The hole transport characteristics of molecule blends of 1, 4, 5, 8, 9 and 11-hexaazatriphenylene-hexacarbonitrile (HAT-CN): N,N'-di(naphthalene-l-yl)-N,N'-diphenyl-benzidine (NPB) and HAT-CN: 4,4'-cyclohex...The hole transport characteristics of molecule blends of 1, 4, 5, 8, 9 and 11-hexaazatriphenylene-hexacarbonitrile (HAT-CN): N,N'-di(naphthalene-l-yl)-N,N'-diphenyl-benzidine (NPB) and HAT-CN: 4,4'-cyclohexylidenebis[N,N- bis(4-methylphenyl)benzenamine] (TAPC) with various NPB and TAPC mixing concentrations (5 90wt%) are studied. When the concentration is in the range of 5-80wt%, it is found that the hole conductions in the two blends are space-charge-limited current (SCLC) with free trap distributions. The current-voltage characteristics of the two blends show SCLC with exponentiM trap distributions at the concentration of 90wt%. The hole mo- bilities of the two blends are very close (10^-4-10^-3 cm2 V^-1 s-X ), the dependence of electric field and temperature can be described by the modified Poole-Frenkel model. The hole mobility and activation energy of the two blends depending on concentration are similar.展开更多
The attainment of suitable ambient air quality standards is a matter of great concern for successfully hosting the ⅩⅩⅣ Olympic Winter Games(OWG). Transport patterns and potential sources of pollutants in Zhangjiako...The attainment of suitable ambient air quality standards is a matter of great concern for successfully hosting the ⅩⅩⅣ Olympic Winter Games(OWG). Transport patterns and potential sources of pollutants in Zhangjiakou(ZJK) were investigated using pollutant monitoring datasets and a dispersion model. The PM_(2.5) concentration during February in ZJK has increased slightly(28%) from 2018 to 2021, mostly owing to the shift of main potential source regions of west-central Inner Mongolia and Mongolian areas(2015–18) to the North China Plain and northern Shanxi Province(NCPS) after 2018.Using CO as an indicator, the relative contributions of the different regions to the receptor site(ZJK) were evaluated based on the source-receptor-relationship method(SRR) and an emission inventory. We found that the relative contribution of pollutants from NCPS increased from 33% to 68% during 2019–21. Central Inner Mongolia(CIM) also has an important impact on ZJK under unfavorable weather conditions. This study demonstrated that the effect of pollution control measures in the NCPS and CIM should be strengthened to ensure that the air quality meets the standard during the ⅩⅩⅣ OWG.展开更多
The actual situation of two sand and dust weather processes with heavy pollution in Ulanqab City in 2021 was analyzed from the aspects of air quality,visibility,PM_(2.5)and PM_(10),and the causes of the sand and dust ...The actual situation of two sand and dust weather processes with heavy pollution in Ulanqab City in 2021 was analyzed from the aspects of air quality,visibility,PM_(2.5)and PM_(10),and the causes of the sand and dust weather with heavy pollution were discussed.The differences between the two processes in transport characteristics of sand and dust were studied,and the roles of high-and low-altitude weather systems and their impact on sand and dust transport were explored.展开更多
A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to per...A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to perform proppant transport experiments.The typical characteristics of proppant transport and placement in rough fractures and its intrinsic mechanisms are investigated,and the influences of fracture inclination,fracture width and fracturing fluid viscosity on proppant transport and placement in rough fractures are analyzed.The results show that the rough fractures cause variations in the shape of the flow channel and the fluid flow pattern,resulting in the bridging buildup during proppant transport to form unfilled zone,the emergence of multiple complex flow patterns such as channeling,reverse flow and bypassing of sand-carrying fluid,and the influence on the stability of the sand dune.The proppant has a higher placement rate in inclined rough fractures,with a maximum increase of 22.16 percentage points in the experiments compared to vertical fractures,but exhibits poor stability of the sand dune.Reduced fracture width aggravates the bridging of proppant and induces higher pumping pressure.Increasing the viscosity of the fracturing fluid can weaken the proppant bridging phenomenon caused by the rough fractures.展开更多
Based on first-principles calculations, Boltzmann transport equation and semiclassical analysis, we conduct a detailed study on the lattice thermal conductivity κL, Seebeck coefficient S, electrical conductivity σ, ...Based on first-principles calculations, Boltzmann transport equation and semiclassical analysis, we conduct a detailed study on the lattice thermal conductivity κL, Seebeck coefficient S, electrical conductivity σ, power factor S2σ and dimensionless figure of merit, zT, for K3IO. It is found that K3IO exhibits relatively low lattice thermal conductivity of 0.93 W·m-1·K-1 at 300 K, which is lower than the value 1.26 W·m-1·K-1 of the classical TE material PbTe. This is due to the smaller phonon group velocity νg and smaller relaxation time τλ. The low lattice thermal conductivity can lead to excellent thermoelectric properties. Thus maximum zT of 2.87 is obtained at 700 K, and the zT = 0.41 at 300 K indicate that K3IO is a potential excellent room temperature TE material. Our research on K3IO shows that it has excellent thermoelectric properties, and it is a promising candidate for applications in fields in terms of thermoelectricity.展开更多
