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Static-torque Characteristics of Three-phase Hybrid(HB) Stepping Motors and Influence of Way of Winding Connection on Operating Characteristics of Motors of This Kind
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作者 刘宝廷 郑萍 崔淑梅 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1997年第4期59-62,共4页
The paper presents the static-torque characteristics of three-phase hybrid stepping motors and discusses the influence of way of winding connection on operating characteristics of motors of this kind.
关键词 STEPPING motors TORQUE CHARACTERISTICS winding CONNECTION
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Current optimization-based control of dual three-phase PMSM for low-frequency temperature swing reduction
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作者 Linlin Lu Xueqing Wang +3 位作者 Luhan Jin Qiong Liu Yun Zhang Yao Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期238-246,共9页
In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur... In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction. 展开更多
关键词 Dual three-phase PMSM Low-frequency temperature swing Copper loss Current optimization Connected neutral points
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Five-phase Synchronous Reluctance Machines Equipped with a Novel Type of Fractional Slot Winding
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作者 S.M.Taghavi Araghi A.Kiyoumarsi B.Mirzaeian Dehkordi 《CES Transactions on Electrical Machines and Systems》 EI CSCD 2024年第3期264-273,共10页
Multi-phase machines are so attractive for electrical machine designers because of their valuable advantages such as high reliability and fault tolerant ability.Meanwhile,fractional slot concentrated windings(FSCW)are... Multi-phase machines are so attractive for electrical machine designers because of their valuable advantages such as high reliability and fault tolerant ability.Meanwhile,fractional slot concentrated windings(FSCW)are well known because of short end winding length,simple structure,field weakening sufficiency,fault tolerant capability and higher slot fill factor.The five-phase machines equipped with FSCW,are very good candidates for the purpose of designing motors for high reliable applications,like electric cars,major transporting buses,high speed trains and massive trucks.But,in comparison to the general distributed windings,the FSCWs contain high magnetomotive force(MMF)space harmonic contents,which cause unwanted effects on the machine ability,such as localized iron saturation and core losses.This manuscript introduces several new five-phase fractional slot winding layouts,by the means of slot shifting concept in order to design the new types of synchronous reluctance motors(SynRels).In order to examine the proposed winding’s performances,three sample machines are designed as case studies,and analytical study and finite element analysis(FEA)is used for validation. 展开更多
关键词 Finite element analysis Five-phase machine Fractional slot concentrated winding(FSCW) Machine slot/pole combination MMF harmonics Synchronous reluctance machine winding factor
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Winding Function Model-based Performance Evaluation of a PM Transverse Flux Generator for Applications in Direct-drive Systems
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作者 Mehrage Ghods Jawad Faiz Ali A Pourmoosa 《CES Transactions on Electrical Machines and Systems》 EI CSCD 2024年第2期216-226,共11页
The magnetic flux in a permanent magnet transverse flux generator(PMTFG) is three-dimensional(3D), therefore, its efficacy is evaluated using 3D magnetic field analysis. Although the 3D finite-element method(FEM) is h... The magnetic flux in a permanent magnet transverse flux generator(PMTFG) is three-dimensional(3D), therefore, its efficacy is evaluated using 3D magnetic field analysis. Although the 3D finite-element method(FEM) is highly accurate and reliable for machine simulation, it requires a long computation time, which is crucial when it is to be used in an iterative optimization process. Therefore, an alternative to 3DFEM is required as a rapid and accurate analytical technique. This paper presents an analytical model for PMTFG analysis using winding function method. To obtain the air gap MMF distribution, the excitation magneto-motive force(MMF) and the turn function are determined based on certain assumptions. The magnetizing inductance, flux density, and back-electro-magnetomotive force of the winding are then determined. To assess the accuracy of the proposed method, the analytically calculated parameters of the generator are compared to those obtained by a 3D-FEM. The presented method requires significantly shorter computation time than the 3D-FEM with comparable accuracy. 展开更多
