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Genesis of the Jianbeigou Gold Deposit on the Southern Margin of the North China Craton: Insights from Fluid Inclusions, H-O-S Isotopes, and Pyrite in situ Trace Element Analyses
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作者 LI Fengchun ZENG Qingdong +5 位作者 ZHU Rixiang CHU Shaoxiong XIE Wei YU Bing WU Jinjian LI Xinghui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第4期969-991,共23页
The Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, inc... The Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, including the quartz ± pyrite, quartz-polymetallic sulfide, and quartz-carbonate ± pyrite stages. From the early to late stages, the homogenization temperatures of primary fluid inclusions are 281–362°C, 227–331°C, and 149–261°C, respectively. The corresponding salinities estimated for these fluids are 3.9–9.9 wt%, 0.4–9.4 wt%, and 0.7–7.2 wt% Na Cl equiv. Combined with laser Raman spectroscopy data, the ore-forming fluid belongs to a H_(2)O-CO_(2)-Na Cl ± CH_4 system with medium–low temperature and salinity. The δ~(18)Ofluid and δD values for the quartz veins are-1.0‰ to 6.0‰ and-105‰ to-84‰, respectively, which indicates that the ore-forming fluid is of mixed source, mainly derived from magma, with a contribution from meteoric water. Pyrite has been identified into three generations based on mineral paragenetic sequencing, including Py1, Py2, and Py3. The pyrites have δ~(34)S sulfur isotopic compositions from three stages between 3.7‰ and 8.4‰, indicating that sulfur mainly originated from magma. Te, Bi, Sb, and Cu contents in pyrite were all high and showed a strong correlation with Au concentrations. Native gold and the Au-Ag-Bi telluride minerals were formed concurrently, and the As concentration was low and decoupled from the Au content. Therefore, Te, Bi, Sb and other low-melting point chalcophile elements play an important role for gold mineralization in arsenic-deficient ore-forming fluid. Combined with the geological setting, evolution of pyrite, and ore-fluids geochemistry, we propose that the Jianbeigou deposit can be classified as a magmatic–hydrothermal lode gold deposit. Gold mineralization on the southern margin of the North China Craton is related to Early Cretaceous magmatism and formed in an extensional setting. 展开更多
关键词 ore genesis H-O-S isotopes fluid inclusions in-situ trace element Jianbeigou gold deposit
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Predictive Study of Trace Metal Pollution of Gold Panning Sites in Birimian Formations: Case of the Yaouré Furrow (Côte d’Ivoire)
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作者 Tonga Paul Tiemoko Gbele Ouattara Kouassi Ernest Ahoussi 《Open Journal of Applied Sciences》 2024年第7期1691-1714,共24页
The present study was carried out on small-scale gold mining sites in the Yaouré region of Côte d’Ivoire. This region is geologically representative of the Birimian formations (2.1 Ga) of West Africa. The a... The present study was carried out on small-scale gold mining sites in the Yaouré region of Côte d’Ivoire. This region is geologically representative of the Birimian formations (2.1 Ga) of West Africa. The aim is to determine the potentially toxic trace metals (TMEs) generated by these sites, with a view to preventing possible contamination and/or metal pollution of the waters that provide fish products for local populations. To this end, a sampling campaign was carried out, resulting in the collection of 20 mining waste samples analyzed by X-ray fluorescence spectrometry (XRF) and 10 by X-ray diffractometer (XRD). The XRF analysis detected 06 predominant TMEs: arsenic, chromium, copper, nickel, zinc and vanadium. Statistical analysis was carried out to determine the distributions and correlations between these ETMs. To assess contamination and/or pollution levels, the following indices were calculated on the basis of reference concentrations of upper continental crust MTEs: Enrichment Factor, Geo-accumulation Index, Concentration Factor, Degree of contamination and those related to ecological risks. The results of statistical analyses and indices have shown that arsenic and chromium are the most predominant and can be, depending on the chemical form, potentially more toxic. The results of the DRX analysis show the occurrence of several minerals carrying these two MTEs, especially that of a rare mineral, Stenhuggarite, an arsenic oxide linked to hydrothermal veins. The majority of gold mining operations in West Africa are located in the birimian zone, hence the need for environmental monitoring by the relevant authorities, to prevent potential ecological risks to water and possibly health risks via the food chain. 展开更多
关键词 Small-Scale Mining Metallic trace Elements Mining Discharges CONTAMINATION POLLUTION CONTAMINATION POLLUTION Index
