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Rare Earth Elements Geochemistry of Laowan Gold Deposit in Henan Province: Trace to Source of Ore-Forming Materials 被引量:12
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作者 谢巧勤 徐晓春 +2 位作者 李晓萱 陈天虎 陆三明 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第1期115-120,共6页
The compositions of REE in quartz and pyrite from the main stage of the Laowan gold deposit in Henan Province and that in quartz from Laowan granite were determined by inductively coupled plasma-mass-spectrometry (IC... The compositions of REE in quartz and pyrite from the main stage of the Laowan gold deposit in Henan Province and that in quartz from Laowan granite were determined by inductively coupled plasma-mass-spectrometry (ICP-MS) to trace the source of ore-forming materials. Meanwhile, the REE compositions of the deposit ore, granite and metamorphic wall rock were also considered for comparative studies in detail. The range of ∑REE of quartz and pyrite from the deposit ores is 4.18 × 10^-6- 30.91 × 10^-6, the average of ∑REE is 13.39 × 10^-6, and the average of ∑REE of quartz in the Laowan granite is 6.68 × 10^-6. There is no distinct difference of REE parameters between the deposit ore quartz and granite quartz. The quartz in gold deposit has the same REE particular parameters as quartzes from Laowan granite, such as δEu, δCe, (La/Yb)N and (La/Sm)N, partition degree of LREE to HREE, especially, the chondrite-normalized REE patterns, but no similarity to those from metamorphic wall rock, which shows that ore-forming hydrothermal fluid is mainly the fluid coming from the Laowan granite magma, rather than metamorphic fluid. Meanwhile, comparison studies on REE features between minerals from the deposit ores and related geological bodies in the deposit show that REE characteristics of minerals can serve as an indicator of ore-forming fluid properties and sources, while the REE characteristics of the bulk samples (such as deposit ores, granites and wall rocks) can not trace the source of the ore-forming materials exactly. 展开更多
关键词 Laowan gold deposit REE geochemistry source of the ore-forming material ore-forming fluid rare earths
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Rare Earth Element Geochemistry Characteristics of Laowan Gold Deposit in Henan Province: Trace to Source of Ore-Forming Materials
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作者 Xie Qiaoqin Xu Xiaochun +2 位作者 Li Xiaoxuan Chen Tianhu Lu Sanming 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第5期646-646,共1页
The compositions of REE in quartz and pyrite from main mineralized stage of the Laowan gold deposit in Henan province and that of quartz from Laowan granite were determined by Inductively Coupled Plasma-Mass-Spectrome... The compositions of REE in quartz and pyrite from main mineralized stage of the Laowan gold deposit in Henan province and that of quartz from Laowan granite were determined by Inductively Coupled Plasma-Mass-Spectrometry (ICP-MS). The REE of deposit ore of the Laowan gold deposit, wall-rock and Laowan granite also were studied to trace the source of metallogenic materials in Laowan gold deposit in detail. The range of ∑ REE in quartz and pyrite from gold deposit is 4.18 × 10^-6 - 30.91 × 10^-6, average of 13.39 × 10^-6, 6.68 × 10^-6 of the Laowan granite quartz, obviously lower to REE concentration of deposit, granite