Effect of bubble morphology and behavior on power consumption in non-Newtonian fluids’aeration process

Due to a prolonged operation time and low mass transfer efficiency, the primary challenge in the aeration process of non-Newtonian fluids is the high energy consumption, which is closely related to the form and rate of impeller, ventilation, rheological properties and bubble morphology in the reactor. In this perspective, through optimal computational fluid dynamics models and experiments, the relationship between power consumption, volumetric mass transfer rate(kLa) and initial bubble size(d0) was constructed to establish an efficient operation mode for the aeration process of non-Newtonian fluids. It was found that reducing the d0could significantly increase the oxygen mass transfer rate, resulting in an obvious decrease in the ventilation volume and impeller speed. When d0was regulated within 2-5 mm,an optimal kLa could be achieved, and 21% of power consumption could be saved, compared to the case of bubbles with a diameter of 10 mm.

Strategies for Rational Design of High-Power Lithium-ion Batteries

Lithium-ion batteries(LIBs)have shown considerable promise as an energy storage system due to their high conversion efficiency,size options(from coin cell to grid storage),and free of gaseous exhaust.For LIBs,power density and energy density are two of the most important parameters for their practical use,and the power density is the key factor for applications such as fast-charging electric vehicles,high-power portable tools,and power grid stabilization.A high rate of performance is also required for devices that store electrical energy from seasonal or irregular energy sources,such as wind energy and wave energy.Significant efforts have been made over the last several years to improve the power density of LIBs through anodes,cathodes,and electrolytes,and much progress has been made.To provide a comprehensive picture of these recent achievements,this review discusses the progress made in high-power LIBs from 2013 to the present,including general and fundamental principles of high-power LIBs,challenges facing LIB development today,and an outlook for future LIB development.

THE CALCULATION OF RATE CONSTANT OF ELECTRON TRANSFER REACTION AT ELECTRODES

After the electron transfers from the metal electrode to the Fe3+(H2O)(6) ion, the free energy of activation of this electron transfer reaction is calculated, then using the transition probability which is calculated by the perturbed degeneration theory and the Fermi golden rule,, the rate constant is gotten. Compared with the experimental results, it is satisfactory.

Research on development of surface-roughness variation and control technology of the automotive plates and rolls

Surface roughness considerably influences the stamping and coating performance of the automotive plates;however,the surface roughness of the automotive plates is transferred from the roll during the rolling process.Therefore,the variation and control technology regarding the roughness of the automotive plates and rolls has drawn increasing attention from researchers in China and around the globe.In this study,the research methods,analytical techniques,prediction models,transfer rules,and control technologies regarding the surface roughness of the automotive plates and rolls were reviewed.Among these,an online measurement system for automotive-plate and roll surface roughness has been applied to the production lines of Germany,China,Belgium,Holland,Austria,and other countries and has achieved remarkable results.Online measurement and timely feedback regarding the automotive-plate and roll surface roughness are needed to ensure favorable conditions for the establishment of automotive-plate roughness-control measurement.

Simultaneous nitrogen and phosphor removal in an aerobic submerged membrane bioreactor

Simultaneous nitrification and denitrification （SND） effect and phosphor removal were investigated in a one-staged aerobic submerged membrane bioreactor on pilot-scale with mixed liquor suspended solids （MLSS） 19--20 g/L. The effects of DO concentration, sludge floc size distribution on SND were studied. Test results suggested that SND was successfully performed in the membrane bioreactor （MBR） and about 70% total nitrogen removal efficiency was achieved when DO concentration was set to 0.2-- 0.3 mg/L. The main mechanisms governing SND were the suitable sludge floc size and the low DO concentration which was caused by low oxygen transfer rate with such a high MLSS concentration in the MBR. In the meantime, phosphor removal was also studied with polymer ferric sulfate （PFS） addition and 14 mg/L dosage of PFS was proper for the MBR to remove phosphor. PFS addition also benefited the MBR operation owing to its reduction of extracellular polymer substances （EPS） of mixed liquor.

Diagnostic Value of Quantitative Parameters of DCE-MRI in Endometrial Carcinoma and Its Correlation with Clinicopathological Factors

In the study,108 patients with endometrial cancer were selected as the observation group,and 105 patients with benign endometrial lesions were selected as the control group.After DCE-MRI examination,it was found that the volume transfer constant(K^(trans)),rate constant(K_(e))and extracellular space volume ratio(V_(e))in the observation group were higher than those in the control group(P<0.05).The area under curve(AUC)of combined K^(trans),K_(e) and V_(e) values in the diagnosis of endometrial cancer was 0.841.The values of K^(trans),K_(e )and V_(e) were positively correlated with the clinical stage and the degree of muscular invasion,but negatively correlated with the degree of differentiation(P<0.05).The results of the study suggested that DCE-MRI quantitative parameters have a certain value in the differential diagnosis of endometrial cancer,which helped to further distinguish the degree of muscular invasion,clinical stage,and differentiation of endometrial cancer patients.

