Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were co...Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.展开更多
With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignit...With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignition for four coal concentration settings covering sub- operation conditions prevailing during the experiments performed with the burner. The numerical simulations conformed to the experimental results, demonstrating the suitability of the model used in the calculations. Simula- tions for a coal concentration of 0.40 kg/kg corresponding to a single burner operating at its rated output were also conducted, which indicated that gas temperatures along the burner centerline were high. As gas flowed to the burner nozzle, the high-temperature region expanded, ensuring a successful pulverized-coal ignition. With increasing coal concentration （0.08-0.40 kg/kg）, the gas temperature along the burner centerline and at the first and second combustion chamber exits decreased at the equivalent radial points. At the center of the second combustion chamber exit, the O2 concentrations were almost depleted for the five coal concentrations, while the CO concentrations peaked.展开更多
The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were c...The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were conducted for four excess air ratios, 0.56, 0.75, 0.98 and 1.14 （corresponding to primary air velocities of 17, 23, 30 and 35 m/s, respectively）, which were chosen because they had been used previously in practical experiments. The numerical simulations agreed well with the experimental results, which demonstrate the suitability of the model used in the calculations. The gas temperatures were high along the center line of the burner for the four excess air ratios. The flame spread to the bumer wall and the high- temperature region was enlarged in the radial direction along the primary air flow direction. The O2 concentrations for the four excess air ratios were 0.5%, 1.1%, 0.9% and 3.0% at the exit of the second combustion chamber. The CO peak concentration was very high with values of 7.9%, 9.9%, 11.3% and 10.6% for the four excess air ratios at the exit of the second combustion chamber.展开更多
为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰...为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰动。不同药剂的点火具抗干扰性能不同,其中以硝酸钡为药剂主成分的点火具和以镁粉+PTFE为药剂主成分的点火具燃烧性能稳定,以氢化锆、二氧化铅为药剂主成分的点火具工作稳定性较差,火焰持续时间标准差为523 m s,点火具喷孔堵塞严重。展开更多
基金supported by National Natural Science Foundation of China(grant No.22005275).
文摘Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.
基金sponsored by the Hi-Tech Research and Development Program of China （863 program） （Grant No. 2006AA05Z321） and supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China （Grant No. 51121004）.
文摘With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignition for four coal concentration settings covering sub- operation conditions prevailing during the experiments performed with the burner. The numerical simulations conformed to the experimental results, demonstrating the suitability of the model used in the calculations. Simula- tions for a coal concentration of 0.40 kg/kg corresponding to a single burner operating at its rated output were also conducted, which indicated that gas temperatures along the burner centerline were high. As gas flowed to the burner nozzle, the high-temperature region expanded, ensuring a successful pulverized-coal ignition. With increasing coal concentration （0.08-0.40 kg/kg）, the gas temperature along the burner centerline and at the first and second combustion chamber exits decreased at the equivalent radial points. At the center of the second combustion chamber exit, the O2 concentrations were almost depleted for the five coal concentrations, while the CO concentrations peaked.
文摘The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were conducted for four excess air ratios, 0.56, 0.75, 0.98 and 1.14 （corresponding to primary air velocities of 17, 23, 30 and 35 m/s, respectively）, which were chosen because they had been used previously in practical experiments. The numerical simulations agreed well with the experimental results, which demonstrate the suitability of the model used in the calculations. The gas temperatures were high along the center line of the burner for the four excess air ratios. The flame spread to the bumer wall and the high- temperature region was enlarged in the radial direction along the primary air flow direction. The O2 concentrations for the four excess air ratios were 0.5%, 1.1%, 0.9% and 3.0% at the exit of the second combustion chamber. The CO peak concentration was very high with values of 7.9%, 9.9%, 11.3% and 10.6% for the four excess air ratios at the exit of the second combustion chamber.
文摘为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰动。不同药剂的点火具抗干扰性能不同,其中以硝酸钡为药剂主成分的点火具和以镁粉+PTFE为药剂主成分的点火具燃烧性能稳定,以氢化锆、二氧化铅为药剂主成分的点火具工作稳定性较差,火焰持续时间标准差为523 m s,点火具喷孔堵塞严重。
