We aim to explore all possible scenarios of(1→2)(where one wing is untrusted and the others two wings are trusted)and(2→1)(where two wings are untrusted,and one wing is trusted)genuine tripartite Einstein-Podolsky-R...We aim to explore all possible scenarios of(1→2)(where one wing is untrusted and the others two wings are trusted)and(2→1)(where two wings are untrusted,and one wing is trusted)genuine tripartite Einstein-Podolsky-Rosen(EPR)steering.The generalized Greenberger-Horne-Zeilinger(GHZ)state is shared between three spatially separated parties,Alice,Bob and Charlie.In both(1→2)and(2→1),we discuss the untrusted party and trusted party performing a sequence of unsharp measurements,respectively.For each scenario,we deduce an upper bound on the number of sequential observers who can demonstrate genuine EPR steering through the quantum violation of tripartite steering inequality.The results show that the maximum number of observers for the generalized GHZ states can be the same with that of the maximally GHZ state in a certain range of state parameters.Moreover,both the sharpness parameters range and the state parameters range in the scenario of(1→2)steering are larger than those in the scenario of(2→1)steering.展开更多
The entangled orbital angular momentum(OAM) three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. T...The entangled orbital angular momentum(OAM) three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. The results indicate that the entangled OAM three-qubit state with higher OAM modes will be more robust against turbulence.Furthermore, it is found that the entangled OAM three-qubit state has a higher overall transmission for small OAM values.展开更多
A new application of cluster states is investigated for quantum information splitting (QIS) of an arbitrary three-qubit state. In our scheme, a four-qubit cluster state and a Bell state are shared by a sender (Alic...A new application of cluster states is investigated for quantum information splitting (QIS) of an arbitrary three-qubit state. In our scheme, a four-qubit cluster state and a Bell state are shared by a sender (Alice), a controller (Charlie), and a receiver (Bob). Both the sender and controller only need to perform Bell-state measurements (BSMs), the receiver can reconstruct the arbitrary three-qubit state by performing some appropriately unitary transformations on his qubits after he knows the measured results of both the sender and the controller. This QIS scheme is deterministic.展开更多
Recently Jiang et al.[Chin.Phys.Lett.24 (2007) 1144] gave a scheme for probabilistic controlled tele-portation of a triplet W state from the sender Alice to the distant receiver Bob.The m controlled qubits are sharedb...Recently Jiang et al.[Chin.Phys.Lett.24 (2007) 1144] gave a scheme for probabilistic controlled tele-portation of a triplet W state from the sender Alice to the distant receiver Bob.The m controlled qubits are sharedby m(s_1,s_2,...,s_m) spatially-separated supervisors.Based on transformation operator,we can extend to teleporting anarbitrary three-qubit state.The relation between the transformation operators and the Bob's unitary transformation isalso obtained.展开更多
We propose a novel scheme for remote state preparation of an arbitrary three-qubit state with unit success probability,utilizing a nine-qubit cluster-GHZ state without introducing auxiliary qubits.Furthermore,we proce...We propose a novel scheme for remote state preparation of an arbitrary three-qubit state with unit success probability,utilizing a nine-qubit cluster-GHZ state without introducing auxiliary qubits.Furthermore,we proceed to investigate the effects of different quantum noises(e.g.,amplitude-damping,phase-damping,bit-flip and phase-flip noises)on the systems.The fidelity results of three-qubit target state are presented,which are usually used to illustrate how close the output state is to the target state.To compare the different effects between the four common types of quantum noises,the fidelities under one specific identical target state are also calculated and discussed.It is found that the fidelity of the phase-flip noisy channel drops the fastest through the four types of noisy channels,while the fidelity is found to always maintain at 1 in bit-flip noisy channel.展开更多
The application of χ state are investigated in remote state preparation (RSP). By constructing useful measurement bases with the aid of Hurwitz matrix equation, we propose several RSP schemes of arbitrary two- and ...The application of χ state are investigated in remote state preparation (RSP). By constructing useful measurement bases with the aid of Hurwitz matrix equation, we propose several RSP schemes of arbitrary two- and three-qubit states via the χ state as the entangled resource. It is shown that the original state can be successfully prepared with the probability 100% and 50% for real coefficients and complex coefficients, respectively. For the latter case, the special ensembles with unit success probability are discussed by the permutation group. It is worth mentioning that the novel measurement bases have no restrictions on the coefficients of the prepared state, which means that the proposed schemes are more applicable.展开更多
We propose a novel deterministic protocol that two senders are capable of remotely preparing arbitrary two-and three-qubit states for a remote receiver using EPR pairs and GHZ state as the quantum channel.Compared wit...We propose a novel deterministic protocol that two senders are capable of remotely preparing arbitrary two-and three-qubit states for a remote receiver using EPR pairs and GHZ state as the quantum channel.Compared with the existing deterministic protocols [An et al.2011 Phys.Lett.A 375 3570 and Chen et al.2012 J.Phys.A:Math.Theor.45 055303],the quantum resources and classical information in our scheme are decreased,and the whole operation process is simplified.展开更多
