Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using ...Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using sodium carboxymethyl starch (CMS) with high hydrophilicity,acrylic acid (AA) containing anionic carboxylic group and acrylamide (AM) containing non-ionic amide group as the main raw materials.The results show that the ratio of CAA-ICA alkali absorption solution is higher than that existing ICA,which solves the low water absorption ratio of the ICA in alkali environment.The water absorption ratio of CAA-ICA in saturated Ca(OH)_(2) solution is 95.8 g·g^(-1),and the alkali tolerance coefficient is 3.4.The application of CAA-ICA in cement-based materials can increase the internal relative humidity and miniaturize the pore structure.The compressive strength of mortar increases up to 12.95%at 28 d,which provids a solution to overcome the reduction of the early strength.展开更多
By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual...By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual hydrophilic modified polyurethane curing agent.Research revealed that introducing PEG400 for hydrophilic chain segments and sodium hydroxyethyl sulfonate for hydrophilic ionic groups in the polyurethane curing agent component leads to a uniform distribution of hydrophilic components,significantly enhancing compatibility with the aqueous polyol component,and results in excellent film performance.The synthesis process and film were characterized using Fourier transform infrared spectroscopy and high-resolution scanning electron microscopy in the study.展开更多
A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Four...A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Fourier transform infrared spectroscopy, nuclear magnetic resonance, mass spectrometry, and gel permeation chro-matography analyses. The thermal properties of the resulting polymer from diglycidyl ether of bisphenol A epoxy resin cured with the novel curing agent were evaluated using dynamic mechanical thermal analysis and thermogra-vimetric analysis. Compared with the conventional curing agent, the resulting polymer cured with naphtha-lene/DCPD navolac shows considerable improvement in heat resistant properties such as higher glass transition temperature (Tg) and thermal stability. The result also shows better moisture resistance because of the hydrophobic nature of naphthalene/DCPD structure.展开更多
One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage ...One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.展开更多
Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability o...Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability of the titanium-oxo-cluster was examined using a microdielectric analytical(DEA)curing monitor,Fourier transformed infrared spectroscopy(FTIR),and Soxhlet extraction experiments,and the properties of the resulted coatings were investigated with pendulum hardness tester,dynamic mechanical analysis(DMA),thermogravimetric analysis(TGA)and ultraviolet-visible spectrometer.The effect of titania-oxo-cluster in leading acrylic oligomers to form thermosetting acrylic coatings was confirmed.An increasing pendulum hardness and modulus of acrylic coatings with increasing titania content was observed, which resulted from the increment of crosslinking degree rather than of the titania content.The thermosetting acrylic/titania coatings also showed better thermal stability and higher UV-blocking properties than those coatings using organic curing agent.展开更多
A new class of novel polymeric crosslinking agent (NPCA), which contained silane coupling group and the epoxy groups, was designed and synthesized in our laboratory. NPCA was a non-formaldehyde multifunctional crossli...A new class of novel polymeric crosslinking agent (NPCA), which contained silane coupling group and the epoxy groups, was designed and synthesized in our laboratory. NPCA was a non-formaldehyde multifunctional crosslinking polymer. The cotton fabrics dyed with 8.0%(owf)Vinylsulpone-type dyes were treated with 3.0%4.0% NPCA, 0.5 mol/L potassium thiocyanate as a catalyst, then padded through two dips and two nips to reach a wet pickup of 80%85%, then dried at 80℃ for 2 minutes and cured in oven at 140150℃ for 3 minutes. Crocking fastness and fixation (%) were improved with up to 1.01.5 units, 35%50%, respectively. And there was little difference between the color yield of dyed fabrics before and after the treatment at certain conditions. The possible crosslinking mechanism of NPCA was also investigated. It was concluded that NPCA can improve colorfastness of cotton fabric by means of the three-dimensional network, covalent bonding and other molecular forces.展开更多
基金Funded by the National Key Research and Development Program of China (No.2019YFC1906202)the Guangxi Key Research and Development Plan (Nos.Guike AA18242007-3, Guike AB19259008, and Guike AB20297014)。
文摘Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using sodium carboxymethyl starch (CMS) with high hydrophilicity,acrylic acid (AA) containing anionic carboxylic group and acrylamide (AM) containing non-ionic amide group as the main raw materials.The results show that the ratio of CAA-ICA alkali absorption solution is higher than that existing ICA,which solves the low water absorption ratio of the ICA in alkali environment.The water absorption ratio of CAA-ICA in saturated Ca(OH)_(2) solution is 95.8 g·g^(-1),and the alkali tolerance coefficient is 3.4.The application of CAA-ICA in cement-based materials can increase the internal relative humidity and miniaturize the pore structure.The compressive strength of mortar increases up to 12.95%at 28 d,which provids a solution to overcome the reduction of the early strength.
