Corrosion inhibition of tolytriazole for galvanized steel was studied in 5 mM NaCl by using potentiodynamic polarization and electrochemical impedance spectroscopy(EIS), scanning vibrating electrode technique(SVET). T...Corrosion inhibition of tolytriazole for galvanized steel was studied in 5 mM NaCl by using potentiodynamic polarization and electrochemical impedance spectroscopy(EIS), scanning vibrating electrode technique(SVET). The results of EIS and polarization tests indicate that tolytriazole is effective in corrosion inhibition of galvanized steel. As the concentration of tolytriazole is increased to 0.01 M, the inhibiting efficiency reaches above 98%. The low values of anodie and cathodic current density in SVET maps suggest that the complex of tolytriazole with galvanized steel inhibits the anodic and cathodie reactions of corrosion of zinc. The adsorption behaviour of tolytriazole is found to conform to Langmuir adsorption isotherm, which is typical chemical adsorption.展开更多
基金financial support from the National Natural Science Fund of China (Grant No. 51571202)National Basic Research Program of China (No. 2014CB643304)
文摘Corrosion inhibition of tolytriazole for galvanized steel was studied in 5 mM NaCl by using potentiodynamic polarization and electrochemical impedance spectroscopy(EIS), scanning vibrating electrode technique(SVET). The results of EIS and polarization tests indicate that tolytriazole is effective in corrosion inhibition of galvanized steel. As the concentration of tolytriazole is increased to 0.01 M, the inhibiting efficiency reaches above 98%. The low values of anodie and cathodic current density in SVET maps suggest that the complex of tolytriazole with galvanized steel inhibits the anodic and cathodie reactions of corrosion of zinc. The adsorption behaviour of tolytriazole is found to conform to Langmuir adsorption isotherm, which is typical chemical adsorption.