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Multiple-stage W mineralization in the Guanfang W deposit,southeastern Yunnan Province,China:Insights from scheelite in-situ trace elemental and Sr isotopic analyses
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作者 Bin Sun Yi Liu +4 位作者 Zhigang Kong Xuelong Liu Xiaojun Jiang Chao Li Wenchang Li 《Acta Geochimica》 2025年第1期112-127,共16页
The Guanfang large-scale W deposit is located in the W polymetallic ore concentration area of Bozhushan in southeastern Yunnan,China.Despite extensive research,the fluid evolution process of the deposit remains ambigu... The Guanfang large-scale W deposit is located in the W polymetallic ore concentration area of Bozhushan in southeastern Yunnan,China.Despite extensive research,the fluid evolution process of the deposit remains ambiguous,leading to controversy regarding its genesis.This study conducted a detailed field geological survey,with systematic sampling of the KT6 orebody,to delineate mineralization stages.Fine mineralogy work,including the use of CL images of scheelite,in-situ LA-ICP-MS trace elements,and Sr isotopes,was carried out on diff erent generations of scheelite formed in various stages.The findings identified the evolution of fluids in the mineralization process,shedding light on the genesis of the deposit.The study revealed four mineralization stages at the Guanfang W deposit:prograde skarn stage,retrograde skarn stage,quartz-sulfide stage,and carbonate-fluorite stage.Diff erent generations of scheelite(Sch I,Sch II,Sch III)were observed in the first three stages,displaying distinct chondrite-normalized REE patterns.The REE of Sch I mainly substituted into the Ca site by REE^(3+)+□_(Ca),and there may be a similar substitution of Nb for REE,whereas it is not the main substitution method.The REE of Sch II mainly enter the scheelite lattice in the form of REE 3++Na+,and there may be a substitution of Nb for REE isomorphism.In the early stage,The REE of Sch III was mainly replaced by Nb for REE isomorphism,while in the later stage,the replacement mode of REE^(3+)+□_(Ca)coexisted with it.The Mo content in scheelite,along with the corresponding Eu anomalies in both scheelite and garnet,collectively imply that the ore-forming fluids during various mineralization stages were predominantly oxidizing,with only slight reducibility observed in Sch II.The in-situ Sr isotope ratios of scheelite concentrates ranged from 0.7093 to 0.7153,resembling those of the Bozhushan granite,indicating a relationship between W mineralization and granite.In addition,the Y/Ho ratios of scheelite from various mineralization stages exhibit a narrow range(19-31),with a pronounced correlation between the contents of Y and Ho and a similar trend in their variation.This consistency suggests that the Guanfang deposit has undergone a uniform or comparable evolutionary process,implying a stable ore-forming fluid across diff erent mineralization stages. 展开更多
关键词 Guanfang W deposit Trace elements of scheelite In-situ Sr isotopes Southeast Yunnan
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Application of BDRM Theory in the Two-AXIS Underwater Channel 被引量:1
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作者 张林 笪良龙 卢晓亭 《Marine Science Bulletin》 CAS 2007年第2期12-17,共6页
Two-axis underwater channel often exists in deep ocean. Because of the coupling between surface channel and SOFAR channel, sound propagation in the two-axis underwater channel is complex and so its calculations of aco... Two-axis underwater channel often exists in deep ocean. Because of the coupling between surface channel and SOFAR channel, sound propagation in the two-axis underwater channel is complex and so its calculations of acoustic fields are difficult. The beam-displacement ray-mode (BDRM) theory is a normal mode method for propagation modeling in the common horizontally stratified shallow water. We improve the theory, proposing a new method for computing the upper boundary reflection coefficient, and apply it to calculate the acoustic fields of two-axis underwater channel. Transmission losses in the two-axis underwater channel are calculated by the BDRM theory. The results are in good agreement with the KRAKEN code and the computational speed excels those of the other methods. 展开更多
关键词 two-axis underwater channel BDRM theory reflection coefficient phase-shift correction
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Studies on GIS Based Tracing and Traceability of Safe Crop Product in China 被引量:29
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作者 QU Xiao-hui ZHUANG Da-fang QIU Dong-sheng 《Agricultural Sciences in China》 CAS CSCD 2007年第6期724-731,共8页
