Displacement characteristics of CO_(2)flooding in extra-high water-cut reservoirs

Carbon dioxide(CO_(2))flooding is a widely applied recovery method during the tertiary recovery of oil and gas.A high water saturation condition in reservoirs could induce a‘water shielding’phenomenon after the injection of CO_(2).This would prevent contact between the injected gas and the residual oil,restricting the development of the miscible zone.A micro-visual experiment of dead-end models,used to observe the effect of a film of water on the miscibility process,indicates that CO_(2)can penetrate the water film and come into contact with the residual oil,although the mixing is significantly delayed.However,the dissolution loss of CO_(2)at high water-cut conditions is not negligible.The oil-water partition coefficient,defined as the ratio of CO_(2)solubility in an oil-brine/two-phase system,keeps constant for specific reservoir conditions and changes little with an injection gas.The NMR device shows that when CO_(2)flooding follows water flooding,the residual oil decreasesdnot only in medium and large pores but also in small and micro pores.At levels of higher water saturation,CO_(2)displacement is characterized initially by a low oil production rate and high water-cut.After the CO_(2)breakthrough,the water-cut decreases sharply and the oil production rate increases gradually.The response time of CO_(2)flooding at high watercut reservoirs is typically delayed and prolonged.These results were confirmed in a pilot test for CO_(2)flooding at the P1-1 well group of the Pucheng Oilfield.Observations from this pilot study also suggest that a larger injection gas pore volume available for CO_(2)injection is required to offset the dissolution loss in high water saturation conditions.

Ultrasonic method for measuring water holdup of low velocity and high-water-cut oil-water two-phase flow

Oil reservoirs with low permeability and porosity that are in the middle and late exploitation periods in China＇s onshore oil fields are mostly in the high-water-cut production stage.This stage is associated with severely non-uniform local-velocity flow profiles and dispersed-phase concentration（of oil droplets） in oil-water two-phase flow,which makes it difficult to measure water holdup in oil wells.In this study,we use an ultrasonic method based on a transmission-type sensor in oil-water two-phase flow to measure water holdup in lowvelocity and high water-cut conditions.First,we optimize the excitation frequency of the ultrasonic sensor by calculating the sensitivity of the ultrasonic field using the finite element method for multiphysics coupling.Then we calculate the change trend of sound pressure level attenuation ratio with the increase in oil holdup to verify the feasibility of the employed diameter for the ultrasonic sensor.Based on the results,we then investigate the effects of oildroplet diameter and distribution on the ultrasonic field.To further understand the measurement characteristics of the ultrasonic sensor,we perform a flow loop test on vertical upward oilwater two-phase flow and measure the responses of the optimized ultrasonic sensor.The results show that the ultrasonic sensor yields poor resolution for a dispersed oil slug in water flow（D OS/W flow）,but the resolution is favorable for dispersed oil in water flow（D O/W flow） and very fine dispersed oil in water flow（VFD O/W flow）.This research demonstrates the potential application of a pulsed-transmission ultrasonic method for measuring the fraction of individual components in oil-water two-phase flow with a low mixture velocity and high water cut.

Design and performance of a high-speed and low-noise preamplifier for SiPM

Considering the R&D for upgrading the K^(0)_(L) andμdetectors in the Belle II experiment using a scintillator and silicon pho-tomultiplier(SiPM),we designed a compact high-speed and low-noise preamplifier.The preamplifier demonstrated a good gain stability,bandwidth of 426 MHz,baseline noise level ofσ≈0.6 mV,dynamic range of up to170 mV of the input signal amplitude,good time resolution of 20 ps,and it can be comprehensively applied to SiPMs.Adopting pole-zero-cancelation in the preamplifier reduces both the rise and fall times of the SiPM signal,which can significantly improve the time resolution and reduce the pile-up when using a large SiPM or an array of SiPMs.Various combinations of the preamplifier and several types of SiPMs demonstrated time resolutions better than 50 ps for most cases;when the number of detected photons was larger than 60,a time resolution of approximately 25 ps was achieved.