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基于“GOLD原则”的金课教学法研究与实践——以离散数学课程为例
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作者 孙丽梅 栾方军 董洁 《计算机教育》 2024年第9期208-212,共5页
针对目前金课教学存在的问题,提出基于“GOLD原则”的金课教学法,从目标(Goal)、选项(Option)、领导(Leading)、展示(Display)4个步骤具体阐述,以离散数学课堂为例介绍基于“GOLD原则”的金课教学法的教学过程,说明教学效果。
关键词 gold原则 金课 教学实践 离散数学
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Genesis of the Nuri Cu-W-Mo Deposit,Tibet,China:Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite 被引量:1
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作者 WANG Yiyun WU Zhishan +8 位作者 CHEN Wenqing DU Qing’an TANG Liwei SHI Hongzhao MA Guotao ZHANG Zhi LIANG Wei WU Bo MIAO Hengyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期117-131,共15页
The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controver... The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controversial since its discovery.Based on a study of the geological characteristics of the deposit,this study presents mineralization stages,focusing on the oxide stage and the quartz-sulfide stage where scheelite is mainly formed,referred to as Sch-A and Sch-B,respectively.Through LA-ICP-MS trace element and Sr isotope analyses,the origin,evolutionary process of the oreforming fluid and genesis of the ore deposit are investigated.Scanning Electron Microscope-Cathodoluminescence(SEMCL)observations reveal that Sch-A consists of three generations,with dark gray homogenous Sch-A1 being replaced by relatively lighter and homogeneous Sch-A2 and Sch-A3,with Sch-A2 displaying a gray CL image color with vague and uneven growth bands and Sch-A3 has a light gray CL image color with hardly any growth band.In contrast,Sch-B exhibits a‘core-rim’structure,with the core part(Sch-B1)being dark gray and displaying a uniform growth band,while the rim part(Sch-B2)is light gray and homogeneous.The normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore-forming fluid in the Nuri deposit originated from granodiorite porphyry and,later on,some country rock material was mixed in,due to strong water-rock interaction.Combining the O-H isotope data further indicates that the ore-forming fluid in the Nuri deposit originated from magmatic-hydrothermal sources,with contributions from metamorphic water caused by water-rock interaction during the mineralization process,as well as later meteoric water.The intense water-rock interaction likely played a crucial role in the precipitation of scheelite,leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz-sulfide stage,while also causing a gradual decrease in oxygen fugacity(fO2)and a slow rise in pH value.Additionally,the high Mo and low Sr contents in the scheelite are consistent with typical characteristics of magmatic-hydrothermal scheelite.Therefore,considering the geological features of the deposit,the geochemical characteristics of scheelite and the O-H isotope data published previously,it can be concluded that the genesis of the Nuri deposit belongs to porphyry-skarn deposit. 展开更多
关键词 trace elements in situ Sr isotopes tungsten mineralization Gangdese metallogenic belt TIBET
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Tailoring MXene Thickness and Functionalization for Enhanced Room‑Temperature Trace NO_(2) Sensing 被引量:2
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作者 Muhammad Hilal Woochul Yang +1 位作者 Yongha Hwang Wanfeng Xie 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期71-86,共16页
In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method... In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method involving high-pressure processing,stirring,and immiscible solutions,sub-100 nm MXene flake thickness is achieved within the MXene film on the Si-wafer.Functionalization control is achieved by defunctionalizing MXene at 650℃ under vacuum and H2 gas in a CVD furnace,followed by refunctionalization with iodine and bromine vaporization from a bubbler attached to the CVD.Notably,the introduction of iodine,which has a larger atomic size,lower electronegativity,reduce shielding effect,and lower hydrophilicity(contact angle:99°),profoundly affecting MXene.It improves the surface area(36.2 cm^(2) g^(-1)),oxidation stability in aqueous/ambient environments(21 days/80 days),and film conductivity(749 S m^(-1)).Additionally,it significantly enhances the gas-sensing performance,including the sensitivity(0.1119Ωppm^(-1)),response(0.2% and 23%to 50 ppb and 200 ppm NO_(2)),and response/recovery times(90/100 s).The reduced shielding effect of the–I-terminals and the metallic characteristics of MXene enhance the selectivity of I-MXene toward NO2.This approach paves the way for the development of stable and high-performance gas-sensing two-dimensional materials with promising prospects for future studies. 展开更多
