领导力的整合:Trickle-down模式下的领导效应

Trickle-down模式正逐渐成为领导效应研究的新范式。它阐释了组织中较高层次领导的行为或其认知如何沿着组织的垂直管理层次自上而下层层滴漏。该模式通过对领导行为联动效应和多层配对的剖析,弥补了传统研究聚焦于单一层次领导研究的不足。系统梳理trickle-down模式下的领导效应之涵义特征、理论基础、效能机制,并深入探讨已有研究的欠缺,对于实现领导力的整合、拓展本土化的领导行为研究具有重要意义。

The Relationship Between Hysteresis and Liquid Flow Distribution in Trickle Beds

Experiments were conducted on a trickle bed with 0.283m ID to elucidate the relationship between hysteretic phenomena and liquid distribution. The hysteresis of pressure drop and the variance of radial liquid distribution were observed simultaneously. Residence time distribution (RTD), holdup and mean residence time (RT) of liquid phase were also found to demonstrate hysteresis of the same nature. RTD, liquid holdup and mean RT calculated with a simple model from the distribution of liquid flow rate show characteristics consistant with the experimental data, suggesting that the hyteretic phenomena originate from the multiplicity and nonuniformity of liquid flow distribution.

Peracetic Acid Synthesis by Acetaldehyde Liquid Phase Oxidation in Trickle Bed Reactor

In this paper,shorter residence time（a few minutes）with high yield in the trickle bed process for per- acetic acid synthesis by acetaldehyde liquid phase oxidation can be realized on the selected packing material SA-5118.For acetaldehyde in acetone with ferric ion as catalyst,the optimized process conditions were presented. The main factors influencing the yield,selectivity and conversion are residence time,temperature and acetaldehyde concentration,respectively.The temperature range checked is from 30 to 65℃.High yield of 81.53%with high se- lectivity of 91.84%can be obtained at higher temperature of 55℃when the residence time is 5.5min and the acet- aldehyde concentration is 9.85%（by mass）.And there is a critical acetaldehyde concentration point（Cccp）between 18%and 19.5%（by mass）.At temperature less than 55℃,the highest yield to peracetic acid at each temperature level increases with temperature when the acetaldehyde concentration is below Cccp and decreases with temperature when the acetaldehyde concentration is above Cccp.

Absorption Enhanced Methanol Synthesis in a Trickle Bed Reactor over Cu/Zn/Al₂O₃Catalyst

Methanol synthesis in a trickle bed reactor with tetraethylene glycol dimethyl ether (TEGDME) as the liquid phase over a Cu/Zn/Al2O3 catalyst was investigated. The pressure was kept constant at 5.0 MPa, while the temperature ranged from 230℃?to 260℃?and the mass space velocity varied between 294 L·Kg-1·h-1 and 1655 L·Kg-1·h-1. The effects of temperature and space velocity on CO conversion and methanol productivity were studied. Methanol synthesis processes in trickle bed with the TEGDME and paraffin oil as liquid phase were compared with the fixed bed process. The results indicated that the optimal temperature was approximately 240℃. When the space velocity was increased, the CO conversion decreased while the methanol productivity increased. The liquid introduced can help to keep the reactor nearly isothermal. For methanol synthesis in trickle-bed reactor, TEGDME was better than paraffin oil. Effect of TEGDME on the reaction was twofold. On one hand, it absorbs the methanol and speeds up the reaction. On the other hand, it also increases the mass transfer resistance and hinders the reaction.

Intensification of Deep Hydrodesulfurization Through a Two-stage Combination of Monolith and Trickle Bed Reactors

Deep hydrodesulfurization （HDS） is an important process to produce high quality liquid fuels with ultra-low sul- fur. Process intensification for deep HDS could be implemented by developing new active catalysts and/or new types of reactors. In this work, the kinetics of dibenzothiophene （DBT） hydrodesulfurization over Ni-P/SBA-15/ cordierite catalyst was investigated at 340-380 ℃ and 3.0-5.0 MPa. The first-order reaction model with respect to both DBT and H2 was used to fit the kinetics data in a batch recycle operation system. It is found that both the activation energy and rate constant over the Ni-P monolithic catalyst under our operating conditions are close to those over conventionally used HDS catalysts. Comparative performance studies of two types of reactors, i.e., trickle bed reactor and monolithic reactor, were performed based on reactor modeling and simulation. The results indicate that the productivity of the monolithic reactor is 3 times higher than that of the trickle bed reactor on a catalyst weight basis since effective utilization of the catalyst is higher in the monolithic reactor, but the volumetric productivity of the monolithic reactor is lower for HDS of DBT. Based on simulation results, a two- reactor-in-series configuration for hydrodesulfurization is proposed, in which a monolithic reactor is followed by a tickled bed reactor so as to attain intensified performance of the system converting fuel oil of different sulfur-containing compounds. It is illustrated that the two reactor scheme outperforms the trickle bed reactor both on reactor volume and catalyst mass bases while the content of sulfur is reduced from 200 μg·g-1 to about 10 μ·g-1.