Effects of fluid recirculation on mass transfer from the arterial surface to flowing blood

The effect of disturbed flow on the mass trans- fer from arterial surface to flowing blood was studied nu- merically, and the results were compared with that of our previous work. The arterial wall was assumed to be vis- coelastic and the blood was assumed to be incompressible and non-Newtonian fluid, which is more close to human arte- rial system. Numerical results indicated that the mass trans- fer from the arterial surface to flowing blood in regions of disturbed flow is positively related with the wall shear rates and it is significantly enhanced in regions of disturbed flow with a local minimum around the reattachment point which is higher than the average value of the downstream. There- fore, it may be implied that the accumulation of cholesterol or lipids within atheromatous plaques is not caused by the reduced efflux of cholesterol or lipids, but by the infiltration of the LDL （low-density lipoprotein） from the flowing blood to the arterial wall.

One Method for Improving RAID5 Performance

As a kind of parallel storage system, RAID5 has been becoming a popular solution for providing better performance at low cost and without sacrificing much redundant data, its main disadvantage is poor performance. It is a general method to improve RAID5 performance by using cache. However, it often happens that the data is not hit in cache, in this case, the RAID5 performance also will be very poor. The method based on combination of disk I/O operations has been proposed for impriving the I/O response time through reducing the number of low-level operations. According to theoretic analysis and experimental test, we find that RAID5 access time and data transfer rate could be largely improved than conventional method.

Modeling of Heat Transfer and Steam Condensation Inside a Horizontal Flattened Tube

This work investigates the steam condensation phenomena in an air-cooled condenser.The considered horizontal flattened tube has a 30 mm hydraulic diameter,and its length is a function of the steam quality with a limit value between 0.95 and 0.05.The mass flow rate ranges from 4 to 40 kg/m^(2).s with a saturated temperature spanning an interval from 40°C to 80°C.A special approach has been implemented using the Engineering Equation Solver(EES)to solve a series of equations for the two-phase flow pattern and the related heat transfer coefficients.A wavy-stratified structure of the two-phase flow has been found when the mass rate was between 4 and 24 kg/m^(2).s.In contrast,an initially annular flow is gradually converted into a wavy stratified flow(due to the condensation process taking place inside the flattened tube)when the considered range ranges from 32 to 40 kg/m^(2).s.

The Intermolecular Interaction in Self-Assembled Monolayers on Gold Electrode

The intermolecular interaction in an azobenzene self-assembled monolayers (SAMs) on gold electrode was investigated by controlling the assembling time and using mixed self-assembled techniques, and the variation of apparent electron transfer rate constant (k(s)) of azobenzene SAMs with different molecular packing density is reported.

Similarity Solutions for Laminar Boundary Layer Flow of Darcian Fluid over Horizontal Plate with a Convective Boundary Condition

This paper considers the problem of hydrodynamics and thermal boundary layers of Darcy flow over horizontal surface embedded in a porous medium. The solutions of such problems for the cases of uniform surface temperature and variable surface temperature have been studied and analysed in many papers. This paper, however, attempts to find similarity solutions for the Darcy flow problem with a convective boundary condition at the plate surface. It is found that the solution is possible when the heat transfer coefficient is proportional to x–2/3. The numerical solutions thus obtained are analyzed for a range of values of the parameter characterizing the hot fluid convection process. Analytical expressions are provided for local surface heat flux and total surface heat transfer rate while the flow variables are discussed graphically.

Lattice Boltzmann Simulation of Magnetic Field Effect on Electrically Conducting Fluid at Inclined Angles in Rayleigh-Bénard Convection

The magneto-hydrodynamics(MHD)effect is studied at different inclined angles in Rayleigh-Bénard(RB)convection inside a rectangular enclosure using the lattice Boltzmann method(LBM).The enclosure is filled with electrically conducting fluids of different characteristics.These characteristics are defined by Prandtl number,Pr.The considered Pr values for this study are 10 and 70.The influence of other dimensionless parameters Rayleigh numbers Ra=10^(3);10^(4);10^(5);10^(6) and Hartmann numbers Ha=0,10,25,50,100,on fluid flow and heat transfer,are also investigated considering different inclined anglesφof magnetic field by analyzing computed local Nusselt numbers and average Nusselt numbers.The results of the study show the undoubted prediction capability of LBM for the current problem.The simulated results demonstrate that the augmentation in heat transfer is directly related to Ra values,but it is opposite while observing the characteristics of Ha values.However,it is also found thatφhas a significant impact on heat transfer for different fluids.Besides,isotherms are found to be always parallel to the horizontal axis at Ra=10^(3) as conduction overcomes the convection in the heat transfer,but this behaviour is not seen at Ra=10^(4) when Ha>25.Furthermore,at Ra=10^(6),oscillatory instability appears but LBM is still able to provide a complete map of this predicted behavior.An appropriate validation with previous numerical studies demonstrates the accuracy of the present approach.