关键词 Controlled MXene thickness Gaseous functionalization approach Lower electronegativity functional groups Enhanced MXene stability trace NO_(2)sensing
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Assessing the Impact of Gold Mining on the Quality of Water Resources in the Commune of Meguet, Burkina Faso
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作者 Issoufou Ouedraogo Samuel Lankoande +3 位作者 Yacouba Konate Boukary Sawadogo Nicolas Kagambega Martin Lompo 《Journal of Water Resource and Protection》 CAS 2024年第4期281-292,共12页
Despite its often illegal nature, artisanal gold mining in Burkina Faso contributes to the economic and social development of the country. However, the rudimentary techniques used in gold panning have a significant im... Despite its often illegal nature, artisanal gold mining in Burkina Faso contributes to the economic and social development of the country. However, the rudimentary techniques used in gold panning have a significant impact on the environment due to inappropriate practices and the use of various chemical substances. This study aims to assess the impact of artisanal gold mining on the quality of water resources in a rural community at Méguet, Burkina Faso. To this end, surface and groundwater samples were collected and analyzed at the BUMIGEB laboratory. Field results show that the waters are slightly alkaline (6.97 < pH < 8.1), weakly mineralized and conductive (124 < EC < 543 μS/cm), with temperatures ranging from 24.6˚C to 31.6˚C. In addition, trace metals (TMEs) analyzed from surface and subsurface waters show very high levels, generally deviating from the levels recommended by WHO guidelines for Burkina Faso. Trace metals contamination of water resources in the commune of Méguet is mainly due to Fe (3.78 - 11.12 mg/kg), Hg (0.03 - 0.29 mg/kg), As (0.01- 6.31 mg/kg) and Pb (0.01 - 3.8 mg/kg). This study can serve as a basis for guiding national environmental policies to protect the water resources of the Méguet mine. 展开更多
关键词 gold Panning Water Quality trace Metal Méguet Burkina Faso
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Correlations between trace elements in pyrite and gold mineralization of gold deposits on the North China platform
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作者 Jianzhao Yin Ying Sun +4 位作者 Haoyu Yin Hongyun Shi James Sparling Yuhong Chao Shoupu Xiang 《Acta Geochimica》 EI CAS CSCD 2023年第6期1079-1103,共25页
By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform... By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance. 展开更多
关键词 Unit cell parameter PYROELECTRICITY Electron paramagnetic resonance Infrared spectrum PYRITE gold deposit
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Characteristics of Gold Mineralization at the Baguiomo Gold Panning Site, Koudougou Region, Burkina Faso, West Africa
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作者 Pascal Ouiya Aziz Fayçal Tarnagda Martial Eric Fozing 《Open Journal of Geology》 CAS 2024年第1期1-18,共18页
The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are ... The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are located in the Kwademen-Baguiomo shear zone. This mineralization, located only a few kilometers from the Kwademen gold deposit, is uncharacterized and, together with the latter, could constitute a gold potential capable of being economically exploitable. It is in this sense that this work is carried out with a view to characterizing the gold mineralization of the Baguiomo gold panning site. To carry out this work, we have made direct field measurements, combined with microstructures, and combined all this with data from geochemical rock analysis of the basalts that are the main host formations. Geochemical data show that tholeitic basalts formed from a mantle plume that was emplaced in an oceanic plateau context. Calc-alkaline basalts and andesites are comparable to Paleoproterozoic tholeitic basalts (PTH3), which are slightly enriched in light rare earths. Fertility tests show that these basalts concentrate between 3 and 6 ppb of gold at the time of accretion, which is sufficient for remobilization of this primary gold during the Eburnian orogeny to yield a deposit of around 4 - 5 Moz. Gold mineralization is associated with pyrite crystals when the latter are disseminated in the rock mass, whereas it is associated with hematite in quartz veins concordant with S1 shear deformation. It is mainly the pyrite crystals in the pressure shadows that contain the gold grains, whose development would be synchronous with micro-shear zone reactivation during the first phase of D1<sub>B</sub> deformation. The second phase of D2<sub>B</sub> deformation, which is a crenulation or fracture schistosity, does not significantly affect the shear deformation that controls mineralization. 展开更多
关键词 Kwademen-Baguiomo Shear Zone gold Panning Site gold Mineralization Eburnian Orogeny
