The synthesis of carbide coatings on graphite substrates using molten salt synthesis(MSS),has garnered significant interest due to its cost-effective nature.This study investigates the reaction process and growth kine...The synthesis of carbide coatings on graphite substrates using molten salt synthesis(MSS),has garnered significant interest due to its cost-effective nature.This study investigates the reaction process and growth kinetics involved in MSS,shedding light on key aspects of the process.The involvement of Ti powder through liquid-phase mass transfer is revealed,where the diffusion distance and quantity of Ti powder play a crucial role in determining the reaction rate by influencing the C content gradient on both sides of the carbide.Furthermore,the growth kinetics of the carbide coating are predominantly governed by the diffusion behavior of C within the carbide layer,rather than the chemical reaction rate.To analyze the kinetics,the thickness of the carbide layer is measured with respect to heat treatment time and temperature,unveiling a parabolic relationship within the temperature range of 700-1300℃.The estimated activation energy for the reaction is determined to be 179283 J·mol^(-1).These findings offer valuable insights into the synthesis of carbide coatings via MSS,facilitating their optimization and enhancing our understanding of their growth mechanisms and properties for various applications.展开更多
To enhance the Young’s modulus(E)and strength of titanium alloys,we designed titanium matrix composites with intercon-nected microstructure based on the Hashin-Shtrikman theory.According to the results,the in-situ re...To enhance the Young’s modulus(E)and strength of titanium alloys,we designed titanium matrix composites with intercon-nected microstructure based on the Hashin-Shtrikman theory.According to the results,the in-situ reaction yielded an interconnected microstructure composed of Ti_(2)C particles when the Ti_(2)C content reached 50vol%.With widths of 10 and 230 nm,the intraparticle Ti lamellae in the prepared composite exhibited a bimodal size distribution due to precipitation and the unreacted Ti phase within the grown Ti_(2)C particles.The composites with interconnected microstructure attained superior properties,including E of 174.3 GPa and ultimate flexural strength of 1014 GPa.Compared with that of pure Ti,the E of the composite was increased by 55% due to the high Ti_(2)C content and interconnected microstructure.The outstanding strength resulted from the strong interfacial bonding,load-bearing capacity of interconnected Ti_(2)C particles,and bimodal intraparticle Ti lamellae,which minimized the average crack driving force.Interrupted flexural tests revealed preferential crack initiation along the{001}cleavage plane and grain boundary of Ti_(2)C in the region with the highest tensile stress.In addition,the propagation can be efficiently inhibited by interparticle Ti grains,which prevented the brittle fracture of the composites.展开更多
A novel technique in which TiC particulate are prepared by an in situ reaction in molten aluminum was introduced for producing TiC/Al composite. In order to reveal the characteristics of the technique, the formation m...A novel technique in which TiC particulate are prepared by an in situ reaction in molten aluminum was introduced for producing TiC/Al composite. In order to reveal the characteristics of the technique, the formation mechanism of TiC particulate prepared by this method was studied. Both theoretical and experimental results show that the TiC particulate is formed by a diffusion mechanism when the molar fraction of aluminum in the preforms is higher than 20.02%. On the contrary, the TiC particulate is formed by a solution-precipitation mechanism when the fraction of aluminum in the preforms is lower than 20.02%.展开更多
A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorab...A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorable for both the solid-liquid synthesis and the densification of Ti3SiC2 rainies. The present work demonstrated that the temperature fluctuation synthesis/simultaneous densification process is one of the most effective and simple methods for the preparation of Ti3SiC2 bulk materials providing relatively low synthesis temperature. short reaction time; and simultaneous synthesis and densification. This work also showed the capability to control the microstructure, e.g., the preferred orientation, of the bulk Ti3SiC2 materials simply by applying the hot pressing pressure at different Stages of the temperature fluctuation process. And textured Ti3SiC2 bulk materials with {002} faces of laminated Ti3SiC2 grains normal to the hot pressing axis were prepared.展开更多