We investigate the equivalence of quantum states under local unitary transformations. A complete set of invariants under local unitary transformations are presented for a class of non-generic three-qubit mixed states....We investigate the equivalence of quantum states under local unitary transformations. A complete set of invariants under local unitary transformations are presented for a class of non-generic three-qubit mixed states. It is shown that two such states in this class are locally equivalent if and only if all these invariants have equal values for them.展开更多
Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas denitrification.However,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption...Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas denitrification.However,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption and waste gas emissions.To address this,electrocatalytic nitric oxide reduction reaction(NORR)has emerged as a promising strategy to bridge NH3consumption to NH3production,harnessing renewable electricity for a sustainable future.Copper(Cu)stands out as a prominent electrocatalyst for NO reduction,given its exceptional NH3yield and selectivity.However,a crucial aspect that remains insufficiently explored is the effects of morphology and valence states of Cu on the NORR performance.In this investigation,we synthesized CuO nanowires(CuO-NF)and Cu nanocubes(Cu-NF)as cathodes through an in situ growth method.Remarkably,CuO-NF exhibited an impressive NH3yield of 0.50±0.02 mg cm^(-2)h^(-1)at-0.6 V vs.reversible hydrogen electrode(RHE)with faradaic efficiency of29,68%±1,35%,surpassing that of Cu-NF(0.17±0.01 mg cm^(-2)h^(-1),16.18%±1.40%).Throughout the electroreduction process,secondary cubes were generated on the CuO-NF surface,preserving their nanosheet cluster morphology,sustained by an abundant supply of subsurface oxygen(s-O)even after an extended duration of 10 h,until s-O depletion ensued.Conversely,Cu-NF exhibited inadequate s-O content,leading to rapid crystal collapse within the same timeframe.The distinctive current-potential relationship,akin to a volcano-type curve,was attributed to distinct NO hydrogenation mechanisms.Further Tafel analysis revealed the exchange current density(i0)and standard heterogeneous rate constant(k0)for CuO-NF,yielding 3.44×10^(-6)A cm^(-2)and 3.77×10^(-6)cm^(-2)s^(-1)when NORR was driven by overpotentials.These findings revealed the potential of CuO-NF for NO reduction and provided insights into the intricate interplay between crystal morphology,valence states,and electrochemical performance.展开更多
Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional climate.Here,we assess the performance and discuss pos...Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional climate.Here,we assess the performance and discuss possible causes of biases in a WRF-based RCM with a grid spacing of 50 km,named WRFG,from the North American Regional Climate Change Assessment Program(NARCCAP)in simulating wet season precipitation over the Central United States for a period when observational data are available.The RCM reproduces key features of the precipitation distribution characteristics during late spring to early summer,although it tends to underestimate the magnitude of precipitation.This dry bias is partially due to the model’s lack of skill in simulating nocturnal precipitation related to the lack of eastward propagating convective systems in the simulation.Inaccuracy in reproducing large-scale circulation and environmental conditions is another contributing factor.The too weak simulated pressure gradient between the Rocky Mountains and the Gulf of Mexico results in weaker southerly winds in between,leading to a reduction of warm moist air transport from the Gulf to the Central Great Plains.The simulated low-level horizontal convergence fields are less favorable for upward motion than in the NARR and hence,for the development of moist convection as well.Therefore,a careful examination of an RCM’s deficiencies and the identification of the source of errors are important when using the RCM to project precipitation changes in future climate scenarios.展开更多
Thermal runaway(TR)is a critical issue hindering the large-scale application of lithium-ion batteries(LIBs).Understanding the thermal safety behavior of LIBs at the cell and module level under different state of charg...Thermal runaway(TR)is a critical issue hindering the large-scale application of lithium-ion batteries(LIBs).Understanding the thermal safety behavior of LIBs at the cell and module level under different state of charges(SOCs)has significant implications for reinforcing the thermal safety design of the lithium-ion battery module.This study first investigates the thermal safety boundary(TSB)correspondence at the cells and modules level under the guidance of a newly proposed concept,safe electric quantity boundary(SEQB).A reasonable thermal runaway propagation(TRP)judgment indicator,peak heat transfer power(PHTP),is proposed to predict whether TRP occurs.Moreover,a validated 3D model is used to quantitatively clarify the TSB at different SOCs from the perspective of PHTP,TR trigger temperature,SOC,and the full cycle life.Besides,three different TRP transfer modes are discovered.The interconversion relationship of three different TRP modes is investigated from the perspective of PHTP.This paper explores the TSB of LIBs under different SOCs at both cell and module levels for the first time,which has great significance in guiding the thermal safety design of battery systems.展开更多
