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Genesis of the Nuri Cu-W-Mo Deposit,Tibet,China:Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite 被引量:1
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作者 WANG Yiyun WU Zhishan +8 位作者 CHEN Wenqing DU Qing’an TANG Liwei SHI Hongzhao MA Guotao ZHANG Zhi LIANG Wei WU Bo MIAO Hengyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期117-131,共15页
The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controver... The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controversial since its discovery.Based on a study of the geological characteristics of the deposit,this study presents mineralization stages,focusing on the oxide stage and the quartz-sulfide stage where scheelite is mainly formed,referred to as Sch-A and Sch-B,respectively.Through LA-ICP-MS trace element and Sr isotope analyses,the origin,evolutionary process of the oreforming fluid and genesis of the ore deposit are investigated.Scanning Electron Microscope-Cathodoluminescence(SEMCL)observations reveal that Sch-A consists of three generations,with dark gray homogenous Sch-A1 being replaced by relatively lighter and homogeneous Sch-A2 and Sch-A3,with Sch-A2 displaying a gray CL image color with vague and uneven growth bands and Sch-A3 has a light gray CL image color with hardly any growth band.In contrast,Sch-B exhibits a‘core-rim’structure,with the core part(Sch-B1)being dark gray and displaying a uniform growth band,while the rim part(Sch-B2)is light gray and homogeneous.The normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore-forming fluid in the Nuri deposit originated from granodiorite porphyry and,later on,some country rock material was mixed in,due to strong water-rock interaction.Combining the O-H isotope data further indicates that the ore-forming fluid in the Nuri deposit originated from magmatic-hydrothermal sources,with contributions from metamorphic water caused by water-rock interaction during the mineralization process,as well as later meteoric water.The intense water-rock interaction likely played a crucial role in the precipitation of scheelite,leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz-sulfide stage,while also causing a gradual decrease in oxygen fugacity(fO2)and a slow rise in pH value.Additionally,the high Mo and low Sr contents in the scheelite are consistent with typical characteristics of magmatic-hydrothermal scheelite.Therefore,considering the geological features of the deposit,the geochemical characteristics of scheelite and the O-H isotope data published previously,it can be concluded that the genesis of the Nuri deposit belongs to porphyry-skarn deposit. 展开更多
关键词 trace elements in situ Sr isotopes tungsten mineralization Gangdese metallogenic belt TIBET
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Trace formula of the integro-differential operator on a quantum graph
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作者 WEI Li-xiao YANG Chuan-fu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第2期311-318,共8页
In this paper we study the eigenvalue problem for integro-differential operators on a lasso graph.The trace formula of the operator is established by applying the residual technique in complex analysis.
关键词 integro-differential operators EIGENVALUE trace formula
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Distribution, health and ecological risk assessments of trace elements in Nigerian oil sands
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作者 Odunayo T.Ore Festus M.Adebiyi 《Acta Geochimica》 EI CAS CSCD 2024年第1期59-71,共13页
The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. I... The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. In the present study, we investigated the distribution pattern of 18trace elements(including biophile and chalcophile elements) as well as the estimated risks associated with exposure to these elements. The results of the study indicated that Fe was the most abundant element, with a mean concentration of 22,131 mg/kg while Br had the lowest mean concentration of 48 mg/kg. The high occurrence of Fe and Ti suggested a possible occurrence of ilmenite(Fe TiO_(3)) in the oil sands. Source apportionment using positive matrix factorization showed that the possible sources of detected elements in the oil sands were geogenic, metal production, and crustal. The contamination factor, geo-accumulation index, modified degree of contamination, pollution load index, and Nemerow pollution index indicated that the oil sands are heavily polluted by the elements. Health risk assessment showed that children were relatively more susceptible to the potentially toxic elements in the oil sands principally via ingestion exposure route(HQ > 1E-04). Cancer risks from inhalation are unlikely due to CR < 1E-06 but ingestion and dermal contact pose severe risks(CR > 1E-04). The high concentrations of the elements pose serious threats due to the potential for atmospheric transport, bioaccessibility, and bioavailability. 展开更多