The titanium carbide phase was synthesized in laser melted-pool in situ as the reinforced particles of nickel based composite coating on Ti-6Al-4V alloy surface using the nickel and graphite blending powder by laser c...The titanium carbide phase was synthesized in laser melted-pool in situ as the reinforced particles of nickel based composite coating on Ti-6Al-4V alloy surface using the nickel and graphite blending powder by laser cladding. The microstructure investigation showed that the petals-shaped particles and granular particles were two main morphology of titanium carbide particles. And a few spiral-shaped titanium carbide pattern and eutectic titanium carbide appeared on the cross-sections of the coating. The spiral-shaped titanium carbide pattern composed of some slender arc-shape titanium carbide particles and the eutectic titanium carbide was fine. The morphology and distribution of the spiral-shaped titanium carbide patterns and eutectic titanium carbide confirmed that their growth mechanism was the dissolution-precipitation mechanism and was affected by the convection behavior of the laser melted pool. The spiral-shaped titanium carbide pattern would precipitate out the high-temperature melts under high-speed convection. The eutectic titanium carbide would precipitate out when the melts stopped convection or dropped to eutectic temperature.展开更多
The hardfacing alloys with different concentrations of titanium were deposited on carbon steel substrates by shielded metal arc welding, and the effect of titanium content on the microstructure characteristics of the ...The hardfacing alloys with different concentrations of titanium were deposited on carbon steel substrates by shielded metal arc welding, and the effect of titanium content on the microstructure characteristics of the hardfacing alloys was investigated. The wear resistance test of the hardfacing alloys was carried out by using a slurry rubber wheel abrasion test machine, and the wear behaviour was also studied. The results indicate that the addition of titanium can effectively promote the precipitation of the complex carbides of Nb and Ti due to the prior precipitation of titanium carbide which acts as nucleation sites for complex carbides. With the increase of titanium content, the wear resistance of the hardfacing alloys is increased gradually resulting from the refinement of microstructure and dispersive distribution of fine carbide precipitates. And the wear mechanism is mainly minimum plastic deformation with interrupted grooves due to the strengthening and protecting effects of carbide precipitates.展开更多
Two kinds of packaged processes by nickel on the surface of titanium carbide particle are studied in this work. One is the chemical nickel-plating, the other is the organometallic compound decomposition. The compositi...Two kinds of packaged processes by nickel on the surface of titanium carbide particle are studied in this work. One is the chemical nickel-plating, the other is the organometallic compound decomposition. The composition, structure and morphology of the packaged powder were analyzed with XRD, DAT/TGA, SEM, EPMA etc. It has been shown that nickel was even dispersed on the surface of titanium carbide particle by the. two kinds of processes, deposited nickel exists as spherical particles of about 0.1 μm in diameter. The merits and demerits of the two kinds of processes have been compared, the organometallic copmound decomposition among them is a kind of hopeful method, which is not used by other researchers.展开更多
The initiation and propagation of the short fatigue crack in a 10vol% titanium carbide particulate reichreed cast Fe-26Cr-14Ni mathe coopsite at 1023K were investigated.It is shown that the titanium carbide particulat...The initiation and propagation of the short fatigue crack in a 10vol% titanium carbide particulate reichreed cast Fe-26Cr-14Ni mathe coopsite at 1023K were investigated.It is shown that the titanium carbide particulate may hinder the crack propagation and fatigue fracture of the composite. The relationships between fatigue crack propagation rate and stress intensity factor are da/dN=4.2×10-c(△K)4 for the matrix alloy and da/dN=1.4×10-19(△K)c for the composite. The fatigue thresholds of the composite and mathe alloy are 78 and 3.2MPa.m1/2, respectively. Microcracks initiate at the intedece between titanium carbide particulate and austenite and then propagate in carkide particles. The fracture sudece of the composite shows a distinct transition from wavy and serated cleavage near the threshold regime to striation-type splitting in the stable fatigue crack propagation stage and to a veined morphology characteristic in unstable rapid region.展开更多