The safety of safe crop products (SCP) is critical to maintain people's health and living standard. With the global efforts on the improvement of the traceability of food products, it is inevitable to establish cor... The safety of safe crop products (SCP) is critical to maintain people's health and living standard. With the global efforts on the improvement of the traceability of food products, it is inevitable to establish corresponding traceability systems to monitor the safety of crop products in China. In this article, the supply chain pattern of SCP in China has been analyzed and its spatial characters have been described in detail. The study deals with on how to relate traceability technology with GIS, and on how to trace and retrace the safety of SCP using the function of excellent spatial representation, spatial locating, and spatial analysis provided in GIS, which has been discussed from several aspects, such as coding technique of traceability information, transferring technique of traceability information, spatialization of traceability information, and application integration of traceability system. A pilot study was carried out to present the basic functions of the system, which provided an efficient and credible way to trace and retrace the safety of SCP in a real supply chain. An innovative idea has been brought forward for how to establish an efficient, credible, applied traceability system of SCP. 展开更多
关键词 safe crop products (SCP) tracing and traceability GIS traceability code information transformation
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A Novel Roll Compensation Method for Two-Axis Transportable Satellite Antennas 被引量:3
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作者 Laiding Zhao Jidong Xie +1 位作者 Xiaodong Bai Zhicheng Qu 《China Communications》 SCIE CSCD 2018年第3期137-148,共12页
Two-axis transportable satellite antennas(TATSAs) have been widely adopted owing to its simple structure and low cost. However, by searching in a wide range, it will take a very long searching time. Under extreme cond... Two-axis transportable satellite antennas(TATSAs) have been widely adopted owing to its simple structure and low cost. However, by searching in a wide range, it will take a very long searching time. Under extreme conditions, it will even fail to work. In this paper, we propose a novel roll compensation(RC) method for the low-cost TATSAs to achieve faster tracking even if when the antenna has no azimuth sensor. By analyzing the influence of roll axis on the system performance, details of the compensation method are derived. Simulation and measurement results indicate that the proposed RC method can effectively reduce the initial searching time for satellite communication. In addition, tracking along with the ellipse path with the RC method provides the highest tracking efficiency. 展开更多
关键词 two-axis transportable satelliteantenna (TATSA) satellite tracking roll com-pensation (RC) searching time.
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Sound propagation in two-axis underwater channel based on beam-displacement ray-mode theory
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作者 张林 笪良龙 卢晓亭 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2007年第3期300-303,共4页
Sound propagation in a deep ocean two-axis underwater channel is often complex and difficult to simulate between surface channel and sound fixing and ranging (SOFAR) channel. The beam-displacement ray-mode (BDRM) theo... Sound propagation in a deep ocean two-axis underwater channel is often complex and difficult to simulate between surface channel and sound fixing and ranging (SOFAR) channel. The beam-displacement ray-mode (BDRM) theory is a normal mode method for propagation modeling in horizontally stratified shallow water. An improved method for computing the upper boundary reflection coefficient in the BDRM is proposed and applied to calculate the acoustic fields of a two-axis underwater channel. Transmission losses in the two-axis underwater channel are calculated in the new BDRM. The corresponding results are in good agreement with those from the Kraken code, and furthermore the computed speed of the new BDRM excels the other methods. 展开更多
关键词 two-axis underwater channel BDRM theory reflection coefficient phase-shift correction
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Tunable two-axis spin model and spin squeezing in two cavities
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作者 俞立先 李彩凤 +3 位作者 樊景涛 陈刚 张天才 贾锁堂 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第5期31-37,共7页
Multi-mode cavities have now attracted much attention both experimentally and theoretically. In this paper, inspired by recent experiments of cavity-assisted Raman transitions, we realize a two-axis spin Hamiltonian H... Multi-mode cavities have now attracted much attention both experimentally and theoretically. In this paper, inspired by recent experiments of cavity-assisted Raman transitions, we realize a two-axis spin Hamiltonian H = q(J_x^2+ χJ_y^2) + ω_0J_z in two cavities. This realized Hamiltonian has a distinct property that all parameters can be tuned independently. For proper parameters, the well-studied one- and two-axis twisting Hamiltonians are recovered, and the scaling of N^(-1) of the maximal squeezing factor can occur naturally. On the other hand, in the two-axis twisting Hamiltonian, spin squeezing is usually reduced when increasing the atomic resonant frequency ω_0. Surprisingly, we find that by combining with the dimensionless parameter χ(-1), this atomic resonant frequency ω_0 can enhance spin squeezing greatly. These results are beneficial for achieving the required spin squeezing in experiments. 展开更多
关键词 two-axis spin model spin squeezing two cavities
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Research of the Data Processing Method in Two-Axis Servo Drift Testing
