Health risk assessment of heavy metal pollution in groundwater of a karst basin,SW China

To investigate the presence of metal elements and assess their health risk for the populace in the Nandong Underground River Basin(NURB),we conducted an analysis of eleven common heavy metals in the water body.A Health risk assessment(HRA)model was employed to analyze 84 water samples from the NURB.The detection results revealed the following order of heavy metals concentrations:Fe>Al>Mn>Zn>As>Cd>Pb>Cr>Ni>Cu>Hg.Correlation analysis indicated a certain similarity in material source and migration transformation among these eleven metal elements.Our study identified that the health risks for local residents exposed to metal elements in the water of NURB primarily stem from carcinogenic risk(10^(−6)–10^(−4)a^(−1))through the drinking water pathway.Moreover,the health risk of heavy metal exposure for children through drinking water was notably higher than for adults.The maximum health risks of Cr in both underground and surface water exceeded the recommendation standard(5.0×10^(−5)a^(−1))from ICRP,surpassing the values recommended by the Swedish Environmental Protection Agency,the Dutch Ministry of Construction and Environment and the British Royal Society(5.0×10^(−6)a^(−1)).The results of the health risk assessment indicate that Cr in the water of NURB is the primary source of carcinogenic risk for local residents,followed by Cd and As.Consequently,it is imperative to control these three carcinogenic metals when the water was used as drinking water resource.

Spatial Assessment of the Perception of Environmental Pollution in Rivers State

This study examines the perception of pollution in Rivers state, to find out the inhabitants opinion of how the government is handling pollution in the area. The study used the survey research design and primary data which were collected using copies of questionnaire were the main data used for the study. Data collected were presented using tables and statistical diagrams, while data analysis was achieved using the welch statistics. It was observed that 37.75% of the respondents suggested that the air quality in the area is very bad, suggesting that they were suffering as a result. The main sources of environmental pollution were petroleum refining (44.25%), illegal refining of petroleum products (52.75%) and fumes from vehicles (46%). Also noted was that vast majority of inhabitants (86.75%) were willing to partake in the cleaner environmental process, but they stated that the government was not forceful enough to achieve the pollution free environment in the area. The welch statistics identified that there was no statistically significant difference in the perception of polluted environment in the area at P > 0.05. The study as a result of the findings advocates partnership between government, individuals and NGOs to achieve cleaner and safer environment in the area.

Analysis on the Status of Agricultural Non-point Source Pollution in Xinan River Basin

Taking Xinan River basin as research object,the status of agricultural non-point source pollution was analyzed based on field survey,as well as the effect of fertilizer and pesticide leaching and runoff,livestock and poultry breeding and rural domestic pollution on non-point source TN and TP.At last,some technical countermeasures of controlling non-point source pollution were put forward according to the characteristics of agricultural non-point source pollution in Xinan River basin.

Comprehensive ecological risk assessment for heavy metal pollutions in three phases in rivers

Literature lacked in providing a comprehensive research on heavy metal detection in aquatic, biological and sedimentary states of rivers. The present study was imparted with all these three components of the river. Heavy metal toxicity or pollution index was used as a tool for ecological risk assessment by considering the single state studies conducted by many researchers. An intensive ecological risk assessment model was constructed and heavy metals were indicated as a serious threat to the environment. The model was applied to determining five toxic heavy metals in three states of the Songhua River. According to the ecological risk index, heavy metal pollution in three phases was categorized as aquatic〉biological〉sedimentary, while the overall descending order of heavy metal ecological risk index was as Cd〉Hg〉As〉Pb〉Cr. Cd and Hg were selected as the priority pollutants of Songhua River.

