We investigated the role of metal atomization and solvent decomposition into reductive species and carbon clusters in the phase formation of transition-metal carbides(TMCs;namely,Co_(3)C,Fe_(3)C,TiC,and MoC)by pulsed ...We investigated the role of metal atomization and solvent decomposition into reductive species and carbon clusters in the phase formation of transition-metal carbides(TMCs;namely,Co_(3)C,Fe_(3)C,TiC,and MoC)by pulsed laser ablation of Co,Fe,Ti,and Mo metals in acetone.The interaction between carbon s-p-orbitals and metal d-orbitals causes a redistribution of valence structure through charge transfer,leading to the formation of surface defects as observed by X-ray photoelectron spectroscopy.These defects influence the evolved TMCs,making them effective for hydrogen and oxygen evolution reactions(HER and OER)in an alkaline medium.Co_(3)C with more oxygen affinity promoted CoO(OH)intermediates,and the electrochemical surface oxidation to Co_(3)O_(4)was captured via in situ/operando electrochemical Raman probes,increasing the number of active sites for OER activity.MoC with more d-vacancies exhibits strong hydrogen binding,promoting HER kinetics,whereas Fe_(3)C and TiC with more defect states to trap charge carriers may hinder both OER and HER activities.The results show that the assembled membrane-less electrolyzer with Co_(3)C∥Co_(3)C and MoC∥MoC electrodes requires~2.01 and 1.99 V,respectively,to deliver a 10 mA cm−2 with excellent electrochemical and structural stability.In addition,the ascertained pulsed laser synthesis mechanism and unit-cell packing relations will open up sustainable pathways for obtaining highly stable electrocatalysts for electrolyzers.展开更多
This paper describes a three-dimensional(3D) numerical analysis of a test embankment on geotextileencased columns(GECs), in comparison with two-dimensional(2D) axisymmetric and plane strain analyses. The 3D numerical ...This paper describes a three-dimensional(3D) numerical analysis of a test embankment on geotextileencased columns(GECs), in comparison with two-dimensional(2D) axisymmetric and plane strain analyses. The 3D numerical analysis was performed considering a rectangular strip under the embankment centerline. The 2D analysis was also carried out using axisymmetric unit cell and plane strain approaches.Numerical results indicated that the adopted 3D strip model represented well the measured deformations and pore pressure evolution during embankment construction and post-contraction periods.Unlike the unit cell model, both plane strain and 3D analyses could properly determine the settlement profile along the embankment base as well as the profile of the horizontal soil deformation beneath the embankment toes. The plane strain analysis, however, was not able to compute the geotextile ring force which might be simply calculated using the axisymmetric unit cell approach. The paper also showed that, due to horizontal boundary fixities applied to the embankment borders, the unit cell model clearly underestimated the tension developed in the basal geogrid.展开更多
Nine square concrete columns including 6 CFRP/ECCs and 3 concrete columns are prepared,which have cross-section of 200 mm×200 mm and height of 600 mm.The CFRP tubes with fibers oriented at hoop direction were man...Nine square concrete columns including 6 CFRP/ECCs and 3 concrete columns are prepared,which have cross-section of 200 mm×200 mm and height of 600 mm.The CFRP tubes with fibers oriented at hoop direction were manufactured to have 3 or 5 layers of CFRP with 10 mm, 20 mm,or 40 mm rounding corner radii at vertical edges.A 100 mm overlap in the direction of fibers was provided to ensure proper bond.Uniaxial compression tests were conducted to investigate the compressive behavior.It is evident that the CFRP tube confinement can improve the behavior of concrete core,in terms of axial compressive strength or axial deformability.Test results show that the stress-strain behavior of CFRP/ECCs vary with different confinement parameters,such as the number of confinement layers and the rounding corner radius.展开更多
Tests of 4 simply supported unbonded prestressed truss concrete composite beams encased with circular steel tube were carried out. It is found that the ratio of the stress increment of the unbonded tendon to that of t...Tests of 4 simply supported unbonded prestressed truss concrete composite beams encased with circular steel tube were carried out. It is found that the ratio of the stress increment of the unbonded tendon to that of the tensile steel tube is 0.252 during the using stage,and the average crack space of beams depends on the ratio of the sum of the bottom chord steel tube's outside diameter and the secondary bottom chord steel tube's section area to the effective tensile concrete area. The coefficient of uneven crack distribution is 1.68 and the formula for the calculation of crack width is established. Test results indicate that the ultimate stress increment of unbonded tendon in the beams decreases in linearity with the increase of the composite reinforcement index β0. The pure bending region of beams accords with the plane section assumption from loading to failure. The calculation formula of ultimate stress increment of the unbonded tendon and the method to calculate the bearing capacity of normal section of beams have been presented. Besides,the method to calculate the stiffness of this sort of beams is brought forward as well.展开更多