and wall-rock. The value of (La/ Yb)N and (La/Sm)N of ore minerals from the gold deposit is 13.23 and 4.17 respectively. The differences in REE parameters, such as δEu, δCe and diffusion degree in REE from light to heavy, among deposit ore minerals and granite mineral are weak. Especially, there are no differences between the chondrite-normalised REE curves of minerals from gold deposit and those of quartzs in Laowan granite, no similarity to wall-rock', which shows that ore-forming hydrothermal fluid mainly came from magma fluid resulting from the Laowan granite magma, metamorphic fluid in few. The results also show that REE characteristics of ore minerals in deposit are effective for disclosing oreforming fluid quality comparing with deposit ore'REE compositions. 展开更多
关键词 laowan gold deposit REE geochemisity source of ore-forming material ore-forming fluid
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Isotopic tracing of ore-forming source materials for Dexing porphyry copper deposit of Jiangxi, China
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作者 Peng QIAN Jianjun LU 《Global Geology》 2008年第1期25-31,共7页
Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite wer... Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite were close to the δ13CPDB value of original magma; δ30Si values of the samples at the ore-forming stage were close to the δ30Si value range of magma, δ30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials. 展开更多
关键词 Dexing copper deposit source material isotope tracing
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Metallogenic Age and Ore-forming Material Sources of the Dahongshan Fe-Cu Deposit,Yunnan Province:Insights from Molybdenite Re-Os Dating and H-O-S-Pb Isotopes
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作者 YE Zifeng YANG Guangshu +2 位作者 YU Wenxiu CHEN Aibing JIA Fuju 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第6期1698-1718,共21页
The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization ... The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism. 展开更多
关键词 stable isotopes Re-Os dating ore-forming material Dahongshan Fe-Cu deposit Kangdian region
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Geochemical Tracing of Ore-forming Material Sources of Carlin-type Gold Deposits in the Yunnan-Guizhou-Guangxi Triangle Area --A Case Study of the Application of the Combined Silicon Isotopes Geochemistry and Siliceous Cathodoluminescence Analysis 被引量:1
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作者 LIU Xianfan NI Shijun +2 位作者 LU Qiuxia JIN Jingfu ZHU Laimin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第1期30-39,共10页
Abstract This paper deals with characteristics of silicon isotope compositions and siliceous cathodoluminescence of host rocks, ores and hydrothermal silicified quartz of the Carlin-type ore deposits in the Yunnan-Gui... Abstract This paper deals with characteristics of silicon isotope compositions and siliceous cathodoluminescence of host rocks, ores and hydrothermal silicified quartz of the Carlin-type ore deposits in the Yunnan-Guizhou-Guangxi triangle area. The study shows that primary silicified quartz is nonluminescent but quartz in host rocks and secondary silicified quartz are luminescent by the action of cathode rays. Correspondingly, silicon isotope compositions of host rocks, ores and hydro6thermal quartz veins are clearly distinguished. In