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作者 郭素云 田自耘 +1 位作者 李东林 张宏伟 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1996年第1期34-37,共4页
The theory and algorithm of Singular Value Decomposition(SVD) is introduced.The advantage of Singular Value Decomposition used in system identification is studied,compared and illustrated through analyzing the data of... The theory and algorithm of Singular Value Decomposition(SVD) is introduced.The advantage of Singular Value Decomposition used in system identification is studied,compared and illustrated through analyzing the data of navigational gyroscopes drift in two-axis servo testing. 展开更多
关键词 ss:Gyroscope DRIFT SINGULAR Value DECOMPOSITION two-axis SERVO
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Paleoenvironmental Characteristics of Paleogene Lacustrine Source Rocks in the Western Bozhong Sag,Bohai Bay Basin,China:Evidence from Biomarkers,Major and Trace Elements 被引量:1
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作者 WANG Xiang LIU Guangdi +6 位作者 SONG Zezhang SUN Mingliang WANG Xiaolin WANG Feilong CHEN Rongtao GENG Mingyang LI Yishu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期220-240,共21页
The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these i... The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain controversial.To address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1 and 2(E_(2)s_(1+2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were studied.The above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1+2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater conditions.Comparatively,the depositional environments of E_(2)s_(1+2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1+2)belong to anoxic or suboxic settings with large evaporation and salinity.During the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant algae.Moreover,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial input.The OM origin of the E_(2)s_(1+2)and E_(2)s_(3)are mainly plankton and bacteria.Tectonic subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct differences.Overall,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace elements.The established models may have positive implications for research of lacustrine source rocks in offshore areas with few drillings. 展开更多
关键词 petroleum geology source rocks depositional environments biomarkers major elements trace elements Bozhong Sag
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Tailoring MXene Thickness and Functionalization for Enhanced Room‑Temperature Trace NO_(2) Sensing 被引量:3
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作者 Muhammad Hilal Woochul Yang +1 位作者 Yongha Hwang Wanfeng Xie 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期71-86,共16页
In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method... In this study,precise control over the thickness and termination of Ti3C2TX MXene flakes is achieved to enhance their electrical properties,environmental stability,and gas-sensing performance.Utilizing a hybrid method involving high-pressure processing,stirring,and immiscible solutions,sub-100 nm MXene flake thickness is achieved within the MXene film on the Si-wafer.Functionalization control is achieved by defunctionalizing MXene at 650℃ under vacuum and H2 gas in a CVD furnace,followed by refunctionalization with iodine and bromine vaporization from a bubbler attached to the CVD.Notably,the introduction of iodine,which has a larger atomic size,lower electronegativity,reduce shielding effect,and lower hydrophilicity(contact angle:99°),profoundly affecting MXene.It improves the surface area(36.2 cm^(2) g^(-1)),oxidation stability in aqueous/ambient environments(21 days/80 days),and film conductivity(749 S m^(-1)).Additionally,it significantly enhances the gas-sensing performance,including the sensitivity(0.1119Ωppm^(-1)),response(0.2% and 23%to 50 ppb and 200 ppm NO_(2)),and response/recovery times(90/100 s).The reduced shielding effect of the–I-terminals and the metallic characteristics of MXene enhance the selectivity of I-MXene toward NO2.This approach paves the way for the development of stable and high-performance gas-sensing two-dimensional materials with promising prospects for future studies. 展开更多
关键词 Controlled MXene thickness Gaseous functionalization approach Lower electronegativity functional groups Enhanced MXene stability Trace NO_(2)sensing
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Genesis of the Nuri Cu-W-Mo Deposit,Tibet,China:Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite 被引量:1
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作者 WANG Yiyun WU Zhishan +8 位作者 CHEN Wenqing DU Qing’an TANG Liwei SHI Hongzhao MA Guotao ZHANG Zhi LIANG Wei WU Bo MIAO Hengyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期117-131,共15页