Multi-level programmable photonic integrated circuits(PICs)and optical metasurfaces have gained widespread attention in many fields,such as neuromorphic photonics,opticalcommunications,and quantum information.In this ...Multi-level programmable photonic integrated circuits(PICs)and optical metasurfaces have gained widespread attention in many fields,such as neuromorphic photonics,opticalcommunications,and quantum information.In this paper,we propose pixelated programmable Si_(3)N_(4)PICs with record-high 20-level intermediate states at 785 nm wavelength.Such flexibility in phase or amplitude modulation is achieved by a programmable Sb_(2)S_(3)matrix,the footprint of whose elements can be as small as 1.2μm,limited only by the optical diffraction limit of anin-house developed pulsed laser writing system.We believe our work lays the foundation for laser-writing ultra-high-level(20 levels and even more)programmable photonic systems and metasurfaces based on phase change materials,which could catalyze diverse applications such as programmable neuromorphic photonics,biosensing,optical computing,photonic quantum computing,and reconfigurable metasurfaces.展开更多
The expansion of a thick-walled hollow cylinder in soil is of non-self-similar nature that the stress/deformation paths are not the same for different soil material points.As a result,this problem cannot be solved by ...The expansion of a thick-walled hollow cylinder in soil is of non-self-similar nature that the stress/deformation paths are not the same for different soil material points.As a result,this problem cannot be solved by the common self-similar-based similarity techniques.This paper proposes a novel,exact solution for rigorous drained expansion analysis of a hollow cylinder of critical state soils.Considering stress-dependent elastic moduli of soils,new analytical stress and displacement solutions for the nonself-similar problem are developed taking the small strain assumption in the elastic zone.In the plastic zone,the cavity expansion response is formulated into a set of first-order partial differential equations(PDEs)with the combination use of Eulerian and Lagrangian descriptions,and a novel solution algorithm is developed to efficiently solve this complex boundary value problem.The solution is presented in a general form and thus can be useful for a wide range of soils.With the new solution,the non-self-similar nature induced by the finite outer boundary is clearly demonstrated and highlighted,which is found to be greatly different to the behaviour of cavity expansion in infinite soil mass.The present solution may serve as a benchmark for verifying the performance of advanced numerical techniques with critical state soil models and be used to capture the finite boundary effect for pressuremeter tests in small-sized calibration chambers.展开更多
Inflammation is closely related to stroke prognosis, and high inflammation status leads to poor functional outcome in stroke. DNA methylation is involved in the pathogenesis and prognosis of stroke. However, the effec...Inflammation is closely related to stroke prognosis, and high inflammation status leads to poor functional outcome in stroke. DNA methylation is involved in the pathogenesis and prognosis of stroke. However, the effect of DNA methylation on stroke at high levels of inflammation is unclear. In this study, we constructed a hyperinflammatory cerebral ischemia mouse model and investigated the effect of hypomethylation and hypermethylation on the functional outcome. We constructed a mouse model of transient middle cerebral artery occlusion and treated the mice with lipopolysaccharide to induce a hyperinflammatory state. To investigate the effect of DNA methylation on stroke, we used small molecule inhibitors to restrain the function of key DNA methylation and demethylation enzymes. 2,3,5-Triphenyltetrazolium chloride staining, neurological function scores, neurobehavioral tests, enzyme-linked immunosorbent assay, quantitative reverse transcription PCR and western blot assay were used to evaluate the effects after stroke in mice. We assessed changes in the global methylation status by measuring DNA 5-mc and DNA 5-hmc levels in peripheral blood after the use of the inhibitor. In the group treated with the DNA methylation inhibitor, brain tissue 2,3,5-triphenyltetrazolium chloride staining showed an increase in infarct volume, which was accompanied by a decrease in neurological scores and worsening of neurobehavioral performance. The levels of inflammatory factors interleukin 6 and interleukin-1 beta in ischemic brain tissue and plasma were elevated, indicating increased inflammation. Related inflammatory pathway exploration showed significant overactivation of nuclear factor kappa B. These results suggested that inhibiting DNA methylation led to poor functional outcome in mice with high inflammation following stroke. Further, the effects were reversed by inhibition of DNA demethylation. Our findings suggest that DNA methylation regulates the inflammatory response in stroke and has an important role in the functional outcome of hyperinflammatory stroke.展开更多
BACKGROUND Regarding the incidence of malignant tumors in China,the incidence of liver cancer ranks fourth,second only to lung,gastric,and esophageal cancers.The case fatality rate ranks third after lung and cervical ...BACKGROUND Regarding the incidence of malignant tumors in China,the incidence of liver cancer ranks fourth,second only to lung,gastric,and esophageal cancers.The case fatality rate ranks third after lung and cervical cancer.In a previous study,the whole-process management model was applied to patients with breast cancer,which effectively reduced their negative emotions and improved treatment adherence and nursing satisfaction.METHODS In this single-center,randomized,controlled study,60 randomly selected patients with liver cancer who had been admitted to our hospital from January 2021 to January 2022 were randomly divided into an observation group(n=30),who received whole-process case management on the basis of routine nursing mea-sures,and a control group(n=30),who were given routine nursing measures.We compared differences between the two groups in terms of anxiety,depression,the level of hope,self-care ability,symptom distress,sleep quality,and quality of life.RESULTS Post-intervention,Hamilton anxiety scale,Hamilton depression scale,memory symptom assessment scale,and Pittsburgh sleep quality index scores in both groups were lower than those pre-intervention,and the observation group had lower scores than the control group(P<0.05).Herth hope index,self-care ability assessment scale-revision in Chinese,and quality of life measurement scale for patients with liver cancer scores in both groups were higher than those pre-intervention,with higher scores in the observation group compared with the control group(P<0.05).CONCLUSION Whole-process case management can effectively reduce anxiety and depression in patients with liver cancer,alleviate symptoms and problems,and improve the level of hope,self-care ability,sleep quality,and quality of life,as well as provide feasible nursing alternatives for patients with liver cancer.