The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but challenging.Herein,a delaminated aerogel film(DAF)is fab...The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but challenging.Herein,a delaminated aerogel film(DAF)is fabricated through filtration-induced delaminated gelation and ambient drying.The delaminated gelation process involves the assembly of fluorinated cellulose nanofiber(FCNF)at the solid-liquid interface between the filter and the filtrate during filtration,resulting in the formation of lamellar FCNF hydrogels with strong intra-plane and weak interlayer hydrogen bonding.By exchanging the solvents from water to hexane,the hydrogen bonding in the FCNF hydrogel is further enhanced,enabling the formation of the DAF with intra-layer mesopores upon ambient drying.The resulting aerogel film is lightweight and ultra-flexible,which pos-sesses desirable properties of high visible-light transmittance(91.0%),low thermal conductivity(33 mW m^(-1) K^(-1)),and high atmospheric-window emissivity(90.1%).Furthermore,the DAF exhibits reduced surface energy and exceptional hydrophobicity due to the presence of fluorine-containing groups,enhancing its durability and UV resistance.Consequently,the DAF has demonstrated its potential as solar-thermal regulatory cooling window materials capable of simultaneously providing indoor lighting,thermal insulation,and daytime radiative cooling under direct sunlight.Significantly,the enclosed space protected by the DAF exhibits a temperature reduction of 2.6℃ compared to that shielded by conventional architectural glass.展开更多
The spin transparency at the normal/ferromagnetic metal （NM/FM） interface was studied in PffYIG/Cu/FM multilayers. The spin current generated by the spin Hall effect （SHE） in Pt flows into Cu/FM due to magnetic in...The spin transparency at the normal/ferromagnetic metal （NM/FM） interface was studied in PffYIG/Cu/FM multilayers. The spin current generated by the spin Hall effect （SHE） in Pt flows into Cu/FM due to magnetic insulator YIG blocking charge current and transmitting spin current via the magnon current. Therefore, the nonlocal voltage induced by an inverse spin Hall effect （ISHE） in FM can be detected. With the magnetization of FM parallel or antiparallel to the spin polarization of pure spin currents （σsc）, the spin-independent nonlocal voltage is induced. This indicates that the spin transparency at the Cu/FM interface is spin-independent, which demonstrates that the influence of spin-dependent electro-chemical potential due to spin accumulation on the interfacial spin transparency is negligible. Furthermore, a larger spin Hall angle of Fe20Ni80 （Py） than that of Ni is obtained from the nonlocal voltage measurements.展开更多
Efforts to recycle copper from electrical conductors have led to the development of specialized machines, which automatically remove insulating covers from wires and cable products. In the past, certain wire and cable...Efforts to recycle copper from electrical conductors have led to the development of specialized machines, which automatically remove insulating covers from wires and cable products. In the past, certain wire and cable products were insulated using chrysotile asbestos. This research was undertaken to determine the asbestos fiber exposure risks associated with power stripping machinery to remove asbestos-containing insulation materials from electrical wire or cable. A Rigby Machinery, Inc., Model 4H electric powered wire/cable insulation stripping machine was acquired along with approximately 42 m of asbestos insulated cable. During two separate, but nearly identical, test sessions, a laborer used the wire stripper to remove the asbestos-containing insulation from the subject cable. This work took place within a closed metal building with a total interior volume of 2500 m3. Industrial hygiene personal and area air samples were collected for airborne fibers throughout all wire stripping periods. Collected air samples were analyzed using phase contract microscopy (PCM) and transmission microscopy (TEM). The results of analysis using PCM for personal samples (n = 3) taken during periods of continuous cable stripping activity showed test period airborne fiber exposures ranging from 0.034 to 0.068 (mean 0.056 f/cc). Follow-up analysis of these personal samples using TEM indicated asbestos adjusted PCM exposures ranging from 0.017 to 0.045 (mean 0.033 f/cc). Area air samples taken at distances ranging from 2 to 9 meters from the wire stripper (n = 16) showed asbestos adjusted PCM concentrations ranging from less than 0.0001 to 0.041 f/cc (mean 0.007 f/cc). The process of power stripping asbestos-containing insulation from electrical wires and cables can cause exposure to airborne asbestos fibers. However, the levels of such exposure are not expected to exceed the current occupational exposure limits for asbestos of 0.1 f/cc as an 8-hr TWA or 1.0 f/cc averaged over a 30-minute exposure period.展开更多