关键词 Biophile Chalcophile Oil sand Risk assessment trace element
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Trace elements in magmatic and hydrothermal quartz:Implications on the genesis of the Xingluokeng Tungsten Deposit,South China
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作者 Qing-Qing Zhang You-Wei Chen Jian-Feng Gao 《Acta Geochimica》 EI CAS CSCD 2024年第3期441-458,共18页
The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,and... The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,andfine-grained granite.The deposit is represented by veinlet-disseminated mineralization with K-feldspathization and biotitization,alongside quartz-vein mineralization with gre-isenization and sericitization.This study investigates in-situ analyses of quartz compositions from both the intrusion and hydrothermal veinlets and veins.Trace element correlations indicate that trivalent Al^(3+)and Fe^(3+)replace Si^(4+)within the quartz lattice,with monovalent cations(such as Li^(+),Na^(+),and K^(+))primarily serving as charge compensators.Low Ge/Al ratios(<0.013)of quartz from granites suggest a mag-matic origin.The low Al/Ti and Ge/Ti ratios,accompanied by high Ti contents in quartz,suggest that the porphyritic biotite granite and biotite granite are characterized by rela-tively low levels of differentiation and high crystallization temperatures.In contrast,thefine-grained granite exhibits a higher degree of fractionation,lower crystallization tem-peratures,and a closer association with tungsten miner-alization.Ti contents in quartz from quartz veins indicate Qz-Ⅰformed at temperatures above 400°C,while Qz-Ⅱto Qz-Ⅴformed at temperatures below 350°C.Variations in different generations of quartz,as indicated by Al content and(Al+Fe)/(Li+Na+K)ratio,suggest that Qz-Ⅰprecipi-tated from a less acidicfluid with a stable pH,whereas Qz-Ⅱto Qz-Ⅴoriginated from a more acidicfluid with notable pH variations.Consequently,alkaline alteration and acidic alteration supplied the essential Ca and Fe for the precipita-tion of scheelite and wolframite,respectively,highlighting a critical mechanism in tungsten mineralization at the Xin-gluokeng deposit. 展开更多
关键词 QUARTZ Xingluokeng Tungsten deposit trace elements South China
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Mobility of Major and Trace Elements during the Bauxitization Processes in Ngaoundal Area (Adamawa Cameroon): Implication on Mining Perspectives
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作者 André Sini Harouna Boukari +4 位作者 Ondoa Augustin Désiré Balla Djetenbe Beral Salomon Wangmené Awé Simon Djakba Basga Jean Pierre Nguetnkam 《Open Journal of Geology》 CAS 2024年第1期81-100,共20页
This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical ... This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical analyses were carried out. Four facies of duricrust were identified and characterized from the summit to the top of the slope of the Ngaoundal mountain: scoriaceous, pisolitic, nodular and massive. Mineralogical and geochemical analyses performed on 16 samples, revealed a significant concentration of Al<sub>2</sub>O<sub>3</sub> mainly in the scoriaceous facies (over 45% in grade), moderate in Fe<sub>2</sub>O<sub>3</sub> (averaging 23.69%) and SiO<sub>2</sub> (averaging 21.7%). Trace elements were generally low, excluding Cr (421 ppm on average), Zr (327 ppm on average and V (213 ppm on average). In addition, the limited quantities of alkalis (Na<sub>2</sub>O, K<sub>2</sub>O) and alkaline earths metals (MgO, CaO) coupled with the very high values of Chemical Index of Alteration (CIA) and Mineralogical Index of Alteration (MIA), (more than 99%) attest to the intense weathering of the studied materials. Allitization and monosiallitization constituted the crystallochemical phenomena that have led to the development of bauxitic minerals. More than 90% of gibbsite in scoriaceous facies, 52.21% - 76.01% of kaolinite in pisolitic facies and more than 40% of hematite in nodular facies were quantified. The relationships between the constitutive components indicated their interdependency during the bauxitization phenomenon. The mineralogical and geochemical properties highlighted the mining interest of the studied duricrusts to be valorized. 展开更多