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Discovery of scheelite in the Zaozigou gold deposit of West Qinling Orogen,Northwest China and its implications for ore genesis
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作者 Meng-xu Guo Jia-jun Liu +2 位作者 De-gao Zhai Guo-ming Weng Rui Zhu 《China Geology》 CAS CSCD 2024年第3期586-588,共3页
1.Objective The West Qinling Orogen extends east-west over 1500 km and is endowed with dozens of large-super large scale gold deposits.The Zaozigou gold deposit has a proven reserve of 134 t with an average grade of 3... 1.Objective The West Qinling Orogen extends east-west over 1500 km and is endowed with dozens of large-super large scale gold deposits.The Zaozigou gold deposit has a proven reserve of 134 t with an average grade of 3.08 g/t thus is one of the largest deposits in the West Qinling Orogen.However,whether the fluid type is metamorphic or magmatichydrothermal and ore-formation processes of the Zaozigou gold deposit are equivocal.Scheelite is a ubiquitous accessory mineral in geologically diverse ore-deposit types and attested to be a strong indicator of ore-forming conditions and oredeposit genesis. 展开更多
关键词 DEPOSIT gold QINLING
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Origin of the Yueguang gold deposit in Xinhua, Hunan Province, South China: insights from fl uid inclusion and hydrogen–oxygen stable isotope analysis
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作者 Hongxin Fan Qiang Wang +2 位作者 Yulong Yang Yao Tang Hao Zou 《Acta Geochimica》 EI CAS CSCD 2024年第2期235-254,共20页
The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,w... The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province. 展开更多
关键词 Hunan province Yueguang gold deposit Fluid inclusions Hydrogen–oxygen isotopes Laser Raman Fluid immiscibility Orogenic gold deposit
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Trace formula of the integro-differential operator on a quantum graph
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作者 WEI Li-xiao YANG Chuan-fu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第2期311-318,共8页
In this paper we study the eigenvalue problem for integro-differential operators on a lasso graph.The trace formula of the operator is established by applying the residual technique in complex analysis.
关键词 integro-differential operators EIGENVALUE trace formula
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Structural Pattern Related to Gold Mineralization in the Essakane Area (Northern Burkina Faso, West African Craton)
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作者 Marc Desire Valea Benjamin Sawadogo +3 位作者 Kalidou Traoré Urbain Wenmenga Naba Seta Benjamin Allou 《Open Journal of Geology》 CAS 2024年第9期855-879,共25页
The finite deformation structures recorded in the Essakane area, located in the northeast corner of Burkina Faso, highlight three major compressive deformation phases, successively named D1, D2, and D3. The D1 event p... The finite deformation structures recorded in the Essakane area, located in the northeast corner of Burkina Faso, highlight three major compressive deformation phases, successively named D1, D2, and D3. The D1 event phase, trending NE-SW, is characterised by P1 folds and S1 axial plane schistosity. The D2 phase trending NW-SE is characterised by folds P2, schistosity (S2) and shear (C) planes. And the D3 phase trending NNE-SSW to N-S is characterised by P3 folds, crenulation microfolds and S3 spaced schistosity. It has also been noted that gold mineralizations are mainly hosted in quartz, carbonate, pyrite, and arsenopyrite veins. Structural interpretation indicates that these veins are organized into lenticular bodies that were formed during the first two deformation phases (D1 and D2). This suggests a strong structural control typical of orogenic gold concentrations. 展开更多
关键词 Burkina Faso Essakane Shear Zone Deformation Phases Orogenic gold
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Trace elements in magmatic and hydrothermal quartz:Implications on the genesis of the Xingluokeng Tungsten Deposit,South China
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作者 Qing-Qing Zhang You-Wei Chen Jian-Feng Gao 《Acta Geochimica》 EI CAS CSCD 2024年第3期441-458,共18页