关键词 Index Terms—Permanent magnet transverse flux generator winding function 3D-FEM Cogging torque PROTOTYPING
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Adaptive RISE Control of Winding Tension with Active Disturbance Rejection
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作者 Junjie Mi Jianyong Yao Wenxiang Deng 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第4期135-145,共11页
A winding system is a time-varying system that considers complex nonlinear characteristics,and how to control the stability of the winding tension during the winding process is the primary problem that has hindered de... A winding system is a time-varying system that considers complex nonlinear characteristics,and how to control the stability of the winding tension during the winding process is the primary problem that has hindered development in this field in recent years.Many nonlinear factors affect the tension in the winding process,such as friction,structured uncertainties,unstructured uncertainties,and external interference.These terms severely restrict the tension tracking performance.Existing tension control strategies are mainly based on the composite control of the tension and speed loops,and previous studies involve complex decoupling operations.Owing to the large number of calculations required for this method,it is inconvenient for practical engineering applications.To simplify the tension generation mechanism and the influence of the nonlinear characteristics of the winding system,a simpler nonlinear dynamic model of the winding tension was established.An adaptive method was applied to update the feedback gain of the continuous robust integral of the sign of the error(RISE).Furthermore,an extended state observer was used to estimate modeling errors and external disturbances.The model disturbance term can be compensated for in the designed RISE controller.The asymptotic stability of the system was proven according to the Lyapunov stability theory.Finally,a comparative analysis of the proposed nonlinear controller and several other controllers was performed.The results indicated that the control of the winding tension was significantly enhanced. 展开更多
关键词 winding tension Continuous robust integral of the sign of the error(RISE)control Adaptive control Disturbance compensation Extended state observer(ESO) Tension control
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Analysis and Control of a Three-Phase Switched Reluctance Wind Generator
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作者 Hassan Bazzi Ali Oshieba +1 位作者 Ahmed Fathy Fahmy El-Khouly 《Journal of Energy and Power Engineering》 2013年第3期545-551,共7页
This paper deals with various aspects of modeling, simulation, analysis, and control ofa SRG (switched reluctance generator) in different modes of operation. Excitation method of such a generator is shortly describe... This paper deals with various aspects of modeling, simulation, analysis, and control ofa SRG (switched reluctance generator) in different modes of operation. Excitation method of such a generator is shortly described. The output power of the SRG is controlled so that it can track the maximum output power of a wind turbine drive applications. Also, the output generator voltage is stabilized under either load or wind speed variations. Basic operational characteristics of a three-phase 6/4 SRG are developed through experimental observation. Meanwhile, the real-time operation was implemented in a DSP (digital signal processor) environment. The simulation of the complete system model has been obtained using the Matlab/Simulink software. A good agreement between experimental and simulation results has been observed which supports the validity of the proposed analysis. 展开更多
关键词 Switched reluctance generator wind power generation variable speed drives.
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Grid Harmonic and Control Delay Compensation for Three-phase Grid-connected VSIs in Small Wind Turbine Systems
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作者 Mary Kaye Chris Diduch Idris Gadoura 《电力电子技术》 CSCD 北大核心 2011年第8期24-31,共8页