Two-dimensional Ti_(3)C_(2)T_(x) exhibits outstanding rate property and cycle performance in lithium-ion capacitors(LICs)due to its unique layered structure,excellent electronic conductivity,and high specific surface ...Two-dimensional Ti_(3)C_(2)T_(x) exhibits outstanding rate property and cycle performance in lithium-ion capacitors(LICs)due to its unique layered structure,excellent electronic conductivity,and high specific surface area.However,like graphene,Ti_(3)C_(2)T_(x) restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces,leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the material.Here,a transition metal selenide MoSe_(2) with a special three-stacked atomic layered structure,derived from metal-organic framework(MOF),is introduced into the Ti_(3)C_(2)T_(x) structure through a solvo-thermal method.The synergic effects of rapid Li+diffusion and pillaring effect from the MoSe_(2) and excellent conductivity from the Ti_(3)C_(2)T_(x) sheets endow the material with excellent electrochemical reaction kinetics and capacity.The composite Ti_(3)C_(2)T_(x)@MoSe_(2) material exhibits a high capacity over 300 mAh·g^(-1) at 150 mA·g^(-1) and excellent rate property with a specific capacity of 150 mAh·g^(-1) at 1500 mA·g^(-1).Addition-ally,the material shows a superior capacitive contribution of 86.0%at 2.0 mV·s^(-1) due to the fast electrochemical reactions.A Ti_(3)C_(2)T_(x)@MoSe_(2)//AC LIC device is also fabricated and exhibits stable cycle performance.展开更多
An innovative processing route, in situ reaction combined with pressureless infiltration, was adopted to fabricate magnesium matrix composites, where the reinforcement TiC formed in situ from elemental Ti and C powder...An innovative processing route, in situ reaction combined with pressureless infiltration, was adopted to fabricate magnesium matrix composites, where the reinforcement TiC formed in situ from elemental Ti and C powders and molten Mg spontaneously infiltrated the preform of Ti and C. The influences of primarily elemental particle sizes, synthesizing temperature, holding time etc on in situ reactive infiltration for Mg-Ti-C system were systematically investigated in order to explore the mechanism of this process. In fabricating TiC/Mg composites, Mg can not only spontaneously infiltrate the preform of reinforcement and thus densify the as fabricated composites as matrix metal, but also it can accelerate the in situ reaction process and lower the synthesizing temperature of Ti and C as well. In situ reaction of Ti and C and Mg infiltration processes are essentially overlapping and interacting during fabrication of TiC/Mg composites. The mechanism proposed in this paper can be used to explain the formation and morphologies of the reinforcement phase TiC.展开更多
The fabrication of AlN-TiC/Al composites by carbon- and nitrogen-containing gas injection into Al-Mg-Ti melts was studied. It was shown that AlN and TiC particles could be formed by the in situ reaction of mixture gas...The fabrication of AlN-TiC/Al composites by carbon- and nitrogen-containing gas injection into Al-Mg-Ti melts was studied. It was shown that AlN and TiC particles could be formed by the in situ reaction of mixture gas (N2 + C2H2 + NH3) with Al-Mg-Ti melts. The condition for the formation of AlN was that the treatment temperature must be higher than 1373 K, and the amounts of AlN and TiC increased with the increase of the treatment temperature and the gas injection time It was considered that AlN was formed by the direct reaction of Al with nitrogen-containing gas at the interface of the gas bubble and the melt. However, the mechanism of TiC formation is a combination mechanism of solution-precipitation and solid-liquid reaction.展开更多
Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrost...Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrostructure of as-cast ingots. Although the addition of VC particles does not cause any significant change of the as-cast microstructure, the microstructure of the alloy after hot-working and recrystallization has been found to be refined. The formation of both VC and TiC particles results in the increase of yield strength, especially at the high temperature of 600°C.展开更多
Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reacti...Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reactions process.TiC and Ti5Si3 were two important intermediate phases during the whole reactions.The microstructure characteristics of the Ti3SiC2/TiB2 composites were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The experimental results show that the grains of Ti3SiC2/TiB2 composite are structured in a layered form,and the formation of TiB2 particles as reinforcements with elongated or equiaxed shape distributes in Ti3SiC2 matrix.展开更多
