High volume aerosol samplers at Great Wall Station in Antarctica were used to collect 73 aerosol samples between January 2012 and November 2013. The main ions in these aerosol samples, Cl^-, NO3-, SO4^2-, Na＋, K＋, ...High volume aerosol samplers at Great Wall Station in Antarctica were used to collect 73 aerosol samples between January 2012 and November 2013. The main ions in these aerosol samples, Cl^-, NO3-, SO4^2-, Na＋, K＋, Ca2＋, Mg2＋, NH4＋, as well as methane sulfonic acid, were analyzed using ion chromatography. Trace metals in these samples, including Pb, Cu, Cd, V, Zn, Fe, and Al, were determined by inductively-coupled plasma mass spectrometry. Results showed that sea salt was the main component in aerosols at Great Wall Station. Most ions exhibited significant seasonal variations, with higher concentrations in summer and autumn than in winter and spring. Variations in ions and trace metals were related to several processes（or sources）, including sea salt emission, secondary aerosol formation, and anthropogenic pollution from both local and distant sources. The sources of ions and trace metals were identified using enrichment factor, correlation, and factor analyses. Clearly, Na＋, K＋, Ca2＋, and Mg2＋were from marine sources, while Cu, Pb, Zn, and Cd were from anthropogenic pollution, and Al and V were mainly from crustal sources.展开更多
The spatial distributions of lead, arsenic, and copper （Pb, As, and Cu, respectively） in surface snow along the transect from the Zhongshan Station to Dome A, East Antarctica, are presented. The mean concentrations ...The spatial distributions of lead, arsenic, and copper （Pb, As, and Cu, respectively） in surface snow along the transect from the Zhongshan Station to Dome A, East Antarctica, are presented. The mean concentrations of Pb, As, and Cu are 1.04±1.56 pg/g, 0.39±0.08 pg/g, and 11.2±14.4 pg/g, respectively. It is estimated that anthropogenic contributions are dominant for Pb, As, and Cu. Spatially, Pb concentrations show an exponentially decreasing trend from the coast inland, while a moderate decreasing trend is observed for Cu concentrations in the coastal area （below 2,000 m above sea level （a.s.1.））. In the intermediate area （2,000-3,000 m a.s.1.）, the concentrations and enrichment factors of all these elements show high variability due to the complicated characteristics of climate and environment. On the inland plateau （above 3,000 m a.s.1.）, the high concentrations of As and Pb are induced by high deposition efficiency, the existence of polar stratospheric precipitation, and the different fraction deposition to East Antarctica. The extremely high concentrations with maximum values of 9.59 pg/g and 69.9 pg/g for Pb and Cu, respectively, are suggested to result mainly from local human activities at the station. Our results suggest that source, transport pathway, and deposition pattern, rather than distance from the coast or altitude, lead to the spatial distributions of Pb, As, and Cu; and it is further confirmed by spatial variations of the three metals deposited over the whole continent of Antarctica.展开更多
基金supported by the National Natural Science Foundation of China (Grant nos. 41230529 and 41476172)the Chinese Polar Environment Comprehensive Investigation & Assessment Programs (Grant no. CHINARE2012-15 for 01-04-02, 02-01, and 03-0402)Chinese International Cooperation Projects, Chinese Arctic and Antarctic Adminstration (Grant nos. 2015DFG22010, IC201201, IC201308 and IC201513)
文摘High volume aerosol samplers at Great Wall Station in Antarctica were used to collect 73 aerosol samples between January 2012 and November 2013. The main ions in these aerosol samples, Cl^-, NO3-, SO4^2-, Na＋, K＋, Ca2＋, Mg2＋, NH4＋, as well as methane sulfonic acid, were analyzed using ion chromatography. Trace metals in these samples, including Pb, Cu, Cd, V, Zn, Fe, and Al, were determined by inductively-coupled plasma mass spectrometry. Results showed that sea salt was the main component in aerosols at Great Wall Station. Most ions exhibited significant seasonal variations, with higher concentrations in summer and autumn than in winter and spring. Variations in ions and trace metals were related to several processes（or sources）, including sea salt emission, secondary aerosol formation, and anthropogenic pollution from both local and distant sources. The sources of ions and trace metals were identified using enrichment factor, correlation, and factor analyses. Clearly, Na＋, K＋, Ca2＋, and Mg2＋were from marine sources, while Cu, Pb, Zn, and Cd were from anthropogenic pollution, and Al and V were mainly from crustal sources.
基金supported by the National Natural Science Foundation of China(41330526)
文摘The spatial distributions of lead, arsenic, and copper （Pb, As, and Cu, respectively） in surface snow along the transect from the Zhongshan Station to Dome A, East Antarctica, are presented. The mean concentrations of Pb, As, and Cu are 1.04±1.56 pg/g, 0.39±0.08 pg/g, and 11.2±14.4 pg/g, respectively. It is estimated that anthropogenic contributions are dominant for Pb, As, and Cu. Spatially, Pb concentrations show an exponentially decreasing trend from the coast inland, while a moderate decreasing trend is observed for Cu concentrations in the coastal area （below 2,000 m above sea level （a.s.1.））. In the intermediate area （2,000-3,000 m a.s.1.）, the concentrations and enrichment factors of all these elements show high variability due to the complicated characteristics of climate and environment. On the inland plateau （above 3,000 m a.s.1.）, the high concentrations of As and Pb are induced by high deposition efficiency, the existence of polar stratospheric precipitation, and the different fraction deposition to East Antarctica. The extremely high concentrations with maximum values of 9.59 pg/g and 69.9 pg/g for Pb and Cu, respectively, are suggested to result mainly from local human activities at the station. Our results suggest that source, transport pathway, and deposition pattern, rather than distance from the coast or altitude, lead to the spatial distributions of Pb, As, and Cu; and it is further confirmed by spatial variations of the three metals deposited over the whole continent of Antarctica.
