Corrosion mechanism of Zn-Al-Mg-coated steel in simulated polluted marine atmosphere

The corrosion behaviour of zinc–aluminium–magnesium-coated steel in a simulated polluted marine atmospheric environment was investigated.Therefore,an indoor ageing acceleration test was carefully designed by simulating a polluted marine environment.The objective was to in-depth investigate the corrosion mechanism of Zn–Al–Mg-coated steel exposed to a simulated polluted marine environment.The experiments were carried out by scanning electron microscopy for micro-morphological characterization,X-ray diffraction,electrochemical impedance spectroscopy and electrodynamic polarization curves for the aged samples.The analysis of the results obtained after an indoor accelerated ageing test shows that Zn–Al–Mg coatings generate insoluble Zn_(5)Cl_(2)(OH)_(8)·H_(2)O and Zn_(4)SO_(4)(OH)_(6)during the corrosion process,which hinders the diffusion of corrosive substances into the substrate,and the insoluble substances are structurally dense and thus inhibit further corrosion.Therefore,this effectively inhibits the occurrence of further corrosion,and thus,Zn–Al–Mg coating can significantly extend the service life of Zn–Al–Mg-coated steel.

Simulating the Escaping Atmosphere of GJ 436 b with Two-fluid Magnetohydrodynamic Models

Observations of transmission spectra reveal that hot Jupiters and Neptunes are likely to possess escaping atmospheres driven by stellar radiation.Numerous models predict that magnetic fields may exert significant influences on the atmospheres of hot planets.Generally,the escaping atmospheres are not entirely ionized,and magnetic fields only directly affect the escape of ionized components within them.Considering the chemical reactions between ionized components and neutral atoms,as well as collision processes,magnetic fields indirectly impact the escape of neutral atoms,thereby influencing the detection signals of planetary atmospheres in transmission spectra.In order to simulate this process,we developed a magnetohydrodynamic multi-fluid model based on MHD code PLUTO.As an initial exploration,we investigated the impact of magnetic fields on the decoupling of H^(+)and H in the escaping atmosphere of the hot Neptune GJ436b.Due to the strong resonant interactions between H and H^(+),the coupling between them is tight even if the magnetic field is strong.Of course,alternatively,our work also suggests that merging H and H^(+)into a single flow can be a reasonable assumption in MHD simulations of escaping atmospheres.However,our simulation results indicate that under the influence of magnetic fields,there are noticeable regional differences in the decoupling of H^(+)and H.With the increase of magnetic field strength,the degree of decoupling also increases.For heavier particles such as O,the decoupling between O and H^(+)is more pronounced.Our findings provide important insights for future studies on the decoupling processes of heavy atoms in the escaping atmospheres of hot Jupiters and hot Neptunes under the influence of magnetic fields.

Impact of Exercise Atmosphere on Adolescents’Exercise Behavior:Chain Mediating Effect of Exercise Identity and Exercise Habit

Appropriate physical exercise has a positive impact on adolescents’physical and mental health,but there is a serious lack of physical exercise among Chinese adolescents.How to shape their exercise behavior(EB)has become an important task in promoting their development.A questionnaire survey was conducted using stratified cluster random sampling on three middle schools by class in Zhejiang Province,China to investigate the impact of exercise atmosphere(EA)on adolescents’exercise behavior and the mediating role of exercise identity(EI)and exercise habit(EH).806 adolescents were investigated by the Exercise Atmosphere Scale(EAS),Exercise-Identity Scale(EIS),Self-Report Habit Index(SRHI),and Physical Activity Rating Scale(PARS-3).The results show that:There is a significant positive correlation between each two of exercise atmosphere,exercise identity,exercise habit,and exercise behavior(p<0.05).Exercise atmosphere could not only directly affect adolescents’physical exercise behavior but can also indirectly affect their physical exercise behavior through the mediating effect of exercise identity and exercise habit,involving three mediating pathways,namely,the mediating path through exercise identity,the mediating pathway through exercise habit and the chain mediating pathway through exercise identity and exercise habit.The direct effect of exercise atmosphere on exercise behavior was 0.459(p<0.01),accounting for 62.62% of the total effect of 0.733,and its indirect effect was 0.274,accounting for 37.28% of the total effect.To a certain extent,the mediating effect model reveals the mechanism of exercise atmosphere affecting exercise behavior and has a certain reference value for promoting adolescents’exercise behavior.We should start by creating an exercise atmosphere,cultivating exercise identity,and enhancing exercise habits to help teenagers form active physical exercise behaviors.