Sustainable production of H2 through electrochemical water splitting is of great importance in the foreseeable future.Transition-metal metaphosphates(TMMPs)have a three-dimensional(3D)open-framework structure and a hi...Sustainable production of H2 through electrochemical water splitting is of great importance in the foreseeable future.Transition-metal metaphosphates(TMMPs)have a three-dimensional(3D)open-framework structure and a high content of P(which exists as PO3-),and therefore have been recognized as highly efficient catalysts for oxygen evolution reaction(OER)and the bottleneck of electrochemical water splitting.Furthermore,TMMPs can also contribute to hydrogen evolution reaction(HER)in alkaline and neutral media by facilitating water dissociation,and thus,overall water splitting can be achieved using this kind of material.In this timely review,we summarize the recent advances in the synthesis of TMMPs and their applications in OER and HER.We present a brief introduction of the structure and synthetic strategies of TMMPs in the first two parts.Then,we review the latest progress made in research on TMMPs as OER,HER,and overall water-splitting electrocatalysts.In this part,the intrinsic activity of TMMPs as well as the current strategy for improving the catalytic activity will be discussed systematically.Finally,we present the future opportunities and the remaining challenges for the application of TMMPs in the electrocatalysis field.展开更多
Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the c...Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical performance.In this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle effect.OM-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain catenation.The OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g-1 after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g-1 even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g-1).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.展开更多
基金National Research Foundation of Korea,Grant/Award Numbers:2019H1D3A1A01071209,2021R1I1A1A01060380,2022R1A2C2010686,2022R1A4A3033528Korea Basic Science Institute,Grant/Award Numbers:2019R1A6C1010042,2021R1A6C103A427。
文摘We investigated the role of metal atomization and solvent decomposition into reductive species and carbon clusters in the phase formation of transition-metal carbides(TMCs;namely,Co_(3)C,Fe_(3)C,TiC,and MoC)by pulsed laser ablation of Co,Fe,Ti,and Mo metals in acetone.The interaction between carbon s-p-orbitals and metal d-orbitals causes a redistribution of valence structure through charge transfer,leading to the formation of surface defects as observed by X-ray photoelectron spectroscopy.These defects influence the evolved TMCs,making them effective for hydrogen and oxygen evolution reactions(HER and OER)in an alkaline medium.Co_(3)C with more oxygen affinity promoted CoO(OH)intermediates,and the electrochemical surface oxidation to Co_(3)O_(4)was captured via in situ/operando electrochemical Raman probes,increasing the number of active sites for OER activity.MoC with more d-vacancies exhibits strong hydrogen binding,promoting HER kinetics,whereas Fe_(3)C and TiC with more defect states to trap charge carriers may hinder both OER and HER activities.The results show that the assembled membrane-less electrolyzer with Co_(3)C∥Co_(3)C and MoC∥MoC electrodes requires~2.01 and 1.99 V,respectively,to deliver a 10 mA cm−2 with excellent electrochemical and structural stability.In addition,the ascertained pulsed laser synthesis mechanism and unit-cell packing relations will open up sustainable pathways for obtaining highly stable electrocatalysts for electrolyzers.
基金Brazilian Funding Agencies CNPq, CAPES, FAPERJ and MCT/INCTREAGEO provided the financial support to the present study
文摘This paper describes a three-dimensional(3D) numerical analysis of a test embankment on geotextileencased columns(GECs), in comparison with two-dimensional(2D) axisymmetric and plane strain analyses. The 3D numerical analysis was performed considering a rectangular strip under the embankment centerline. The 2D analysis was also carried out using axisymmetric unit cell and plane strain approaches.Numerical results indicated that the adopted 3D strip model represented well the measured deformations and pore pressure evolution during embankment construction and post-contraction periods.Unlike the unit cell model, both plane strain and 3D analyses could properly determine the settlement profile along the embankment base as well as the profile of the horizontal soil deformation beneath the embankment toes. The plane strain analysis, however, was not able to compute the geotextile ring force which might be simply calculated using the axisymmetric unit cell approach. The paper also showed that, due to horizontal boundary fixities applied to the embankment borders, the unit cell model clearly underestimated the tension developed in the basal geogrid.
