A mixed Langmuir-Blodgett film was built up by mixture 1:1 of bis (ethyldithio)tetrathiafulvalene-tetracyanoquinodimethane/stearie acid(BEDT-TTF- TCNQ/SA).A degree of charge transfer(CT)in complex of BEDT-TTF with TCN...A mixed Langmuir-Blodgett film was built up by mixture 1:1 of bis (ethyldithio)tetrathiafulvalene-tetracyanoquinodimethane/stearie acid(BEDT-TTF- TCNQ/SA).A degree of charge transfer(CT)in complex of BEDT-TTF with TCNQ was estimated at 0.477~0,486 by Raman frequencies of central Vc=c and Vc-s,The existence of charge transfer in BEDT-TTF-TCNQ has been confirmed by FTIR and XPS spectroscopy.展开更多
Serving as gas diffusion layers(GDLs),the thermal conductivity of carbon paper(CP)plays a significant role in the heat transfer management in fuel cells.In the present study,the effect of graphitization degree of CP o...Serving as gas diffusion layers(GDLs),the thermal conductivity of carbon paper(CP)plays a significant role in the heat transfer management in fuel cells.In the present study,the effect of graphitization degree of CP on its through plane thermal conductivity and in-plane thermal conductivity is investigated.The relationship between heat treatment temperatures(1800,2000,2200,2400 and 2500℃)and graphitization degree is also investigated by SEM,XRD and Raman measurements.A model for CP under different graphitization degree is suggested considering the thermal conductivity difference of carbon fiber and matrix carbon.The experimental and simulation results are compared.The results show that the graphitization degree has a significant impact on the through-plane thermal conductivity and in plane thermal conductivity.展开更多
A novel compliant mechanism with RPR degrees of freedom(DOF)is proposed where R and P represent rotation and translation DOFs,respectively.The proposed compliant mechanism is obtained from dimension synthesizing a 2-R...A novel compliant mechanism with RPR degrees of freedom(DOF)is proposed where R and P represent rotation and translation DOFs,respectively.The proposed compliant mechanism is obtained from dimension synthesizing a 2-RPU-UPR rigid parallel mechanism with the method of optimization of motion/force transfer characteristic.R,P and U represent rotation,translation and universal pairs,respectively.Firstly,inverse kinematics and Jacobian matrix are analyzed for the dimensional synthesis.Then,output transmission indexes of branches in the parallel mechanism are given.Dimensional synthesis is completed based on the normalized design parameter.And optimization of flexure joints based on constrained energy is carried out.Afterwards,the novel compliant mechanism is obtained by direct replacing method.Mechanical model of the compliant mechanism including static stiffness and input stiffness is built based on the pseudo-rigid body modeling method and virtual work principle.Finally,FEA simulation by Ansys Workbench is carried out to verify DOF,effectiveness of the dimension synthesis,and compliant model.Optimization of motion/force transfer characteristic is first applied for the design of compliant mechanisms to suppress drift of rotation axis in the paper.展开更多
承接产业转移对促进区域协调发展具有重要意义。基于2013—2021年湘南湘西示范区数据,通过构建承接产业转移能力评价指标体系,使用熵权逼近理想解排序法(technique for order preference by similarity to an ideal solution,TOPSIS法)...承接产业转移对促进区域协调发展具有重要意义。基于2013—2021年湘南湘西示范区数据,通过构建承接产业转移能力评价指标体系,使用熵权逼近理想解排序法(technique for order preference by similarity to an ideal solution,TOPSIS法)测度承接能力;再利用障碍度模型识别影响承接能力的关键因素。研究结果表明,2013—2021年,示范区内六个地区承接产业转移能力均呈现逐年提升态势,但存在明显差距;邮电业务量、实际利用外资、普通高等学校在校学生数等是阻碍承接能力提升的关键因素。最后根据研究结论提出相应的建议。展开更多
为揭示南宁市土地利用的时空变化规律,运用地理信息系统(Geographic information system,GIS)技术和土地利用动态度、利用程度和转移矩阵等方法,深入分析1990—2020年南宁市土地利用的时空演变特征。结果表明,1990—2020年南宁市各土地...为揭示南宁市土地利用的时空变化规律,运用地理信息系统(Geographic information system,GIS)技术和土地利用动态度、利用程度和转移矩阵等方法,深入分析1990—2020年南宁市土地利用的时空演变特征。结果表明,1990—2020年南宁市各土地利用类型的变化明显、土地利用变化的总体速度加快,建设用地和未利用地增加且表现为增速,耕地、林地、草地和水域减少且表现为减速;南宁市的土地利用程度处于中等水平,随着人为活动对土地的不断干扰和影响,土地利用程度水平呈逐渐升高的趋势;30年间南宁市共有1051.61 km2的土地利用类型发生转移,其中建设用地和未利用地表现为净转入特征,耕地、林地、草地、水域表现为净转出特征。展开更多
文摘A mixed Langmuir-Blodgett film was built up by mixture 1:1 of bis (ethyldithio)tetrathiafulvalene-tetracyanoquinodimethane/stearie acid(BEDT-TTF- TCNQ/SA).A degree of charge transfer(CT)in complex of BEDT-TTF with TCNQ was estimated at 0.477~0,486 by Raman frequencies of central Vc=c and Vc-s,The existence of charge transfer in BEDT-TTF-TCNQ has been confirmed by FTIR and XPS spectroscopy.