Optimization of Injection Parameters for Profile Control and Flooding in an Oilfield during High Water Cut Period

In order to improve the effect of water control and oil stabilization during high water cut period, a mathematical model of five point method well group was established with the high water cut well group of an Oilfield as the target area, the variation law of water cut and recovery factor of different injection parameters was analyzed, and the optimization research of injection parameters of polymer enhanced foam flooding was carried out. The results show that the higher the injection rate, the lower the water content curve, and the higher the oil recovery rate. As the foam defoamed when encountering oil, when the injection time was earlier than 80% of water cut, the later the injection time was, the better the oil displacement effect would be. When the injection time was later than 80% of water cut, the later the injection time was, the worse the oil displacement effect would be. The larger the injection volume, the lower the water content curve and the higher the recovery rate. After the injection volume exceeded 0.2 PV, the amplitude of changes in water content and recovery rate slowed down. The optimal injection parameters of profile control agent for high water content well group in Oilfield A were: injection rate of 15 m3/d, injection timing of 80% water content, and injection volume of 0.2 PV.

Tidal Analysis of High and Low Water Data

The harmonic analysis method based on high and low water levels is discussed in this paper. In order to make full use of the information of high and low water observations (the time derivative of water level at the observation time is zero), the weight coefficient, w, is introduced to control the importance of the part related to this information in the error formula. The major diurnal constituents, O 1 and K 1, and semi diurnal constituents, N 2, M 2 and S 2 are selected directly from the monthly data analysis, and some other important constituents, P 1, ν 2 and K 2, are included as the inferred constituents. The obtained harmonic constants of the major constituents are very close to those obtained from the analysis of hourly data, and this shows that high and low water data can be used to extract tidal constants with high accuracy. The analysis result also shows that the inference and the weighting coefficient are important in the high and low water data analysis, and it is suggested that w ≥1 should be taken in monthly high and low water data analysis. This analysis method can be used directly to analyze altimetric data with w =0.

Research and Application of an Environmental-Friendly Low-Damage and High Salt-Resistance Slick Water Fracturing Fluid System

The Sulige gas field is a typical low-pressure low-permeability tight sandstone gas reservoir. The reservoir has poor seepage capacity, strong heterogeneity, high mineralization of formation water and extremely scarce water resources on the site. These unfavorable factors have brought great difficulties to the on-site mining process. Now, a nano-composite green environmental protection slick water fracturing fluid system CQFR can be quickly dissolved because of the larger specific surface area, and the small molecular size makes the damage to the reservoir less than 5%, and the average drag reduction effect can reach more than 73%. It can quickly and well dissolve and maintain performance under high salinity conditions and fracturing flowback fluids. It responds well to the complex reservoir conditions on the construction site and makes the flowback fluid recyable, which greatly reduces the consumption of water resources on the construction site and effectively improves the construction efficiency and economic benefits.

Study on the Monitoring Malfunction of Water Pollution during Drought or Flood Period and Low-carbon and High-value Methodology--A Case Study of the Correlation Test of Water,Soil and Gas Pollution in Xiangxiang County

Based on the low-carbon and high-value methodology of chemical ecology and chemical informatics,combining theory and methods,taking saving,environmental protection,low carbon,high production,high value and circulation as values and aims,the relationship between human and land as a basis,ecosystem as a center,overall control as a goal and agricultural ecological engineering as a mean,environmental pollution detection,as one of bottlenecks for agricultural products and food security,should be solved firstly;through the field survey in dry years from 2009 to 2010 when drought and flood were frequent and the frequency of drought was higher than that of flood,plus the determination of surface water flow and water quantity in a small typical river basin,the correlation of local water,soil and gas in the county could be found,and the transfer of monitoring focus from water environment to atmospheric environment was possible and necessary.The study would promote the quantitative research on the correlation among water,soil and gas,and the results were in accordance with the conclusions of related studies.

Development and application of multi-field coupled high-pressure triaxial apparatus for soil

The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.

