In the thermodynamic evaluation Y was selected as a typical heavy rare earth metal for reducing the detrmental effects of tramp elements in the petroleum pipe steel. The possibilities of reactions between Y and trampe...In the thermodynamic evaluation Y was selected as a typical heavy rare earth metal for reducing the detrmental effects of tramp elements in the petroleum pipe steel. The possibilities of reactions between Y and trampelements such as Sn, Sb, As, etc. after deoxidation and desulphurization were estimated by calculating the Gibbsfree energies of formation. The equilibrium content of Y for eliminating the detrimental effects of tramp elements inthe steel was recommended from the results of thermodynamic calculation.展开更多
The effect of tramp elements in the steel was intensively studied. It was found that the solubility of tramp elements decreased as the temperature decreased under normal cooling conditions. The tramp elements （Cu, Pb...The effect of tramp elements in the steel was intensively studied. It was found that the solubility of tramp elements decreased as the temperature decreased under normal cooling conditions. The tramp elements （Cu, Pb, and Sn） diffused toward the grain boundaries, and intermetallic compounds or rich phases which have low melting points were formed, causing reduction in ductility and failure during the bending test. Rebars with Cu content which were left to air cooling after the last step showed drop in elongation, up to 32 %. On contrast, the samples with high per- centage of tramp elements （Cu, Pb, and Sn） in the billet, which were rolled and subjected to Tempcore process, did not show drop in elongation or failure in bending test （especially for rebar with diameter less than 32 mm）; however, copper must be less than 0.35 mass% to prevent the precipitation of Cu-rich zones of critical size in 32 mm. When quench- ing was applied, the tramp elements remained in the interstitial supersaturated solid solution positions inside the grains and would not have the chance to diffuse and form precipitates, hindering the copper precipitates from reac- hing the critical size necessary for impairing the properties. This would hinder the occurrence of the harmful effect of the tramp elements on the elongation or the hot shortness after rolling.展开更多
Effect of tin and antimony on hot ductility of GCr15 bearing steel as well as interaction between lanthanum and tramp elements, were studied by simulator Gleeble-1500 and the fractures for the tested steels were analy...Effect of tin and antimony on hot ductility of GCr15 bearing steel as well as interaction between lanthanum and tramp elements, were studied by simulator Gleeble-1500 and the fractures for the tested steels were analyzed using SEM and EDS. The results show that with increasing contents of tin and antimony elements, the hot ductility of GCr15 bearing steel was decreased. Lanthanum can reduce the harmful effect of tramp elements on the hot ductility of GCr15, which can react with antimony to form compound and segregate at grain boundary in steel. Lanthanum can refine the recrystallized austenite grains after deformation and subsequent martensite structure.展开更多
文摘In the thermodynamic evaluation Y was selected as a typical heavy rare earth metal for reducing the detrmental effects of tramp elements in the petroleum pipe steel. The possibilities of reactions between Y and trampelements such as Sn, Sb, As, etc. after deoxidation and desulphurization were estimated by calculating the Gibbsfree energies of formation. The equilibrium content of Y for eliminating the detrimental effects of tramp elements inthe steel was recommended from the results of thermodynamic calculation.
文摘The effect of tramp elements in the steel was intensively studied. It was found that the solubility of tramp elements decreased as the temperature decreased under normal cooling conditions. The tramp elements （Cu, Pb, and Sn） diffused toward the grain boundaries, and intermetallic compounds or rich phases which have low melting points were formed, causing reduction in ductility and failure during the bending test. Rebars with Cu content which were left to air cooling after the last step showed drop in elongation, up to 32 %. On contrast, the samples with high per- centage of tramp elements （Cu, Pb, and Sn） in the billet, which were rolled and subjected to Tempcore process, did not show drop in elongation or failure in bending test （especially for rebar with diameter less than 32 mm）; however, copper must be less than 0.35 mass% to prevent the precipitation of Cu-rich zones of critical size in 32 mm. When quench- ing was applied, the tramp elements remained in the interstitial supersaturated solid solution positions inside the grains and would not have the chance to diffuse and form precipitates, hindering the copper precipitates from reac- hing the critical size necessary for impairing the properties. This would hinder the occurrence of the harmful effect of the tramp elements on the elongation or the hot shortness after rolling.
文摘Effect of tin and antimony on hot ductility of GCr15 bearing steel as well as interaction between lanthanum and tramp elements, were studied by simulator Gleeble-1500 and the fractures for the tested steels were analyzed using SEM and EDS. The results show that with increasing contents of tin and antimony elements, the hot ductility of GCr15 bearing steel was decreased. Lanthanum can reduce the harmful effect of tramp elements on the hot ductility of GCr15, which can react with antimony to form compound and segregate at grain boundary in steel. Lanthanum can refine the recrystallized austenite grains after deformation and subsequent martensite structure.