A concise definition of Transport Efficiency (TE) was given to examine the amount of transported grains in the pipe flow with certain energy consumption. The transport characteristics and the so-called 'roto-float...A concise definition of Transport Efficiency (TE) was given to examine the amount of transported grains in the pipe flow with certain energy consumption. The transport characteristics and the so-called 'roto-floating' characteristics were studied from the tests of sediment transport in the normal pipe flow and the spiral pipe flow, and hereby the energy gradients of the two kinds of pipe flows were obtained. By comparing the mean concentrations at the same gradient, it was concluded that the TE of the latter is several times to over ten times higher than that of the former, and the lift of the latter is 200 times larger than that of the former for the nearly same TE. The spiral flow in circular pipe is suitable for transporting fine grains of high concentration, and with sedimentation trend and coarse grains.展开更多
The Rotation and Curvature(RC)correction is an important turbulence model modifi-cation approach,and the Spalart-Allmaras model with the RC correction(SA-RC)has been exten-sively studied and used.As a multiplier of th...The Rotation and Curvature(RC)correction is an important turbulence model modifi-cation approach,and the Spalart-Allmaras model with the RC correction(SA-RC)has been exten-sively studied and used.As a multiplier of the modelling equation’s production term,the rotation function f_(r1)should have a cautiously designed value range,but its limit varies in different models and flow solvers.Therefore,the need of restriction is discussed theoretically,and the common range of f_(r1)is explored in Burgers vortexes.Afterwards,the SA-RC model with different limits is tested numerically.Negative f_(r1)always appears in the SA-RC model,and the difference between simula-tion results brought by the limits is not negligible.A lower limit of 0 enhances turbulence produc-tion,and therefore the vortex structures are dissipated faster and shrink in size,while an upper limit plays an opposite role.Considering that the lower limit of 0 usually promotes the simulation accu-racy and fixes the numerical defect,whereas the upper limit worsens the predictive performance in most cases,it is recommended to limit f_(r1)non-negative while utilizing the SA-RC model.In addi-tion,the RC-corrected model has a better prediction of the attached flow near curved walls,while the SA-Helicity model largely improves the simulation accuracy of three-dimensional large-scale vortices.The model combining both corrections has the potential to become more adaptive and more accurate.展开更多
Au/TbMnO3/YBa2 Cu3O7-x capacitors were fabricated on SrTiO3 substrates by pulse laser deposition technique, of which electric properties were investigated in the temperature range from 25 to 300 K. Both current-voltag...Au/TbMnO3/YBa2 Cu3O7-x capacitors were fabricated on SrTiO3 substrates by pulse laser deposition technique, of which electric properties were investigated in the temperature range from 25 to 300 K. Both current-voltage characteristics and junction resistances with bias voltages showed remarkable temperature dependence, in which obvious thermally excited relaxation processes were found between 150 and 200 K. At the temperatures lower than the activation process, the leakage currents of the capacitors were studied. Interestingly, at high electric field, the mechanism of the leakage was Poole-Frenkel emission. However, at low electric field, the conduction was not Ohmic, and ideal lnJ∝E 1/4 characteristics were observed. Analysis showed that the possible origin was related to the inherent inhomogeneous nature of activationless percolating transport.展开更多
We summarize in this overview achievements in current research frontiers in Asian sand dust with emphasis on the method for sand dust research, the sources of sand dust aerosols, emission of sand dust, mechanism of sa...We summarize in this overview achievements in current research frontiers in Asian sand dust with emphasis on the method for sand dust research, the sources of sand dust aerosols, emission of sand dust, mechanism of sand dust weather, chemical transformation during transport, and influences on climatic environment and oceans. Our main results show that most of Asian sand dust comes from Mongolia, the Gobi Desert, arid and semiarid desert areas in northwest China, which is divided into initial sources and enhanced sources. Half of the global production of dust originates from Asian dust source regions. Asian dust weather is so immense that it can cover a 5-?-day journey from the sources to the Korean Peninsula, Japan Islands, and the Pacific Ocean to even impact North America. Asian dust weather plays an active role in the hiogeochemical cycles of trace elements in the mid-latitude Northern Hemisphere.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 51333007,91433201 and 61204059the National Basic Research Program of China under Grant No 2013CB834805+1 种基金the Foundation of Jilin Research Council under Grant Nos 2012ZDGG001 and 20130206003GXthe Key Research Program of the Chinese Academy of Sciences under Grant No KGZD-EW-303-3
文摘The hole transport characteristics of molecule blends of 1, 4, 5, 8, 9 and 11-hexaazatriphenylene-hexacarbonitrile (HAT-CN): N,N'-di(naphthalene-l-yl)-N,N'-diphenyl-benzidine (NPB) and HAT-CN: 4,4'-cyclohexylidenebis[N,N- bis(4-methylphenyl)benzenamine] (TAPC) with various NPB and TAPC mixing concentrations (5 90wt%) are studied. When the concentration is in the range of 5-80wt%, it is found that the hole conductions in the two blends are space-charge-limited current (SCLC) with free trap distributions. The current-voltage characteristics of the two blends show SCLC with exponentiM trap distributions at the concentration of 90wt%. The hole mo- bilities of the two blends are very close (10^-4-10^-3 cm2 V^-1 s-X ), the dependence of electric field and temperature can be described by the modified Poole-Frenkel model. The hole mobility and activation energy of the two blends depending on concentration are similar.