TiC/Si3N4 composites were prepared using the β-Si3N4 powder synthesized by self-propagating high-temperature synthesis (SHS) and 35 wt.% TiC by spark plasma sintering. Y2O3 and Al2O3 were added as sintering additiv...TiC/Si3N4 composites were prepared using the β-Si3N4 powder synthesized by self-propagating high-temperature synthesis (SHS) and 35 wt.% TiC by spark plasma sintering. Y2O3 and Al2O3 were added as sintering additives. The almost full sintered density and the highest fracture toughness (8.48 MPa·m1/2) values of Si3N4-based ceramics could be achieved at 1550℃. No interfacial interactions were noticeable between TiC and Si3N4. The toughening mechanisms in TiC/Si3N4 composites were attributed to crack deflection, microcrack toughening, and crack impedance by the periodic compressive stress in the Si3N4 matrix. However, increasing microcracks easily led to excessive connection of microcracks, which would not be beneficial to the strength.展开更多
The Al/TiC composites were prepared by reaction synthesis. The temperature characteristics and the effect of Al content on it have also been investigated. It has been shown that the Al melts before the reaction synthe...The Al/TiC composites were prepared by reaction synthesis. The temperature characteristics and the effect of Al content on it have also been investigated. It has been shown that the Al melts before the reaction synthesis occurs and with increasing of Al content the temperature maximum decreases, but the start temperature and the reaction lasting time do not change during the process. In addition, the effect of Al content on the reaction synthesis phase has been studied. The result shows that when the Al content is less than 60 at%, the TiC will be synthesized; when the Al content is more than 60 at%, the Al3Ti will also be synthesized. The micrograph of Al3Ti and TiC have been observed by SEM.展开更多
The 50 wt pct TiC-C films were prepared on stainless steel substrates by using a technique of ion beam mixing. These films were irradiated by hydrogen ion beam with a dose of 1×10^18 ions/cm^2 and an energy of 5 ...The 50 wt pct TiC-C films were prepared on stainless steel substrates by using a technique of ion beam mixing. These films were irradiated by hydrogen ion beam with a dose of 1×10^18 ions/cm^2 and an energy of 5 keV. Microanalysis of X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) were used to analyze the films before and after hydrogen ion irradiation and to study the mechanism of hydrogen resistance.展开更多
The diagrams of stability relations(namely,Predominance area phase diagram,PAPD)of nitride,carbide and oxides in Ti-C-N-O system were plotted by thermodynamic calculation.The optimum conditions and main influence fa...The diagrams of stability relations(namely,Predominance area phase diagram,PAPD)of nitride,carbide and oxides in Ti-C-N-O system were plotted by thermodynamic calculation.The optimum conditions and main influence factors for the synthesis of titanium nitride and titanium carbide by carbothermal reduction in nitrogen atmosphere were discussed.展开更多
X-ray diffraction (XRD) analysis on different polished surfaces normal to the hot pressing direction reveals that the phase compositions of the polished surfaces from the outside to the inside are pure TiC, Ti_3AlC_2+...X-ray diffraction (XRD) analysis on different polished surfaces normal to the hot pressing direction reveals that the phase compositions of the polished surfaces from the outside to the inside are pure TiC, Ti_3AlC_2+TiC, pure Ti_3AlC_2 and Ti_2AlC+Ti_3AlC_2, no matter elemental powder or TiC is used as raw materials. It is found that ternary-layered carbide Ti_2AlC samples synthesized at 1500 ℃ by hot-pressing sintering are inhomogeneous and have a gradient structure.Electron probe X-ray micro-analysis (EPMA) indicates that the Al content along the hot pressing axis is parabolic, it is the highest in the center and the lowest at the both ends, while the Ti content is constant along the axis. The experimental result reveals that the evaporation of Al in samples in an open system during hot pressing sintering results in a gradient structure.展开更多
Polycrystalline bulk Ti 3SiC 2 material with a high purity and density was fabricated by spark plasma sintering from the elemental powder mixture with starting composition of Ti 3Si 1-x Al xC 2,where x=0.05-0...Polycrystalline bulk Ti 3SiC 2 material with a high purity and density was fabricated by spark plasma sintering from the elemental powder mixture with starting composition of Ti 3Si 1-x Al xC 2,where x=0.05-0.2.X ray diffraction patterns and scanning electron microscopy photographs of the fully dense samples show that a proper addition of aluminum promotes the formation,and accelerates the crystal growth rate of Ti 3SiC 2,consequently results in a high purity of the prepared samples.The synthesized Ti 3SiC 2 is in plane shape with a size of about 10-25μm in the elongated dimension.Solid solution of aluminum decreases the thermal stability of Ti 3SiC 2,and lowers the temperature of Ti 3SiC 2 decomposeing to be 1300 ℃.展开更多
In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) s...In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(No.52171144)the Fundamental Research Special Zone Program of Shanghai Jiao Tong University(No.21TQ1400215).