Study of the reaction mechanism for preparing powdered activated coke with SO_(2)adsorption capability via one-step rapid activation method under flue gas atmosphere

In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is summarized.Results indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this stage.This stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of particles.This stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as material.Besides,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third stage.Mastering the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.

Investigating the Creation of Cultural Atmospheres in Physical Bookstores Within the Context of Scene-Based Consumption:A Perspective Based on the Ways of Seeing

In an era of scene-based consumption,the essence of operating a bookstore lies in accepting and enabling the bookstore to play its role as a cultural medium for browsing and appreciating books,which in turn fosters the development of a distinctive bookstore culture.This new type of consumption context has led to an evolution in the book-reading culture in physical bookstores that is characterized by a shift from a paradigm of passive reading to one where the emphasis is on interactive viewing.This transition has laid the foundation for the creation of cultural atmospheres in bookstores,and it highlights the visual interactions that now exist between readers and books as well as with other related cultural industries.The dominant and fundamental logic behind this process is symbiosis,experience,aesthetics,immersion,and creativity.However,when a form of culture that focuses on consumption-oriented browsing begins to overshadow knowledge acquisition during the process of book reading,the cultural essence of bookstores is likely to be diminished.Therefore,the cultural essence within the scene-based consumption context should be enhanced by creating innovative viewing activities that showcase the cultural and emotional implications inherent in the scene itself,and thus help to align the identity of the bookstore with its in-situ cultural space.

Analysis of quality-related proteins in golden pompano(Trachinotus ovatus)fillets with modified atmosphere packaging under superchilling storage

Here,we aimed to study the changes in proteome of golden pompano fillets during post-mortem storage.Tandem mass tags(TMT)-labeled quantitative proteomic strategy was applied to investigate the relationships between protein changes and quality characteristics of modified atmosphere packaging(MAP)fillets during superchilling(-3°C)storage.Scanning electron microscopy was used to show that the muscle histology microstructure of fillets was damaged to varying degrees,and low-field nuclear magnetic resonance was used to find that the immobilized water and free water in the muscle of fillets changed significantly.Total sulfhydryl content,TCA-soluble peptides and Ca2+-ATPase activity also showed that the fillet protein had a deterioration by oxidation and denaturation.The Fresh(FS),MAP,and air packaging(AP)groups were set.Total of 150 proteins were identified as differential abundant proteins(DAPs)in MAP/FS,while 209 DAPs were in AP/FS group.The KEGG pathway analysis indicated that most DAPs were involved in binding proteins and protein turnover.Correlation analysis found that 52 DAPs were correlated with quality traits.Among them,8 highly correlated DAPs are expected to be used as potential quality markers for protein oxidation and water-holding capacity.These results provide a further understanding of the muscle deterioration mechanism of packaging golden pompano fillets during superchilling.

Role of land-atmosphere coupling in persistent extreme climate events in eastern China in summer 2022

2022年暖季,中国东部地区遭受持续性高温,少雨和土壤干旱的复合极端事件.特征分析指出,在研究时段内,中国东部地区的气温,降水和土壤湿度呈现明显的季节内变化和南北差异。由1940-2022年的气候态可知,长江流域和东南地区的土壤含水充足,蒸散主要受限于陆面有效能量.然而,潜在机制研究指出,2022年土壤湿度对蒸散的限制作用在上述区域异常偏强,土壤湿度与气候要素之间的强反馈可能在2022年复合极端事件的演变和持续中发挥了关键作用。

Monitoring and identification of spoilage-related microorganisms in braised chicken with modified atmosphere packaging during refrigerated storage

This study mainly monitored the dominant bacterial populations and identified the spoilage-related microorganisms of braised chicken meat stored under different CO_(2)-modified atmosphere packaging(MAP)during refrigerated storage using a culture-dependent method and 16S rDNA identification.The quality changes and shelf life of the meat were also measured.The growth rate of total viable count(TVC)in braised chicken was slower with an increase of CO_(2) content in MAP,which also occurred in the remaining bacterial species monitored(lactic acid bacteria,Pseudomonas spp.,Brochothrix thermosphacta).The MAP exerted beneficial effects on the quality of braised chicken,as demonstrated by retarding the production of total volatile basic nitrogen(TVB-N)and delaying lipid oxidation(TBARS test).A total of 14 isolates were identified from braised chickens with different packaging at the end of storage,these included P.fragi(6 isolates),P.psychrophila(2 isolates),Enterococcus faecalis(3 isolates),B.thermosphacta(2 isolates),Staphylococcus equorum(1 isolate).