展开更多
Neural networks are becoming ubiquitous in various areas of physics as a successful machine learning(ML)technique for addressing different tasks.Based on ML technique,we propose and experimentally demonstrate an effic...Neural networks are becoming ubiquitous in various areas of physics as a successful machine learning(ML)technique for addressing different tasks.Based on ML technique,we propose and experimentally demonstrate an efficient method for state reconstruction of the widely used Sagnac polarization-entangled photon source.By properly modeling the target states,a multi-output fully connected neural network is well trained using only six of the sixteen measurement bases in standard tomography technique,and hence our method reduces the resource consumption without loss of accuracy.We demonstrate the ability of the neural network to predict state parameters with a high precision by using both simulated and experimental data.Explicitly,the mean absolute error for all the parameters is below 0.05 for the simulated data and a mean fidelity of 0.99 is achieved for experimentally generated states.Our method could be generalized to estimate other kinds of states,as well as other quantum information tasks.展开更多
In many engineering networks, only a part of target state variables are required to be estimated.On the other hand,multi-layer complex network exists widely in practical situations.In this paper, the state estimation ...In many engineering networks, only a part of target state variables are required to be estimated.On the other hand,multi-layer complex network exists widely in practical situations.In this paper, the state estimation of target state variables in multi-layer complex dynamical networks with nonlinear node dynamics is studied.A suitable functional state observer is constructed with the limited measurement.The parameters of the designed functional observer are obtained from the algebraic method and the stability of the functional observer is proven by the Lyapunov theorem.Some necessary conditions that need to be satisfied for the design of the functional state observer are obtained.Different from previous studies, in the multi-layer complex dynamical network with nonlinear node dynamics, the proposed method can estimate the state of target variables on some layers directly instead of estimating all the individual states.Thus, it can greatly reduce the placement of observers and computational cost.Numerical simulations with the three-layer complex dynamical network composed of three-dimensional nonlinear dynamical nodes are developed to verify the effectiveness of the method.展开更多
We present a stable valley photonic crystal(VPC)unit cell with C_(3v)symmetric quasi-ring-shaped dielectric columns and realize its topological phase transition by breaking mirror symmetry.Based on this unit cell stru...We present a stable valley photonic crystal(VPC)unit cell with C_(3v)symmetric quasi-ring-shaped dielectric columns and realize its topological phase transition by breaking mirror symmetry.Based on this unit cell structure,topological edge states(TESs)and topological corner states(TCSs)are realized.We obtain a new type of wave transmission mode based on photonic crystal zipper-like boundaries and apply it to a beam splitter assembled from rectangular photonic crystals(PCs).The constructed beam splitter structure is compact and possesses frequency separation functions.In addition,we construct a box-shaped triangular PC structures with zipper-like boundaries and discover phenomena of TCSs in the corners,comparing its corner states with those formed by other boundaries.Based on this,we explore the regularities of the electric field patterns of TESs and TCSs,explain the connection between the characteristic frequencies and locality of TCSs,which helps better control photons and ensures low power consumption of the system.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62171056 and 61973021)Henan Key Laboratory of Network Cryptography Technology(Grant No.LNCT2022-A03)。
文摘We aim to explore all possible scenarios of(1→2)(where one wing is untrusted and the others two wings are trusted)and(2→1)(where two wings are untrusted,and one wing is trusted)genuine tripartite Einstein-Podolsky-Rosen(EPR)steering.The generalized Greenberger-Horne-Zeilinger(GHZ)state is shared between three spatially separated parties,Alice,Bob and Charlie.In both(1→2)and(2→1),we discuss the untrusted party and trusted party performing a sequence of unsharp measurements,respectively.For each scenario,we deduce an upper bound on the number of sequential observers who can demonstrate genuine EPR steering through the quantum violation of tripartite steering inequality.The results show that the maximum number of observers for the generalized GHZ states can be the same with that of the maximally GHZ state in a certain range of state parameters.Moreover,both the sharpness parameters range and the state parameters range in the scenario of(1→2)steering are larger than those in the scenario of(2→1)steering.