Voltage space vector pulse-width modulation(SVPWM) has been widely applied to control current in three-phase voltage source inverters(VSI).However,as a voltage type modulator,SVPWM has certain drawbacks compared with ... Voltage space vector pulse-width modulation(SVPWM) has been widely applied to control current in three-phase voltage source inverters(VSI).However,as a voltage type modulator,SVPWM has certain drawbacks compared with current type modulators for grid-connected applications.For a grid-connected VSI,the performance of existing current controllers based on SVPWM is compromised by grid harmonics,control delay and system nonlinearities such as switching dead time.Moreover,unlike current type PWM,SVPWM does not inherently have over-current protection.A novel SVPWM-based current controller is proposed for three-phase grid-connected VSIs for small wind turbine appli-cations.To overcome the drawbacks of SVPWM,a grid harmonic compensation method is proposed along with compen-sation for control delays.Both simulation and experimental results have established excellent steady-state response and fast dynamic response of the current controller.In addition,the DSP-based control system has both improved real-time control performance and fast response for over-current protection. 展开更多
关键词 摘要 编辑部 编辑工作 作者
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Analysis of rock physics response of gas-bearing volcanic reservoir based on three-phase poroelastic theory 被引量:3
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作者 吴清岭 赵海波 +1 位作者 李来林 范兴才 《Applied Geophysics》 SCIE CSCD 2008年第4期277-283,共7页
Unlike previous theories with velocity and/or elastic modulus averaging, we use a three-phase porous rock physics model developed by Santos for analyzing the seismic response of two immiscible fluids in saturated poro... Unlike previous theories with velocity and/or elastic modulus averaging, we use a three-phase porous rock physics model developed by Santos for analyzing the seismic response of two immiscible fluids in saturated porous media. Considering reservoir reference pressure and coupling drag of two fluids in pores, the effects of frequency, porosity, and gas saturation on the phase velocities of the P-and S-waves are discussed in detail under field conditions. The effects of porosity and gas saturation on Vp/Vs are also provided. The data for our numerical experiments are from a sample of deep volcanic rock from Daqing. The numerical results show that the frequency dispersion effect can be ignored for deep volcanic rocks with low porosity and low permeability. It is concluded that for deep volcanic rocks the effect of gas content in pores on Vp/Vs is negligible but the effect of porosity is significant when there is a certain amount of water contained in the pores. The accurate estimate of lithology and porosity in this case is relatively more important. 展开更多
关键词 rock physics three-phase porous media seismic response and volcanic rock
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THREE-PHASE BRIDGE INVERTER FOR 9kW DOUBLY SALIENT PERMANENT MAGNET MOTOR
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作者 黄伟君 秦海鸿 +1 位作者 王慧贞 严仰光 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2006年第1期27-33,共7页
The three-phase bridge inverter is used as the converter topology in the power controller for a 9 kW doubly salient permanent magnet (DSPM) motor. Compared with common three-phase bridge inverters, the proposed inve... The three-phase bridge inverter is used as the converter topology in the power controller for a 9 kW doubly salient permanent magnet (DSPM) motor. Compared with common three-phase bridge inverters, the proposed inverter works under more complicated conditions with different principles for special winding back EMFs, position signals of hall sensors, and the given mode of switches. The ideal steady driving principles of the inverter for the motor are given. The working state with asymmetric winding back EMFs, inaccurate position signals of hall sensors, and the changing input voltage is analyzed. Finally, experimental results vertify that the given anal ysis is correct. 展开更多
关键词 doubly salient permanent magnet motor three-phase bridge inverter winding back EMF position signal of hall sensor input voltage
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COMPARISON AND EVALUATION OF CURRENT REFERENCE GENERATION STRATEGIES FOR ACTIVE POWER FILTERS IN THREE-PHASE FOUR-WIRE SYSTEMS
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作者 陈东华 郭涛 +1 位作者 谢少军 周波 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2005年第4期298-306,共9页
For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous act... For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous active current (IAC) methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result. 展开更多