Performance analysis of high-static-low-dynamic stiffness vibration isolator with time-delayed displacement feedback

The displacement feedback with time delay considered is introduced in order to enhance the vibration isolation performance of a high-static-low-dynamic stiffness(HSLDS) vibration isolator. Such feedback is detailedly analyzed from the viewpoint of equivalent damping. Firstly, the primary resonance of the controlled HSLDS vibration isolator subjected to a harmonic force excitation is obtained based on the multiple scales method and further verified by numerical integration. The stability of the primary resonance is subsequently investigated. Then, the equivalent damping is defined to study the effects of feedback gain and time delay on primary resonance. The condition of jump avoidance is obtained with the purpose of eliminating the adverse effects induced by jumps. Finally, the force transmissibility of the controlled HSLDS vibration isolator is defined to evaluate its isolation performance. It is shown that an appropriate choice of feedback parameters can effectively suppress the force transmissibility in resonant region and reduce the resonance frequency. Furthermore, a wider vibration isolation frequency bandwidth can be achieved compared to the passive HSLDS vibration isolator.

Characteristics of the Correlation between Regional Water Vapor Transport along with the Convective Action and Variation of the Pacific Subtropical High in 1998

This paper explores the impact of the convective action over the low-latitude region, the water vapor transport around the West Pacific subtropical high (WPSH), and its convective action on the seasonal northward jump and southward withdrawal of the WPSH in summer by using the daily data set of NCEP and TBB for 1998. The research shows that in summer, the WPSH moves northward when the convection over the low-latitude tropical region intensifies and the subsidence region of the meridional vertically vertical circulation in meridional direction circulation over the region of 110?150癊 moves northward. Furthermore, as revealed by diagnostic analysis, the subtropical high moves northward after the obvious weakening of the longitudinal water vapor transport over the region around the subtropical high, but withdraws southward a pentad after the reduction of the latitudinal water vapor transport over the tropical West Pacific region. The research results show that the northward jump and southward withdrawal of the WPSH are closely related to the release of the convective latent heat at low latitudes and the water vapor transport at boundaries around WPSH and its convective action. The numerical simulation further validates the above-mentioned correlation between the variation of the action of the subtropical high and the preceding water vapor transport along with the convection characteristics.

Timing of advanced water flooding in low permeability reservoirs

It is very important to design the optimum starting time of water injection for the development of low permeability reservoirs. In this type of reservoir the starting time of water injection will be affected by a reservoir pressure-sensitive effect. In order to optimize the starting time of water injection in low permeability reservoirs, this effect of pressure change on rock permeability of low permeability reservoirs was, at first, studied by physical simulation. It was shown that the rock permeability decreases exponentially with an increase in formation pressure. Secondly, we conducted a reservoir engineering study, from which we obtained analytic relationships between formation pressure, oil production rate, water production rate and water injection rate. After our physical, theoretical and economical analyses, we proposed an approach which takes the pressure-sensitive effect into consideration and designed the optimum starting time of water injection, based on the principle of material balance. Finally, the corresponding software was developed and applied to one block of the Jiangsu Oilfield. It is shown that water injection, in advance of production, can decrease the adverse impact of the pressure-sensitive effect on low permeability reservoir development. A water-flooding project should be preferably initiated in advance of production for no more than one year and the optimum ratio of formation pressure to initial formation pressure should be maintained at a level between 1.05 and 1.2.

A high salt tolerance and low adsorption drag reducer based on non-covalent enhancement

To formulate fluids with flowback water,produced water directly to improve the utilization rate of recycling and reduce the adsorption damage of slick water to reservoirs,a high salt tolerance and low adsorption drag reducer was designed and prepared by introducing polar cation fragments to enhance the non-covalent interactions between the chains.The drag reducer was characterized by IR and NMR.Friction resistance and viscosity tests were conducted to evaluate its salt resistance property.Static adsorption and dynamic adsorption retention tests were carried out to evaluate the damage of this reducer to shale reservoirs.The introduction of cation units into the molecular structure can weak the shielding effect of metal cations to some extent,so the drag reducer can keep a stable molecular structure and good resistant reducing performance under high salinity.The enhancement of non-covalent interaction between chains decreased the free polarity sites,further reduced the possibility of hydrogen bonding between drag reducer molecules and shale.In high salinity condition,both the adsorption capacity of the drag reducer on the shale surface and the average damage rate to the core permeability are low.Compared with the conventional salt-tolerant system,the overall liquid cost was reduced by 17%and the production per well increased by 44%.The application of this slick water system has achieved remarkable results.