The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controver... The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controversial since its discovery.Based on a study of the geological characteristics of the deposit,this study presents mineralization stages,focusing on the oxide stage and the quartz-sulfide stage where scheelite is mainly formed,referred to as Sch-A and Sch-B,respectively.Through LA-ICP-MS trace element and Sr isotope analyses,the origin,evolutionary process of the oreforming fluid and genesis of the ore deposit are investigated.Scanning Electron Microscope-Cathodoluminescence(SEMCL)observations reveal that Sch-A consists of three generations,with dark gray homogenous Sch-A1 being replaced by relatively lighter and homogeneous Sch-A2 and Sch-A3,with Sch-A2 displaying a gray CL image color with vague and uneven growth bands and Sch-A3 has a light gray CL image color with hardly any growth band.In contrast,Sch-B exhibits a‘core-rim’structure,with the core part(Sch-B1)being dark gray and displaying a uniform growth band,while the rim part(Sch-B2)is light gray and homogeneous.The normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore-forming fluid in the Nuri deposit originated from granodiorite porphyry and,later on,some country rock material was mixed in,due to strong water-rock interaction.Combining the O-H isotope data further indicates that the ore-forming fluid in the Nuri deposit originated from magmatic-hydrothermal sources,with contributions from metamorphic water caused by water-rock interaction during the mineralization process,as well as later meteoric water.The intense water-rock interaction likely played a crucial role in the precipitation of scheelite,leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz-sulfide stage,while also causing a gradual decrease in oxygen fugacity(fO2)and a slow rise in pH value.Additionally,the high Mo and low Sr contents in the scheelite are consistent with typical characteristics of magmatic-hydrothermal scheelite.Therefore,considering the geological features of the deposit,the geochemical characteristics of scheelite and the O-H isotope data published previously,it can be concluded that the genesis of the Nuri deposit belongs to porphyry-skarn deposit. 展开更多
关键词 trace elements in situ Sr isotopes tungsten mineralization Gangdese metallogenic belt TIBET
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The abundance,distribution,and enrichment mechanism of harmful trace elements in coals from Guizhou,Southwestern China 被引量:1
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作者 Hui Hou Wei Cheng +1 位作者 Ruidong Yang Yan Zhang 《Acta Geochimica》 EI CAS CSCD 2024年第5期889-903,共15页
Coal seams can enrich a variety of harmful trace elements under specific geological conditions.The spatial distribution of harmful trace elements in coal is extremely uneven,and the distribution characteristics of eac... Coal seams can enrich a variety of harmful trace elements under specific geological conditions.The spatial distribution of harmful trace elements in coal is extremely uneven,and the distribution characteristics of each element content are different.The harmful elements released in the process of coal mining and utilization will cause serious harm to the environment and the human body.It is of great resource significance to study the geochemistry of coal that affects the enrichment and distribution characteristics of harmful trace elements.Based on the domestic and foreign literature on coal geochemistry in Guizhou published by previous investigators,this study counted 1097 sample data from 23 major coal-producing counties in Guizhou Province,systematically summarized the relevant research results of harmful trace elements in the coal of Guizhou,and revealed the overall distribution and enrichment characteristics of harmful trace elements in the coal of Guizhou.The results show that the average contents of Cd,Pb,Se,Cu,Mo,U,V,As,Hg,and Cr in coal of Guizhou are higher than those in Chinese coal and world coal.A variety of harmful trace elements in the coal of Guizhou have high background values,especially in Liupanshui,Xingyi and Qianbei coalfield.The enrichment of various harmful trace elements in the Late Permian coal in Guizhou is mainly related to the combined action of various geological and geochemical factors.The supply of terrigenous debris and sedimentary environment may be the basic background of the enrichment of harmful elements in western Guizhou,while low-temperature hydrothermal activity and volcanic ash deposition may be the main reasons for the enrichment of harmful elements in southwestern Guizhou. 展开更多
关键词 Harmful trace elements Distribution characteristics Enrichment law Geological and geochemical features GUIZHOU
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Endoscopic Optical Doppler Tomography Based on Two-Axis Scanning MEMS Mirror
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作者 王东琳 郝蕴琦 +4 位作者 翟凤潇 杨坤 刘洪琼 陈巧 谢会开 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第12期5-9,共5页
We study the feasibility of endoscopic optical Doppler tomography with a micro-electro-mechanical system(MEMS) mirror based probe. The additional phase shifts introduced by the probe are tracked and formulated.The sup... We study the feasibility of endoscopic optical Doppler tomography with a micro-electro-mechanical system(MEMS) mirror based probe. The additional phase shifts introduced by the probe are tracked and formulated.The suppression method of the probe phase shifts is proposed and validated by fluid flow detection experiments.In vivo blood flow detection is also implemented on a hairless mouse. The velocities of the blood flow in two directions are obtained to be-8.1 mm/s and 6.6 mm/s, respectively. 展开更多