Research on the Pricing of Convertible bonds in China Migration risk based on credit rating

At present,further research and exploration on credit risks are being carried out in the global field,and increasingly profound modem credit risks are exposed to the bond market.This requires that we cannot ignore the impact of credit rating migration risk on bond pricing,so as to adapt to the sustainable and healthy development of the bond market under the new normal of China's economy.The innovation point of this paper is to try to analyze the pricing of Convertible bonds in China from the perspective of credit rating migration risk.Tsiveriotis and Femandes(1998)model is selected,and the credit risk in the model is assumed to be caused by the credit rating migration risk,and the credit spread is used to measure the credit rating migration risk.The research conclusion of this paper is as follows:First,it is valid to consider the risk of credit rating migration in the TF(1998)model.The market price of convertible bonds is on average 1.22% higher 1han the theoretical value of the model.In general,the theoretical value obtained from the model has little deviation from the market price,and has a good fitting degree.Second,from the Angle of credit rating,the selection of 32 samples of convertible bonds only empirical research shows that the credit rating of AA-convertible bonds average deviation rate is negative,suggest that the credit rating of AA-the phenomenon of convertible bonds value is underestimated,and AAA credit rating to AA,AA+,the average deviation rate of convertible bonds is positive,that credit rating AA(containing AA)more convertible bond value is overrated phenomenon,and the higher the credit rating of the average deviation rate of convertible bond,the greater the overvalued levels.It has certain guiding significance for participants in the convertible bond market.

Constructal design of printed circuit recuperator for S-CO_(2)cycle via multi-objective optimization algorithm

Based on a constructal theory,the structure design of a printed circuit recuperator with a semicircular heat transfer channel for supercritical CO_(2)cycle is carried out.First,a complex function composed of weighted sum of the reciprocal of total heat transfer rate and total pumping power consumption is regarded as an optimization objective,and total volumes of the recuperator and heat transfer channel are regarded as constraints.The optimal heat transfer channel radius and minimum complex function of the recuperator are obtained.It turns out that heat transfer rate,pumping power consumption,and complex function under the optimal construct of recuperator are reduced by 15.10%,82.44%,and 32.33%,respectively.There exists the optimal single plate channel number which results in the double minimum complex function.Second,for the purpose of minimizing the reciprocal of heat transfer rate and pumping power consumption,NSGA-II algorithm is used to achieve multi-objective optimization,and the minimum deviation index derived by the decision-making methods is 0.076,which can be taken as multi-objective optimal design scheme for printed circuit recuperator with semicircular heat transfer channels.The findings presented here can serve as theoretical recommendations for the structure design of printed circuit recuperator.

Cold Simulation of Oxygen Transfer Rate in BOF

By measuring the mass transfer coefficient of benzoic acid between water and oil, the oxygen transfer rate in BOF bath was researched, and the influence of top and bottom blowing gas flow rate on the mass transfer between metal and slag was discussed. The results show that with increasing the bottom blowing gas flow rate under the conditions of fixed top blowing, the mass transfer rate evidently increases, and the influence of fixed top blowing on the mass transfer is 10% of bottom blowing. The stirring intensity was determined as a function of top blowing gas flow rate, bottom blowing gas flow rate, and lance height. The equation of the mass transfer coefficient between metal and slag was established. The relationship between the emulsification ratio of oil to water and the bottom blowing gas flow rate under the conditions of top and bottom blowing was obtained. The result shows that with the increase in the bottom blowing gas flow rate, the emulsification ratio increases linearly, which increases the mass transfer rate of benzoic acid between water and oil.

Determination of real-time oxygen transfer rate based on an electrochemical method

The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;however,it is difficult to be studied in situ.Here,a new method of measuring the oxygen transfer rate at the gas-slag and slag-metal interfaces was reported based on electrochemical analyses.The interfacial oxygen transfer rate in the smelting process of Inconel 718 superalloy was investigated at 1723,1773,1823,and 1873 K.The experimental results show that the electrochemical method can measure the real-time oxygen content;hence,this method is promising in controlling the oxygen content in alloys.As the temperature increased,both the equilibrium oxygen content and the rate of oxygen absorption increased significantly,and the increase was the most obvious when the temperature was 1873 K.The possible reason is that the increase in temperature weakens the mass transfer resistance of the electric double layer at the interface,thus accelerating the oxygen transfer rate.