基金the National Key Scientific and Technological Infrastructure project “Earth System Science Numerical Simulator Facility” (Earth Lab)
文摘The attainment of suitable ambient air quality standards is a matter of great concern for successfully hosting the ⅩⅩⅣ Olympic Winter Games(OWG). Transport patterns and potential sources of pollutants in Zhangjiakou(ZJK) were investigated using pollutant monitoring datasets and a dispersion model. The PM_(2.5) concentration during February in ZJK has increased slightly(28%) from 2018 to 2021, mostly owing to the shift of main potential source regions of west-central Inner Mongolia and Mongolian areas(2015–18) to the North China Plain and northern Shanxi Province(NCPS) after 2018.Using CO as an indicator, the relative contributions of the different regions to the receptor site(ZJK) were evaluated based on the source-receptor-relationship method(SRR) and an emission inventory. We found that the relative contribution of pollutants from NCPS increased from 33% to 68% during 2019–21. Central Inner Mongolia(CIM) also has an important impact on ZJK under unfavorable weather conditions. This study demonstrated that the effect of pollution control measures in the NCPS and CIM should be strengthened to ensure that the air quality meets the standard during the ⅩⅩⅣ OWG.
文摘The actual situation of two sand and dust weather processes with heavy pollution in Ulanqab City in 2021 was analyzed from the aspects of air quality,visibility,PM_(2.5)and PM_(10),and the causes of the sand and dust weather with heavy pollution were discussed.The differences between the two processes in transport characteristics of sand and dust were studied,and the roles of high-and low-altitude weather systems and their impact on sand and dust transport were explored.
基金Supported by National Key Research and Development Program of China(2022YFE0137200)Outstanding Youth Natural Science Fund of Shaanxi Province(2022JC-37)+2 种基金Innovation Capability Support Program of Shaanxi(2023-CX-TD-31)Natural Science Basic Research Project of Shaanxi Province(2024JC-YBQN-0381)National Natural Science Foundation of China(51874240,52204021)。
文摘A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to perform proppant transport experiments.The typical characteristics of proppant transport and placement in rough fractures and its intrinsic mechanisms are investigated,and the influences of fracture inclination,fracture width and fracturing fluid viscosity on proppant transport and placement in rough fractures are analyzed.The results show that the rough fractures cause variations in the shape of the flow channel and the fluid flow pattern,resulting in the bridging buildup during proppant transport to form unfilled zone,the emergence of multiple complex flow patterns such as channeling,reverse flow and bypassing of sand-carrying fluid,and the influence on the stability of the sand dune.The proppant has a higher placement rate in inclined rough fractures,with a maximum increase of 22.16 percentage points in the experiments compared to vertical fractures,but exhibits poor stability of the sand dune.Reduced fracture width aggravates the bridging of proppant and induces higher pumping pressure.Increasing the viscosity of the fracturing fluid can weaken the proppant bridging phenomenon caused by the rough fractures.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11974302,11774396,and 11704322)the Shandong Natural Science Funds for Doctoral Program,China(Grant No.ZR2017BA017).