关键词 Duricrust Bauxitization Phenomenon Mineralogical and Geochemical Characterization Major and trace Elements Mining Potential
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Paleoenvironmental Characteristics of Paleogene Lacustrine Source Rocks in the Western Bozhong Sag,Bohai Bay Basin,China:Evidence from Biomarkers,Major and Trace Elements
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作者 WANG Xiang LIU Guangdi +6 位作者 SONG Zezhang SUN Mingliang WANG Xiaolin WANG Feilong CHEN Rongtao GENG Mingyang LI Yishu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期220-240,共21页
The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these i... The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings. 展开更多
关键词 petroleum geology source rocks depositional environments biomarkers major elements trace elements Bozhong Sag
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Trace element compositions of pyrite and stibnite:implications for the genesis of antimony mineralization in the Yangla Cu skarn deposit,Northwestern Yunnan,China
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作者 Ping Pan Xinfu Wang +2 位作者 Bo Li Guo Tang Zuopeng Xiang 《Acta Geochimica》 EI CAS CSCD 2024年第3期535-554,共20页
The Yangla Cu skarn deposit is located in the central part of the Jinshajiang Suture Zone,southwest China,with a total reserve of 150 Mt Cu@1.03%.The newly discovered antimony orebodies at the depth of Yangla are stri... The Yangla Cu skarn deposit is located in the central part of the Jinshajiang Suture Zone,southwest China,with a total reserve of 150 Mt Cu@1.03%.The newly discovered antimony orebodies at the depth of Yangla are strictly controlled by the stratum,structure,and lithology,which are lenticular and vein-like within the marble fracture zone,which can provide a window into multistage miner-alization and ore genesis at Yangla.Mineralization can be divided into three types,Cu–Pb–Zn(skarn)pyrite,galena,and sphalerite,Cu(porphyry)chalcopyrite and pyrite,and Sb(hydrothermal)stibnite and pyrite.The mineral assem-blages were stibnite+pyrite+calcite+quartz±minor scheelite in antimony ores.This study presents quantitative measurements of the trace element compositions of pyrite and stibnite from the Yangla antimony ores.Analysis of pyrite with electron probe microanalysis(EPMA)showed enrichment in Co,Ni,Sb,As,and Mo,and deficit in its S and Fe contents when compared to the stoichiometric con-centrations of S and Fe in pyrite.The Sb-related pyrite may belong to sedimentary-reworked genesis and may be modi-fied by hydrothermalfluids,thereby presenting a certain dif-ference(i.e.,crystal morphology,texture,and chemical com-position)compared to the skarn and porphyry Cu-related pyrite in the Yangla Cu skarn deposit.Analysis of stibnite with EPMA and inductively coupled plasma-mass spectrom-etry showed enrichment in As,Pb,Sn,Pb,Cu,and Zn,and presented much higher Sb contents and slightly lower S con-tents when compared to the stoichiometric concentrations of Sb and S in stibnite.Statistical analysis of the stibnite trace elements showed correlations for the elemental pairs Cu–Pb,As–Sb,and Sn–Pb,and the coupled substitution equations Sb^(3+)↔Cu^(+)+Pb^(2+),Sb^(3+)↔As^(3+),and Sn^(2+)↔Pb^(2+)may be the major factors governed the incorporating Cu,Pb,As and Sn within the stibnite.Moreover,this study preliminary shows that the antimony mineralization may belong to a car-bonate replacement hydrothermal genesis at Yangla. 展开更多
关键词 trace elements PYRITE STIBNITE Substitution mechanisms Antimony mineralization Yangla Cu skarn deposit
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Weathering and accumulation of trace elements in the soils of the Porali Plain, Balochistan: repercussions in agriculture
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作者 Maria Kaleem Erum Bashir +2 位作者 Shahid Naseem Tahir Rafique Bushra Shahab 《Acta Geochimica》 EI CAS CSCD 2024年第2期214-234,共21页