基金Projects(2020 JJ 5142,2019 RS 2067)supported by the Science and Technology Planning Project of Hunan Province,ChinaProject(19 C 0581)supported by the Research Foundation of Education Bureau of Hunan Province,China。
文摘Serving as gas diffusion layers(GDLs),the thermal conductivity of carbon paper(CP)plays a significant role in the heat transfer management in fuel cells.In the present study,the effect of graphitization degree of CP on its through plane thermal conductivity and in-plane thermal conductivity is investigated.The relationship between heat treatment temperatures(1800,2000,2200,2400 and 2500℃)and graphitization degree is also investigated by SEM,XRD and Raman measurements.A model for CP under different graphitization degree is suggested considering the thermal conductivity difference of carbon fiber and matrix carbon.The experimental and simulation results are compared.The results show that the graphitization degree has a significant impact on the through-plane thermal conductivity and in plane thermal conductivity.
基金National Natural Science Foundation of China(Grant No.51975007).
文摘A novel compliant mechanism with RPR degrees of freedom(DOF)is proposed where R and P represent rotation and translation DOFs,respectively.The proposed compliant mechanism is obtained from dimension synthesizing a 2-RPU-UPR rigid parallel mechanism with the method of optimization of motion/force transfer characteristic.R,P and U represent rotation,translation and universal pairs,respectively.Firstly,inverse kinematics and Jacobian matrix are analyzed for the dimensional synthesis.Then,output transmission indexes of branches in the parallel mechanism are given.Dimensional synthesis is completed based on the normalized design parameter.And optimization of flexure joints based on constrained energy is carried out.Afterwards,the novel compliant mechanism is obtained by direct replacing method.Mechanical model of the compliant mechanism including static stiffness and input stiffness is built based on the pseudo-rigid body modeling method and virtual work principle.Finally,FEA simulation by Ansys Workbench is carried out to verify DOF,effectiveness of the dimension synthesis,and compliant model.Optimization of motion/force transfer characteristic is first applied for the design of compliant mechanisms to suppress drift of rotation axis in the paper.
文摘承接产业转移对促进区域协调发展具有重要意义。基于2013—2021年湘南湘西示范区数据,通过构建承接产业转移能力评价指标体系,使用熵权逼近理想解排序法(technique for order preference by similarity to an ideal solution,TOPSIS法)测度承接能力;再利用障碍度模型识别影响承接能力的关键因素。研究结果表明,2013—2021年,示范区内六个地区承接产业转移能力均呈现逐年提升态势,但存在明显差距;邮电业务量、实际利用外资、普通高等学校在校学生数等是阻碍承接能力提升的关键因素。最后根据研究结论提出相应的建议。
文摘为揭示南宁市土地利用的时空变化规律,运用地理信息系统(Geographic information system,GIS)技术和土地利用动态度、利用程度和转移矩阵等方法,深入分析1990—2020年南宁市土地利用的时空演变特征。结果表明,1990—2020年南宁市各土地利用类型的变化明显、土地利用变化的总体速度加快,建设用地和未利用地增加且表现为增速,耕地、林地、草地和水域减少且表现为减速;南宁市的土地利用程度处于中等水平,随着人为活动对土地的不断干扰和影响,土地利用程度水平呈逐渐升高的趋势;30年间南宁市共有1051.61 km2的土地利用类型发生转移,其中建设用地和未利用地表现为净转入特征,耕地、林地、草地、水域表现为净转出特征。