文摘Nine square concrete columns including 6 CFRP/ECCs and 3 concrete columns are prepared,which have cross-section of 200 mm×200 mm and height of 600 mm.The CFRP tubes with fibers oriented at hoop direction were manufactured to have 3 or 5 layers of CFRP with 10 mm, 20 mm,or 40 mm rounding corner radii at vertical edges.A 100 mm overlap in the direction of fibers was provided to ensure proper bond.Uniaxial compression tests were conducted to investigate the compressive behavior.It is evident that the CFRP tube confinement can improve the behavior of concrete core,in terms of axial compressive strength or axial deformability.Test results show that the stress-strain behavior of CFRP/ECCs vary with different confinement parameters,such as the number of confinement layers and the rounding corner radius.
文摘Tests of 4 simply supported unbonded prestressed truss concrete composite beams encased with circular steel tube were carried out. It is found that the ratio of the stress increment of the unbonded tendon to that of the tensile steel tube is 0.252 during the using stage,and the average crack space of beams depends on the ratio of the sum of the bottom chord steel tube's outside diameter and the secondary bottom chord steel tube's section area to the effective tensile concrete area. The coefficient of uneven crack distribution is 1.68 and the formula for the calculation of crack width is established. Test results indicate that the ultimate stress increment of unbonded tendon in the beams decreases in linearity with the increase of the composite reinforcement index β0. The pure bending region of beams accords with the plane section assumption from loading to failure. The calculation formula of ultimate stress increment of the unbonded tendon and the method to calculate the bearing capacity of normal section of beams have been presented. Besides,the method to calculate the stiffness of this sort of beams is brought forward as well.
基金The authors gratefully thank the National Natural Science Foundation of China （51308070, 51408070, and 51378080）, the National Basic Research Program of China （2015CB057702）, the Key Discipline Fund of Creative Project of Bridge and Tunnel Engineering （13ZDXK04） from the Changsha University of Science and Technology, the Open Fund of the Hunan Province University Key Laboratory of Bridge Engineering （13KA04）, and the Applied Basic Research Program of Shanxi Province for their support,
基金the Natural Science Foundation of China(Grant Nos.21871065,22209129,and 22071038)the Heilongjiang Touyan Team(HITTY-20190033)+3 种基金High-Level Innovation and Entrepreneurship(QCYRCXM-2022-123)the Talent Project of Qinchuangyuan and Interdisciplinary Research Foundation of HIT(IR2021205)Professor Li acknowledges the financial support from the“Young Talent Support Plan”of Xi'an Jiaotong University(HG6J024)the“Young Talent Lift Plan”of Xi'an city(095920221352).
文摘Sustainable production of H2 through electrochemical water splitting is of great importance in the foreseeable future.Transition-metal metaphosphates(TMMPs)have a three-dimensional(3D)open-framework structure and a high content of P(which exists as PO3-),and therefore have been recognized as highly efficient catalysts for oxygen evolution reaction(OER)and the bottleneck of electrochemical water splitting.Furthermore,TMMPs can also contribute to hydrogen evolution reaction(HER)in alkaline and neutral media by facilitating water dissociation,and thus,overall water splitting can be achieved using this kind of material.In this timely review,we summarize the recent advances in the synthesis of TMMPs and their applications in OER and HER.We present a brief introduction of the structure and synthetic strategies of TMMPs in the first two parts.Then,we review the latest progress made in research on TMMPs as OER,HER,and overall water-splitting electrocatalysts.In this part,the intrinsic activity of TMMPs as well as the current strategy for improving the catalytic activity will be discussed systematically.Finally,we present the future opportunities and the remaining challenges for the application of TMMPs in the electrocatalysis field.
基金Ministry of Trade,Industry and Energy,Grant/Award Number:20010095Korea Evaluation Institute of Industrial Technology,Grant/Award Number:20012341。
文摘Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy density.However,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical performance.In this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle effect.OM-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain catenation.The OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g-1 after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g-1 even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g-1).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.