This study is thefirst attempt to assess the nature of the soil,especially on the western side of the Porali Plain in Balochistan;a new emerging agriculture hub,using weathering and pollution indices supplemented by mu... This study is thefirst attempt to assess the nature of the soil,especially on the western side of the Porali Plain in Balochistan;a new emerging agriculture hub,using weathering and pollution indices supplemented by multi-variate analysis based on geochemical data.The outcomes of this study are expected to help farmers in soil manage-ment and selecting suitable crops for the region.Twenty-five soil samples were collected,mainly from the arable land of the Porali Plain.After drying and coning-quarter-ing,soil samples were analyzed for major and trace ele-ments using the XRF technique;sieving and hydrometric methods were employed for granulometric analysis.Esti-mated data were analyzed using Excel,SPSS,and Surfer software to calculate various indices,correlation matrix,and spatial distribution.The granulometric analysis showed that 76%of the samples belonged to loam types of soil,12%to sand type,and 8%to silt type.Weathering indices:CIA,CIW,PIA,PWI,WIP,CIX,and ICV were calculated to infer the level of alteration.These indices reflect mod-erate to intense weathering;supported by K_(2)O/AI_(2)O_(3),Rb/K_(2)O,Rb/Ti,and Rb/Sr ratios.Assessment of the geo-ac-cumulation and Nemerow Pollution indices pinpoint rela-tively high concentrations of Pb,Ni,and Cr concentration in the soils.The correlation matrix and Principal Compo-nent Analysis show that the soil in this study area is mainly derived from the weathering of igneous rocks of Bela Ophiolite(Cretaceous age)and Jurassic sedimentary rocks of Mor Range having SEDEX/MVT type mineralization.Weathering may result in the undesirable accumulation of certain trace elements which adversely affects crops. 展开更多
关键词 Weathering indices Pollution indices ACCUMULATION Repercussions trace elements Multivariate analyses Porali Plain BALOCHISTAN
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Efficient concentration of trace analyte with ordered hotspot construction for a robust and sensitive SERS platform
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作者 Youdi Hu Yanlei Hu +4 位作者 Zhenyu Wang Jiale Yong Wei Xiong Dong Wu Shixiang Xu 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第3期532-542,共11页
Surface-enhanced Raman scattering(SERS)platform,which enables trace analyte detection,has important application prospects.By structuring/modifying the surface of the SERSsubstrate,analyte in highly diluted solutions c... Surface-enhanced Raman scattering(SERS)platform,which enables trace analyte detection,has important application prospects.By structuring/modifying the surface of the SERSsubstrate,analyte in highly diluted solutions can be concentrated into localized active areas for highly sensitive detection.However,subject to the difficulty of the fabrication process,itremains challenging to balance hot-spot construction and the concentration capacity of analyte simultaneously.Therefore,preparing SERS substrates with densely ordered hot spots andefficient concentration capacity is of great significance for highly sensitive detection.Herein,we propose an Ag and fluoroalkyl-modified hierarchical armour substrate(Ag/F-HA),which has a double-layer stacking design to combine analyte concentration with hotspot construction.The microarmour structure is fabricated by femtosecond-laser processing to serve as asuperhydrophobic and low-adhesive surface to concentrate analyte,while the anodic aluminium oxide(AAO)template creates a nanopillar array serving as dense and ordered hot spots.Under the synergistic action of hot spots and analyte concentration,Ag/F-HA achieves a detectionlimit down to 10^(-7)M doxorubicin(DOX)molecules with a RSD of 7.69%.Additionally,Ag/F-HA exhibits excellent robustness to resist external disturbances such as liquid splash or abrasion.Based on our strategy,SERS substrates with directional analyte concentrations are further explored by patterning microcone arrays with defects.This work opens a way to the realistic implementation of SERS in diverse scenarios. 展开更多
关键词 surface-enhanced Raman scattering anodic aluminium oxide femtosecond laser processing concentration of trace analytes mechanical robustness
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Evaluation of Trace Elements in the Soil of Typical Peach Orchards in Zunyi City
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作者 Wenzhao LI Xiong YAN +5 位作者 Jun CHENG Xingyong WANG Changling SUI Xiangchun ZHANG Zhuang ZHAO Peng ZHOU 《Agricultural Biotechnology》 2024年第1期17-19,共3页