基金supported by the National Defense Innovation Foundation of China,Chinese Academy of Sciences(Grant No.CXJJ-16S080)
文摘The entangled orbital angular momentum(OAM) three photons propagating in Kolmogorov weak turbulence are investigated. Here, the single phase screen model is used to study the entanglement evolution of OAM photons. The results indicate that the entangled OAM three-qubit state with higher OAM modes will be more robust against turbulence.Furthermore, it is found that the entangled OAM three-qubit state has a higher overall transmission for small OAM values.
基金*Supported by the National Natural Science Foundation of China under Grant No. 60807014, the Natural Science Foundation of Jiangxi Province of China under Grant No. 2009GZW0005, the Research Foundation of state key laboratory of advanced optical communication systems and networks, and the Research Foundation of the Education Department of Jiangxi Province under Grant No. G J J09153
文摘A new application of cluster states is investigated for quantum information splitting (QIS) of an arbitrary three-qubit state. In our scheme, a four-qubit cluster state and a Bell state are shared by a sender (Alice), a controller (Charlie), and a receiver (Bob). Both the sender and controller only need to perform Bell-state measurements (BSMs), the receiver can reconstruct the arbitrary three-qubit state by performing some appropriately unitary transformations on his qubits after he knows the measured results of both the sender and the controller. This QIS scheme is deterministic.
基金Natural Science Foundation of Shaanxi Province under Grant No.2004A15the Science Plan Foundation of the Education Department of Shaanxi Province under Grant No.05JK288
文摘Recently Jiang et al.[Chin.Phys.Lett.24 (2007) 1144] gave a scheme for probabilistic controlled tele-portation of a triplet W state from the sender Alice to the distant receiver Bob.The m controlled qubits are sharedby m(s_1,s_2,...,s_m) spatially-separated supervisors.Based on transformation operator,we can extend to teleporting anarbitrary three-qubit state.The relation between the transformation operators and the Bob's unitary transformation isalso obtained.
基金supported by the Tang Scholar Project of Soochow Universitythe National Natural Science Foundation of China(Grant No.61873162)+1 种基金the Open Research Project of the State Key Laboratory of Industrial Control Technology,Zhejiang University(Grant No.ICT2021B24)China Jiangsu Engineering Research Center of Novel Optical Fiber Technology and Communication Network and Suzhou Key Laboratory of Advanced Optical Communication Network Technology。
文摘We propose a novel scheme for remote state preparation of an arbitrary three-qubit state with unit success probability,utilizing a nine-qubit cluster-GHZ state without introducing auxiliary qubits.Furthermore,we proceed to investigate the effects of different quantum noises(e.g.,amplitude-damping,phase-damping,bit-flip and phase-flip noises)on the systems.The fidelity results of three-qubit target state are presented,which are usually used to illustrate how close the output state is to the target state.To compare the different effects between the four common types of quantum noises,the fidelities under one specific identical target state are also calculated and discussed.It is found that the fidelity of the phase-flip noisy channel drops the fastest through the four types of noisy channels,while the fidelity is found to always maintain at 1 in bit-flip noisy channel.
基金supported by the National Natural Science Foundation of China(Grant Nos.61201253 and 61303039)the Fundamental Research Funds for the Central Universities of China(Grant No.2682014CX095)
文摘The application of χ state are investigated in remote state preparation (RSP). By constructing useful measurement bases with the aid of Hurwitz matrix equation, we propose several RSP schemes of arbitrary two- and three-qubit states via the χ state as the entangled resource. It is shown that the original state can be successfully prepared with the probability 100% and 50% for real coefficients and complex coefficients, respectively. For the latter case, the special ensembles with unit success probability are discussed by the permutation group. It is worth mentioning that the novel measurement bases have no restrictions on the coefficients of the prepared state, which means that the proposed schemes are more applicable.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11064016 and 61068001)
文摘We propose a novel deterministic protocol that two senders are capable of remotely preparing arbitrary two-and three-qubit states for a remote receiver using EPR pairs and GHZ state as the quantum channel.Compared with the existing deterministic protocols [An et al.2011 Phys.Lett.A 375 3570 and Chen et al.2012 J.Phys.A:Math.Theor.45 055303],the quantum resources and classical information in our scheme are decreased,and the whole operation process is simplified.