关键词 active power filters instantaneous reactive power current reference three-phase four wire power
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A Novel Open-winding Permanent Magnetic Starter-generator 被引量:13
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作者 魏佳丹 周波 +3 位作者 韩楚 邓清唐 史明明 刘颖 《中国电机工程学报》 EI CSCD 北大核心 2011年第36期I0008-I0008,243,共1页
针对永磁电机应用于车载起动/发电系统时存在的电压调节困难、适用转速范围窄、功率因数较低等问题,提出一种新型永磁车载起动/发电系统。通过引入绕组开路型永磁电机,绕组一端接整流桥形成输出直流侧,另一端接逆变桥形成控制端,... 针对永磁电机应用于车载起动/发电系统时存在的电压调节困难、适用转速范围窄、功率因数较低等问题,提出一种新型永磁车载起动/发电系统。通过引入绕组开路型永磁电机,绕组一端接整流桥形成输出直流侧,另一端接逆变桥形成控制端,构成具有宽转速范围和高效率的永磁电机起动/发电系统。分析该系统的起动、发电一体化工作原理,给出了通过逆变侧变换器实现发电机电压、电流控制的方案。仿真和实验结果表明,该新型车载起动/发电系统具有优良的发电调压控制性能,并且适应较宽的转速范围。 展开更多
关键词 永磁起动机 永磁发电机 开放式 绕组 起动发电机 电压调节 功率因数 生成模式
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Calculation of torque and speed of induction machines under rotor winding faults
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作者 马宏忠 胡虔生 +1 位作者 黄允凯 张利民 《Journal of Southeast University(English Edition)》 EI CAS 2005年第1期39-43,共5页
Based on the multi-loop method, the rotating torque and speed of theinduction machine are analyzed. The fluctuating components of the torque and speed caused by rotorwinding faults are studied. The models for calculat... Based on the multi-loop method, the rotating torque and speed of theinduction machine are analyzed. The fluctuating components of the torque and speed caused by rotorwinding faults are studied. The models for calculating the fluctuating components are put forward.Simulation and computation results show that the rotor winding faults will cause electromagnetictorque and rotating speed to fluctuate; and fluctuating frequencies are the same and their magnitudewill increase with the rise of the severity of the faults. The load inertia affects the torque andspeed fluctuation, with the increase of inertia, the fluctuation of the torque will rise, while thecorresponding speed fluctuation will obviously decline. 展开更多
关键词 induction machine rotor winding fault TORQUE SPEED fluctuating
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Electromagnetic Design of a Switched Reluctance Motor With Segmental Rotors and Full-pitch Windings 被引量:9
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作者 陈小元 邓智泉 +1 位作者 许培林 范娜 《中国电机工程学报》 EI CSCD 北大核心 2011年第36期I0010-I0010,245,共1页
整距绕组分块转子开关磁阻电机具有高速运行时低风(油)阻和低铁心损耗等优点,特别适合用于航天航空驱动系统。根据整距绕组分块转子开关磁阻电机的基本工作原理,结合输出功率与平均转矩的关系,将绕组电流等效为方波,推导出了整距... 整距绕组分块转子开关磁阻电机具有高速运行时低风(油)阻和低铁心损耗等优点,特别适合用于航天航空驱动系统。根据整距绕组分块转子开关磁阻电机的基本工作原理,结合输出功率与平均转矩的关系,将绕组电流等效为方波,推导出了整距绕组分块转子开关磁阻电机的主体尺寸计算公式;基于电机定转子未对齐位置和对齐位置的电磁特性,以及整距绕组分块转子开关磁阻电机的电磁特点,确定了定、转子极弧系数选取的规则;同时分析了绕组匝数等主要尺寸的选取的规则;最后,基于上述方法优化设计了一台实验样机,并通过有限元仿真及实验验证了整距绕组分块转子开关磁阻电机的电磁设计方法的正确性。 展开更多
关键词 开关磁阻电机 电磁设计 绕组 节距 转子 节段 开关磁阻电动机 航空航天环境
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Simulation and calculation of internal faults in long-stator linear synchronous motor based on winding function theory 被引量:1
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作者 于芳 余海涛 胡敏强 《Journal of Southeast University(English Edition)》 EI CAS 2010年第1期53-57,共5页
To guarantee the safety of the high speed maglev train system, a novel model based on the winding function theory is proposed for the long-stator linear synchronous motor(LSM), which is suitable for the real-time ca... To guarantee the safety of the high speed maglev train system, a novel model based on the winding function theory is proposed for the long-stator linear synchronous motor(LSM), which is suitable for the real-time calculation of the running state. The accurate coupled mathematical models under different internal fault conditions of the LSM are derived based on the normal model. Then the fault currents and electromagnetic forces are simulated and calculated for the major potential internal faults of the LSM, such as the single-phase short circuit, the phase-phase short circuit and the single-phase open circuit. The characteristic curve between the electromagnetic force and the armature current of the LSM, which is compared with the results from the finite element method, proves the validation of the proposed method. The fault rule is determined and the proposed analytical model also shows its feasibility in the fast fault diagnosis through the comparison of the simulation results of currents and electromagnetic forces under different internal fault types and short circuit ratios. 展开更多
关键词 long-stator linear synchronous motor winding function theory internal faults
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Design and Analysis of a Novel Tension Control Method for Winding Machine 被引量:7