文摘The synthesis of carbide coatings on graphite substrates using molten salt synthesis(MSS),has garnered significant interest due to its cost-effective nature.This study investigates the reaction process and growth kinetics involved in MSS,shedding light on key aspects of the process.The involvement of Ti powder through liquid-phase mass transfer is revealed,where the diffusion distance and quantity of Ti powder play a crucial role in determining the reaction rate by influencing the C content gradient on both sides of the carbide.Furthermore,the growth kinetics of the carbide coating are predominantly governed by the diffusion behavior of C within the carbide layer,rather than the chemical reaction rate.To analyze the kinetics,the thickness of the carbide layer is measured with respect to heat treatment time and temperature,unveiling a parabolic relationship within the temperature range of 700-1300℃.The estimated activation energy for the reaction is determined to be 179283 J·mol^(-1).These findings offer valuable insights into the synthesis of carbide coatings via MSS,facilitating their optimization and enhancing our understanding of their growth mechanisms and properties for various applications.
基金financially supported by the National Key R&D Program of China(No.2021YFB3701203)the National Natural Science Foundation of China(Nos.U22A20113,52201116,52071116,and 52261135543)+1 种基金Heilongjiang Touyan Team ProgramChina Postdoctoral Science Foundation(No.2022M710939).
文摘To enhance the Young’s modulus(E)and strength of titanium alloys,we designed titanium matrix composites with intercon-nected microstructure based on the Hashin-Shtrikman theory.According to the results,the in-situ reaction yielded an interconnected microstructure composed of Ti_(2)C particles when the Ti_(2)C content reached 50vol%.With widths of 10 and 230 nm,the intraparticle Ti lamellae in the prepared composite exhibited a bimodal size distribution due to precipitation and the unreacted Ti phase within the grown Ti_(2)C particles.The composites with interconnected microstructure attained superior properties,including E of 174.3 GPa and ultimate flexural strength of 1014 GPa.Compared with that of pure Ti,the E of the composite was increased by 55% due to the high Ti_(2)C content and interconnected microstructure.The outstanding strength resulted from the strong interfacial bonding,load-bearing capacity of interconnected Ti_(2)C particles,and bimodal intraparticle Ti lamellae,which minimized the average crack driving force.Interrupted flexural tests revealed preferential crack initiation along the{001}cleavage plane and grain boundary of Ti_(2)C in the region with the highest tensile stress.In addition,the propagation can be efficiently inhibited by interparticle Ti grains,which prevented the brittle fracture of the composites.
文摘A novel technique in which TiC particulate are prepared by an in situ reaction in molten aluminum was introduced for producing TiC/Al composite. In order to reveal the characteristics of the technique, the formation mechanism of TiC particulate prepared by this method was studied. Both theoretical and experimental results show that the TiC particulate is formed by a diffusion mechanism when the molar fraction of aluminum in the preforms is higher than 20.02%. On the contrary, the TiC particulate is formed by a solution-precipitation mechanism when the fraction of aluminum in the preforms is lower than 20.02%.