基金The project supported by the National Natural Science Foundation of China under Grant No. 10375038
文摘We investigate the equivalence of quantum states under local unitary transformations. A complete set of invariants under local unitary transformations are presented for a class of non-generic three-qubit mixed states. It is shown that two such states in this class are locally equivalent if and only if all these invariants have equal values for them.
基金supported by the Fundamental Research Funds for the Central Universities(FRF-EYIT-23-07)。
文摘Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas denitrification.However,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption and waste gas emissions.To address this,electrocatalytic nitric oxide reduction reaction(NORR)has emerged as a promising strategy to bridge NH3consumption to NH3production,harnessing renewable electricity for a sustainable future.Copper(Cu)stands out as a prominent electrocatalyst for NO reduction,given its exceptional NH3yield and selectivity.However,a crucial aspect that remains insufficiently explored is the effects of morphology and valence states of Cu on the NORR performance.In this investigation,we synthesized CuO nanowires(CuO-NF)and Cu nanocubes(Cu-NF)as cathodes through an in situ growth method.Remarkably,CuO-NF exhibited an impressive NH3yield of 0.50±0.02 mg cm^(-2)h^(-1)at-0.6 V vs.reversible hydrogen electrode(RHE)with faradaic efficiency of29,68%±1,35%,surpassing that of Cu-NF(0.17±0.01 mg cm^(-2)h^(-1),16.18%±1.40%).Throughout the electroreduction process,secondary cubes were generated on the CuO-NF surface,preserving their nanosheet cluster morphology,sustained by an abundant supply of subsurface oxygen(s-O)even after an extended duration of 10 h,until s-O depletion ensued.Conversely,Cu-NF exhibited inadequate s-O content,leading to rapid crystal collapse within the same timeframe.The distinctive current-potential relationship,akin to a volcano-type curve,was attributed to distinct NO hydrogenation mechanisms.Further Tafel analysis revealed the exchange current density(i0)and standard heterogeneous rate constant(k0)for CuO-NF,yielding 3.44×10^(-6)A cm^(-2)and 3.77×10^(-6)cm^(-2)s^(-1)when NORR was driven by overpotentials.These findings revealed the potential of CuO-NF for NO reduction and provided insights into the intricate interplay between crystal morphology,valence states,and electrochemical performance.
文摘Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional climate.Here,we assess the performance and discuss possible causes of biases in a WRF-based RCM with a grid spacing of 50 km,named WRFG,from the North American Regional Climate Change Assessment Program(NARCCAP)in simulating wet season precipitation over the Central United States for a period when observational data are available.The RCM reproduces key features of the precipitation distribution characteristics during late spring to early summer,although it tends to underestimate the magnitude of precipitation.This dry bias is partially due to the model’s lack of skill in simulating nocturnal precipitation related to the lack of eastward propagating convective systems in the simulation.Inaccuracy in reproducing large-scale circulation and environmental conditions is another contributing factor.The too weak simulated pressure gradient between the Rocky Mountains and the Gulf of Mexico results in weaker southerly winds in between,leading to a reduction of warm moist air transport from the Gulf to the Central Great Plains.The simulated low-level horizontal convergence fields are less favorable for upward motion than in the NARR and hence,for the development of moist convection as well.Therefore,a careful examination of an RCM’s deficiencies and the identification of the source of errors are important when using the RCM to project precipitation changes in future climate scenarios.
基金supported by the National Natural Science Foundation of China(No.U20A20310 and No.52176199)sponsored by the Program of Shanghai Academic/Technology Research Leader(No.22XD1423800)。
文摘Thermal runaway(TR)is a critical issue hindering the large-scale application of lithium-ion batteries(LIBs).Understanding the thermal safety behavior of LIBs at the cell and module level under different state of charges(SOCs)has significant implications for reinforcing the thermal safety design of the lithium-ion battery module.This study first investigates the thermal safety boundary(TSB)correspondence at the cells and modules level under the guidance of a newly proposed concept,safe electric quantity boundary(SEQB).A reasonable thermal runaway propagation(TRP)judgment indicator,peak heat transfer power(PHTP),is proposed to predict whether TRP occurs.Moreover,a validated 3D model is used to quantitatively clarify the TSB at different SOCs from the perspective of PHTP,TR trigger temperature,SOC,and the full cycle life.Besides,three different TRP transfer modes are discovered.The interconversion relationship of three different TRP modes is investigated from the perspective of PHTP.This paper explores the TSB of LIBs under different SOCs at both cell and module levels for the first time,which has great significance in guiding the thermal safety design of battery systems.