文摘Based on first-principles calculations, Boltzmann transport equation and semiclassical analysis, we conduct a detailed study on the lattice thermal conductivity κL, Seebeck coefficient S, electrical conductivity σ, power factor S2σ and dimensionless figure of merit, zT, for K3IO. It is found that K3IO exhibits relatively low lattice thermal conductivity of 0.93 W·m-1·K-1 at 300 K, which is lower than the value 1.26 W·m-1·K-1 of the classical TE material PbTe. This is due to the smaller phonon group velocity νg and smaller relaxation time τλ. The low lattice thermal conductivity can lead to excellent thermoelectric properties. Thus maximum zT of 2.87 is obtained at 700 K, and the zT = 0.41 at 300 K indicate that K3IO is a potential excellent room temperature TE material. Our research on K3IO shows that it has excellent thermoelectric properties, and it is a promising candidate for applications in fields in terms of thermoelectricity.
文摘A concise definition of Transport Efficiency (TE) was given to examine the amount of transported grains in the pipe flow with certain energy consumption. The transport characteristics and the so-called 'roto-floating' characteristics were studied from the tests of sediment transport in the normal pipe flow and the spiral pipe flow, and hereby the energy gradients of the two kinds of pipe flows were obtained. By comparing the mean concentrations at the same gradient, it was concluded that the TE of the latter is several times to over ten times higher than that of the former, and the lift of the latter is 200 times larger than that of the former for the nearly same TE. The spiral flow in circular pipe is suitable for transporting fine grains of high concentration, and with sedimentation trend and coarse grains.
基金supported by the National Natural Science Foundation of China(Nos.51976006,51790513)the Aeronautical Science Foundation of China(No.2018ZB51013)+1 种基金the National Science and Technology Major Project,China(2017-II-003-0015)the Open Fund from State Key Laboratory of Aerodynamics,China(No.SKLA2019A0101).
文摘The Rotation and Curvature(RC)correction is an important turbulence model modifi-cation approach,and the Spalart-Allmaras model with the RC correction(SA-RC)has been exten-sively studied and used.As a multiplier of the modelling equation’s production term,the rotation function f_(r1)should have a cautiously designed value range,but its limit varies in different models and flow solvers.Therefore,the need of restriction is discussed theoretically,and the common range of f_(r1)is explored in Burgers vortexes.Afterwards,the SA-RC model with different limits is tested numerically.Negative f_(r1)always appears in the SA-RC model,and the difference between simula-tion results brought by the limits is not negligible.A lower limit of 0 enhances turbulence produc-tion,and therefore the vortex structures are dissipated faster and shrink in size,while an upper limit plays an opposite role.Considering that the lower limit of 0 usually promotes the simulation accu-racy and fixes the numerical defect,whereas the upper limit worsens the predictive performance in most cases,it is recommended to limit f_(r1)non-negative while utilizing the SA-RC model.In addi-tion,the RC-corrected model has a better prediction of the attached flow near curved walls,while the SA-Helicity model largely improves the simulation accuracy of three-dimensional large-scale vortices.The model combining both corrections has the potential to become more adaptive and more accurate.
基金Project supported by National Natural Science Foundation of China(10975103)
文摘Au/TbMnO3/YBa2 Cu3O7-x capacitors were fabricated on SrTiO3 substrates by pulse laser deposition technique, of which electric properties were investigated in the temperature range from 25 to 300 K. Both current-voltage characteristics and junction resistances with bias voltages showed remarkable temperature dependence, in which obvious thermally excited relaxation processes were found between 150 and 200 K. At the temperatures lower than the activation process, the leakage currents of the capacitors were studied. Interestingly, at high electric field, the mechanism of the leakage was Poole-Frenkel emission. However, at low electric field, the conduction was not Ohmic, and ideal lnJ∝E 1/4 characteristics were observed. Analysis showed that the possible origin was related to the inherent inhomogeneous nature of activationless percolating transport.
基金supported by the National Science Foundation for Post-doctoral Scientists of China(Grant No.20070420419)Central research institutes of basic research and public service special operations,Chinese Research Academy of Environmental Sciences(2007KYYW17,2008KYYW01)the National High-Tech Research and Development Program of China(Grant No.2006AA06A307)
文摘We summarize in this overview achievements in current research frontiers in Asian sand dust with emphasis on the method for sand dust research, the sources of sand dust aerosols, emission of sand dust, mechanism of sand dust weather, chemical transformation during transport, and influences on climatic environment and oceans. Our main results show that most of Asian sand dust comes from Mongolia, the Gobi Desert, arid and semiarid desert areas in northwest China, which is divided into initial sources and enhanced sources. Half of the global production of dust originates from Asian dust source regions. Asian dust weather is so immense that it can cover a 5-?-day journey from the sources to the Korean Peninsula, Japan Islands, and the Pacific Ocean to even impact North America. Asian dust weather plays an active role in the hiogeochemical cycles of trace elements in the mid-latitude Northern Hemisphere.