The constraints on the variation in the ratios of pairs of trace elements during crystal fractionation are described by using a set of inequality functions. This approach to the interpretation of the variation in trac...The constraints on the variation in the ratios of pairs of trace elements during crystal fractionation are described by using a set of inequality functions. This approach to the interpretation of the variation in trace element ratios provides a more thorough basis for describing the quantitative relationships between the variation of trace element ratios during the fractional crystallization, the difference of the bulk distribution coefficients of the two elements and the degree of fractionation. The constraints imposed by the inequalities lead to certain consequences on the variation in the ratios of pairs of trace elements during crystal fractionation. For these consequences not yet recognized in literature detailed explanation will be given in the present paper.展开更多
An one-year of sampling aerosol program was carried out during the period of April 1995 to April 1996 at coastal region, Cape D′Aguilar, in Hong Kong. The trace element composition of aerosol particles(TSP and PM ...An one-year of sampling aerosol program was carried out during the period of April 1995 to April 1996 at coastal region, Cape D′Aguilar, in Hong Kong. The trace element composition of aerosol particles(TSP and PM 10 ) were measured and analyzed by using the Instrumental Neutron Activation Analysis(INAA) and Inductive Couple Plasma-Mass Spectrometry(ICP-MS) techniques. The results showed that the polluted elements such as: V, Zn, As, Pb, Cd, Sb, I, Se, Bi, with high enrichment factor(E.F) values, are derived from anthropogenic sources, while Sc, Al, Fe, Mn, Sm, La, Sr are less than 10 in E.F, these elements are related the crust and soil. The concentration of the trace elements are present seasonal variation i.e. summer low and winter high, whereas the V or noncrustal V(V *) present summer high and winter low, this phenomenon might be explained by local or regional oil combustion sources. Use three type of elemental ratio, e.g. La/Sm, Mn */V * and Bi/Al indicate that both TSP and PM 10 of La/Sm ratios are mainly related to soil and dust, Mn */V * are probably represent fossil combustion and Bi/Al are possibly associated with refuse incineration, ferromanganese alloys and aluminum production. The varimax rotation factor analysis for trace elements was performed. By means of the absolute principal component analysis(APCA) and multiple regression, the contribution of trace elements to possible sources and overall means of trace elements were estimated. The results showed that the present station is impacted by the anthropogenic species, although the quantities are different during the summertime and wintertime.展开更多
Background: Type 2 Diabetes Mellitus (T2DM) is a chronic polymetabolic disorder characterized by chronic hyperglycemia resulting from resistance to insulin action or inadequacy of insulin secretion. Role of the micro ...Background: Type 2 Diabetes Mellitus (T2DM) is a chronic polymetabolic disorder characterized by chronic hyperglycemia resulting from resistance to insulin action or inadequacy of insulin secretion. Role of the micro & macro nutrients in the pathogenesis of T2DM has not been studied thoroughly. The aim of this study was to evaluate the status of calcium, magnesium, zinc and chromium in relation to HbA1c in a group of subjects with T2DM patients. Methodology: The study comprised of seventy three patients with T2DM, attending the OP of a tertiary care medical college hospital. Thirty four individuals were with HbA1c < 7% (group 1) and thirty nine with HbA1c ≥ 7% (group 2). Cation concentrations were determined using Atomic Absorption Spectroscopy and HbA1c by ion exchange chromatography. Results: The individual cation concentrations were not significantly different between the groups. Association of these serum ion concentrations with the glycemic control in group 2 (HbA1c 7%) was noted. Significant association of cation ratios with glycemic control was noted. Conclusion: The concentration of magnesium, zinc and chromium were low in subjects with poor glycemic control (HbA1c > 7%). Cation ratios were significantly associated with the glycemic control in T2DM.展开更多
文摘The constraints on the variation in the ratios of pairs of trace elements during crystal fractionation are described by using a set of inequality functions. This approach to the interpretation of the variation in trace element ratios provides a more thorough basis for describing the quantitative relationships between the variation of trace element ratios during the fractional crystallization, the difference of the bulk distribution coefficients of the two elements and the degree of fractionation. The constraints imposed by the inequalities lead to certain consequences on the variation in the ratios of pairs of trace elements during crystal fractionation. For these consequences not yet recognized in literature detailed explanation will be given in the present paper.
文摘An one-year of sampling aerosol program was carried out during the period of April 1995 to April 1996 at coastal region, Cape D′Aguilar, in Hong Kong. The trace element composition of aerosol particles(TSP and PM 10 ) were measured and analyzed by using the Instrumental Neutron Activation Analysis(INAA) and Inductive Couple Plasma-Mass Spectrometry(ICP-MS) techniques. The results showed that the polluted elements such as: V, Zn, As, Pb, Cd, Sb, I, Se, Bi, with high enrichment factor(E.F) values, are derived from anthropogenic sources, while Sc, Al, Fe, Mn, Sm, La, Sr are less than 10 in E.F, these elements are related the crust and soil. The concentration of the trace elements are present seasonal variation i.e. summer low and winter high, whereas the V or noncrustal V(V *) present summer high and winter low, this phenomenon might be explained by local or regional oil combustion sources. Use three type of elemental ratio, e.g. La/Sm, Mn */V * and Bi/Al indicate that both TSP and PM 10 of La/Sm ratios are mainly related to soil and dust, Mn */V * are probably represent fossil combustion and Bi/Al are possibly associated with refuse incineration, ferromanganese alloys and aluminum production. The varimax rotation factor analysis for trace elements was performed. By means of the absolute principal component analysis(APCA) and multiple regression, the contribution of trace elements to possible sources and overall means of trace elements were estimated. The results showed that the present station is impacted by the anthropogenic species, although the quantities are different during the summertime and wintertime.
文摘Background: Type 2 Diabetes Mellitus (T2DM) is a chronic polymetabolic disorder characterized by chronic hyperglycemia resulting from resistance to insulin action or inadequacy of insulin secretion. Role of the micro & macro nutrients in the pathogenesis of T2DM has not been studied thoroughly. The aim of this study was to evaluate the status of calcium, magnesium, zinc and chromium in relation to HbA1c in a group of subjects with T2DM patients. Methodology: The study comprised of seventy three patients with T2DM, attending the OP of a tertiary care medical college hospital. Thirty four individuals were with HbA1c < 7% (group 1) and thirty nine with HbA1c ≥ 7% (group 2). Cation concentrations were determined using Atomic Absorption Spectroscopy and HbA1c by ion exchange chromatography. Results: The individual cation concentrations were not significantly different between the groups. Association of these serum ion concentrations with the glycemic control in group 2 (HbA1c 7%) was noted. Significant association of cation ratios with glycemic control was noted. Conclusion: The concentration of magnesium, zinc and chromium were low in subjects with poor glycemic control (HbA1c > 7%). Cation ratios were significantly associated with the glycemic control in T2DM.