-in-One Modification

LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) is extensively researched as one of the most widely used commercially materials for Li-ion batteries at present.However,the poor high-voltage performance(≥4.3 V)with low reversible capacity limits its replacement for LiCoO_(2) in high-end digital field.Herein,three-in-one modification,Na-doping and Al_(2)O_(3)@Li_(3)BO_(3) dual-coating simultaneously,is explored for single-crystalline LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2)(N-NCM@AB),which exhibits excellent high-voltage performance.N-NCM@AB displays a discharge-specific capacity of 201.8 mAh g^(−1) at 0.2 C with a high upper voltage of 4.6 V and maintains 158.9 mAh g^(−1) discharge capacity at 1 C over 200 cycles with the corresponding capacity retention of 87.8%.Remarkably,the N-NCM@AB||graphite pouch-type full cell retains 81.2% of its initial capacity with high working voltage of 4.4 V over 1600 cycles.More importantly,the fundamental understandings of three-in-one modification on surface morphology,crystal structure,and phase transformation of N-NCM@AB are clearly revealed.The Na+doped into the Li–O slab can enhance the bond energy,stabilize the crystal structure,and facilitate Li+transport.Additionally,the interior surface layer of Li^(+)-ions conductor Li_(3)BO_(3) relieves the charge transfer resistance with surface coating,whereas the outer surface Al_(2)O_(3) coating layer is beneficial for reducing the active materials loss and alleviating the electrode/electrolyte parasite reaction.This three-in-one strategy provides a reference for the further research on the performance attenuation mechanism of NCM,paving a new avenue to boost the high-voltage performance of NCM cathode in Li-ion batteries.

Linguistic landscape and its impacts on place-making in mountain destination:A case of Mogan Mountain Town of Huzhou City,China

The place and placeness are believed to be a crucial perspective for comprehending the transformative dynamics of tourist destinations in the context of globalization and the rapid development of the tourism industry.As the material carrier of language,linguistic landscape is an intermediary for people to endow emotions and personalities into the place,becoming an effective path for exploring the place-making in a certain area.Mogan Mountain is a famous national tourist resort,which is located in Mogan Mountain Town,Deqing County,Huzhou City,China.This is a good case area for studying the relationship between linguistic landscape and placemaking in tourist destinations.There are two theories that form the theoretical foundation of the study,namely the place and the geosemiotics.Firstly,the results showed the overall style of the linguistic landscape.Multilingual labelling(52.7%),official signs(55.3%),and standardized Chinese characters predominantly shaped the linguistic landscape,with English and other languages being complementary.Secondly,from the perspective of three dimensions of the geosemiotics framework,such as inscription,language preference,and placement position,we conduct a comprehensive semiotic analysis of the linguistic landscape,which encompasses diverse facets such as fonts,materials,shifts in state,text vectors,and symmetrical arrangements.Finally,we explore the influence of linguistic landscapes on the place-making of Mogan Mountain through the dimensions of location,locale,and sense of place.The information on linguistic landscapes indicates the geographical location.These linguistic landscapes play an important role in constructing the language order,nostalgic atmosphere,exotic atmosphere,and elegant and tasteful lifestyle of the public space in Mogan Mountain.Readers of linguistic landscapes,including tourists and residents,generate and identify with the unique sense of place in Mogan Mountain.These linguistic landscapes construct the destination placeness of Mogan Mountain that combines both foreign and nostalgic styles,and the integration of Chinese and Western cultures.It will help promote the image positioning of tourism destinations and have practical guiding significance for the tourism planning,landscape-making,language management,and other aspects of tourism destinations.

Assessing Flexible Places for Adaptive Urban Design:A New Method and the Case of Cittaducale

Each place has its own peculiarities,determining that the resilience and adaptation to diverse types of risks will be different,requiring different time and methods for mitigation as well.The coexistence of several risks determines further resolution difficulties as commonly,since risks are sudden and unforeseen,there is a tendency to treat the last risk more carefully,neglecting the previous one even if it is just as important.Most of the methodologies used to analyse areas affected by different risks are aimed at focusing in particular on seismic risks without considering those relating to intangible aspects linked to the identity of the places or aspects related to urban health and liveability.And,more in general,in relation to design aspects,urban methodologies do not consider all the results of the analyses,maybe for the difficulty deriving from translating the complexity of collected data in project interventions.Starting from these premises,the objective of the article,elaborated within the SISMI and PRIN 2020 research projects is to propose an original methodology capable of analysing the places affected by multiple risks and planning its resilience attentive to its cultural resources and to its liveability.To this end,the proposed method will be aimed at creating flexible and adaptive places and the case-study of Cittaducale will be illustrated.Criticalities and qualities of this place affected by an earthquake in 2016 will be reported and project interventions to transform its risks into opportunities will be shown.