基金the National Outstanding YOung Scientist Foundation Under Grant !No.59925208 the National Natural Science Foundation of China
文摘A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorable for both the solid-liquid synthesis and the densification of Ti3SiC2 rainies. The present work demonstrated that the temperature fluctuation synthesis/simultaneous densification process is one of the most effective and simple methods for the preparation of Ti3SiC2 bulk materials providing relatively low synthesis temperature. short reaction time; and simultaneous synthesis and densification. This work also showed the capability to control the microstructure, e.g., the preferred orientation, of the bulk Ti3SiC2 materials simply by applying the hot pressing pressure at different Stages of the temperature fluctuation process. And textured Ti3SiC2 bulk materials with {002} faces of laminated Ti3SiC2 grains normal to the hot pressing axis were prepared.
基金Funded by the Shanghai Science and Technology Committee Innovation(17JC1400600 and 17JC1400601)the National Natural Science Foundation of China(51471105)+1 种基金the Graduate Students’Innovative Research Projects of Shanghai University of Engineering Science(17KY0513)the College Student Innovation Training Projects of Shanghai University of Engineering Scienc(CX1805007)
文摘The titanium carbide phase was synthesized in laser melted-pool in situ as the reinforced particles of nickel based composite coating on Ti-6Al-4V alloy surface using the nickel and graphite blending powder by laser cladding. The microstructure investigation showed that the petals-shaped particles and granular particles were two main morphology of titanium carbide particles. And a few spiral-shaped titanium carbide pattern and eutectic titanium carbide appeared on the cross-sections of the coating. The spiral-shaped titanium carbide pattern composed of some slender arc-shape titanium carbide particles and the eutectic titanium carbide was fine. The morphology and distribution of the spiral-shaped titanium carbide patterns and eutectic titanium carbide confirmed that their growth mechanism was the dissolution-precipitation mechanism and was affected by the convection behavior of the laser melted pool. The spiral-shaped titanium carbide pattern would precipitate out the high-temperature melts under high-speed convection. The eutectic titanium carbide would precipitate out when the melts stopped convection or dropped to eutectic temperature.
基金Funded by the National Natural Science Foundation of China(No.51101050)Fundamental Research Funds for the Central Universities,Natural Science Foundation of Jiangsu Province of China(No.BK20141156)Program for Outstanding Innovative Talents in Hohai University
文摘The hardfacing alloys with different concentrations of titanium were deposited on carbon steel substrates by shielded metal arc welding, and the effect of titanium content on the microstructure characteristics of the hardfacing alloys was investigated. The wear resistance test of the hardfacing alloys was carried out by using a slurry rubber wheel abrasion test machine, and the wear behaviour was also studied. The results indicate that the addition of titanium can effectively promote the precipitation of the complex carbides of Nb and Ti due to the prior precipitation of titanium carbide which acts as nucleation sites for complex carbides. With the increase of titanium content, the wear resistance of the hardfacing alloys is increased gradually resulting from the refinement of microstructure and dispersive distribution of fine carbide precipitates. And the wear mechanism is mainly minimum plastic deformation with interrupted grooves due to the strengthening and protecting effects of carbide precipitates.
文摘Two kinds of packaged processes by nickel on the surface of titanium carbide particle are studied in this work. One is the chemical nickel-plating, the other is the organometallic compound decomposition. The composition, structure and morphology of the packaged powder were analyzed with XRD, DAT/TGA, SEM, EPMA etc. It has been shown that nickel was even dispersed on the surface of titanium carbide particle by the. two kinds of processes, deposited nickel exists as spherical particles of about 0.1 μm in diameter. The merits and demerits of the two kinds of processes have been compared, the organometallic copmound decomposition among them is a kind of hopeful method, which is not used by other researchers.