[Objectives]This study was conducted to clarify the enrichment and paucity of trace elements in the soil environment of peach orchards in Zunyi City,and to provide reference for supplementary application of microeleme... [Objectives]This study was conducted to clarify the enrichment and paucity of trace elements in the soil environment of peach orchards in Zunyi City,and to provide reference for supplementary application of microelement fertilizers and high-quality peach production in peach orchards.[Methods]Taking the soil of three typical peach orchards(Taoli Renjia peach orchard,Pengrui peach orchard and Taohuadao peach orchard)in Shenxi Town,Honghuagang District,Zunyi City as the research object,the contents of trace elements in soil were analyzed through field sampling and indoor determination of trace elements.[Results]The effective contents of trace elements in the soil of peach orchard bases in the study area were at a medium level,and the soil of the peach orchards was rich in available Fe and Se.The contents of available Cu,Mo and Mn were relatively rich.The contents of available B were not high overall.The contents of available Zn were at a moderate to low level overall.The soil of Taoli Renjia peach orchard was relatively rich in trace elements.[Conclusions]The research results can provide a scientific basis for the production of high-quality crispy peaches in peach orchards. 展开更多
关键词 Zunyi Soil in peach orchard trace elements EVALUATION
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Health risk assessment of trace metal(loid)s in agricultural soils based on Monte Carlo simulation coupled with positive matrix factorization model in Chongqing, southwest China
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作者 MA Jie CHU Lijuan +3 位作者 SUN Jing WANG Shenglan GE Miao DENG Li 《Journal of Mountain Science》 SCIE CSCD 2024年第1期100-112,共13页
This study aimed to investigate the pollution characteristics, source apportionment, and health risks associated with trace metal(loid)s(TMs) in the major agricultural producing areas in Chongqing, China. We analyzed ... This study aimed to investigate the pollution characteristics, source apportionment, and health risks associated with trace metal(loid)s(TMs) in the major agricultural producing areas in Chongqing, China. We analyzed the source apportionment and assessed the health risk of TMs in agricultural soils by using positive matrix factorization(PMF) model and health risk assessment(HRA) model based on Monte Carlo simulation. Meanwhile, we combined PMF and HRA models to explore the health risks of TMs in agricultural soils by different pollution sources to determine the priority control factors. Results showed that the average contents of cadmium(Cd), arsenic (As), lead(Pb), chromium(Cr), copper(Cu), nickel(Ni), and zinc(Zn) in the soil were found to be 0.26, 5.93, 27.14, 61.32, 23.81, 32.45, and 78.65 mg/kg, respectively. Spatial analysis and source apportionment analysis revealed that urban and industrial sources, agricultural sources, and natural sources accounted for 33.0%, 27.7%, and 39.3% of TM accumulation in the soil, respectively. In the HRA model based on Monte Carlo simulation, noncarcinogenic risks were deemed negligible(hazard index <1), the carcinogenic risks were at acceptable level(10^(-6)<total carcinogenic risk ≤ 10^(-4)), with higher risks observed for children compared to adults. The relationship between TMs, their sources, and health risks indicated that urban and industrial sources were primarily associated with As, contributing to 75.1% of carcinogenic risks and 55.7% of non-carcinogenic risks, making them the primary control factors. Meanwhile, agricultural sources were primarily linked to Cd and Pb, contributing to 13.1% of carcinogenic risks and 21.8% of non-carcinogenic risks, designating them as secondary control factors. 展开更多
关键词 Monte Carlo simulation Health risk assessment trace metal(loid)s Positive matrix factorization Agricultural soils
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Tailoring MXene Thickness and Functionalization for Enhanced Room‑Temperature Trace NO_(2) Sensing
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作者 Muhammad Hilal Woochul Yang +1 位作者 Yongha Hwang Wanfeng Xie 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期71-86,共16页
In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method... In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method involving high-pressure processing,stirring,and immiscible solutions,sub-100 nm MXene flake thickness is achieved within the MXene film on the Si-wafer.Functionalization control is achieved by defunctionalizing MXene at 650℃ under vacuum and H2 gas in a CVD furnace,followed by refunctionalization with iodine and bromine vaporization from a bubbler attached to the CVD.Notably,the introduction of iodine,which has a larger atomic size,lower electronegativity,reduce shielding effect,and lower hydrophilicity(contact angle:99°),profoundly affecting MXene.It improves the surface area(36.2 cm^(2) g^(-1)),oxidation stability in aqueous/ambient environments(21 days/80 days),and film conductivity(749 S m^(-1)).Additionally,it significantly enhances the gas-sensing performance,including the sensitivity(0.1119Ωppm^(-1)),response(0.2% and 23%to 50 ppb and 200 ppm NO_(2)),and response/recovery times(90/100 s).The reduced shielding effect of the–I-terminals and the metallic characteristics of MXene enhance the selectivity of I-MXene toward NO2.This approach paves the way for the development of stable and high-performance gas-sensing two-dimensional materials with promising prospects for future studies. 展开更多