VISUALIZATION OF FLOW STRUCTURES IN A TURBULENT BOUNDARY LAYER USING A NEW TECHNIQUE

In this paper, an experimental investigation on the flow structures in a turbulent bounda- ry layer employing a special laser light sheet-Hydrogen bubble flow visualization technique is described. It is observed that the high/low speed streaks are directly related to the hairpin or horseshoe-like vortices. This observation can give a better understanding of the physical mechanism in the turbulent boundary layer.

Application of Dual-Energy X-Ray Image Detection of Dangerous Goods Based on YOLOv7

X-ray security equipment is currently a more commonly used dangerous goods detection tool, due to the increasing security work tasks, the use of target detection technology to assist security personnel to carry out work has become an inevitable trend. With the development of deep learning, object detection technology is becoming more and more mature, and object detection framework based on convolutional neural networks has been widely used in industrial, medical and military fields. In order to improve the efficiency of security staff, reduce the risk of dangerous goods missed detection. Based on the data collected in X-ray security equipment, this paper uses a method of inserting dangerous goods into an empty package to balance all kinds of dangerous goods data and expand the data set. The high-low energy images are combined using the high-low energy feature fusion method. Finally, the dangerous goods target detection technology based on the YOLOv7 model is used for model training. After the introduction of the above method, the detection accuracy is improved by 6% compared with the direct use of the original data set for detection, and the speed is 93FPS, which can meet the requirements of the online security system, greatly improve the work efficiency of security personnel, and eliminate the security risks caused by missed detection.

某锂矿低温熟化—水浸提锂和提纯高纯石英新工艺

皖南低品位热液蚀变型锂矿Li_(2)O含量0.21%,属于新类型锂矿资源,主要矿物成分有长石、石英、白云母、绿泥石,锂主要以晶格形式赋存于锂绿泥石中。新工艺采用-1 mm原矿筛分,+0.425 mm粒级进入磨矿,制备-0.425+0.074 mm合格粒级。脱泥后合格粒级产品经磁选得云母精矿,非磁性物浮选得到长石精矿和石英精矿,长石精矿和云母精矿分别进行提锂,石英精矿进行酸处理提纯得高纯石英。将原矿筛出的-0.074 mm细泥、再磨产生的-0.074 mm细泥、合格粒级搅拌擦洗产生的-0.074 mm细泥,合并为总泥进行后续提锂。试验结果表明:总泥、云母、长石分别采用低温熟化—水浸工艺提锂,累计得Li_(2)O浸出率88.78%,酸浸后石英精矿含SiO_(2)99.942%,Fe 4.38 mg/kg,达到高纯石英低端产品要求,提锂后的长石和云母浸渣产率54.48%,可用于建筑材料。浸出前后样品的XRD和SEM分析表明,硫酸低温熟化破坏了锂绿泥石晶格结构,H+代替锂绿泥石中Li+,将锂释放出来。新工艺降低了磨矿成本,锂浸出率高,兼顾云母、石英、长石的回收,减少了尾矿排放,提高了低品位热液蚀变型锂矿的综合利用水平。

高燃压中型运载火箭发射地面低高度排导技术

综合高燃压中型运载火箭高密度发射燃气流地面排导需求及烧蚀风险分析,提出基于地面双面导流装置与高位挡流墙结合的地面低高度排导技术方案。利用火箭发射燃气动力学研究总结的燃气流膨胀特性以及导流型面设计方法,解决了地面低高度排导技术涉及的地面导流装置导流型面气动设计以及尺度控制两个关键问题。地面低高度排导技术方案设计与燃气流场瞬态仿真多轮叠代,实现了燃气流排导烧蚀范围合理控制,避免了燃气流低高度排导烧蚀反溅影响箭体。地面低高度排导技术采用专利支撑的喷水冷却防护方案实现高燃压中型运载火箭发射燃气流强烧蚀环境发射系统、发射设施综合防护。基于喷流缩比试验相似性控制方法研制了1∶10比例喷流缩比试验系统,通过喷流缩比试验验证确认高燃压中型运载火箭发射燃气流能够实现地面低高度安全、顺畅排导,同时与发射台、导流装置结构融合的阵列喷水方案能够行之有效解决高燃压中型运载火箭地面低高度排导强烧蚀难题。