The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,and... The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,andfine-grained granite.The deposit is represented by veinlet-disseminated mineralization with K-feldspathization and biotitization,alongside quartz-vein mineralization with gre-isenization and sericitization.This study investigates in-situ analyses of quartz compositions from both the intrusion and hydrothermal veinlets and veins.Trace element correlations indicate that trivalent Al^(3+)and Fe^(3+)replace Si^(4+)within the quartz lattice,with monovalent cations(such as Li^(+),Na^(+),and K^(+))primarily serving as charge compensators.Low Ge/Al ratios(<0.013)of quartz from granites suggest a mag-matic origin.The low Al/Ti and Ge/Ti ratios,accompanied by high Ti contents in quartz,suggest that the porphyritic biotite granite and biotite granite are characterized by rela-tively low levels of differentiation and high crystallization temperatures.In contrast,thefine-grained granite exhibits a higher degree of fractionation,lower crystallization tem-peratures,and a closer association with tungsten miner-alization.Ti contents in quartz from quartz veins indicate Qz-Ⅰformed at temperatures above 400°C,while Qz-Ⅱto Qz-Ⅴformed at temperatures below 350°C.Variations in different generations of quartz,as indicated by Al content and(Al+Fe)/(Li+Na+K)ratio,suggest that Qz-Ⅰprecipi-tated from a less acidicfluid with a stable pH,whereas Qz-Ⅱto Qz-Ⅴoriginated from a more acidicfluid with notable pH variations.Consequently,alkaline alteration and acidic alteration supplied the essential Ca and Fe for the precipita-tion of scheelite and wolframite,respectively,highlighting a critical mechanism in tungsten mineralization at the Xin-gluokeng deposit. 展开更多
关键词 QUARTZ Xingluokeng Tungsten deposit trace elements South China
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Distribution, health and ecological risk assessments of trace elements in Nigerian oil sands
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作者 Odunayo T.Ore Festus M.Adebiyi 《Acta Geochimica》 EI CAS CSCD 2024年第1期59-71,共13页
The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. I... The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. In the present study, we investigated the distribution pattern of 18trace elements(including biophile and chalcophile elements) as well as the estimated risks associated with exposure to these elements. The results of the study indicated that Fe was the most abundant element, with a mean concentration of 22,131 mg/kg while Br had the lowest mean concentration of 48 mg/kg. The high occurrence of Fe and Ti suggested a possible occurrence of ilmenite(Fe TiO_(3)) in the oil sands. Source apportionment using positive matrix factorization showed that the possible sources of detected elements in the oil sands were geogenic, metal production, and crustal. The contamination factor, geo-accumulation index, modified degree of contamination, pollution load index, and Nemerow pollution index indicated that the oil sands are heavily polluted by the elements. Health risk assessment showed that children were relatively more susceptible to the potentially toxic elements in the oil sands principally via ingestion exposure route(HQ > 1E-04). Cancer risks from inhalation are unlikely due to CR < 1E-06 but ingestion and dermal contact pose severe risks(CR > 1E-04). The high concentrations of the elements pose serious threats due to the potential for atmospheric transport, bioaccessibility, and bioavailability. 展开更多
关键词 Biophile Chalcophile Oil sand Risk assessment trace element
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Fast synthesis of gold nanoparticles by cold atmospheric pressure plasma jet in the presence of Au^(+) ions and a capping agent
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作者 Tatiana HABIB José Mauricio A.CAIUT Bruno CAILLIER 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期108-115,共8页
Homogeneous gold nanoparticles were synthesized under atmospheric pressure using a nonthermal helium plasma jet in a single-step process.A current power supply was used to generate the plasma discharge rich in diverse... Homogeneous gold nanoparticles were synthesized under atmospheric pressure using a nonthermal helium plasma jet in a single-step process.A current power supply was used to generate the plasma discharge rich in diverse reactive species.These species induce rapid chemical reactions responsible for the reduction of the gold salts upon contact with the liquid solution.In this study,spherical and monodispersed gold nanoparticles were obtained within 5 min of plasma exposure using a solution containing gold(Ⅲ)chloride hydrate(HAuCl_(4))as a precursor and polyvinylpyrrolidone(PVP)as a capping agent to inhibit agglomerations.The formation of these metal nanoparticles was initially perceptible through a visible change in the sample's color,transitioning from light yellow to a red/pink color.This was subsequently corroborated by UVvis spectroscopy,which revealed an optical absorption in the 520-550 nm range for Au NPs,corresponding to the surface plasmon resonance(SPR)band.An investigation into the impact of various parameters,including plasma discharge duration,precursor and capping agent concentrations,was carried out to optimize conditions for the formation of well-separated,spherical gold nanoparticles.Dynamic light scattering(DLS)was used to measure the size of these nanoparticles,transmission electron microscopy(TEM)was used to observe their morphology and X-ray diffraction(XRD)was also employed to determine their crystallographic structure.The results confirm that homogeneous spherical gold nanoparticles with an average diameter of 13 nm can be easily synthesized through a rapid,straightforward,and environmentally friendly approach utilizing a helium atmospheric pressure plasma. 展开更多