strata from the Middle Triassic to the “Dachang” host bed, δ30Si of the host rocks ranges from 0.0% ?0.3%, while that of primary ore-forming silicified fluids from ?0.1% to ?0.4%; in the Upper Permian and Lower Carboniferous strata and Indosinian diabase host beds, δ30Si of the host rocks is from ?0.1% to ?0.2% and that of the primary silicified quartz veins from 0.3 % ?0.5 %. This pattern demonstrates the following geochemical mineralization process, primary ore-forming siliceous fluids migrated upwards quickly along the main passages of deep-seated faults from mantle to crust and entered secondary faults where gold deposits were eventually formed as a result of permeation and replacement of the siliceous ore-forming fluids into different ore-bearing strata. This gives important evidence for the fact that ore-forming fluids of this type of gold deposits were mainly derived from upper mantle differentiation and shows good prospects for deep gold deposits and geochemical background for large and superlarge gold deposits. 展开更多
关键词 silicon isotope siliceous cathodoluminescence tracing of ore-forming material source Carlin-type gold deposit Yunnan-Guizhou-Guangxi triangle area
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Rb-Sr Dating of Pyrite and Quartz Fluid Inclusions and Origin of Ore-forming Materials of the Jinshan Gold Deposit, Northeast Jiangxi Province, South China 被引量:2
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作者 MAO Guangzhou HUA Renmin +1 位作者 LONG Guangming LU Huijuan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第6期1658-1667,共10页
The Jinshan gold deposit is located in the Northeast Jiangxi province,South China,which related to the ductile shear zone.It contains two ore types,i.e.the alteration-type ore and the goldbearing quartz vein ore.Rb-Sr... The Jinshan gold deposit is located in the Northeast Jiangxi province,South China,which related to the ductile shear zone.It contains two ore types,i.e.the alteration-type ore and the goldbearing quartz vein ore.Rb-Sr age dating is applied to both gold-bearing pyrite in the alteration-type ore and fluid inclusion in the gold-bearing quartz vein to make clear the time of the gold mineralization of the Jinshan deposit.Analytical results of this study yielded that the age of the alteration-type ore bodies is about 838±110Ma,with an initial 87Sr/86Sr value of 0.7045±0.0020.However,the age of the gold-bearing quartz vein-type ore is about 379±49Ma,and the initial 87Sr/86Sr is 0.7138±0.0011.Based on the age data from this work and many previous studies,the authors consider that the Jinshan gold deposit is a product of multi-staged mineralization,which may include the Jinninian,Caledonian,Hercynian,and Yanshanian Periods.Among them,the Jinninian Period and the Hercynian Period might be the two most important ore-forming periods for Jinshan deposit.The Jinninian Period is the main stage for the formation of alteration-type ore bodies,while the Hercynian Period is the major time for ore bodies of gold-bearing quartz vein type.The initial values of the 87Sr/86Sr from this study,as well as the previous isotope and trace element studies,indicate that the ore-forming materials mainly derived from the metamorphic wall rocks,and the ore-forming fluids mainly originated from the deep metamorphic water. 展开更多
关键词 Gold deposit mineralization time quartz fluid inclusion PYRITE Rb-Sr dating Origin of the ore-forming materials Jinshan Jiangxi province