Pollution status and potential ecological risk assessment in the surface sediments of the Yellow River estuary

Based on the ＂Project 908＂ survey data in 2006--2007 on surface sediments of the sea area adjacent to the Yellow River estuary, the research was conducted on the concentration distribution characteristics of heavy metals in surface sediments of the estuary, which show that the mean contents of seven heavy metals （Cu, Pb, Zn, Cd, Cr, Hg, As） in the Yellow River estuary and its surrounding areas all comply with the Level-I of National Marine Sediments Quality Standard of China. Statistically significant correlation between the elements Cu-Cd, Pb-Cr and Cr-As in sediments indicates that the two heavy metals in each group may respectively have similar geochemical properties and sources. By using the Potential Ecological Risk Index （PERI） proposed by Hakanson, the assessment shows that the potential ecological risks in the estuary surface sediments are mainly attributed to Cd and Hg. The biological toxicity effects are assessed with the biological effects of concentration method, resulting in a conclusion that the adverse effects of As on organisms in the estuary marine environment occasionally occur, in contrast, Cu, Pb, Zn, Cd, Cr and Hg will not generate adverse biological effects on a short and medium time scale.

Test Research on the Characteristics of Pollution Boundary Layer in the River Outlet Area of Grand Liao River

By using the meteorological data in the pollution boundary layer which was observed in two ground observation sites:coast and land in the river outlet area of Grand Liao River during January-February in 2007,the daily change characteristics of pollute boundary layer in winter in the area were discussed. The results showed that the pollute boundary layer in the river outlet area of Grand Liao River was affected by the sea and land. In the certain weather condition,maybe the sea-land breeze appeared in the low altitude which was below 200 m in the coastal zone. The stability change in the different height in the coastal zone was more stable than in the land zone,and the wind field change in the area was mainly in 300 m low altitude. At night,the temperature inversion often appears in the area,and the thickness of temperature inversion layer is stably during 200-300 m. The thermal internal boundary layer penetrated deeply into the land about 10 km,and the height could reach 800 m. The atmospheric diffusion ability in the coastal area was weaker and stronger in the land area.

Discussion on the Construction of Negotiation Mechanism of Cross-bounder Water Pollution Treatment in Changjiang River

In order to construct cooperation platform for the treatment of water pollution in Changjiang River,thoughts and revolution were performed from both central government and regional area two aspects.From the national level,Changjiang region water resources management cooperation counsel committee was constructed as the national cooperation platform;from the regional level,Changjiang region water resources management cooperation counsel committee was constructed as the platform of Changjiang cooperation platform.The two platforms built fine interaction mechanism to deal with the national water management and Changjiang regional water management.

Analysis on Strategic Future of Application of Agricultural Ecological Source in Control on Agricultural Nonpoint Source Pollution in Xi River Area in Guangxi

Non-point source pollution has become a hot issue on aquatic ecological environment at home and abroad. The research analyzed the challenges confronted by Xi River and proposed to construct agricultural ecological source in middle and upper reaches of the Xi River from the perspectives of scientific layout, legal construction, routine monitoring, technology integration, and coordination system in order to promote sustainable development of eco-environment in Xi River.

Heavy metal pollution of soils and vegetables in the midstream and downstream of the Xiangjiang River, Hunan Province

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.

A distributed non-point source pollution model: calibration and validation in the Yellow River Basin

The applicability of a non-point source pollution model—SWAT(soil and water assessment tools) in a large river basin with high sediment runoff modulus(770 t/km2 in the Yellow River) was examined. The basic database, which includes DEM, soil and landuse map, weather data, and land management data, was established for the study area using GIS. A two-stage “Brute Force' optimization method was used to calibrate the parameters with the observed monthly flow and sediment data from 1992 to 1997. In the process of calibration automated digital filter technique was used to separate direct runoff and base flow. The direct runoff was firstly calibrated, and the base flow, then the total runoff was matched. The sediment yield was calibrated to match well. Keeping input parameters set during the calibration process unchanged, the model was validated with 1998—1999's observed monthly flow and sediment. The evaluation coefficients for simulated and observed flow and sediment showed that SWAT was successfully applied in the study area: relative error was within 20%, coefficient of determination and Nash-Suttcliffe simulation efficiency were all equal to or above 0.70 during calibration and validation period.