基于效益复产的控水采气技术——以磨溪气田嘉陵江组二段气藏为例

高产水气井因低效或无效益关停后,井口压力恢复较高,井控安全风险大。按照原有常规开发模式复产将面临地层水处理成本高、无人值守生产管理难度大等问题。为实现磨溪气田下三叠统嘉陵江组二段气藏安全效益复产,综合考虑气藏生产管理、安全环保和经济效益等因素,提出新型控水采气技术作为高压、高产水、低负效气井复产的工艺措施。通过开展控水采气生产现场试验,分析不同产水量、产气量、生产时长和间开周期条件下油压、产量等动态数据之间的关系,确定合理生产压差、产水规模和间开周期;同时结合气藏生产组织、生产管理等综合因素确定开关井制度,通过安装智能间开系统等配套工艺,进一步提升控水采气技术措施效果。研究结果表明:(1)该技术确保气藏关停井整体成功复产,有效降低了井控风险;(2)通过现场试验和推广应用,验证了选井标准和工艺参数计算方法的科学性;(3)“智能间开系统”等配套工艺进一步提升了现场运用效果。该技术为关停井复产、高压井管控、精细生产管理及提高气藏采收率提供了有力的技术支撑,在同类气藏中具有较强的推广应用价值。

基于NMD算法的水电高占比电网低频振荡模态辨识

水电高占比电网中的调速控制问题会导致低于0.1 Hz的超低频振荡,与低频振荡混合加大了低频振荡参数辨识的难度。因此本文提出一种基于自适应的时频分析方法-非线性模态分解(Nonlinear mode decomposition,NMD)来对低频振荡进行参数识别。该方法能够根据信号结构提取时频脊线,估得谐波参数,辨别出对应分量真谐波,消除虚假模态分量。并利用提取出分量的频谱熵特征来设定一个停止分解准则,使分解出的非线性模态分量(Nonlinear mode,NM)具备实际物理意义。对每个NM分量进行Hilbert变换(Hilbert transform,HT)求取振荡参数。最后通过自合成测试信号仿真算例、四机二区系统仿真算例和电网实测算例验证所提方法可行性和有效性。

湿基α-半水石膏制备高强石膏制品研究

为实现湿基α-半水石膏制备高强石膏制品,研究了湿基α-半水石膏陈化时间、粉磨时间、浇筑料浆温度及缓凝剂掺量等工艺参数对高强石膏凝结时间和强度的影响,并确定最佳制备工艺。此外,采用X射线衍射、扫描电子显微镜等微观测试手段,揭示了各因素对强度的影响机理。结果表明:陈化时间越长,石膏凝结时间越短,制品强度越低;随着粉磨时间延长,石膏凝结时间显著缩短,制品强度先升高后降低;料浆温度越高,石膏凝结时间越长,制品强度越低。最佳制备工艺:陈化时间5 min、粉磨时间20 s、料浆温度20℃。在此基础上加入0.08%(质量分数)缓凝剂能够有效地延长石膏凝结时间并提高硬化强度,制备的石膏制品性能优异,绝干抗折强度为14.1 MPa,绝干抗压强度为58.3 MPa。微观测试结果表明,各工艺参数会通过改变石膏标稠用水量和水化进程来影响石膏内部结构的密实程度和二水石膏晶体的生长发育,最终影响制品硬化强度。

某700 MW锅炉水冷壁高温腐蚀原因分析及其防治措施

针对某电厂700 MW对冲式燃烧锅炉水冷壁腐蚀严重问题,对该锅炉高温腐蚀产生的原因进行了分析。在现场割取了腐蚀的水冷壁管,对其腐蚀垢层进行了X射线衍射(XRD)、能量色散X射线谱(EDS)和扫描电镜(SEM)分析,结果发现腐蚀产物中主要含有ZnS、FeS、Fe_(7)S_(8)、Fe_(3)O_(4)和α-FeOOH,推定此炉主要为硫化物型高温腐蚀,并制定了该锅炉的防治措施。