An integrated and efficient process for borax preparation and magnetite recovery from soda-ash roasted ludwigite ore under CO–CO_(2)–N_(2) atmosphere

To realize the comprehensive utilization of ludwigite ore,an integrated and efficient route for the boron and iron separation was proposed in this work,which via soda-ash roasting under CO–CO_(2)–N_(2) atmosphere followed by grind-leaching,magnetic separation,and CO_(2) carbonation.The effects of roasting temperature,roasting time,CO/(CO+CO_(2))composition,and Na_(2)CO_(3) dosage on the boron and iron separation indices were primarily investigated.Under the optimized conditions of the roasting temperature of 850℃,roasting time of 60 min,soda ash dosage of 20 wt%,and CO/(CO+CO_(2)) of 10 vol%,92%of boron was leached during wet grinding,and 88.6%of iron was recovered during the magnetic separation and magnetic concentrate with a total iron content of 61.51 wt%.Raman spectra and^(11)B NMR results indicated that boron exists asB(OH)_(4)^(-) in the leachate,from which high-purity borax pentahydrate could be prepared by CO_(2) carbonation.

Current state of research on microplastics in the marine- atmosphere environment of the Arctic region

Microplastics,plastic particles smaller than 5 mm in size,are a growing source of environmental pollution.Microplastic pollution has been observed in situ in the remote Arctic,where it has been found in the land,sea,cryosphere,and atmosphere.This review summarizes the sample pretreatment techniques and analytical methods commonly used in microplastic research,as well as the pollution status of microplastics in the Arctic,their sources,and their effects on the environment.In the Arctic,the size distribution of microplastics is more inclined to small-scale aggregation,the shape of microplastics is mostly fibrous,with the proportion of fibers often accounting for more than 70%.There are marked differences among studies in terms of abundance and polymer composition,but polyester is generally dominant in seawater.Many microplastic particles are transported to the Arctic by ocean currents and rivers,but atmospheric transport and deposition are slowly being recognized as an important transport route.Sea ice is particularly important for the temporary storage,transport,and release of Arctic microplastics.The average storage of microplastics in sea ice was estimated to be approximately 6.1×108 items.Given their properties,microplastics can affect glacier melting,sea surface temperature changes,and even the carbon cycle.Urgent measures must be taken to improve research standards and overcome sampling difficulties in the Arctic region to achieve time continuity and large-scale distribution patterns of Arctic microplastics.

Marlowe’s Tamburlaine the Great and the Tragedy of Karbala

This essay analyses Christopher Marlowe’s play Tamburlaine the Great and its intricate interweaving of historical events and cultural nuances.Focusing on the character of Tamburlaine,the essay explores themes of power,revenge,and divine justice within the context of the broader Shiite-Sunni conflict and the tragic history of Imam Al-Hussein.By examining Marlowe’s incorporation of historical accounts and creative narrative techniques,the essay highlights how the play provides insights into the complexities of human ambition,political manoeuvring,and the consequences of wielding authority.Ultimately,Tamburlaine the Great is shown to be a timeless exploration of the interplay between history,religion,and individual agency,inviting readers to reflect on the enduring relevance of its themes in both historical and contemporary contexts.