文摘The initiation and propagation of the short fatigue crack in a 10vol% titanium carbide particulate reichreed cast Fe-26Cr-14Ni mathe coopsite at 1023K were investigated.It is shown that the titanium carbide particulate may hinder the crack propagation and fatigue fracture of the composite. The relationships between fatigue crack propagation rate and stress intensity factor are da/dN=4.2×10-c(△K)4 for the matrix alloy and da/dN=1.4×10-19(△K)c for the composite. The fatigue thresholds of the composite and mathe alloy are 78 and 3.2MPa.m1/2, respectively. Microcracks initiate at the intedece between titanium carbide particulate and austenite and then propagate in carkide particles. The fracture sudece of the composite shows a distinct transition from wavy and serated cleavage near the threshold regime to striation-type splitting in the stable fatigue crack propagation stage and to a veined morphology characteristic in unstable rapid region.
基金supported by the National Natural Science Foundation of China(No.51972023)。
文摘Two-dimensional Ti_(3)C_(2)T_(x) exhibits outstanding rate property and cycle performance in lithium-ion capacitors(LICs)due to its unique layered structure,excellent electronic conductivity,and high specific surface area.However,like graphene,Ti_(3)C_(2)T_(x) restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces,leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the material.Here,a transition metal selenide MoSe_(2) with a special three-stacked atomic layered structure,derived from metal-organic framework(MOF),is introduced into the Ti_(3)C_(2)T_(x) structure through a solvo-thermal method.The synergic effects of rapid Li+diffusion and pillaring effect from the MoSe_(2) and excellent conductivity from the Ti_(3)C_(2)T_(x) sheets endow the material with excellent electrochemical reaction kinetics and capacity.The composite Ti_(3)C_(2)T_(x)@MoSe_(2) material exhibits a high capacity over 300 mAh·g^(-1) at 150 mA·g^(-1) and excellent rate property with a specific capacity of 150 mAh·g^(-1) at 1500 mA·g^(-1).Addition-ally,the material shows a superior capacitive contribution of 86.0%at 2.0 mV·s^(-1) due to the fast electrochemical reactions.A Ti_(3)C_(2)T_(x)@MoSe_(2)//AC LIC device is also fabricated and exhibits stable cycle performance.
文摘An innovative processing route, in situ reaction combined with pressureless infiltration, was adopted to fabricate magnesium matrix composites, where the reinforcement TiC formed in situ from elemental Ti and C powders and molten Mg spontaneously infiltrated the preform of Ti and C. The influences of primarily elemental particle sizes, synthesizing temperature, holding time etc on in situ reactive infiltration for Mg-Ti-C system were systematically investigated in order to explore the mechanism of this process. In fabricating TiC/Mg composites, Mg can not only spontaneously infiltrate the preform of reinforcement and thus densify the as fabricated composites as matrix metal, but also it can accelerate the in situ reaction process and lower the synthesizing temperature of Ti and C as well. In situ reaction of Ti and C and Mg infiltration processes are essentially overlapping and interacting during fabrication of TiC/Mg composites. The mechanism proposed in this paper can be used to explain the formation and morphologies of the reinforcement phase TiC.
文摘The fabrication of AlN-TiC/Al composites by carbon- and nitrogen-containing gas injection into Al-Mg-Ti melts was studied. It was shown that AlN and TiC particles could be formed by the in situ reaction of mixture gas (N2 + C2H2 + NH3) with Al-Mg-Ti melts. The condition for the formation of AlN was that the treatment temperature must be higher than 1373 K, and the amounts of AlN and TiC increased with the increase of the treatment temperature and the gas injection time It was considered that AlN was formed by the direct reaction of Al with nitrogen-containing gas at the interface of the gas bubble and the melt. However, the mechanism of TiC formation is a combination mechanism of solution-precipitation and solid-liquid reaction.
文摘Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrostructure of as-cast ingots. Although the addition of VC particles does not cause any significant change of the as-cast microstructure, the microstructure of the alloy after hot-working and recrystallization has been found to be refined. The formation of both VC and TiC particles results in the increase of yield strength, especially at the high temperature of 600°C.
基金Funded by the National Natural Science Foundation of China (No. 50572080)Doctoral Foundation of Wuhan University of Technology (No. 471-38650142)
文摘Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reactions process.TiC and Ti5Si3 were two important intermediate phases during the whole reactions.The microstructure characteristics of the Ti3SiC2/TiB2 composites were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The experimental results show that the grains of Ti3SiC2/TiB2 composite are structured in a layered form,and the formation of TiB2 particles as reinforcements with elongated or equiaxed shape distributes in Ti3SiC2 matrix.