Making the World a Better Place for All

In bidding farewell to 2023,Chinese President Xi Jinping’s New Year message,with its commitment to advance Chinese modernization,deliver a better life for the people,and build a community with a shared future for mankind,effectively ushered in a new year brimming with hope.

Analysis of the Appealing Structure in Hemingway’s“A Clean,Well-lighted Place”

In the novel“A Clean,Well-lighted Place”,Hemingway tells the story of two waiters in a Spanish caféjust before closing time,talking about an old man who drank heavily in the caféevery night and lived a wealthy life but still wants to commit suicide.Using the iceberg principle,Hemingway purposely omits the plot,characterization of the story,and uses symbolism and repetition to describe people’s different attitudes facing the spiritual emptiness after the war,breaking the readers’expectations,and inspiring them to explore the meaning of individual life.Therefore,based on Wolfgang Iser and Zhu Liyuan’s appealing structure theory,this paper will analyze the appealing structure in“A Clean,Well-lighted Place”at three levels:meaning construction,rhetorical techniques,and thoughts and themes.It is hoped that readers can find a new way to interpret the short story,better understand the author’s creative ideas and dig deeper into the connotation of the work.

从Place连接Space助推“机械原理”一流课程建设

基于教学实践,从教学内容、教学组织和双向评价这三个关键维度出发,分别在先进理论和现代设计方法、大规模在线教育和工程实践及教师评价“学”的过程和学生评价“教”的过程等重要方向建立连接,使课程体系从有限容量的线性place占位扩展到大容量现代化教学的多方向space占位。建设结果表明,多方向的space课程体系既能解决学生学习过程中的主动性、积极性问题,又能助推课程自身迭代,促使“机械原理”始终处于一流课程的领先地位。

Communication in the Third Places

对以Kramsch为代表的跨文化交际研究思路与该领域其他研究思路进行对比探索性研究。笔者认为Kramsch的研究非常成功地描述了真实情景下跨文化交际的模式 ,也就是说 ,跨文化交际发生在所谓的第三位置 ,既不在本族语文化情境环境中 ,又不在目标语文化情境环境中。根据这一理解 ,Kramsch的研究思路强调文化的真实性及其动态特性。这一研究思路在中国外语教学环境下 ,可帮助我们避免在外语教学中走极端。即完全文化融入或文化霸权。Kramsch的理论总体上来说是无懈可击的 ,但由于还缺乏足够的数据资料支持以及语言学习过程的复杂性 ,因而要将其理论付诸语言教学实践 。

Contribution of public places in proliferation of dengue vectors in Penang Island,Malaysia

Objective: To determine abundance, distribution and diversity of potential breeding container habitats of the dengue vectors in public places including schools, restaurants,mosques and parks in southwest areas of Penang Island, Malaysia.Methods: Premises at restaurants, schools, parks and mosques were surveyed simultaneously and inspected visually for container habitats and production of immature mosquitoes from March 2015 to March 2016. Abundance(mean ± SE) of breeding containers between sites was compared using One-way ANOVA. Independent sample ttest was used to compare total number of Aedes albopictus(Ae. albopictus) and Aedes aegypti(Ae. aegypti) surveyed.Results: The surveyed locations yielded a total of 3 741 breeding containers and 19 537 immature mosquitoes from four areas. Concurrent artificial and natural containers produced 78.4% immature Ae. albopictus and 6.3% Ae. aegypti mosquitoes in wet season,with 14.2% Ae. albopictus and 1.1% Ae. aegypti mosquitoes in dry season. Artificial containers accounted for 98.1% of the total containers recorded, with restaurants being the most productive locations(8 012) and schools being the least productive(2 234).Conclusions: It was concluded that public places are good sources of potential container habitats of Aedes mosquitoes in Penang Island, Malaysia and Ae. albopictus has exclusively replaced the home-grown Ae. aegypti even in urban areas. Therefore, treatment of artificial containers in such locations is critical in Aedes mosquito control campaigns during dengue outbreaks.