The energy of solar radiation absorbed by the Earth,as well as the thermal radiation of the Earth’s surface,which is released to the space through the atmospheric transparency window,depends on variations of the area...The energy of solar radiation absorbed by the Earth,as well as the thermal radiation of the Earth’s surface,which is released to the space through the atmospheric transparency window,depends on variations of the area of the cloud cover.Svensmark et al.suggest that the increase in the area of the cloud cover in the lower atmosphere,presumably caused by an increase in the flux of galactic cosmic rays during the quasi-bicentennial minimum of solar activity,results only in an increase in the fraction of the solar radiation reflected back to the space and weakens the flux of the solar radiation that reached the Earth surface.It is suggested,without any corresponding calculations of the variations of the average annual energy balance of the EarthЕ,that the consequences will include only a deficit of the solar energy absorbed by the Earth and a cooling of the climate up to the onset of the Little Ice Age.These suggestions ignore simultaneous impact of the opposite aspects of the increase in the area of the cloud cover on the climate warming.The latter will result from a decrease in the power of thermal radiation of the Earth’s surface released to the space,and also in the power of the solar radiation reflected from the Earth’s surface,due to the increase in their absorption and reflection back to the surface.A substantial strengthening in the greenhouse effect and the narrowing of the atmospheric transparency window will also occur.Here,we estimate the impact of all aspects of possible long-term 2%growth of the cloud cover area in the lower atmosphere byЕ.We found that an increase in the cloud cover area in the lower atmosphere will result simultaneously both in the decrease and in the increase in the temperature,which will virtually compensate each other,while the energy balance of the Earth E before and after the increase in the cloud cover area by 2%will stay essentially the same:E1-E0≈0.展开更多
以某型柴油机的油底壳作为研究对象,对其声振特性进行识别与分析,确定设计穿孔板隔声罩的共振频带范围。使用粒子群算法针对共振频率进行穿孔板参数的优化设计,再通过阻抗管试验确定小孔分布对吸声性能的影响,并对穿孔板隔声罩进行多目...以某型柴油机的油底壳作为研究对象,对其声振特性进行识别与分析,确定设计穿孔板隔声罩的共振频带范围。使用粒子群算法针对共振频率进行穿孔板参数的优化设计,再通过阻抗管试验确定小孔分布对吸声性能的影响,并对穿孔板隔声罩进行多目标形貌优化设计以避开共振及激励频率。目标柴油机上加装优化的油底壳穿孔板隔声罩后,整机总声压级降低0.5 d B,降噪效果较好。展开更多
Energy-saving windows play a crucial role in sustainable development of green buildings.Integrating super-insulating aerogels with glasses is an attractive method to minimize the energy loss through building windows.H...Energy-saving windows play a crucial role in sustainable development of green buildings.Integrating super-insulating aerogels with glasses is an attractive method to minimize the energy loss through building windows.However,achieving energy-saving windows with high transparency,super insulation,mechanical robustness,low cost,and scalable aerogels remains a challenge.In a recent study published in Nature Energy,Smalyukh and coworkers synthesized a highly transparent silanized cellulose aerogel for energy-saving windows,overcoming the challenges.This work promotes the practical application of aerogel-based glazing and provides an effective way to save energy of buildings.展开更多
基金The authors are grateful for the financial support from the National Natural Science Foundation of China(Grant Nos.52273067,52122303,52233006)the Fundamental Research Funds for the Central Universities(Grant No.2232023A-03)the Shuguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(23SG29).
文摘The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but challenging.Herein,a delaminated aerogel film(DAF)is fabricated through filtration-induced delaminated gelation and ambient drying.The delaminated gelation process involves the assembly of fluorinated cellulose nanofiber(FCNF)at the solid-liquid interface between the filter and the filtrate during filtration,resulting in the formation of lamellar FCNF hydrogels with strong intra-plane and weak interlayer hydrogen bonding.By exchanging the solvents from water to hexane,the hydrogen bonding in the FCNF hydrogel is further enhanced,enabling the formation of the DAF with intra-layer mesopores upon ambient drying.The resulting aerogel film is lightweight and ultra-flexible,which pos-sesses desirable properties of high visible-light transmittance(91.0%),low thermal conductivity(33 mW m^(-1) K^(-1)),and high atmospheric-window emissivity(90.1%).Furthermore,the DAF exhibits reduced surface energy and exceptional hydrophobicity due to the presence of fluorine-containing groups,enhancing its durability and UV resistance.Consequently,the DAF has demonstrated its potential as solar-thermal regulatory cooling window materials capable of simultaneously providing indoor lighting,thermal insulation,and daytime radiative cooling under direct sunlight.Significantly,the enclosed space protected by the DAF exhibits a temperature reduction of 2.6℃ compared to that shielded by conventional architectural glass.
基金Project supported by the National Basic Research Program of China(Grant No.2015CB921502)the National Natural Science Foundation of China(Grant Nos.11474184 and 11627805)+1 种基金the 111 Project,China(Grant No.B13029)the Fundamental Research Funds of Shandong University,China
文摘The spin transparency at the normal/ferromagnetic metal （NM/FM） interface was studied in PffYIG/Cu/FM multilayers. The spin current generated by the spin Hall effect （SHE） in Pt flows into Cu/FM due to magnetic insulator YIG blocking charge current and transmitting spin current via the magnon current. Therefore, the nonlocal voltage induced by an inverse spin Hall effect （ISHE） in FM can be detected. With the magnetization of FM parallel or antiparallel to the spin polarization of pure spin currents （σsc）, the spin-independent nonlocal voltage is induced. This indicates that the spin transparency at the Cu/FM interface is spin-independent, which demonstrates that the influence of spin-dependent electro-chemical potential due to spin accumulation on the interfacial spin transparency is negligible. Furthermore, a larger spin Hall angle of Fe20Ni80 （Py） than that of Ni is obtained from the nonlocal voltage measurements.