文摘TiC/Si3N4 composites were prepared using the β-Si3N4 powder synthesized by self-propagating high-temperature synthesis (SHS) and 35 wt.% TiC by spark plasma sintering. Y2O3 and Al2O3 were added as sintering additives. The almost full sintered density and the highest fracture toughness (8.48 MPa·m1/2) values of Si3N4-based ceramics could be achieved at 1550℃. No interfacial interactions were noticeable between TiC and Si3N4. The toughening mechanisms in TiC/Si3N4 composites were attributed to crack deflection, microcrack toughening, and crack impedance by the periodic compressive stress in the Si3N4 matrix. However, increasing microcracks easily led to excessive connection of microcracks, which would not be beneficial to the strength.
文摘The Al/TiC composites were prepared by reaction synthesis. The temperature characteristics and the effect of Al content on it have also been investigated. It has been shown that the Al melts before the reaction synthesis occurs and with increasing of Al content the temperature maximum decreases, but the start temperature and the reaction lasting time do not change during the process. In addition, the effect of Al content on the reaction synthesis phase has been studied. The result shows that when the Al content is less than 60 at%, the TiC will be synthesized; when the Al content is more than 60 at%, the Al3Ti will also be synthesized. The micrograph of Al3Ti and TiC have been observed by SEM.
文摘The 50 wt pct TiC-C films were prepared on stainless steel substrates by using a technique of ion beam mixing. These films were irradiated by hydrogen ion beam with a dose of 1×10^18 ions/cm^2 and an energy of 5 keV. Microanalysis of X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) were used to analyze the films before and after hydrogen ion irradiation and to study the mechanism of hydrogen resistance.
文摘The diagrams of stability relations(namely,Predominance area phase diagram,PAPD)of nitride,carbide and oxides in Ti-C-N-O system were plotted by thermodynamic calculation.The optimum conditions and main influence factors for the synthesis of titanium nitride and titanium carbide by carbothermal reduction in nitrogen atmosphere were discussed.
文摘X-ray diffraction (XRD) analysis on different polished surfaces normal to the hot pressing direction reveals that the phase compositions of the polished surfaces from the outside to the inside are pure TiC, Ti_3AlC_2+TiC, pure Ti_3AlC_2 and Ti_2AlC+Ti_3AlC_2, no matter elemental powder or TiC is used as raw materials. It is found that ternary-layered carbide Ti_2AlC samples synthesized at 1500 ℃ by hot-pressing sintering are inhomogeneous and have a gradient structure.Electron probe X-ray micro-analysis (EPMA) indicates that the Al content along the hot pressing axis is parabolic, it is the highest in the center and the lowest at the both ends, while the Ti content is constant along the axis. The experimental result reveals that the evaporation of Al in samples in an open system during hot pressing sintering results in a gradient structure.
文摘Polycrystalline bulk Ti 3SiC 2 material with a high purity and density was fabricated by spark plasma sintering from the elemental powder mixture with starting composition of Ti 3Si 1-x Al xC 2,where x=0.05-0.2.X ray diffraction patterns and scanning electron microscopy photographs of the fully dense samples show that a proper addition of aluminum promotes the formation,and accelerates the crystal growth rate of Ti 3SiC 2,consequently results in a high purity of the prepared samples.The synthesized Ti 3SiC 2 is in plane shape with a size of about 10-25μm in the elongated dimension.Solid solution of aluminum decreases the thermal stability of Ti 3SiC 2,and lowers the temperature of Ti 3SiC 2 decomposeing to be 1300 ℃.
基金financially supported by the National Science and Technology Major Project of China (No. 2012ZX04010-081)the National High-Tech Research and Development Program of China (No. 2013AA040404)
文摘In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350-400μm thickness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti-Fe alloy powder. Microhard- ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual anstenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam- ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc- ture and to the presence of TiC particles.