DIAGNOSTICS OF FATIGUE CRACK IN ULTERIOR PLACES OF LARGER-SCALE OVERLOADED SUPPORTING SHAFT BASED ON TIME SERIES AND NEURAL NETWORKS

To improve the diagnosis accuracy and self-adaptability of fatigue crack in ulterior place of the supporting shaft, time series and neural network are attempted to be applied in research on diag-nosing the fatigue crack’s degree based on analyzing the vibration characteristics of the supporting shaft. By analyzing the characteristic parameter which is easy to be detected from the supporting shaft’s exterior, the time series model parameter which is hypersensitive to the situation of fatigue crack in ulterior place of the supporting shaft is the target input of neural network, and the fatigue crack’s degree value of supporting shaft is the output. The BP network model can be built and net-work can be trained after the structural parameters of network are selected. Furthermore, choosing the other two different group data can test the network. The test result will verify the validity of the BP network model. The result of experiment shows that the method of time series and neural network are effective to diagnose the occurrence and the development of the fatigue crack’s degree in ulterior place of the supporting shaft.

Heterobifunctional PEG-grafted black phosphorus quantum dots: “Three-in-One”nano-platforms for mitochondria-targeted photothermal cancer therapy

Black phosphorus(BP)nano-materials,especially BP quantum dots(BPQDs),performs outstanding photothermal antitumor effects,excellent biocompatibility and biodegradability.However,there are several challenges to overcome before offering real benefits,such as poor stability,poor dispersibility as well as difficulty in tailoring other functions.Here,a“three-in-one”mitochondria-targeted BP nano-platform,called as BPQD-PEG-TPP,was designed.In this nano-platform,BPQDs were covalently grafted with a heterobifunctional PEG,in which one end was an aryl diazo group capable of reacting with BPQDs to form a covalent bond and the other end was a mitochondria-targeted triphenylphosphine(TPP)group.In addition to its excellent near-infrared photothermal properties,BPQD-PEG-TPP had much enhanced stability and dispersibility under physiological conditions,efficient mitochondria targeting and promoted ROS production through a photothermal effect.Both in vitro and in vivo experiments demonstrated that BPQD-PEG-TPP performed much superior photothermal cytotoxicity than BPQDs and BPQD-PEG as the mitochondria targeted PTT.Thus this“three-in-one”nanoplatform fabricated through polymer grafting,with excellent stability,dispersibility and negligible side effects,might be a promising strategy for mitochondria-targeted photothermal cancer therapy.

Signifying,Spiritual Places and Langston Hughes's Poems

Hughes's inheritance of literal language rooted in spiritual places constitutes important aspect of Hughes's parody of African American literary tradition.Three categories of themes about spiritual places of African American literary tradition were discussed in this essay to show better understanding of Hughes's poems from Signifying perspective.

Spatial Structure of Central Places in Jilin Central Urban Agglomeration, Jilin Province, China

Using the radius of gyration from fractal theory, this paper describes the calculation of fractal dimensions for the four tiers of central places in the Jilin Central Urban Agglomeration(JCUA), Jilin Province, China and the structural characteristics of each tier: 1) the 1st tier central place, Changchun Proper(not including Shuangyang District), provides the most service functions and has the most stable primate position; 2) the 2nd tier central places, Jilin Proper, Siping Proper, Liaoyuan Proper and Songyuan Proper have unclear statuses and do not provide certain functions; 3) the 3rd tier central places comprise 23 county-level cities, counties and urban districts(including Shuangyang District of Changchun), exhibiting a dense spatial structure that agrees with theory; 4) the 4th tier contains the largest number of central places(248 designated towns), but they are loosely distributed. In this study, a spatial image of the JCUA was created, based on vectorized data of the urban settlement distribution, which was then modified and abstracted to create a hexagonal network covering the JCUA. Compared to the traditional central place model, the modified spatial image conforms to the K = 3 principle. In reality, however, the growth of some 3rd tier central places should be increased with the cities being upgraded to the 2nd tier so as to overcome that tier′s functional deficiency. The loose distribution in the 4th tier should also be changed. This apparent anomaly can be explained by the fact that the classic hexagon model used to describe the way market areas layout does not exist in the real world. However, this should not be viewed as an obstacle to using central place theory. If its assumptions are properly applied, it can still assist research into the spatial structure of regions.