Detection of TiO and VO in the Atmosphere of WASP-121b and Evidence For its Temporal Variation

We report the transit observations of the ultra-hot Jupiter WASP-121b using the Goodman High Throughput Spectrograph at the 4 m ground-based Southern Astrophysical Research Telescope,covering the wavelength range502-900 nm.By dividing the target and reference star into 19 spectroscopic passbands and applying differential spectrophotometry,we derive spectroscopic transit light curves and fit them using a Gaussian process framework to determine transit depths for every passband.The obtained optical transmission spectrum shows a steep increased slope toward the blue wavelength,which seems to be too steep to be accounted for by Rayleigh scattering alone.We note that the transmission spectrum from this work and other works differ obviously from each other,which was pointed out previously by Wilson et al.as evidence for temporal atmospheric variation.We perform a free chemistry retrieval analysis on the optical transmission spectra from this work and the literature HST/WFC3 NIR spectrum.We determine TiO,VO and H_(2)O with abundances of-5.95_(-0.42)^(+0.47)dex,-6.72_(-1.79)^(+0.51)dex and-4.13_(-0.46)^(+0.63)dex,respectively.We compare the abundances of all three of these molecules derived from this work and previous works,and find that they are not consistent with each other,indicating the chemical compositions of the terminator region may change over long timescales.Future multi-epoch and high-precision transit observations are required to further confirm this phenomenon.We note that when combining the transmission spectra in the optical and in NIR in retrieval analysis,the abundances of V and VO,the NIR-to-optical offset and the cloud deck pressure may be coupled with each other.

A Variational Multiscale Method for Particle Dispersion Modeling in the Atmosphere

A LES model is proposed to predict the dispersion of particles in the atmosphere in the context of Chemical,Biological,Radiological and Nuclear(CBRN)applications.The code relies on the Finite Element Method(FEM)for both the fluid and the dispersed solid phases.Starting from the Navier-Stokes equations and a general description of the FEM strategy,the Streamline Upwind Petrov-Galerkin(SUPG)method is formulated putting some emphasis on the related assembly matrix and stabilization coefficients.Then,the Variational Multiscale Method(VMS)is presented together with a detailed illustration of its algorithm and hierarchy of computational steps.It is demonstrated that the VMS can be considered as a more general version of the SUPG method.The final part of the work is used to assess the reliability of the implemented predictor/multicorrector solution strategy.

The Possibilities of Using the Minimax Method to Diagnose the State of the Atmosphere

The article is devoted to the discussion of the possibilities of approbation of one of the probabilistic methods of verification of evaluation works-the minimax method or the method of establishing the minimum risk of making erroneous diagnoses of the instability of the planetary boundary layer of air.Within the framework of this study,the task of probabilistic forecasting of diagnostic parameters and their combinations,leading in their totality to the formation of an unstable state of the planetary boundary layer of the atmosphere,was carried out.It is this state that,as shown by previous studies,a priori contribution to the development of a number of weather phenomena dangerous for society(squalls,hail,heavy rains,etc.).The results of applying the minimax method made it possible to identify a number of parameters,such as the intensity of circulation,the activity of the Earth’s magnetosphere,and the components of the geostrophic wind velocity,the combination of which led to the development of instability.In the future,it is possible to further expand the number of diagnosed parameters to identify more sensitive elements.In this sense,the minimax method,the usefulness of which is shown in this study,can be considered as one of the preparatory steps for the subsequent more detailed method for forecasting individual hazardous weather phenomena.

人工影响天气虚拟仿真实验及课程体系建设

在“人工影响天气”的相关课程教学中,构建虚拟仿真实验教学平台有助于学生深入理解基础理论知识,并对实际业务操作及催化方案设计、优化产生感性认识。虚拟仿真实验教学突破了室内教学时空及仪器设备昂贵的局限性,解决了自然界中不能对同一块云反复催化的实际困难,对云降水环境及人工催化过程高度重现,对理论教学体系及教学形式进行补充,完善了课程教学体系。此外,科技成果在教学和本科生科研创新活动的引入,进一步增强学生科技创新意识及学习兴趣,促进了科研创新型人才的培养。

2022年华南极端“龙舟水”与大气环流及海温异常的关系

利用华南192个国家气象观测站逐日降水资料,NCEP/NCAR大气环流再分析资料,NOAA月平均海表温度资料(ERSST V5)及向外长波辐射(OLR)资料,采用相关、合成分析的方法研究了2022年华南“龙舟水”异常与大气环流及海温异常的关系。结果表明,2022年“龙舟水”期间,东亚大槽、东北冷涡偏强,南下冷空气偏强,同时西太平洋副热带高压和南支槽均偏强,在华南存在明显的水汽辐合。2022年发生的拉尼娜事件,大气环流对其有明显响应,Walker环流增强,华南对流明显加强,菲律宾以东存在异常反气旋环流,副高加强导致其西北侧的西南风加强,向华南水汽输送显著增强,同时华南存在显著的上升运动。大气环流和海温的异常导致2022年华南极端“龙舟水”。