Nitrobenzene biodegradation ability of microbial communities in water and sediments along the Songhua River after a nitrobenzene pollution event

More than 100 t of nitrobenzene (NB) and related compounds were discharged into the Songhua River,the fourth longest river in China,because of the world-shaking explosion of an aniline production factory located in Jilin City on November 13,2005.As one of the efforts to predict the fate of residual NB in the river,NB biodegradation abilities by microbes in the water and sediments from different river sections were evaluated systematically.The results indicated that microbial communities from any section of ...

Method for calculating non-point source pollution distribution in plain rivers

The land area in a river network is divided into certain-scale square cells for the sake of precision, and, based on the physical mechanisms of rainfall-runoff processes and runoff pollution, the non-point source pollution from cells is estimated using the export coefficients of different land use types. The non-point source pollution from a land cell should all go into the closest fiver reach, so it is distributed according to the terrain of the plain river network area and the positions of land cells and river network reaches. A relationship between a single land cell and its pollution-receiving reach can be determined using this system. In view of the above, a spatial distribution model of the rainfall runoff and non-point source pollution in reaches of a plain river network area was established. This model can provide technological support for further research on the dynamic effects of non-point source pollution on water quality.

Distribution and their pollution assessment of heavy metals in the sediments of the Yalu River Estuary and its adjacent coastal waters

The present paper deals with the distribution patterns of heavy metals and the associated influenc- ing factors in the Yalu River Estuary and its adjacent coastal waters. Based upon the analysis of the surficial and core sediments measurements, the pollution of heavy metal and potentiM ecological risk were evaluated. The burial flux and contents of heavy metals （except for copper） have been continuously increasing since the 1920s. Therefore, the gross potential ecological risk for the sedi- ments was high or very high, and the study area was endangered by heavy metals contamination. Heavy metals originated mainly from upstream pollutant input, correlation analysis showed that chromium, nickel, zinc~ cadmium, lead, arsenic, and mercury in the sediments of the middle and west channels as well as the sea area of the western Yalu River Estuary concentrations were most probably derived from similar sources. In contrast, the metal of copper most probably originated from sources different from the other metals. Preliminary studies indicate that copper contamina- tion was most likely the result of emission from mining activities situated at the upstream of the river. The contents of heavy metals in the sediments of estuarine turbidity maximum zone of Yalu River were larger than those of any other areas in the middle channel. With large portion of fine sediments, weaker hydrodynamics, and richer sources of heavy metals, the sediments of the west channel, were even more enriched with heavy metals than those of the middle channel.

Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

Model for water pollution remote sensing based on double scattering and its application in the Zhujiang River outfall

It is a valid route for quantitatively remote sensing on water pollution to build a model according to the physical mechanisms of scattering and absorbing of suspended substance, pollutant, and molecules of water. Remote sensing model for water pollution based on single scattering is simple and easy to be used, but the precision is affected by turbidity of water. The characteristics of the energy composition of multiple scattering, are analyzed and it is proposed that, based on the model of single scattering, if the flux of the second scattering is considered additionally, the precision of the model will be remarkably improved and the calculation is still very simple. The factor of the second scattering is deduced to build a double scattering model, and the practical arithmetic for the calculation of the model is put forward. The result of applying this model in the water area around the Zhujiang(Pearl) River outfall shows that the precision is obviously improved. The result also shows that the seriously polluted water area is distributed in the northeast of Lingding Sea, the Victoria Bay of Hong Kong, and the Shengzhen Bay.

POLLUTION TREND IN THE TUMEN RIVER AND ITS INFLUENCE ON REGIONAL DEVELOPMENT

The Tumen River had failed to meet Grade Ⅲ and Ⅳ levels in the environmental quality standard for surface water, and had exceeded Grade Ⅴ level. Surface water pollution is serious. The major excessive standard pollutants were COD Mn and SS. After taking effective treatment steps, the worsening trend of water pollution will be basically under control. But the change of runoff in the Tumen River is large in a year, especially during as long as five month freezing period, smaller flow and lower temperature of river waters led to weak dilution and self purification capacity. The water quality of the Tumen River will not reach the appoint functional water quality standards, even if sewage meets discharge standard, which will influence water resources utilization in the lower reaches of the Tumen River and regional economic development. Therefore water pollution has become the major restrictive factor of the development of the Tumen River area.