基金funded by the National Nature Science Foundation of China(Grant Nos.52175509 and 52130504)National Key Research and Development Program of China(2017YFF0204705)2021 Postdoctoral Innovation Research Plan of Hubei Province(0106100226)。
文摘Multi-level programmable photonic integrated circuits(PICs)and optical metasurfaces have gained widespread attention in many fields,such as neuromorphic photonics,opticalcommunications,and quantum information.In this paper,we propose pixelated programmable Si_(3)N_(4)PICs with record-high 20-level intermediate states at 785 nm wavelength.Such flexibility in phase or amplitude modulation is achieved by a programmable Sb_(2)S_(3)matrix,the footprint of whose elements can be as small as 1.2μm,limited only by the optical diffraction limit of anin-house developed pulsed laser writing system.We believe our work lays the foundation for laser-writing ultra-high-level(20 levels and even more)programmable photonic systems and metasurfaces based on phase change materials,which could catalyze diverse applications such as programmable neuromorphic photonics,biosensing,optical computing,photonic quantum computing,and reconfigurable metasurfaces.
基金funding support from the National Key Research and Development Program of China(Grant No.2023YFB2604004)the National Natural Science Foundation of China(Grant No.52108374)the“Taishan”Scholar Program of Shandong Province,China(Grant No.tsqn201909016)。
文摘The expansion of a thick-walled hollow cylinder in soil is of non-self-similar nature that the stress/deformation paths are not the same for different soil material points.As a result,this problem cannot be solved by the common self-similar-based similarity techniques.This paper proposes a novel,exact solution for rigorous drained expansion analysis of a hollow cylinder of critical state soils.Considering stress-dependent elastic moduli of soils,new analytical stress and displacement solutions for the nonself-similar problem are developed taking the small strain assumption in the elastic zone.In the plastic zone,the cavity expansion response is formulated into a set of first-order partial differential equations(PDEs)with the combination use of Eulerian and Lagrangian descriptions,and a novel solution algorithm is developed to efficiently solve this complex boundary value problem.The solution is presented in a general form and thus can be useful for a wide range of soils.With the new solution,the non-self-similar nature induced by the finite outer boundary is clearly demonstrated and highlighted,which is found to be greatly different to the behaviour of cavity expansion in infinite soil mass.The present solution may serve as a benchmark for verifying the performance of advanced numerical techniques with critical state soil models and be used to capture the finite boundary effect for pressuremeter tests in small-sized calibration chambers.
基金supported by the National Natural Science Foundation of China,No.82171270 (to ZL)Public Service Platform for Artificial In telligence Screening and Auxiliary Diagnosis for the Medical and Health Industry,Ministry of Industry and Information Technology of the People's Republic of China,No.2020-0103-3-1 (to ZL)+3 种基金the Natural Science Foundation of Beijing,No.Z200016 (to ZL)Beijing Talents Project,No.2018000021223ZK03 (to ZL)Beijing Municipal Committee of Science and Technology,No.Z201 100005620010 (to ZL)CAMS Innovation Fund for Medical Sciences,No.2019-I2M-5-029 (to YongW)。
文摘Inflammation is closely related to stroke prognosis, and high inflammation status leads to poor functional outcome in stroke. DNA methylation is involved in the pathogenesis and prognosis of stroke. However, the effect of DNA methylation on stroke at high levels of inflammation is unclear. In this study, we constructed a hyperinflammatory cerebral ischemia mouse model and investigated the effect of hypomethylation and hypermethylation on the functional outcome. We constructed a mouse model of transient middle cerebral artery occlusion and treated the mice with lipopolysaccharide to induce a hyperinflammatory state. To investigate the effect of DNA methylation on stroke, we used small molecule inhibitors to restrain the function of key DNA methylation and demethylation enzymes. 2,3,5-Triphenyltetrazolium chloride staining, neurological function scores, neurobehavioral tests, enzyme-linked immunosorbent assay, quantitative reverse transcription PCR and western blot assay were used to evaluate the effects after stroke in mice. We assessed changes in the global methylation status by measuring DNA 5-mc and DNA 5-hmc levels in peripheral blood after the use of the inhibitor. In the group treated with the DNA methylation inhibitor, brain tissue 2,3,5-triphenyltetrazolium chloride staining showed an increase in infarct volume, which was accompanied by a decrease in neurological scores and worsening of neurobehavioral performance. The levels of inflammatory factors interleukin 6 and interleukin-1 beta in ischemic brain tissue and plasma were elevated, indicating increased inflammation. Related inflammatory pathway exploration showed significant overactivation of nuclear factor kappa B. These results suggested that inhibiting DNA methylation led to poor functional outcome in mice with high inflammation following stroke. Further, the effects were reversed by inhibition of DNA demethylation. Our findings suggest that DNA methylation regulates the inflammatory response in stroke and has an important role in the functional outcome of hyperinflammatory stroke.