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Discussion on the Source of Ore-forming Materials of the Yinan Gold Deposit,Shandong 被引量:1
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作者 S.Y.Dong~(1,2),X.X.Gu~1,K.Li~3,Y.M.Zhang~1,L.Liu~1,W.B.Cheng~1 1.School of Earth Sciences and Resources,China University of Geosciences(Beijing),Beijing 100083,China. 2.School of Earth Sciences,Chengdu University of Technology,Chengdu 610059,China 3.Sichuan Institute of Metallurgical Geology and Exploration,Chengdu 610051,China 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期217-217,共1页
Based on the main characteristics of the tectonic -magmatic evolution of region and Tanlu fault zone,we have discussed ore-bearing magmatic rocks petrochemistry,strontium and lead isotope,and the source of ore-forming... Based on the main characteristics of the tectonic -magmatic evolution of region and Tanlu fault zone,we have discussed ore-bearing magmatic rocks petrochemistry,strontium and lead isotope,and the source of ore-forming materials in Yinan skarn deposit in this paper.The petrochemical features show that the ore-bearing magmatic rocks are calc-alkaline rocks of sub-alkaline series formed during 展开更多
关键词 PETROCHEMISTRY strontium ISOTOPE lead ISOTOPE source of ore-forming materials Yinan gold deposit granite-greenstone belt Tanlu fault zone tectonic-magmatic evolution
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Ore-forming fluid characteristics and ore-forming materials source of the Tudimiaogou – Yindongshan lead-zinc polymetallic orefield, west Henan
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作者 TAN Huajie SHAO Yongjun +4 位作者 ZHENG Minghong ZHOU Houdi ZHANG Jiandong PENG Guangxiong Cheng Luping 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期227-228,共2页
1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan... 1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc 展开更多
关键词 In Pb rock west Henan ore-forming fluid characteristics and ore-forming materials source of the Tudimiaogou Yindongshan lead-zinc polymetallic orefield
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Geological characteristics and the origin of ore-forming materials of(Laozhaiwan gold deposit, Yunnan Province
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作者 ZHAO DeKun CHEN CuiHua +3 位作者 ZHANG Yan GU XueXiang TU ZongLin DAI HongZhang 《矿床地质》 CAS CSCD 北大核心 2014年第S1期853-854,共2页
"Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Pro... "Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Province had reached through several decades studies,but geological environment was very complex in the southeastern Yunnan,and Carlin-type gold deposits produced in the southeastern Yunnan were different from that of America,few studies were taken there.Based on a large number of field work,studies on the geological characteristics combining with geochemistry characteristics were taken,and analysis the genesis of Laozhaiwan gold deposit.The types of alteration in Laozhaiwan gold deposit were mainly silicification and pyritization,and Gold grade was high when silicification and pyritization were both occurred.It could be caculated that fluid density(g/cm3)varied from 0.7 to 4.9,salinity varied from 0.76%to 0.95%and ore-forming pressure(Pa)varied from 1.81×105 to 49.96×105 according to fluid inclusion test results,showed that Laozhaiwan gold deposit was hypabyssal hydrothermal deposit in low temperature and low salinity.According to composition of fluid inclusion analysis,combining with H-O isotope,made theδD-δ18O figure,showed that the fluid of the deposit rooted in formation water and mixed with meteoric waters later. 展开更多