关键词 gold nanoparticles NON-THERMAL plasma jet HELIUM DBD
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Multi-Scale Approach for Gold Targeting in Côte d’Ivoire Paleoproterozoic Rocks
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作者 Martial Pohn Koffi Adingra Yao Augustin Koffi +3 位作者 N’guessan Nestor Houssou Zié Ouattara Tokpa Kakeu Lionel-Dimitri Boya Marc Ephrem Allialy 《Open Journal of Geology》 CAS 2024年第2期155-176,共22页
The aim of this study is to contribute to better targeting of gold prospecting areas using geospatial information. To this end, 3 mining sites were selected for the study. They are: the Sénoufo belt (Barrick Gold... The aim of this study is to contribute to better targeting of gold prospecting areas using geospatial information. To this end, 3 mining sites were selected for the study. They are: the Sénoufo belt (Barrick Gold mine), the Yaouré complex (Perseus Mining mine) and the South Fetêkro belt (Bonikro, Hiré and Agbaou mines). For this study, a multi-scale approach was carried out at regional, mine and microscopic levels. At the regional scale, a comparative analysis of 1:200,000 scale geological maps revealed that 3 main lithologies are regularly repeated on and around the various mining sites. These are: undifferentiated volcanics, metagranodiorites and metasiltites dominated by meta-arenites. Most of these lithologies are affected by undifferentiated faults generally oriented NE-SW, N-S, ENE-WSW and WNW-ESE. In addition, gold and manganese occurrences are present on all the sites studied. At the mine scale, radarsat-1 images processing indicate that the main mining sites are generally located near or at the intersection of lineaments-oriented NE-SW or N-S on the one hand and E-W or ENE-WSW or WNW-ESE or again NW-SE on the other. These mines are also located at the interface between zones of high and low lineament density. At the microscopic scale, petrographic studies of undifferentiated volcanic samples from the various sites indicate that they consist of andesites, meta-andesites and tuffs. 展开更多
关键词 gold Targeting Undifferentiated Volcanics Mineral Occurrences LINEAMENTS Côte d’Ivoire
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Mobility of Major and Trace Elements during the Bauxitization Processes in Ngaoundal Area (Adamawa Cameroon): Implication on Mining Perspectives
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作者 André Sini Harouna Boukari +4 位作者 Ondoa Augustin Désiré Balla Djetenbe Beral Salomon Wangmené Awé Simon Djakba Basga Jean Pierre Nguetnkam 《Open Journal of Geology》 CAS 2024年第1期81-100,共20页
This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical ... This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical analyses were carried out. Four facies of duricrust were identified and characterized from the summit to the top of the slope of the Ngaoundal mountain: scoriaceous, pisolitic, nodular and massive. Mineralogical and geochemical analyses performed on 16 samples, revealed a significant concentration of Al<sub>2</sub>O<sub>3</sub> mainly in the scoriaceous facies (over 45% in grade), moderate in Fe<sub>2</sub>O<sub>3</sub> (averaging 23.69%) and SiO<sub>2</sub> (averaging 21.7%). Trace elements were generally low, excluding Cr (421 ppm on average), Zr (327 ppm on average and V (213 ppm on average). In addition, the limited quantities of alkalis (Na<sub>2</sub>O, K<sub>2</sub>O) and alkaline earths metals (MgO, CaO) coupled with the very high values of Chemical Index of Alteration (CIA) and Mineralogical Index of Alteration (MIA), (more than 99%) attest to the intense weathering of the studied materials. Allitization and monosiallitization constituted the crystallochemical phenomena that have led to the development of bauxitic minerals. More than 90% of gibbsite in scoriaceous facies, 52.21% - 76.01% of kaolinite in pisolitic facies and more than 40% of hematite in nodular facies were quantified. The relationships between the constitutive components indicated their interdependency during the bauxitization phenomenon. The mineralogical and geochemical properties highlighted the mining interest of the studied duricrusts to be valorized. 展开更多
关键词 Duricrust Bauxitization Phenomenon Mineralogical and Geochemical Characterization Major and trace Elements Mining Potential