Process intensification in gas/liquid/solid reaction in trickle bed reactors: A review

As an important form of reactors for gas/liquid/solid catalytic reaction,trickle bed reactors (TBRs) are widely applied in petroleum industry,biochemical,fine chemical and pharmaceutical industries because of their flexibility,simplicity of operation and high throughput.However,TBRs also show inefficient production and hot pots caused by non-uniform fluid distribution and incomplete wetting of the catalyst,which limit their further application in chemical industry.Also,process intensification in TBRs is necessary as the decrease in quality of processed crude oil,caused by increased exploitation depths,and more restrictive environmental regulations and emission standards for industry,caused by increased environment protection consciousness.In recent years,lots of strategies for process intensification in TBRs have been proposed to improve reaction performance to meet the current and future demands of chemical industry from the environmental and economic perspective.This article summarizes the recent progress in techniques for intensifying gas/liquid/solid reaction in TBRs and application of intensified TBRs in petroleum industry.

HYSTERESIS OF GAS-LIQUID MASS TRANSFER IN A TRICKLE BED REACTOR

1 INTRODUCTIONTrickle bed reactors are widely used in the process industry,particularly in petroleumhydroprocessing operations,and have been extensively studied by chemical engineers.In atrickle bed reactor,the gas and liquid flow cocurrently down through the packed bedand undergo chemical reactions.However,there exist multiple hydrodynamic stateswhich correspond to either uniform or,in most cases,nonuniform radial distributionof the gas and liquid flows in the packed section.Moreover,the hydrodynamic state

Quick Trickle Permutation Based on Quick Trickle Characteristic Sequence

The concept of quick trickle characteristic sequence is presented, the properties and count of quick trickle characteristic sequence are researched, the mapping relationship between quick trickle characteristic sequence and quick trickle permutation is discussed. Finally, an efficient construction of quick trickle permutation based on quick trickle characteristic sequence is given, by which quick trickle permutation can be figured out after constructing quick trickle characteristic sequence. Quick trickle permutation has good cryptographic properties.

Analysis of Operating Variables in the Catalytic Purification of Butene-1 in a Trickle Bed

A mathematical model for analyzing and simulating selective hydrogenation of butyne-1 and 1,3-bu-tadiene in industrial trickle bed reactors operated to obtain high purity butene-1 is presented in this work.Fromthe analysis of typical operating conditions,only the relevant phenomena are finally retained in the model formu-lation.The model is then employed to analyze the effect of operating variables and catalyst selectivity in processperformance.In particular,the search for the minimum hydrogen flow rate necessary to fulfil butene-1 purityspecifications is undertaken.

Chrestenson Spectrum and Auto-Correlation Function of Inverse Permutations of Quick Trickle Permutations

In this paper, a sufficient and necessary condition of quick trickle permutations is given from the point of inverse permutations. The bridge is built between quick trickle permutations and m-value logic functions. By the methods of the Chrestenson spectrum of m-value logic functions and the auto-correlation function of m-value logic functions to investigate the Chrestenson spectral characteristics and the auto-correlation function charac- teristics of inverse permutations of quick trickle permutations, a determinant arithmetic of quick trickle permutations is given. Using the results, it becomes easy to judge that a permutation is a quick trickle permutation or not by using computer. This gives a new pathway to study constructions and enumerations of quick trickle permutations.

Application of Laplace Transform for a Gas-Liquid-Solid Trickle Bed Reactor by Using the Tracer Technique

Experimental evaluation and dynamic modelling were presented for a liquid flow (H2O + NaOH tracer) on solid particles in a trickle bed reactor. One-dimensional dynamic mathematical model has been described to study the gas-liquid-solid process in which the liquid phase with the NaOH tracer is treated as a continuum. The physical model has been analyzed, including the formulation of initial and boundary conditions and the description of the solution methodology. An experimental setup to measure the concentrations of the NaOH tracer has been performed. The concentration measurements of this NaOH tracer have been performed in a fixed be reactor on trickling flow of the liquid phase for a range of operating conditions. The axial dispersion (Dax) of the liquid phase, liquid-solid mass transfer (kLS) coefficient and partial wetting efficiency (fe) were chosen as the hydrodynamic parameters of the proposed mathematical model. Such parameters have been optimized with experimental measurents of the NaOH tracer at the exit of the trickle-bed reactor. The optimized parameters (Dax, kLS, and fe) were calculated simultaneously by using the theoretical model with minimization of the objective function. Results of the proposed mathematical model have been presented and compared as of the two experimental cases. These hydrodynamic parameters were fitted by means of the empirical correlations.