关键词 Geological characteristics and the origin of ore-forming materials of Laozhaiwan gold deposit Yunnan Province
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Ore-Forming Material Sources of the Shizishan Pb-Zn Deposit in Western Hunan Province,China
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作者 WANG Yunfeng YANG Hongmei +2 位作者 QIU Xiaofei LU Shansong CAI Yingxiong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第5期1929-1930,共2页
Objective The Shizishan Pb-Zn deposit is located in the southeastern margin of the Yangtze Block,and its Pb-Zn orebodies are mainly hosted in the Lower Cambrian Qingxudong Formation limestone.Previous researches have ... Objective The Shizishan Pb-Zn deposit is located in the southeastern margin of the Yangtze Block,and its Pb-Zn orebodies are mainly hosted in the Lower Cambrian Qingxudong Formation limestone.Previous researches have investigated the geological characteristics,geochemistry and fluid inclusions of this deposit. 展开更多
关键词 PB ore-forming material Sources of the Shizishan Pb-Zn Deposit in Western Hunan Province China ZN
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Mykert-Sanzheevka Field of Polycomponent Ores (Pb, Zn, Ag, Au, PGE): Geologic-Substance Characteristics and Formation Features of Ore-Forming System 被引量:2
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作者 Alexander Vasilyevich Tatarinov Lyubov Ilyinichna Yalovik +1 位作者 Anatoly Georgievich Mironov Victor Fedorovich Posokhov 《Geomaterials》 2020年第1期1-23,共23页
The new results of geologic-structural, petrographic and mineralogic-geochemical researches of Mykert-Sanzheevka ore field—the Uda-Vitim mineragenic zone South-West ending of West Transbaikalia are given. Its main or... The new results of geologic-structural, petrographic and mineralogic-geochemical researches of Mykert-Sanzheevka ore field—the Uda-Vitim mineragenic zone South-West ending of West Transbaikalia are given. Its main ore-controlling structure, represented by losange, consisting of rhombohedral and tetrahedral blocks-duplexes mosaic clusters, which are separated by narrow tectonic sutures, is specified. It is clarified that polycomponent ores clusters are confined with these small-block sutures, made by subvolcanic dykes of shoshonite-latite volcano-plutonic association (233 - 188 million years), apodyke dynamometamorphites (breccias, cataclasite, mylonites) and also mechanometasomatites. Four stages of the dynamometamorphites formation characterized by different species compositions of ore minerals appeared as a result of mechanochemical reactions are determined. A carbonyl model of mineral microaggregates formation with films containing noble metal nanoparticles is proposed. Ore-forming system features of Mykert-Sanzheevka field are considered. 展开更多
关键词 Polycomponent ORES Dynamometamorphism Mechanometasomatites Noble Metals MICROAGGREGATES NANOPHASES Trace Minerals ore-forming SYSTEM CARBONYL Compounds Geochemical Microanomalies
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Characteristics of Ore-forming Fluid of the Gaoshan Gold-Silver Deposit in the Longquan Area, Zhejiang Province and its Implications for the Ore Genesis