The river chief system and agricultural non-point source water pollution control in China

As part of their efforts to control water pollution,local governments in China introduced the river chief system,whereby a named individual undertakes responsibility for protecting a specified waterway.As one of the most prominent sources of water pollution,agricultural non-point-source(NPS)pollution is becoming increasingly serious.Determining whether the river chief system,an institutional reform in China's decentralized environmental regulation regime,is effective in alleviating NPS pollution is important for the realization of green development.The effect of the river chief system on reducing agricultural NPS pollution is explored in this study using panel data from 308 Chinese counties during the period from 2004 to 2015.The results reveal that the negative impact of manure output from animal breeding operations on surface water quality is reduced with the implementation of the river chief system.However,the river chief system is ineffective in dealing with the water pollution caused by fertilizer use.Furthermore,in the current system,cooperation among river chiefs only occurs within a province.Local governments should increase their efforts in reducing fertilizer source loads and preventing fertilizer loads from entering surface waters.In addition,the central government should improve cooperation among the river chiefs in upstream and downstream provinces.

Characterization of Air Pollution in Urban Areas of Yangtze River Delta,China

The hallmark of development in the Yangtze River Delta(YRD) of East China has been sprawling urbanization. However, air pollution is a significant problem in these urban areas. In this paper, we investigated and analyzed the air pollution index(API) in four cities(Shanghai, Nanjing, Hangzhou and Ningbo) in the YRD from 2001 to 2012. We attempted to empirically examine the relationship between meteorological factors and air quality in the urban areas of the YRD. According to the monitoring data, the API in Shanghai, Nanjing, Hangzhou slightly declined and that in Ningbo increased over the study period. We analyzed the inter-annual, seasonal, and monthly variations of API, from which we found that the air quality had different temporal changes in the four cities. It was indicated that air quality was poor in winter and spring and best in summer. Furthermore, different weather conditions affected air quality level. The wind direction was considered as an important and influential factor to air pollution, which has an impact on the accumulating or cleaning processes of pollutants. The air quality was influenced by the different wind directions that varied with seasons and cities.

Pollution pattern of underground river in karst area of the Southwest China

Investigation of groundwater pollution has been carried out on multiple typical karst underground river systems in recent years in order to reveal the characteristics and mechanism of underground river pollution. Through the summary of the survey results, five characteristics of underground river pollution have been revealed, including directionality, weak hysteresis, easier for reversibility, linear and intermittent(or seasonal); combining with karst geomorphic types, pollution sources(primordial, secondary pollution and compound), pollution ways and pollution receptors, three basic pollution patterns of the underground river were depicted: Recharge area pollution, runoff area pollution and discharge area pollution. At the same time, the study discloses the reality of the underground river pollution is the three basic patterns and their subgenera in combination with super imposition on the space and time. And from the angle of the hydrogeological model, the study expounds the process of underground river pollution. Finally, the study gives naming rules of pollution pattern of the underground river and sets up PISAB method of pattern recognition. The results provide scientific basis for pollution repair and management of underground river in the southwest karst region.

Developing sediment quality criteria for heavy metal pollution in the Le An River with equilibrium partitioning approach

Equilibrium partitioning(EqP) approach was selected to establish the sediment quality criteria(SQC) in the Le An River near Dexing Copper Mine. Both freshwater quality criteria (WQC) for some heavy metals regulated by USEPA and national quality standards of surface water recommended by CNEPA were used as protective levels of aquatic organisms in this study. Meanwhile, the partitioning coefficients were derived directly from measured data. Comparison between SQC in this region and concentrations of contaminants in situ clearly indicated the distribution characteristics of metal contamination along the river. And the results also illustrated that measures of some metals exceeded their SQC levels in different degree, especially Cu.