Modification of water application uniformity among closed circuit trickle irrigation systems

The aim of this research was determine the ma- ximum application uniformity of closed circuit trickle irrigation systems designs. Laboratory tests carried out for Two types of closed circuits: a) One manifold for lateral lines or Closed circuits with One Manifold of Trikle Irrigation System (COMTIS);b) Closed circuits with Two Manifolds of Trikle Irrigation System (CTMTIS), and c) Traditional Trikle Irrigation System (TTIS) as a control. Three lengths of lateral lines were used, 40, 60, and 80 meters. PE tubes lateral lines: 16 mm diameter;30 cm emitters distance, and GR built-in emitters 4 lph when operating pressure 1 bar. Experiments were conducted at the Agric. Eng. Res. Inst., ARC, MALR, Egypt. With COMTIS the emitter flow rate was 4.07, 3.51, and 3.59 lph compared to 4.18, 3.72, and 3.71 lph with CTMTIS and 3.21, 2.6, and 2.16 lph with TTIS (lateral lengths 40, 60, and 80 meters respectively). Uniformity varied widely within individual lateral lengths and between circuit types. Under CTMTIS uniformity values were 97.74, 95.14, and 92.03 %;with COMTIS they were 95.73, 89.45, and 83.25 %;and with TTIS they were 88.27, 84.73, and 80.53 % (for lateral lengths 40, 60, 80 meters respectively). The greatest uniformity was observed under CTMTIS and COMTIS when using the shortest lateral length 40 meters, then lateral length 60 meters, while the lowest value was observed when using lateral length 80 meters this result depends on the physical and hydraulic characteristics of the emitter and lateral line. CTMTIS was more uniform than either COMTIS or TTIS. Friction losses were decreased with CTMTIS in the emitter laterals at lengths 40 meters compared to TTIS and COMTIS. Therefore, differences may be related to increased friction losses when using TDIS and COMDIS.

Prediction of Pulsation Frequency of Pulsing Flow in Trickle Beds Based on Artificial Neural Network

An extensive database (946 measurements) for the frequency of pulsing flow in trickle beds was established by collecting the experimental results published over past 30 years. A new correlation based on artificial neural network (ANN) to predict the pulsation frequency was developed. Seven dimensionless numbers (groups) employed in the proposed correlation were liquid and gas Reynolds, liquid Weber, liquid Eotvos, gas Froude, and gas Stokes numbers and a bed correction factor. The comparisons of performance reported in the of literature and present correlations show that ANN correlation is a significant improvement in predicting pulsation frequency with an average absolute relative error (AARE) of 10% and a standard deviation less than 18%.

Experimental study on the particle flow patterns in a cyclone dipleg with a trickle valve

An experimental apparatus including a dipleg and a trickle valve was established to simulate the operation of a suspended dipleg-trickle valve system of cyclone used in fluid catalytic cracking(FCC)unit.The flow regimes in the dipleg and the discharge modes in the trickle valve were studied by combining the observation of experimental phenomena with the analysis of transient pressure fluctuation.The results show that the flow regimes in the dipleg have two types-the dilute–dense phase coexisting falling flow and the dilute falling flow.Correspondingly,the trickle valve also has two discharge modes-the intermittent periodic dumping discharge and the continuous trickling discharge.The power spectrum density of pressure fluctuation displays that the gas–solids flow in the dipleg-trickle valve system is characterized by a low-frequency pulsation.The coherence coefficient explains the origin and propagation of pressure fluctuation in the system.Eventually,a map describing the flow regimes and discharge modes related to the operation parameters was proposed,which can provide a helpful guidance for the operation of cyclone dipleg-trickle valve system in FCC unit.