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作者 JIANG Biao WANG Chenghui +4 位作者 CHEN Yuchuan WU Baogui LIAO Peng CHEN Zhengle HAN Fengbin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第4期1321-1340,共20页
The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted ... The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and Jiangshan- Shaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted an investigation for ore-forming fluids using microthermometry, D-O isotope and trace element. The results show that two types of fluid inclusions involved into the formation of the deposit are pure liquid phase and gas-liquid phase aqueous inclusions. The homogenization temperature and salinity of major mineralization phase ranges from 156~C to 236~C (average 200~C) and 0.35% to 8.68% (NaCleqv) (average 3.68%), respectively, indicating that the ore-forming fluid is characteristic of low temperature and low salinity. The ore- forming pressure ranges between in 118.02 to 232.13"105 pa, and it is estabmiated that the ore- forming depth ranges from 0.39 to 0.77 km, indicating it is a hypabyssal deposit in genesis. The low rare earth elements content in pyrites, widely developed fluorite in late ore-forming stage and lack of chlorargyrite (AgCI), indicates that the ore-forming fluid is rich in F rather than CI. The ratios of Y/ Ho, Zr/Hf and Nb/Ta of between different samples have little difference, indicating that the later hydrothermal activities had no effects on the former hydrothermal fluid. The chondrite-normalized REE patterns of pyrites from country rocks and ore veins are basically identical, with the characteristics of light REE enrichment and negative Eu anomalies, implying that the ore-forming fluid was oxidative and derived partly from the country rocks. The JD and jlSo of fluid inclusions in quartz formed during the main metallogenic stage range from -105%o to -69 %0 and -6.01%o to -3.81%o, respectively. The D-O isotopic diagram shows that the metallogenic fluid is characterized by the mixing of formation water and meteoric water, without involvement of magmatic water. The geological and geochemical characteristics of the Gaoshan gold-silver deposit are similar to those of continental volcanic hydrothermal deposit, and could be assigned to the continental volcanic hydrothermal gold-silver deposit type. 展开更多
关键词 ore-forming fluid trace elements D-O isotope ore genesis Gaoshan glod-silver deposit
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Origin of the Dashuigou Independent Tellurium Deposit at the Southeastern Qinghai-Tibet Plateau:Based on the Abundances of Trace Elements in the Country Rocks
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作者 Jianzhao Yin Shoupu Xiang +2 位作者 Haoyu Yin Hongyun Shi Yuhong Chao 《Advances in Geological and Geotechnical Engineering Research》 2023年第4期41-55,共15页
Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,a... Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,and in combination with other research findings of previous researchers in this area,the authors conclude as follows:Abundances of the main ore-forming elements Te,Bi,As,Se,Au,and Ag are not high in the regional geological background,generally lower or close to their respective crustal Clark values,but almost all altered country rocks contain high levels of ore-forming elements.This indicates that the deposit’s ore-forming elements do not come from the country rocks.This also indicates that the geological thermal events that cause alteration and mineralization originate from depths and may be related to mantle plumes.Considering the distribution pattern of these ore-forming elements in the ore bodies’hanging wall and footwall,the metallogenic mechanism may be as follows:Mineralization is not achieved through lateral secretion in the horizontal or near horizontal direction,but rather through the upward movement and emplacement of deep ore-forming elements driven by geological processes such as mantle plumes.In addition,the migration of deep ore-forming elements is not achieved through dispersed infiltration between overlying rock particles,but through non widespread concentrated penetrating channels.This type of channel is likely to be the expansion structures where faults from different directions intersect,or where linear faults intersect with circular structures. 展开更多
关键词 Origin of ore-forming elements The Dashuigou independent tellurium deposit Trace element abundance The country rocks The mantle plume
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邢窑六世纪晚期制瓷原料的同位素和微量元素分析
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作者 鲁晓珂 宗若菲 +1 位作者 李伟东 徐嫦松 《文物保护与考古科学》 北大核心 2024年第1期11-20,共10页
白瓷的出现是我国陶瓷历史上较为重要的技术突破,白瓷的烧制成功为后世青花瓷、彩绘瓷的繁荣奠定了重要基础,被誉为中国古陶瓷工艺发展史中的“第四里程碑”。因此,关于白瓷起源的问题就成为考古界和科技考古界关注的重要学术问题,而邢... 白瓷的出现是我国陶瓷历史上较为重要的技术突破,白瓷的烧制成功为后世青花瓷、彩绘瓷的繁荣奠定了重要基础,被誉为中国古陶瓷工艺发展史中的“第四里程碑”。因此,关于白瓷起源的问题就成为考古界和科技考古界关注的重要学术问题,而邢窑2012年考古发掘出土的北朝晚期窑炉和器物遗存自然成为研究白瓷起源的重要实物资料。本研究利用电感耦合等离子体质谱(ICP-MS)和热电离质谱(TIMS)分析技术,对河北内丘城关服务楼窑址出土的北朝晚期至隋朝初期的早期瓷器样品胎釉原料进行分析,为邢窑早期瓷业的发展演变提供科学依据。结果表明邢窑早期瓷胎的微量元素统计模式明显可以分为两类,说明邢窑早期制瓷存在两种不同的胎料来源。邢窑陶工在开发早期白瓷这一新品种的过程中有意识地选择了一种有别于青瓷的更为优质的原料制胎,这种胎料中与锆石、锐钛矿等杂质赋存密切相关的V、Cr、Ni、Nb、Ta、Zr和Hf等微量元素含量普遍小于青瓷胎。锶(Sr)同位素混合模式分析表明,邢窑早期的大部分样品不符合草木灰配以胎料的制釉方式,应该是采用了草木灰混合其他制釉黏土。同时,早期白瓷釉与青瓷釉的锶同位素特征存在一定差异,说明在制作过程中邢窑陶工为了提高釉面白度对制釉工艺也进行了变革,体现了为创烧早期白瓷而做出的努力。这些结果为科学认知邢窑六世纪晚期制瓷原料的特点和来源提供依据,同时也为破解白瓷起源提供新的科技支撑。 展开更多
关键词 邢窑 制瓷原料 锶同位素比值 微量元素
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电子级磷酸的纯化精制技术发展现状与研究进展 被引量:2
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作者 余留洋 刘书博 +7 位作者 贾晟哲 马航 万邦隆 苏琦雯 王静康 汤伟伟 贺豫娟 龚俊波 《化工学报》 EI CSCD 北大核心 2024年第1期1-19,共19页
电子级磷酸作为一种超高纯化学试剂,主要用于微电子行业中芯片的清洗与蚀刻,其纯度会显著影响电子元器件的成品率、电性能以及可靠性。然而,极低杂质(10^(-9)水平)的高端电子级磷酸,对于化工分离纯化技术的要求极高。从电子级磷酸在芯... 电子级磷酸作为一种超高纯化学试剂,主要用于微电子行业中芯片的清洗与蚀刻,其纯度会显著影响电子元器件的成品率、电性能以及可靠性。然而,极低杂质(10^(-9)水平)的高端电子级磷酸,对于化工分离纯化技术的要求极高。从电子级磷酸在芯片清洗与蚀刻方面的应用出发,梳理了电子级磷酸产品的主要国内外标准,概述了杂质离子的主要分析监测方法。重点综述了电子磷酸的制备和纯化精制方法,特别是结晶法在磷酸深度净化方面的显著优势,最后,对电子级磷酸的净化技术发展做出了前景展望。 展开更多
关键词 电子级磷酸 电子材料 纯化 结晶 技术集成 痕量杂质
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几种钝化材料对铅冶炼场地土壤重金属的钝化修复效果
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作者 张欣惠 周青云 +6 位作者 许超 武美燕 帅红 张泉 朱奇宏 朱捍华 黄道友 《中国农学通报》 2024年第21期99-105,共7页