文摘Efforts to recycle copper from electrical conductors have led to the development of specialized machines, which automatically remove insulating covers from wires and cable products. In the past, certain wire and cable products were insulated using chrysotile asbestos. This research was undertaken to determine the asbestos fiber exposure risks associated with power stripping machinery to remove asbestos-containing insulation materials from electrical wire or cable. A Rigby Machinery, Inc., Model 4H electric powered wire/cable insulation stripping machine was acquired along with approximately 42 m of asbestos insulated cable. During two separate, but nearly identical, test sessions, a laborer used the wire stripper to remove the asbestos-containing insulation from the subject cable. This work took place within a closed metal building with a total interior volume of 2500 m3. Industrial hygiene personal and area air samples were collected for airborne fibers throughout all wire stripping periods. Collected air samples were analyzed using phase contract microscopy (PCM) and transmission microscopy (TEM). The results of analysis using PCM for personal samples (n = 3) taken during periods of continuous cable stripping activity showed test period airborne fiber exposures ranging from 0.034 to 0.068 (mean 0.056 f/cc). Follow-up analysis of these personal samples using TEM indicated asbestos adjusted PCM exposures ranging from 0.017 to 0.045 (mean 0.033 f/cc). Area air samples taken at distances ranging from 2 to 9 meters from the wire stripper (n = 16) showed asbestos adjusted PCM concentrations ranging from less than 0.0001 to 0.041 f/cc (mean 0.007 f/cc). The process of power stripping asbestos-containing insulation from electrical wires and cables can cause exposure to airborne asbestos fibers. However, the levels of such exposure are not expected to exceed the current occupational exposure limits for asbestos of 0.1 f/cc as an 8-hr TWA or 1.0 f/cc averaged over a 30-minute exposure period.
文摘The energy of solar radiation absorbed by the Earth,as well as the thermal radiation of the Earth’s surface,which is released to the space through the atmospheric transparency window,depends on variations of the area of the cloud cover.Svensmark et al.suggest that the increase in the area of the cloud cover in the lower atmosphere,presumably caused by an increase in the flux of galactic cosmic rays during the quasi-bicentennial minimum of solar activity,results only in an increase in the fraction of the solar radiation reflected back to the space and weakens the flux of the solar radiation that reached the Earth surface.It is suggested,without any corresponding calculations of the variations of the average annual energy balance of the EarthЕ,that the consequences will include only a deficit of the solar energy absorbed by the Earth and a cooling of the climate up to the onset of the Little Ice Age.These suggestions ignore simultaneous impact of the opposite aspects of the increase in the area of the cloud cover on the climate warming.The latter will result from a decrease in the power of thermal radiation of the Earth’s surface released to the space,and also in the power of the solar radiation reflected from the Earth’s surface,due to the increase in their absorption and reflection back to the surface.A substantial strengthening in the greenhouse effect and the narrowing of the atmospheric transparency window will also occur.Here,we estimate the impact of all aspects of possible long-term 2%growth of the cloud cover area in the lower atmosphere byЕ.We found that an increase in the cloud cover area in the lower atmosphere will result simultaneously both in the decrease and in the increase in the temperature,which will virtually compensate each other,while the energy balance of the Earth E before and after the increase in the cloud cover area by 2%will stay essentially the same:E1-E0≈0.
文摘以某型柴油机的油底壳作为研究对象,对其声振特性进行识别与分析,确定设计穿孔板隔声罩的共振频带范围。使用粒子群算法针对共振频率进行穿孔板参数的优化设计,再通过阻抗管试验确定小孔分布对吸声性能的影响,并对穿孔板隔声罩进行多目标形貌优化设计以避开共振及激励频率。目标柴油机上加装优化的油底壳穿孔板隔声罩后,整机总声压级降低0.5 d B,降噪效果较好。
基金the Major Program of National Natural Science Foundation of China under contract No.52293412.
文摘Energy-saving windows play a crucial role in sustainable development of green buildings.Integrating super-insulating aerogels with glasses is an attractive method to minimize the energy loss through building windows.However,achieving energy-saving windows with high transparency,super insulation,mechanical robustness,low cost,and scalable aerogels remains a challenge.In a recent study published in Nature Energy,Smalyukh and coworkers synthesized a highly transparent silanized cellulose aerogel for energy-saving windows,overcoming the challenges.This work promotes the practical application of aerogel-based glazing and provides an effective way to save energy of buildings.