雄安新区绿色金融与大气环境耦合协调的时空演变

绿色金融与大气环境耦合协调发展是经济可持续发展的一个重要问题,也是雄安新区建设绿色之城的前提和保障。以雄安新区为研究对象,构建绿色金融与大气环境综合评价的指标体系,运用熵权TOPSIS法、耦合度模型、协调度模型和相对发展度模型,研究了2018年1季度至2021年4季度雄安新区绿色金融与大气环境耦合协调的时空演变。研究表明:(1)从时间层面来看,雄安新区绿色金融和大气环境综合指数呈现波动上升的趋势,两系统耦合度处于0.193~0.862之间,其相互影响逐渐增强;协调度水平从0.227增长到0.697,进入初级协调等级;相对发展度大幅上升,但整体上仍处于绿色金融发展滞后的阶段,绿色金融对大气环境的支撑力度还有待加强。(2)从空间层面来看,雄安新区绿色金融与大气环境耦合度、协调度和相对发展度总体水平均高于其周边绝大多数区县,雄安新区的设立与建设极大促进了该地区绿色金融与大气环境的协调发展。

大型太阳望远镜镜面视宁度的实验研究

太阳望远镜内部因太阳辐射作用使镜面升温,镜面上方产生局部大气湍流,导致镜面视宁度不佳,从而造成像质的严重衰减。文中基于温度梯度和气体流动导致固体-流场的耦合作用,提出镜面视宁度效应的形成机制,建立湍流大气光学产生镜面视宁度效应的理论,利用1 550 mm大口径双曲面镜的实验数据推导并验证镜面视宁度的实验模型,并对太阳望远镜主镜温控目标进行确定。在自然对流和强迫对流两种条件下,不同环境风速时镜面温差改变对镜面视宁度的影响。结果表明:镜面温差和环境风速与镜面视宁度相关性很强,增加主动通风可以降低镜面视宁度。温差是4℃条件下,自然对流时镜面视宁度为1.43″;温差是3℃条件下,0.2 m/s强迫对流时镜面视宁度为0.44″,1 m/s强迫对流时镜面视宁度为0.27″。根据镜面视宁度效应容差标准,在0.2 m/s强迫对流条件下,镜面-空气温差应控制在0.2 K以下;在1.0 m/s强迫对流条件下,镜面-空气温差应控制在1 K以下。此研究成果旨在揭示空气湍流的形成机理与传播规律及其对望远镜像质退化影响规律,为提升大口径太阳望远镜工作分辨率奠定基础。

一种光波大气折射率剖面模型构建方法

根据经典光波折射率计算公式和ITU-R建议书中水汽密度经验公式,给出了一种新的光波大气折射率计算公式;借鉴Hopfield折射率静力项剖面模型和ITU-R建议书中水汽密度剖面模型,给出了一种基于历史气象探空数据构建光波大气折射率剖面模型的方法。以青岛地区为例,通过对1986—1995年历史气象探空数据的处理并结合参考标准大气,建立了适合当地的光波大气折射率剖面模型;统计剖面模型预测折射率剖面与实测折射率剖面的均方根误差,结果表明:构建的剖面模型具有较好的预测精度,这对光学外测设备的折光修正数据处理具有很好的参考价值。

空空导弹海洋大气自然环境试验研究

针对空空导弹随航母服役需求和海洋大气自然环境适应性风险,结合相关标准和研制经验,对空空导弹海洋大气自然环境试验方案设计流程、方法及要点进行了研究。提出了一套空空导弹海洋大气自然环境试验方案,可用于指导新研型号科学有效地开展自然环境试验,为回答空空导弹海洋大气自然环境适应性指标提供了支撑。空空导弹应系统策划海洋大气自然环境试验,以尽早暴露问题,实现产品设计改进,为上舰环境适应性的提高奠定基础。同时,还应大力开展自然加速环境试验技术和动态自然环境试验技术研究工作。