关键词 Controlled MXene thickness Gaseous functionalization approach Lower electronegativity functional groups Enhanced MXene stability trace NO_(2)sensing
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Low-complexity signal detection for massive MIMO systems via trace iterative method
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作者 IMRAN A.Khoso ZHANG Xiaofei +2 位作者 ABDUL Hayee Shaikh IHSAN A.Khoso ZAHEER Ahmed Dayo 《Journal of Systems Engineering and Electronics》 SCIE CSCD 2024年第3期549-557,共9页
Linear minimum mean square error(MMSE)detection has been shown to achieve near-optimal performance for massive multiple-input multiple-output(MIMO)systems but inevitably involves complicated matrix inversion,which ent... Linear minimum mean square error(MMSE)detection has been shown to achieve near-optimal performance for massive multiple-input multiple-output(MIMO)systems but inevitably involves complicated matrix inversion,which entails high complexity.To avoid the exact matrix inversion,a considerable number of implicit and explicit approximate matrix inversion based detection methods is proposed.By combining the advantages of both the explicit and the implicit matrix inversion,this paper introduces a new low-complexity signal detection algorithm.Firstly,the relationship between implicit and explicit techniques is analyzed.Then,an enhanced Newton iteration method is introduced to realize an approximate MMSE detection for massive MIMO uplink systems.The proposed improved Newton iteration significantly reduces the complexity of conventional Newton iteration.However,its complexity is still high for higher iterations.Thus,it is applied only for first two iterations.For subsequent iterations,we propose a novel trace iterative method(TIM)based low-complexity algorithm,which has significantly lower complexity than higher Newton iterations.Convergence guarantees of the proposed detector are also provided.Numerical simulations verify that the proposed detector exhibits significant performance enhancement over recently reported iterative detectors and achieves close-to-MMSE performance while retaining the low-complexity advantage for systems with hundreds of antennas. 展开更多
关键词 signal detection LOW-COMPLEXITY linear minimum mean square error(MMSE) massive multiple-input multiple-output(MIMO) trace iterative method(TIM)
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Predictive Study of Trace Metal Pollution of Gold Panning Sites in Birimian Formations: Case of the Yaouré Furrow (Côte d’Ivoire)
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作者 Tonga Paul Tiemoko Gbele Ouattara Kouassi Ernest Ahoussi 《Open Journal of Applied Sciences》 2024年第7期1691-1714,共24页
The present study was carried out on small-scale gold mining sites in the Yaouré region of Côte d’Ivoire. This region is geologically representative of the Birimian formations (2.1 Ga) of West Africa. The a... The present study was carried out on small-scale gold mining sites in the Yaouré region of Côte d’Ivoire. This region is geologically representative of the Birimian formations (2.1 Ga) of West Africa. The aim is to determine the potentially toxic trace metals (TMEs) generated by these sites, with a view to preventing possible contamination and/or metal pollution of the waters that provide fish products for local populations. To this end, a sampling campaign was carried out, resulting in the collection of 20 mining waste samples analyzed by X-ray fluorescence spectrometry (XRF) and 10 by X-ray diffractometer (XRD). The XRF analysis detected 06 predominant TMEs: arsenic, chromium, copper, nickel, zinc and vanadium. Statistical analysis was carried out to determine the distributions and correlations between these ETMs. To assess contamination and/or pollution levels, the following indices were calculated on the basis of reference concentrations of upper continental crust MTEs: Enrichment Factor, Geo-accumulation Index, Concentration Factor, Degree of contamination and those related to ecological risks. The results of statistical analyses and indices have shown that arsenic and chromium are the most predominant and can be, depending on the chemical form, potentially more toxic. The results of the DRX analysis show the occurrence of several minerals carrying these two MTEs, especially that of a rare mineral, Stenhuggarite, an arsenic oxide linked to hydrothermal veins. The majority of gold mining operations in West Africa are located in the birimian zone, hence the need for environmental monitoring by the relevant authorities, to prevent potential ecological risks to water and possibly health risks via the food chain. 展开更多
