Two-dimensional(2D)nanomaterials,such as graphene,MoS_(2),and MAX,have attracted increasing research attention in recent years due to their unique structural and performance advantages.However,their complex production...Two-dimensional(2D)nanomaterials,such as graphene,MoS_(2),and MAX,have attracted increasing research attention in recent years due to their unique structural and performance advantages.However,their complex production processes and equipment requirements are significant issues affecting their widespread use.Here,with an exfoliation strategy using three-roll milling,we present a simple,cost-effective,and extensible method to produce multilayer graphene,BN,MoS_(2),and Ti_(3)AlC_(2) nanosheets.The roller and phenolic resin created three kinds of forces on the layered 2D materials,i.e.,shear forces,compressive forces,and adhesive forces,which exfoliated layered materials from their edges and surfaces into nanosheets.Subsequently,the exfoliated materials were ultrasonically washed with alcohol,treated with ultrasonic vibration,and centrifuged to obtain 2D nanomaterials.The easy operation and high yield are attractive for research based on the construction of high-performance 2D nanosheet-based devices at low cost.Herein,the obtained multilayer graphene and MoS_(2) nanosheets were used as anode materials of sodium/potassium-ion batteries,respectively,to test their electrochemical properties.Better performances are obtained compared with their primary bulk materials.展开更多
The geometry of plate after edge pre-bending mode is compared with that after roll-bending mode and the relationship among edge pre-bending angle, pre-bending edge length, and cylindrical desired radius is presented f...The geometry of plate after edge pre-bending mode is compared with that after roll-bending mode and the relationship among edge pre-bending angle, pre-bending edge length, and cylindrical desired radius is presented for a three-roller plate bender with bottom rollers adjustable horizontally. The analytical moment-curvature model and springhaek model for pure bending are established, assuming that the stress-strain relationship of material is linear, and the material is in plain strain and yields according to Mises yield criterion. The mathematical model for three- roller edge pre-bending of plate is developed considering the effect of pre-bending edge length, bottom roller radius, friction between plate and roller, etc. The plate tensile test and plate bending test are done and the numerical results agree well with the test data. The results are shown graphically and analyzed in the following aspects： （1） the error between numerical results and test data of top roiler force; （2） the influence of bottom roller radius, relative curva- ture, and bending arc length on springback angle; （3） the relationship between springhack ratio and edge pre-ben- ding angle.展开更多
Due to its larger ionic radius,further studies are needed before graphite can be used as an anode for sodium/potassium-ion batteries(SIBs/KIBs).It is believed that doping and increasing the layer spacing can improve t...Due to its larger ionic radius,further studies are needed before graphite can be used as an anode for sodium/potassium-ion batteries(SIBs/KIBs).It is believed that doping and increasing the layer spacing can improve the Na+/K+storage.Herein,S/N co-doped graphite nanosheets(GNS)with an enlarged interlayer spacing of 0.39 nm were prepared via exfoliation with three-roll milling(TRM)combined with thiourea heated at different temperatures.This method generates abundant defects and active sites for GNS,as well as facilitates rapid access and transport of electrolytes and electrons/ions.The electrochemical results show that the S/N-doped GNS exfoliated 15 times and heated at 600°C(SNGNS15-600)with thiourea as the electrode delivers a discharge capacity of 94 mAh g–1 over 6000 cycles at 10 A g–1 with an enhanced rate capability and stable performance for application in SIBs.Calculations using density functional theory show that the increased interlayer spacing by TRM and S,N co-doping enhances the adsorption energies of Na+on graphite,thus improving the Na+storage.As the anode for KIBs,the SNGNS15-600 electrode has a capacity of 142 mAh g–1 after 5000 cycles at 0.5 A g–1.This study provides an essential theoretical basis for the effective exfoliation of layered graphite-based materials and their applications in energy storage.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.52272063 and 22262024)Key Research and Development Program of Jiangxi Province(Grant No.20203BBE53066)+1 种基金Natural Science Foundation of Jiangxi Province(Grant No.20224BAB214037)Graduate Innovation Special Fund of Nanchang Hangkong University(Grant No.YC_(2)023-S683).
文摘Two-dimensional(2D)nanomaterials,such as graphene,MoS_(2),and MAX,have attracted increasing research attention in recent years due to their unique structural and performance advantages.However,their complex production processes and equipment requirements are significant issues affecting their widespread use.Here,with an exfoliation strategy using three-roll milling,we present a simple,cost-effective,and extensible method to produce multilayer graphene,BN,MoS_(2),and Ti_(3)AlC_(2) nanosheets.The roller and phenolic resin created three kinds of forces on the layered 2D materials,i.e.,shear forces,compressive forces,and adhesive forces,which exfoliated layered materials from their edges and surfaces into nanosheets.Subsequently,the exfoliated materials were ultrasonically washed with alcohol,treated with ultrasonic vibration,and centrifuged to obtain 2D nanomaterials.The easy operation and high yield are attractive for research based on the construction of high-performance 2D nanosheet-based devices at low cost.Herein,the obtained multilayer graphene and MoS_(2) nanosheets were used as anode materials of sodium/potassium-ion batteries,respectively,to test their electrochemical properties.Better performances are obtained compared with their primary bulk materials.
基金Sponsored by Shanxi Major Special Plan of Science and Technology of China(20111101032)
文摘The geometry of plate after edge pre-bending mode is compared with that after roll-bending mode and the relationship among edge pre-bending angle, pre-bending edge length, and cylindrical desired radius is presented for a three-roller plate bender with bottom rollers adjustable horizontally. The analytical moment-curvature model and springhaek model for pure bending are established, assuming that the stress-strain relationship of material is linear, and the material is in plain strain and yields according to Mises yield criterion. The mathematical model for three- roller edge pre-bending of plate is developed considering the effect of pre-bending edge length, bottom roller radius, friction between plate and roller, etc. The plate tensile test and plate bending test are done and the numerical results agree well with the test data. The results are shown graphically and analyzed in the following aspects： （1） the error between numerical results and test data of top roiler force; （2） the influence of bottom roller radius, relative curva- ture, and bending arc length on springback angle; （3） the relationship between springhack ratio and edge pre-ben- ding angle.
基金supported by the Natural Science Foundation of China(Nos.51862024 and 51962023)the Key Research and Development Program of Jiangxi Province(No.20203BBE53066).
文摘Due to its larger ionic radius,further studies are needed before graphite can be used as an anode for sodium/potassium-ion batteries(SIBs/KIBs).It is believed that doping and increasing the layer spacing can improve the Na+/K+storage.Herein,S/N co-doped graphite nanosheets(GNS)with an enlarged interlayer spacing of 0.39 nm were prepared via exfoliation with three-roll milling(TRM)combined with thiourea heated at different temperatures.This method generates abundant defects and active sites for GNS,as well as facilitates rapid access and transport of electrolytes and electrons/ions.The electrochemical results show that the S/N-doped GNS exfoliated 15 times and heated at 600°C(SNGNS15-600)with thiourea as the electrode delivers a discharge capacity of 94 mAh g–1 over 6000 cycles at 10 A g–1 with an enhanced rate capability and stable performance for application in SIBs.Calculations using density functional theory show that the increased interlayer spacing by TRM and S,N co-doping enhances the adsorption energies of Na+on graphite,thus improving the Na+storage.As the anode for KIBs,the SNGNS15-600 electrode has a capacity of 142 mAh g–1 after 5000 cycles at 0.5 A g–1.This study provides an essential theoretical basis for the effective exfoliation of layered graphite-based materials and their applications in energy storage.