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作者 Xiao-Ming Xu Wu-Xiang Zhang +2 位作者 Xi-Lun Ding Ming Zhang Shi-Hou Wei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2018年第6期79-94,共16页
Filament winding has emerged as the main process for carbon fiber reinforced plastic(CFRP) fabrication, and tension control plays a key role in enhancing the quality of the winding products. With the continuous improv... Filament winding has emerged as the main process for carbon fiber reinforced plastic(CFRP) fabrication, and tension control plays a key role in enhancing the quality of the winding products. With the continuous improvement of prod?uct quality and e ciency, the precision of the tension control system is constantly improving. In this paper, a novel tension control method is proposed, which can regulate the fiber tension and transport speed of the winding process by governing the outputs of three di erent driven rollers(the torque of the unwind roll, the torque of the magnetic powder brake roller, and the speed of the master speed roller) in three levels. The mechanical structures and dynamic models of the driven rollers and idle rollers are established by considering the time?varying features of the roller radius and inertia. Moreover, the influence of parameters and speed variation on fiber tension is investigated using the increment model. Subsequently, the control method is proposed by applying fiber tension in three levels accord?ing to the features of the three driven rollers. An adaptive fuzzy controller is designed for tuning the PID parameters online to control the speed of the master speed roller. Simulation is conducted for verifying the performance and sta?bility of the proposed tension control method by comparing with those of the conventional PID control method. The result reveals that the proposed method outperforms the conventional method. Finally, an experimental platform is constructed, and the proposed system is applied to a winding machine. The performance and stability of the tension control system are demonstrated via a series of experiments using carbon fiber under di erent reference speeds and tensions. This paper proposes a novel tension control method to regulate the fiber tension and transport speed. 展开更多
关键词 Tension control Control method Fuzzy logic Filament winding
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Abnormal Shape Mould Winding 被引量:5
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作者 Fu Hongya Wang Xianfeng Han Zhenyu Fu Yunzhong 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2007年第6期552-558,共7页
A theory of composite material patch winding is proposed to determine the winding trajectory with a meshed data model. Two different conditions are considered in this study. One is Bridge condition on the concave surf... A theory of composite material patch winding is proposed to determine the winding trajectory with a meshed data model. Two different conditions are considered in this study. One is Bridge condition on the concave surface and the other is Slip line condition in the process of patch winding. This paper presents the judgment principles and corresponding solutions by applying differential geometry theory and space geometry theory. To verify the feasibility of the patch winding method, the winding control code is programmed. Furthermore, the winding experiments on an airplane inlet and a vane are performed. From the experiments, it shows that the patch winding theory has the advantages of flexibility, easy design and application. 展开更多
关键词 filament winding fiber technology composite material airplane inlet VANE
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Stability analysis of unsaturated soil slope during rainfall infiltration using coupled liquid-gas-solid three-phase model 被引量:13
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作者 Dong-mei Sun Xiao-min Li +1 位作者 Ping Feng Yong-ge Zang 《Water Science and Engineering》 EI CAS CSCD 2016年第3期183-194,共12页
Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loos... Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loosely coupled liquid-gas-solid three-phase model, linking two numerical codes,TOUGH2/EOS3, which is used for water-air two-phase flow analysis, and FLAC^(3D), which is used for mechanical analysis, was established. The model was validated through a documented water drainage experiment over a sandy column and a comparison of the results with measured data and simulated results from other researchers. The proposed model was used to investigate the features of water-air two-phase flow and stress fields in an unsaturated soil slope during rainfall infiltration. The slope stability analysis was then performed based on the simulated water-air two-phase seepage and stress fields on a given slip surface. The results show that the safety factor for the given slip surface decreases first, then increases, and later decreases until the rainfall stops. Subsequently, a sudden rise occurs. After that, the safety factor decreases continually and reaches its lowest value, and then increases slowly to a steady value. The lowest value does not occur when the rainfall stops, indicating a delayed effect of the safety factor. The variations of the safety factor for the given slip surface are therefore caused by a combination of pore-air pressure, matric suction, normal stress, and net normal stress. 展开更多
关键词 COUPLED liquid-gas-solid three-phase model Pore-air pressure UNSATURATED soil slope stability Rainfall INFILTRATION
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应用Winding-Number算法快速确定中国地震地理位置名称
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作者 任枭 殷翔 +1 位作者 徐志国 孙丽 《地震地磁观测与研究》 2011年第4期145-151,共7页
应用winding Number算法,快速确定中国地震地理位置名称(精确到县市区一级),查询过程具有准确性、高效性和误差小等特点。根据实际要求,将地名查询程序应用到F-E分区程序,可得到中国地震地理位置详细名称,顺应地震观测报告的出版要求,... 应用winding Number算法,快速确定中国地震地理位置名称(精确到县市区一级),查询过程具有准确性、高效性和误差小等特点。根据实际要求,将地名查询程序应用到F-E分区程序,可得到中国地震地理位置详细名称,顺应地震观测报告的出版要求,为地震基础科学研究提供便利。 展开更多
关键词 winding-Number算法 中国地震 查询 地名
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Three-phase flow of submarine gas hydrate pipe transport 被引量:7
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作者 李立 徐海良 杨放琼 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第9期3650-3656,共7页
In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-p... In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-phase flow(hydrate and water) transforms into gas-solid-liquid three-phase flow(methane, hydrate and water) inside the pipeline. The Euler model and CFD-PBM model were used to simulate gas-solid-liquid three-phase flow. Numerical simulation results show that the gas and solid phase gradually accumulate to the center of the pipe. Flow velocity decreases from center to boundary of the pipe along the radial direction. Comparison of numerical simulation results of two models reveals that the flow state simulated by CFD-PBM model is more uniform than that simulated by Euler model, and the main behavior of the bubble is small bubbles coalescence to large one. Comparison of numerical simulation and experimental investigation shows that the values of flow velocity and gas fraction in CFD-PBM model agree with experimental data better than those in Euler model. The proposed PBM model provides a more accurate and effective way to estimate three-phase flow state of transporting gas hydrate within the submarine pipeline. 展开更多
关键词 gas hydrate pipe transport three-phase flow Euler model CFD-PBM model
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AmmAmmoximation of Cyclohexanone to Cyclohexanone Oxime Catalyzed by Titanium Silicalite-1 Zeolite in Three-phase System 被引量:7
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作者 刘国清 吴剑 罗和安 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第5期889-894,共6页
An innovative green process of producing ε-caprolactam was proposed by integrating ammoximation and Beckmann rearrangement effectively. As a first part of the new process, TS-1 molecular sieve-catalyzed synthesis of ... An innovative green process of producing ε-caprolactam was proposed by integrating ammoximation and Beckmann rearrangement effectively. As a first part of the new process, TS-1 molecular sieve-catalyzed synthesis of cyclohexanone oxime from cyclohexanone, ammonia and hydrogen peroxide was carried out in a batch plant. Cyclohexane was used as the solvent in the three-phase reaction system. The influences of essential process parameters on ammoximation were investigated. Under the reaction conditions as catalyst content of 2.5% (by mass); H 2 O 2 /yclohexanone molar ratio of 1.10; NH 3 /cyclohexanone molar ratio of 2.20; reaction temperature of 343 K; reaction time of 5 h, high conversion of cyclohexanone and selectivity to oxime (both>99%) were obtained. Thus, the three-phase ammoximation process showed equal catalytic activity as TS-1 but much more convenient and simpler for the separation of catalyst in comparison to the industrial two-phase system with t-butanol used as solvent. 展开更多
关键词 AMMOXIMATION molecular sieve TS-1 cyclohexanone oxime CYCLOHEXANE three-phase system
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