文摘By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual hydrophilic modified polyurethane curing agent.Research revealed that introducing PEG400 for hydrophilic chain segments and sodium hydroxyethyl sulfonate for hydrophilic ionic groups in the polyurethane curing agent component leads to a uniform distribution of hydrophilic components,significantly enhancing compatibility with the aqueous polyol component,and results in excellent film performance.The synthesis process and film were characterized using Fourier transform infrared spectroscopy and high-resolution scanning electron microscopy in the study.
文摘A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Fourier transform infrared spectroscopy, nuclear magnetic resonance, mass spectrometry, and gel permeation chro-matography analyses. The thermal properties of the resulting polymer from diglycidyl ether of bisphenol A epoxy resin cured with the novel curing agent were evaluated using dynamic mechanical thermal analysis and thermogra-vimetric analysis. Compared with the conventional curing agent, the resulting polymer cured with naphtha-lene/DCPD navolac shows considerable improvement in heat resistant properties such as higher glass transition temperature (Tg) and thermal stability. The result also shows better moisture resistance because of the hydrophobic nature of naphthalene/DCPD structure.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51408159)the China Postdoctoral Science Foundation of China(Grant No.2013T60375 and 2012M520744)
文摘One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.
基金supported by the National Natural Science Foundation of China(No.20774023)Shanghai Leading Academic Discipline Project(No.B113).
文摘Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability of the titanium-oxo-cluster was examined using a microdielectric analytical(DEA)curing monitor,Fourier transformed infrared spectroscopy(FTIR),and Soxhlet extraction experiments,and the properties of the resulted coatings were investigated with pendulum hardness tester,dynamic mechanical analysis(DMA),thermogravimetric analysis(TGA)and ultraviolet-visible spectrometer.The effect of titania-oxo-cluster in leading acrylic oligomers to form thermosetting acrylic coatings was confirmed.An increasing pendulum hardness and modulus of acrylic coatings with increasing titania content was observed, which resulted from the increment of crosslinking degree rather than of the titania content.The thermosetting acrylic/titania coatings also showed better thermal stability and higher UV-blocking properties than those coatings using organic curing agent.
基金Supported by the Nation Nature Science Foundation of China (No.20325210)
文摘A new class of novel polymeric crosslinking agent (NPCA), which contained silane coupling group and the epoxy groups, was designed and synthesized in our laboratory. NPCA was a non-formaldehyde multifunctional crosslinking polymer. The cotton fabrics dyed with 8.0%(owf)Vinylsulpone-type dyes were treated with 3.0%4.0% NPCA, 0.5 mol/L potassium thiocyanate as a catalyst, then padded through two dips and two nips to reach a wet pickup of 80%85%, then dried at 80℃ for 2 minutes and cured in oven at 140150℃ for 3 minutes. Crocking fastness and fixation (%) were improved with up to 1.01.5 units, 35%50%, respectively. And there was little difference between the color yield of dyed fabrics before and after the treatment at certain conditions. The possible crosslinking mechanism of NPCA was also investigated. It was concluded that NPCA can improve colorfastness of cotton fabric by means of the three-dimensional network, covalent bonding and other molecular forces.