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Environmental characteristics of trace metals in seawater from the Ninety East Ridge in the Indian Ocean
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作者 Jingxi LI Di ZHANG +3 位作者 Fenghua JIANG Hong CHEN Wei CAO Chengjun SUN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1119-1129,共11页
The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East ... The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East Ridge in the Indian Ocean were investigated.Results show that the average concentrations of different trace metals in all the collected seawater samples were 1.134μg/L for V,0.158μg/L for Cr,0.489μg/L for Mn,0.427μg/L for Fe,0.011μg/L for Co,0.395μg/L for Ni,0.403μg/L for Cu,0.097μg/L for Cd,0.139μg/L for Pb,and 3.470μg/L for U.Differences in the horizontal and vertical distributions of all measured trace metals were revealed,and the occurrence of high concentrations was nonuniform.In addition,the significant differences in the concentration distribution of different trace metals in seawater on both sides of the Ninety East Ridge present regional segmentation in the area for various trace metals in deep sea water.This study provided basic data for future investigations on the environmental and ecological impact of trace metals in the Indian Ocean and the potential water mass transport mechanism. 展开更多
关键词 trace metal environmental characteristic Ninety East Ridge seawater Indian Ocean
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Tamping the movement of the laser absorption cutoff position using gold foam hohlraum
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作者 张璐 李丽灵 +14 位作者 林稚伟 董云松 景龙飞 郑建华 况龙钰 黎航 郑金华 张继彦 宋天明 张志宇 赵阳 牛高 杨冬 杨家敏 丁永坤 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第5期56-61,共6页
In indirect-driven laser fusion experiments,the movement of the laser absorption layer will distort the radiation uniformity on the capsule.The gold foam has advantages in symmetry control and lowering wall plasma blo... In indirect-driven laser fusion experiments,the movement of the laser absorption layer will distort the radiation uniformity on the capsule.The gold foam has advantages in symmetry control and lowering wall plasma blowoff when used in an inertial confinement fusion(ICF)hohlraum.This work investigates the motion of the laser absorption cutoff position using lowdensity foam gold walls.It is found that the motion of the laser absorption cutoff position can be significantly mitigated through optimal initial low density,tailored to a specific laser shape.For a short square laser pulse,the laser absorption cutoff position remains almost stationary at an initial density of approximately 0.6 g cm^(-3).For a long-shaped laser pulse,the minimal motion of the laser absorption cutoff position is observed at an initial density of about 0.1 g cm^(-3).This approach allows for the adjustment of the symmetry of the hohlraum radiation source.The insights gained from this study serve as a crucial reference for optimizing the hohlraum wall density. 展开更多
关键词 hohlraum symmetry laser absorption plasma blowoff gold foam
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Industrial utilization of arsenic-containing gold dressing tailings as pellet prepared by straight grate process
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作者 LIU Wei GUO Zheng-qi +5 位作者 ZHU De-qing PAN Jian ZHANG Wu-ju WANG Jin ZHANG Ying-qun YIN Fu-xing 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第6期1888-1899,共12页
The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide.The thermodynamic analysis results indicate that ferrous arsenate(FeAsO_(4)),pyrite(FeS_(2))... The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide.The thermodynamic analysis results indicate that ferrous arsenate(FeAsO_(4)),pyrite(FeS_(2))and sodium cyanide(NaCN)in the arsenic-containing gold metallurgical tailings can be effectively removed using straight grate process,and the removal of pyrite and sodium cyanide is basically completed during the preheating stage,while the removal of ferrous arsenate requires the roasting stage.The pellets undergo a transformation from magnetite to hematite during the preheating process,and are solidified through micro-crystalline bonding and high-temperature recrystallization of hematite(Fe_(2)O_(3))during the roasting process.Ultimately,pellets with removal rates of 80.77% for arsenic,88.78% for sulfur,and 99.88% for cyanide are obtained,as well as the iron content is 61.1% and the compressive strength is 3071 N,meeting the requirements for blast furnace burden.This study provides an industrially feasible method for treating arsenic-containing gold smelting tailings,benefiting gold production enterprises. 展开更多
关键词 arsenic-containing gold dressing tailings pelletizing straight grate process recycling
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