关键词 Small-Scale Mining Metallic trace Elements Mining Discharges CONTAMINATION POLLUTION CONTAMINATION POLLUTION Index
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RT-Trace:基于指令步进识别的工控设备执行流采集技术
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作者 刘厚志 麻荣宽 魏强 《信息工程大学学报》 2024年第1期110-119,共10页
由于薄弱的安全措施和重要的军事、经济价值,现代工业控制设备迅速成为了网络攻击的重要目标。工控设备因其在人们生产生活中的作用以及当前严峻的不安全现状,引起了研究人员的重点关注。其中,固件作为工控设备的核心部分,其安全的重要... 由于薄弱的安全措施和重要的军事、经济价值,现代工业控制设备迅速成为了网络攻击的重要目标。工控设备因其在人们生产生活中的作用以及当前严峻的不安全现状,引起了研究人员的重点关注。其中,固件作为工控设备的核心部分,其安全的重要性不言而喻。然而由于固件在烧录的过程中其烧录方法和固件安全性保护的标准、等级和措施均不相同,使得固件在提取过程中依赖专家经验。同时由于大部分工控设备为了能够应对极端环境通常使用定制化专有芯片,少有配备如嵌入式跟踪宏单元(Embedded Trace Macro cell,ETM)等执行跟踪组件,因此难以采集设备执行时的信息。提出一种基于指令步进识别的工控设备执行流采集技术RT-Trace,通过对工控设备进行硬件分析、固件提取和监控采集,将工控设备的固件整体安全情况进行分析和梳理。实验结果表明,该方法能够提取出大部分的工控设备固件并且能够对设备执行过程中的函数调用次数、服务开启情况、内存污染度进行较为全面的数据采集。 展开更多
关键词 工控设备 跟踪 固件提取 执行流跟踪
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Probability Distribution of China Aviation Network Average Degree of Edge Vertices and Its Evolutionary Trace Based on Complex Network
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作者 Cheng Xiangjun Zhang Chunyue Liang Yanping 《Journal of Traffic and Transportation Engineering》 2024年第2期51-62,共12页
In order to reveal the complex network characteristics and evolution principle of China aviation network, the probability distribution and evolution trace of average degree of edge vertices of China aviation network w... In order to reveal the complex network characteristics and evolution principle of China aviation network, the probability distribution and evolution trace of average degree of edge vertices of China aviation network were studied based on the statistics data of China civil aviation network in 1988, 1994, 2001, 2008 and 2015. According to the theory and method of complex network, the network system was constructed with the city where the airport was located as the network node and the route between cities as the edge of the network. Based on the statistical data, the average degrees of edge vertices in China aviation network in 1988, 1994, 2001, 2008 and 2015 were calculated. Using the probability statistical analysis method and regression analysis approach, it was found that the average degree of edge vertices had the probability distribution of normal function and the position parameters and scale parameters of the probability distribution had linear evolution trace. 展开更多
关键词 Complex network China aviation network average degree of edge vertices normal distribution linear evolution trace
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Nonlinear Relationship and Its Evolutionary Trace between Node Degree and Average Path Length of China Aviation Network Based on Complex Network
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作者 Cheng Xiangjun Zhang Xiaoxuan Li Yangqi 《Journal of Traffic and Transportation Engineering》 2024年第1期11-22,共12页
In order to reveal the complex network characteristics and evolution principle of China aviation network,the relationship between the node degree and the average path length of China aviation network in 1988,1994,2001... In order to reveal the complex network characteristics and evolution principle of China aviation network,the relationship between the node degree and the average path length of China aviation network in 1988,1994,2001,2008 and 2015 was studied.According to the theory and method of complex network,the network system was constructed with the city where the airport was located as the network node and the airline as the edge of the network.On the basis of the statistical data,the node average path length of China aviation network in 1988,1994,2001,2008 and 2015 was calculated.Through regression analysis,it was found that the node degree had a logarithmic relationship with the average length of node path,and the two parameters of the logarithmic relationship had linear evolutionary trace.Key word:China aviation network,complex network,node degree,average length of node path,logarithmic relationship,evolutionary trace. 展开更多
关键词 China aviation network complex network node degree average length of node path logarithmic relationship evolutionary trace.