CORRELATION BETWEEN HYSTERESIS OF GAS-LIQUID MASS TRANSFER AND LIQUID DISTRIBUTION IN A TRICKLE BED

The hysteresis of gas-liquid mass transfer rate and the corresponding radial liquiddistribution in a trickle bed reactor are measured to provide evidence for the correlation between thesetwo behaviors.Experimental results indicate that the hysteresis of gas-liquid mass transfer originatesfrom the nonuniformity of the hydrodynamic state of gas-liquid flow and the radial maldistributionof local kgia corresponds very well to the radial maldistribution of liquid flow in the bed.The localliquid flow rate is also found to be nonuniform in the azimuthal direction.In view of maldistributedliquid flow even in the pulsing flow regime,the conventional plug flow model seems oversimplifiedfor describing the behavior of a trickle bed.

Liquid Phase Catalytic Oxidation of Aqueous Solutions That Contain Organic Matter in a Trickle-Bed Reactor

In this study, catalytic wet air oxidation of wastewater that contains organic matter (phenol) is investigated in a laboratory scale trickle-bed reactor. The aim of this project is to determine the optimum operating conditions for the reaction of phenol in the wastewater with oxygen using a catalyst. For this purpose, the effects of temperature, gas flow rate, liquid space velocity and initial concentration of phenol on the conversion of phenol at constant pressure and the effect of pressure on the conversion of phenol at constant temperature are investigated. An industrial copper chromite catalyst was used in the experimental studies. It is seen from the experimental results, conversion of phenol increases with increasing temperature, pressure, gas flow rate and liquid space velocity;and also, it is seen that conversion of phenol decreases with increasing initial concentration of phenol. The conversion of phenol reaches at 130?C and 4 bar to 40%. It was also found that, 3 ppm copper amount was determined from the exit stream of the reactor. This result shows that cupper placed in the structure of the catalyst, mixes with the liquid stream during the reaction.

新型农业经营主体促进山区小农户机械化的“滴涓效应”研究——以云南山区为例

本文旨在研究促进山区小农户与现代农业衔接的路径和机理。通过对云南省山区小农户的调查数据,采用回归和调节模型进行实证分析,验证促进山区小农户机械化水平的外部和内部路径以及相关机理的有效性,并探讨新型农业主体对山区小农户机械化水平影响的“涓滴效应”。研究结果表明,山区小农户的机械化水平主要受其社会和自然资源的影响以及内部互助行为的作用。新型农业经营主体在提升山区小农户整体机械化水平方面并不显著,但在提升部分山区小农户的机械化水平方面具有显著作用。农业企业的带动效应对于提升“非合作社社员”和“未获得免费培训”的山区小农户机械化水平起到明显的促进作用。而农民合作社仅在提升合作社社员的机械化水平方面发挥显著作用。因此,建议加大山地农业机械的研发投入,增强新型农业经营主体在提升小农户整体现代农业水平方面的作用,以促进小农户与现代农业的有机衔接。

领导者心理韧性下行传递效应的多元实现路径

心理韧性是个体应对危机挑战不可或缺的心理能力。如何促进领导者心理韧性的下行传递效应成为提升领导有效性、强化员工心理韧性,进而增强组织危机应对能力的关键。本文融合质性与实证方法,挖掘并验证了心理韧性下行传递效应的实现机制。首先,基于程序化扎根理论的三级编码过程,构建了领导者心理韧性的下行传递效应理论模型,并结合社会信息加工理论探讨了不同传递路径的实现机制。其次,运用Bootst rap方法,通过纵向追踪数据验证了理论模型的普适性。结论包括:1.心理韧性下行传递效应实现机制包括情感传递、认知传递和行为传递三条路径,各路径存在协同作用关系;2.领导与员工间的积极情绪感染构成心理韧性的情感传递路径;3.领导建设性反馈和员工自我效能感搭建了心理韧性的认知传递路径;4.领导容错行为和员工差错反思构成心理韧性的行为传递路径。研究结论增添了心理韧性在组织行为领域的应用场景,为增强组织环境适应力提供新的启示。

高铁开通与边缘城市金融要素发展:极化还是涓滴效应

高铁开通对金融要素在核心城市和边缘城市流动的影响一直存在争议。本文采用区位熵、城市的金融规模和人口流动等因素区分金融要素集中的核心城市和相对不集中的边缘城市,并使用双重差分(DID)法进行实证检验。结果显示,高铁开通使边缘城市与核心城市的金融要素发展差距扩大,极化效应凸显,这一现象在不同区域间存在异质性,且距离愈远极化效应表现愈显著。伴随极化效应,区域内金融要素高度集中,金融要素市场潜力下降。研究结论为高铁开通下边缘城市扮演的金融要素角色提供了经验证据。