Effect of surfactant type on interfacial area and liquid mass transfer for CO_2 absorption in a bubble column

The effect of different surfactants(n-octyltrimethylammonium bromide(OTABr),sodium dodecyl benzene sulfonate(SDBS) and Tween 80) with different critical micelle concentrations(CMC) on the CO_2 absorption into aqueous solutions in a bubble column is analyzed in the present work.The presence of these surfactants increased the gas-liquid interfacial area,and decreased the liquid phase mass transfer coefficient,but with significant different extent.The results indicated that the CMC can be a key parameter affecting the mass transfer of CO_2 absorption into a dilute aqueous solution of a surfactant.Sardeing's model was used to fit the experimental data successfully by re-correlating the parameters.

Heat Transfer Process of Bubble during the Occurrence of Cavitation in Hydraulic System

Thermal characteristic of cavitation has great influence on the process of occurrence,development and collapse of bubble in hydraulic system. By choosing the stage of bubble growth as the research object,combining with the characteristic of the process of bubble occurrence and development in hydraulic system, and ignoring the impact of thermal radiation,the heat transfer situation of bubble growth was analyzed under appropriate assumptions of thermodynamic conditions in the bubble generation and development process. The mathematical expression of the temperature change of bubble was deduced using thermodynamic principle. Through combining the expression with classic Rayleigh-Plesset Equation,numerical calculation was carried out and the temperature variation over time( or bubble radius) was obtained. The influences of convective heat transfer coefficient of bubble and polytropic exponent on the thermodynamic process of bubble were analyzed. Finally,the thermal characteristic of bubble growth after cavitation occurrence was summarized.

Bubble transfer on wettability-heterogeneous surfaces

Researches have investigated the formation, transportation and spreading of bubble on solid surface with specific wettability. However, bubble transfer on wettability-heterogeneous surfaces has been rarely reported, which also plays significant role in water electrolysis, heat transfer, micro-bubble collection, etc.In this work, we carefully investigate the behavior of bubble transfer from the aerophobic or aerophilic region to the superaerophilic region through fabricating the wettability-heterogenous surfaces. Surface energy was elucidated to be transformed to the kinetic energy during bubble transfer process. Theoretical analysis on the average velocity of bubble transfer was consistent with the experimental results.The influence of wettability of solid substrate, bubble volume and superaerophilic stripe width on bubble transfer are carefully investigated. Moreover, wettability-heterogeneous surfaces were explored to be applied in micro-CO_(2) bubble collection and H_(2) bubble removement in water splitting.