通过土壤培养试验,评估了水泥、锰磷改性生物炭和锰磷改性谷壳灰在0%、1%、2%、4%4个施用量下对铅冶炼场地土壤pH以及Cd、Pb和微量元素(Zn、Fe和Mn)有效态含量的影响。研究结果显示:随着水泥施用量的提高,铅冶炼场地土壤pH显著提高,Cd... 通过土壤培养试验,评估了水泥、锰磷改性生物炭和锰磷改性谷壳灰在0%、1%、2%、4%4个施用量下对铅冶炼场地土壤pH以及Cd、Pb和微量元素(Zn、Fe和Mn)有效态含量的影响。研究结果显示:随着水泥施用量的提高,铅冶炼场地土壤pH显著提高,Cd和Pb有效性逐渐降低,水泥处理济源某冶炼场地和株洲某冶炼场地土壤pH分别提高0.89~1.84和0.89~1.76个单位,DTPA-Cd含量分别降低34.3%~53.1%(P<0.05)和59.6%~73.2%(P<0.05),DTPA-Pb含量分别降低21.6%~44.7%(P<0.05)和38.4%~44.3%(P<0.05)。随着锰磷改性生物炭和锰磷改性谷壳灰施用量的提高,铅冶炼场地土壤pH与Cd和Pb有效性均逐渐降低。4%锰磷改性生物炭处理两铅冶炼场地土壤pH分别降低0.51(济源)和0.40(株洲)个单位,DTPA-Cd含量显著降低18.0%(济源)和39.8%(株洲),DTPA-Pb含量显著降低37.8%(济源)和63.1%(株洲)。4%锰磷改性谷壳灰处理两铅冶炼场地土壤pH分别降低0.70(济源)和0.23(株洲)个单位,DTPA-Cd含量显著降低14.9%(济源)和30.2%(株洲),DTPA-Pb含量显著降低37.3%(济源)和54.1%(株洲)。4%水泥处理两铅冶炼场地土壤DTPA-Zn含量分别显著降低36.5%(济源)和59.4%(株洲),DTPA-Fe含量分别显著提高122.7%(济源)和142.9%(株洲),DTPA-Mn含量分别显著降低13.8%(济源)和69.1%(株洲)。4%锰磷改性生物炭处理土壤DTPA-Zn含量显著提高48.7%(济源),DTPA-Mn含量分别显著提高409.7%(济源)和538.6%(株洲),DTPA-Fe含量分别显著降低33.4%(济源)和30.7%(株洲)。4%锰磷改性谷壳灰处理土壤DTPA-Zn含量显著提高63.0%(济源),DTPA-Mn含量分别显著提高290.3%(济源)和73.5%(株洲),DTPA-Fe含量分别显著降低9.5%(济源)和12.0%(株洲)。3种钝化材料降低两铅冶炼场地Cd有效性顺序均为水泥>锰磷改性生物炭>锰磷改性谷壳灰,降低Pb有效性顺序分别为水泥>锰磷改性生物炭>锰磷改性谷壳灰(济源)和锰磷改性生物炭>锰磷改性谷壳灰>水泥(株洲)。研究建议根据铅冶炼场地的具体Cd和Pb污染特征选择合适的钝化材料,以实现对土壤Cd和Pb的有效同步钝化。 展开更多
关键词 钝化材料 CD PB 微量元素 有效性
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原油中痕量化合物的研究进展
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作者 韩云浩 朱光有 +1 位作者 张志遥 姜振学 《吉林大学学报(地球科学版)》 CAS CSCD 北大核心 2024年第3期735-751,共17页
痕量化合物是油气成因、来源、形成环境、次生地球化学改造等研究的重要指示物,随着当前油气研究不断地向非常规储层以及深层储层进发,此类化合物在油气地球化学研究中显得愈发重要。本文综述了近年来原油中痕量化合物的定义、分类,及... 痕量化合物是油气成因、来源、形成环境、次生地球化学改造等研究的重要指示物,随着当前油气研究不断地向非常规储层以及深层储层进发,此类化合物在油气地球化学研究中显得愈发重要。本文综述了近年来原油中痕量化合物的定义、分类,及其在母质来源与形成环境分析、高演化阶段油气成熟度与油源对比、油气运移路径示踪、油气次生地球化学改造等方面的研究进展,总结了基于痕量化合物所建立的原油热裂解、硫酸盐热化学还原反应、气侵改造作用等评价参数的应用现状;同时,指出痕量化合物的形成机理以及寻找具有指示物源意义的痕量分子化合物、加强单体同位素分析是未来的研究重点,并且随着测试技术与研究认识的不断提升或将发现新的过渡型分子化合物。 展开更多
关键词 原油 痕量化合物 母质来源 油源对比 运移路径示踪 油气次生改造
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干式厌氧发酵失稳调控机制及策略研究进展
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作者 常虹 苏小红 +1 位作者 秦国辉 刘伟 《中国沼气》 CAS 2024年第3期14-21,共8页
干式厌氧发酵技术是一项有机废弃物处理与资源化利用技术,在处理有机废弃物的同时既可产生清洁的甲烷能源,又可实现区域环境的改善,但其反应过程中极易出现酸化和氨氮抑制现象,进而导致反应体系产气效率降低甚至崩溃。综述了干式厌氧发... 干式厌氧发酵技术是一项有机废弃物处理与资源化利用技术,在处理有机废弃物的同时既可产生清洁的甲烷能源,又可实现区域环境的改善,但其反应过程中极易出现酸化和氨氮抑制现象,进而导致反应体系产气效率降低甚至崩溃。综述了干式厌氧发酵体系失稳调控机制,总结了酸化和氨氮抑制两类失稳情况的调控策略,分析了外源添加导电材料(生物炭、磁铁矿等)、添加微量元素(铁、镍等)和生物强化以及各项调控策略之间的混合协同调控。以期为缓解干式厌氧发酵过程中出现的酸化和高氨氮抑制现象,从而实现高效稳定运行提供相应的理论参考。 展开更多
关键词 干式厌氧发酵 失稳预警 导电材料 微量元素 生物强化 混合协同调控
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不同蛋白原料中矿物质元素含量分析
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作者 王威 门晓冬 +4 位作者 薛敏 刘璐 范志影 包郁明 谷旭 《中国饲料》 北大核心 2024年第11期129-136,共8页
本试验旨在研究不同蛋白原料中常量元素、微量元素、重金属元素等26种元素的含量及分布规律,分析其含量差异可能成因,为不同蛋白原料科学利用提供数据依据。本实验利用电感耦合等离子体质谱(ICP-MS)技术,系统分析了鸡肉粉、鱼粉、花生... 本试验旨在研究不同蛋白原料中常量元素、微量元素、重金属元素等26种元素的含量及分布规律,分析其含量差异可能成因,为不同蛋白原料科学利用提供数据依据。本实验利用电感耦合等离子体质谱(ICP-MS)技术,系统分析了鸡肉粉、鱼粉、花生浓缩蛋白、大豆浓缩蛋白、棉籽蛋白、菌体蛋白、藻粉和昆虫粉等8种15批次的蛋白原料中元素组成及分布规律。结果表明,所有蛋白原料均含有供试矿物质元素,不同种类的蛋白原料矿物质元素含量差异较大(P<0.05);某些元素在同种不同来源的原料中含量水平差异显著(P<0.05);存在蛋白原料中单一元素含量明显高于其他原料的现象(P<0.05)。通过对数据结果的分析有利于推广应用新型蛋白质饲料原料,促进我国养殖业的可持续发展。 展开更多
关键词 蛋白原料 常量元素 微量元素 重金属元素 电感耦合等离子体质谱(ICP-MS)
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吸波材料覆盖直升机强散射源RCS缩减分析
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作者 程健来 孔祥鲲 +1 位作者 费钟阳 招启军 《南京航空航天大学学报》 CAS CSCD 北大核心 2024年第2期217-226,共10页
针对武装直升机的宽带隐身问题,提出利用射线追踪和逆合成孔径雷达(Inverse synthetic aperture radar,ISAR)成像确定直升机强散射源位置的方法,形成电磁超构材料和磁性材料一体化设计直升机部分强散射源的隐身设计构想,并计算分析了两... 针对武装直升机的宽带隐身问题,提出利用射线追踪和逆合成孔径雷达(Inverse synthetic aperture radar,ISAR)成像确定直升机强散射源位置的方法,形成电磁超构材料和磁性材料一体化设计直升机部分强散射源的隐身设计构想,并计算分析了两款隐身材料加载后对整机隐身效果的影响。首先,分析等效媒质理论、射线追踪与ISAR成像原理。然后,通过射线追踪以及ISAR成像的计算,精确且直观地捕获强散射源部位。最后,给出了两款材料的反射系数并分析加载直升机后单站雷达散射截面(Radar cross section,RCS)变化。计算结果表明,两种不同类型隐身材料覆盖直升机强散射源部位后可以达到局部角域范围内RCS缩减的目的,为隐身材料和直升机蒙皮及旋翼的融合设计提供了参考。 展开更多
关键词 直升机 雷达散射截面 射线追踪 逆合成孔径雷达成像 电磁超构材料 磁性材料
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