Electron transfer dynamics in Schottky junction photocatalyst during electron donor-assisted hydrogen production

Electron donors(EDs)are widely used to improve the H 2 production performance of Schottky junction photocatalysts,but the functions of EDs are still unknown from the perspective of electron transfer dy-namics.Herein,Pt nanocluster-decorated CdS nanorod is successfully prepared to construct a typical CdS/Pt Schottky junction.Pt nanoclusters with a diameter of∼2 nm are deposited on the surface of CdS nanorods by in situ photoreduction at sub-zero temperature.The CdS/Pt photocatalyst using lactic acid shows a higher H_(2)production rate of 4762μmol g^(-1)h^(-1)compared to that using methanol,tri-ethanolamine,and glycerol.To understand the cause,the dynamics of photogenerated carriers in CdS/Pt photocatalysts during ED-assisted H_(2)production are revealed by femtosecond transient absorption spec-troscopy.Among the four organic EDs,lactic acid enables the fastest electron transfer rate of 1.8×10^(9)s^(-1)and the highest electron transfer efficiency of 76%at the CdS/Pt interface due to the most efficient hole consumption.This work sheds light on the importance of efficient interfacial electron transfer for im-proving the photocatalytic performance of Schottky junction photocatalysts.

An efficient and safe platform based on the tube-in-tube reactor for implementing gas-liquid processes in flow

Recently,the continuous tube-in-tube reactor based on the Teflon AF membrane is emerging as a powerful toolkit for accelerating gas-liquid mass transfer and reaction rate.Because of its large gas-liquid interfacial area and short mass transfer distance,the reactor can allow a fast gas-liquid mass transfer without direct contact between gas and liquid phases,offering an efficient and safe platform for implementing gas-liquid reaction and rapid determination of gas-liquid parameters.In this review,a detailed description and construction method of this reactor are pro-vided.Then,the recent advancements of the tube-in-tube reactor in fundamental studies and practical applica-tions in gas-involved chemical reactions and biosynthetic processes are discussed.Finally,a perspective on future potential applications of such flow reactors is provided.

Modeling of Strip Heating Process in Vertical Continuous Annealing Furnace

The mechanism for heat transfer of radiation is usually adopted to heat strip in vertical continuous annealing furnace. The rate of heat transfer among strip and other objects can be hugely affected by the parameters of strip speed, geometry factors and radiating characteristic of surfaces of strip, radiating tubes and walls of furnace. A model including all parameters is proposed for calculating the heat transfer coefficient, predicting the strip tempera- ture and boundary temperature of strip through analyzing these parameters. The boundary temperature is a important datum and different from average arithmetic value of temperature of strip and temperature in furnace. Also, the model can be used to analyze the relation for temperature of strip and heat transfer coefficient, total heat transfer quantity and heating time. The model is built by using the radiating heat transfer rate, the Newtonrs law of cooling, and lumped system analysis. The results of calculation are compared to the data from production line. The comparisons indicate that the model can well predict the heating process. The model is already applied for process control in pro- duction line. Also, this research will provide a new method for analyzing the radiation heat transfer.

Free and Hidden Fumonisins in Hordei Fructus Germinatus and Their Transfer to the Decoction

Objective:This study aimed to determine the free and hidden fumonisins in Hordei Fructus Germinatus samples and to investigate the transfer rates of these mycotoxins from Hordei Fructus Germinatus to its decoction.Materials and Methods:The contamination levels of free and hidden fumonisins in a total of 60 Hordei Fructus Germinatus samples were analyzed using high-performance liquid chromatography coupled to tandem mass spectrometry(LC-MS/MS).The decoction procedure was simulated with a highly contaminated Hordei Fructus Germinatus sample,and fumonisins in the resulting decoction preparation were determined by LC-MS/MS.Results:Among all the samples,8.3%were contaminated with free fumonisins(FB1 and/or FB2)and 13.3%were contaminated with total fumonisins(free+hidden,measured as hydrolyzed fumonisins,i.e.,HFB1 and/or HFB2).The concentrations of FB1 and HFB1 reached up to 83 and 95μg/kg,respectively,whereas FB2 and HFB2 were detected only in traces.The transfer rates of free and total fumonisins from Hordei Fructus Germinatus to the decoction were 71.8%and 83.3%for FB1 and FB2,respectively.In comparison,much lower transfer rates were found for total fumonisins,i.e.,38.2%and 24.7%for HFB1 and HFB2,respectively.Conclusion:The incidence and contamination levels of free and hidden fumonisins in Hordei Fructus Germinatus samples were generally low.Regarding decoction preparation,the transfer rates of free fumonisins into the decoction were high,whereas a large part of hidden fumonisins were retained in Hordei Fructus Germinatus rather than migrating into water.