Going places教学设计比较研究

人都说编辑是为她人做嫁衣裳的幕后英雄，但每天看那么多稿件、接触那么多教师、校长、教育专家．总有一些感触和想法如鲠在喉、不吐不快。所以斗胆站在这里，“编看编说”，与您分享我最真实的心情。

Studies on the Levels of Indoor PM10 and PM2.5 in Public Places in Chaoyang District, Beijing

[Objective]The research aimed to understand the levels of indoor air particles of PM_(10) and PM_(2.5)in public places in Chaoyang District of Beijing City,which will provide scientific basis for making health standards and policies and regulations of indoor air particulate matter in public places.[Method]In order to characterize indoor air quality of public places,shopping mall near the walking street,shopping mall near arterial traffic,barbecue style restaurant and eat hutch unicom Chinese restaurant were selected for this study.LD-3Claser measuring dust detector and Sidepak AM-510 artificial intelligence anti-explosion dust detector were used to test the levels of PM_(10) and PM_(2.5)in the air of the shopping malls and restaurants.The number of smoking customers and if smelling the smoke were recorded simultaneously.[Result]The average densities of PM_(10) and PM_(2.5)in the shopping mall near the walking street were noticeably lower than that near arterial traffic(P< 0.05).The highest level of PM_(2.5)at the barbecue style restaurant and eating hutch unicom Chinese restaurants were 1 090and666g/m^3.The average levels of PM_(10) at the barbecue style restaurant and eating hutch unicom restaurants were 286 and 399g/m3(P<0.05).[Conclusion]The indoor PM_(10) and PM_(2.5)concentrations were high in public places,especially in shopping mall near arterial traffic and restaurant.It should be enhanced to supervise indoor air in public places and establish the risk rating of indoor air quality to protect public health.

Relationship between Dining Place, Iodine Source, and Iodine Nutrition in School-Age Children: A Cross-Sectional Study in China

Objective This study assesses the impact of iodine-rich processed foods and dining places on the iodine nutritional status of children.Methods School-aged children(SAC) in seven provinces in China were selected by school-based multistage sampling. Urinary iodine, salt iodine, and thyroid volume(TVOL) were determined. Questionnaires were used to investigate dining places and iodine-rich processed foods. The water iodine was from the2017 national survey. Multi-factor regression analysis was used to find correlations between variables.Results Children ate 78.7% of their meals at home, 15.1% at school canteens, and 6.1% at other places.The percentage of daily iodine intake from water, iodized salt, iodine-rich processed foods, and cooked food were 1.0%, 79.2%, 1.5%, and 18.4%, respectively. The salt iodine was correlated with the urinary iodine and TVOL, respectively(r = 0.999 and-0.997, P < 0.05). The iodine intake in processed foods was weakly correlated with the TVOL(r = 0.080, P < 0.01). Non-iodized salt used in processed foods or diets when eating out had less effect on children’s iodine nutrition status.Conclusion Iodized salt remains the primary source of daily iodine intake of SAC, and processed food has less effect on iodine nutrition. Therefore, for children, iodized salt should be a compulsory supplement in their routine diet.

Modeling of Fuel Elements Cycling System in Pebble Bed Reactor Based on Timed Places Control Petri Nets

Pebble bed reactors use cycling scheme of spherical fuel elements relying on fuel elements cycling system (FECS). The structure and control logic of FECS are very complex. Each control link has strict requirements on time and sequence. This increases the difficulties of description and analysis. In this paper, timed places control Petri nets (TPCPN) is applied for the modeling of FECS. On this basis the simulation of two important processes, namely uploading fuel elements into the core for the first time and emptying the core is finished by simulation software Arena. The results show that as TPCPN is able to describe different kinds of logic relationship and has time properties and control properties, it’s very suitable for the modeling and analysis of FECS.

Effect of Spinning Parameters on Thick, Thin Places and Neps of Rotor Spun Yarn

Defect free yarn is a great demand for spinner, knitter, and weaver and also other textile personnel because numerous end products from knit apparels to woven fabrics, from towels to sheets and from carpets to industrial fabrics characteristics significantly depend on the physical properties of yarn. The qualities of rotor yarn are really directed by spinning parameters. The aim of this study is to observe the effect of spinning parameters such as rotor diameter and speed on thick, thin places and neps of yarn in rotor spinning process. 0.11 sliver hank of 100% cotton was used to produce 12 Ne yarn. 65% virgin cotton and 35% wastage cotton were mixed together. The positive impact of spinning parameters on yarn properties were accessed by thick places, thin places and neps. Results indicate that the yarn qualities were improved with increasing of rotor speed and rotor diameter. The rotor diameter was settled to 43 mm while rotor speed fluctuated from 35,000 to 45,000 rpm and rotor speed was fixed to 35,000 rpm while rotor diameter across contrasts from 43 mm to 66 mm.