基金This study protocol was approved by the General Hospital of the Yangtze River Shipping,and all the families have voluntarily participated in the study and have signed informed consent forms.
文摘BACKGROUND Regarding the incidence of malignant tumors in China,the incidence of liver cancer ranks fourth,second only to lung,gastric,and esophageal cancers.The case fatality rate ranks third after lung and cervical cancer.In a previous study,the whole-process management model was applied to patients with breast cancer,which effectively reduced their negative emotions and improved treatment adherence and nursing satisfaction.METHODS In this single-center,randomized,controlled study,60 randomly selected patients with liver cancer who had been admitted to our hospital from January 2021 to January 2022 were randomly divided into an observation group(n=30),who received whole-process case management on the basis of routine nursing mea-sures,and a control group(n=30),who were given routine nursing measures.We compared differences between the two groups in terms of anxiety,depression,the level of hope,self-care ability,symptom distress,sleep quality,and quality of life.RESULTS Post-intervention,Hamilton anxiety scale,Hamilton depression scale,memory symptom assessment scale,and Pittsburgh sleep quality index scores in both groups were lower than those pre-intervention,and the observation group had lower scores than the control group(P<0.05).Herth hope index,self-care ability assessment scale-revision in Chinese,and quality of life measurement scale for patients with liver cancer scores in both groups were higher than those pre-intervention,with higher scores in the observation group compared with the control group(P<0.05).CONCLUSION Whole-process case management can effectively reduce anxiety and depression in patients with liver cancer,alleviate symptoms and problems,and improve the level of hope,self-care ability,sleep quality,and quality of life,as well as provide feasible nursing alternatives for patients with liver cancer.
基金Project supported by the National Key Research and Development Program of China (Grant No.2019YFA0705000)Leading-edge technology Program of Jiangsu Natural Science Foundation (Grant No.BK20192001)the National Natural Science Foundation of China (Grant No.11974178)。
文摘Neural networks are becoming ubiquitous in various areas of physics as a successful machine learning(ML)technique for addressing different tasks.Based on ML technique,we propose and experimentally demonstrate an efficient method for state reconstruction of the widely used Sagnac polarization-entangled photon source.By properly modeling the target states,a multi-output fully connected neural network is well trained using only six of the sixteen measurement bases in standard tomography technique,and hence our method reduces the resource consumption without loss of accuracy.We demonstrate the ability of the neural network to predict state parameters with a high precision by using both simulated and experimental data.Explicitly,the mean absolute error for all the parameters is below 0.05 for the simulated data and a mean fidelity of 0.99 is achieved for experimentally generated states.Our method could be generalized to estimate other kinds of states,as well as other quantum information tasks.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.62373197 and 61873326)。
文摘In many engineering networks, only a part of target state variables are required to be estimated.On the other hand,multi-layer complex network exists widely in practical situations.In this paper, the state estimation of target state variables in multi-layer complex dynamical networks with nonlinear node dynamics is studied.A suitable functional state observer is constructed with the limited measurement.The parameters of the designed functional observer are obtained from the algebraic method and the stability of the functional observer is proven by the Lyapunov theorem.Some necessary conditions that need to be satisfied for the design of the functional state observer are obtained.Different from previous studies, in the multi-layer complex dynamical network with nonlinear node dynamics, the proposed method can estimate the state of target variables on some layers directly instead of estimating all the individual states.Thus, it can greatly reduce the placement of observers and computational cost.Numerical simulations with the three-layer complex dynamical network composed of three-dimensional nonlinear dynamical nodes are developed to verify the effectiveness of the method.
基金Project supported by the Suzhou Basic Research Project (Grant No.SJC2023003)Suzhou City University National Project Pre-research Project (Grant No.2023SGY014)。
文摘We present a stable valley photonic crystal(VPC)unit cell with C_(3v)symmetric quasi-ring-shaped dielectric columns and realize its topological phase transition by breaking mirror symmetry.Based on this unit cell structure,topological edge states(TESs)and topological corner states(TCSs)are realized.We obtain a new type of wave transmission mode based on photonic crystal zipper-like boundaries and apply it to a beam splitter assembled from rectangular photonic crystals(PCs).The constructed beam splitter structure is compact and possesses frequency separation functions.In addition,we construct a box-shaped triangular PC structures with zipper-like boundaries and discover phenomena of TCSs in the corners,comparing its corner states with those formed by other boundaries.Based on this,we explore the regularities of the electric field patterns of TESs and TCSs,explain the connection between the characteristic frequencies and locality of TCSs,which helps better control photons and ensures low power consumption of the system.