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Probability Distribution of Ratio of China Aviation Network Edge Vertices Degree and Its Evolutionary Trace Based on Complex Network
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作者 Cheng Xiangjun Yang Fang Wei Liying 《Journal of Traffic and Transportation Engineering》 2024年第3期119-129,共11页
In order to reveal the complex network characteristics and evolution principle of China aviation network, the probability distribution and evolution trace of ratio of China aviation network edge vertices degree were s... In order to reveal the complex network characteristics and evolution principle of China aviation network, the probability distribution and evolution trace of ratio of China aviation network edge vertices degree were studied based on the statistics data of China civil aviation network in 1988, 1994, 2001, 2008 and 2015. According to the theory and method of complex network, the network system was constructed with the city where the airport was located as the network node and the route between cities as the edge of the network. Based on the statistical data, the ratio of edge vertices degree in China aviation network in 1988, 1994, 2001, 2008 and 2015 were calculated. Using the probability statistical analysis method and regression analysis approach, it was found that the ratio of edge vertices degree had linear probability distribution and the two parameters of the probability distribution had linear evolution trace. 展开更多
关键词 Complex network China aviation network ratio of edge vertices degree linear probability distribution linear evolution trace.
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Probability Distribution of Arithmetic Average of China Aviation Network Edge Vertices Nearest Neighbor Average Degree Value and Its Evolutionary Trace Based on Complex Network
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作者 Cheng Xiangjun Yang Fang Xiong Zhihua 《Journal of Traffic and Transportation Engineering》 2024年第4期163-174,共12页
In order to reveal the complex network characteristics and evolution principle of China aviation network,the probability distribution and evolution trace of arithmetic average of edge vertices nearest neighbor average... In order to reveal the complex network characteristics and evolution principle of China aviation network,the probability distribution and evolution trace of arithmetic average of edge vertices nearest neighbor average degree values of China aviation network were studied based on the statistics data of China civil aviation network in 1988,1994,2001,2008 and 2015.According to the theory and method of complex network,the network system was constructed with the city where the airport was located as the network node and the route between cities as the edge of the network.Based on the statistical data,the arithmetic averages of edge vertices nearest neighbor average degree values of China aviation network in 1988,1994,2001,2008 and 2015 were calculated.Using the probability statistical analysis method,it was found that the arithmetic average of edge vertices nearest neighbor average degree values had the probability distribution of normal function and the position parameters and scale parameters of the probability distribution had linear evolution trace. 展开更多
关键词 Complex network China aviation network arithmetic average of edge vertices nearest neighbor average degree value linear evolution trace
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基于西门子Trace Service数控机床五轴联动精度评估模块二次开发 被引量:1
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作者 费亚 李颖 +2 位作者 陶文坚 蒋云峰 周昕 《制造技术与机床》 北大核心 2023年第6期105-111,共7页
以西门子840D sl SINUMERIK Operate为系统应用框架,基于Trace Service数据采集功能,开发了一种以空走S试件轨迹为对象的数控机床五轴联动精度评估模块。针对Trace Service数据采集机制进行核心原理分析,通过S试件轨迹运行过程的数据需... 以西门子840D sl SINUMERIK Operate为系统应用框架,基于Trace Service数据采集功能,开发了一种以空走S试件轨迹为对象的数控机床五轴联动精度评估模块。针对Trace Service数据采集机制进行核心原理分析,通过S试件轨迹运行过程的数据需求,梳理数据采集流程并设计坐标轴数据采集子模块,再将数据采集结果进行分析提取进行坐标轴向刀尖点的转换,结合图形数字化手段完成轮廓误差图形与指标展示,综合实现数控机床五轴联动精度的评估。该模块利用S试件优秀的联动精度评估性能,集成高效数据采集与轮廓评估展示,避免了传统模式下采集和评估过程的繁琐性,有效提升了评估过程的经济性与效率。 展开更多
关键词 trace Service S试件 联动精度评估 二次开发
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