关键词 Endoscopic Optical Doppler Tomography Based on two-axis Scanning MEMS Mirror
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Health risk assessment of trace metal(loid)s in agricultural soils based on Monte Carlo simulation coupled with positive matrix factorization model in Chongqing, southwest China 被引量:1
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作者 MA Jie CHU Lijuan +3 位作者 SUN Jing WANG Shenglan GE Miao DENG Li 《Journal of Mountain Science》 SCIE CSCD 2024年第1期100-112,共13页
This study aimed to investigate the pollution characteristics, source apportionment, and health risks associated with trace metal(loid)s(TMs) in the major agricultural producing areas in Chongqing, China. We analyzed ... This study aimed to investigate the pollution characteristics, source apportionment, and health risks associated with trace metal(loid)s(TMs) in the major agricultural producing areas in Chongqing, China. We analyzed the source apportionment and assessed the health risk of TMs in agricultural soils by using positive matrix factorization(PMF) model and health risk assessment(HRA) model based on Monte Carlo simulation. Meanwhile, we combined PMF and HRA models to explore the health risks of TMs in agricultural soils by different pollution sources to determine the priority control factors. Results showed that the average contents of cadmium(Cd), arsenic (As), lead(Pb), chromium(Cr), copper(Cu), nickel(Ni), and zinc(Zn) in the soil were found to be 0.26, 5.93, 27.14, 61.32, 23.81, 32.45, and 78.65 mg/kg, respectively. Spatial analysis and source apportionment analysis revealed that urban and industrial sources, agricultural sources, and natural sources accounted for 33.0%, 27.7%, and 39.3% of TM accumulation in the soil, respectively. In the HRA model based on Monte Carlo simulation, noncarcinogenic risks were deemed negligible(hazard index <1), the carcinogenic risks were at acceptable level(10^(-6)<total carcinogenic risk ≤ 10^(-4)), with higher risks observed for children compared to adults. The relationship between TMs, their sources, and health risks indicated that urban and industrial sources were primarily associated with As, contributing to 75.1% of carcinogenic risks and 55.7% of non-carcinogenic risks, making them the primary control factors. Meanwhile, agricultural sources were primarily linked to Cd and Pb, contributing to 13.1% of carcinogenic risks and 21.8% of non-carcinogenic risks, designating them as secondary control factors. 展开更多
关键词 Monte Carlo simulation Health risk assessment Trace metal(loid)s Positive matrix factorization Agricultural soils
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Trace formula of the integro-differential operator on a quantum graph
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作者 WEI Li-xiao YANG Chuan-fu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第2期311-318,共8页
In this paper we study the eigenvalue problem for integro-differential operators on a lasso graph.The trace formula of the operator is established by applying the residual technique in complex analysis.
关键词 integro-differential operators EIGENVALUE trace formula
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Major ions and trace metals in glacial meltwaters nearby Ny-Ålesund, Svalbard
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作者 Zhan Shen Liping Ye +2 位作者 Jing Zhang Hongmei Ma Ruifeng Zhang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第10期86-99,共14页
Ny-Ålesund,located in Arctic Svalbard,is one of the most sensitive areas on Earth to global warming.In recent years,accelerated glacier ablation has become remarkable in Ny-Ålesund.Glacial meltwaters dischar... Ny-Ålesund,located in Arctic Svalbard,is one of the most sensitive areas on Earth to global warming.In recent years,accelerated glacier ablation has become remarkable in Ny-Ålesund.Glacial meltwaters discharge a substantial quantity of materials to the ocean,affecting downstream ecosystems and adjacent oceans.In August 2015,various water samples were taken near Ny-Ålesund,including ice marginal meltwater,proglacial meltwater,supraglacial meltwater,englacial meltwater,and groundwater.Trace metals(Al,Cr,Mn,Fe,Co,Cu,Zn,Cd,and Pb),major ions,alkalinity,pH,dissolved oxygen,water temperature and electric conductivity were also measured.Major ions were mainly controlled by chemical weathering intensity and reaction types,while trace metals were influenced by both chemical weathering and physicochemical control upon their mobility.Indeed,we found that Brøggerbreen was dominated by carbonate weathering via carbonation of carbonate,while Austre Lovénbreen and Pedersenbreen were dominated by sulfide oxidation coupled with carbonate dissolution with a doubled silicate weathering.The higher enrichment of trace metals in supraglacial meltwater compared to ice marginal and proglacial meltwater suggested anthropogenic pollution from atmospheric deposition.In ice marginal and proglacial meltwater,principal component analysis indicated that trace metals like Cr,Al,Co,Mn and Cd were correlated to chemical weathering.This implies that under accelerated glacier retreat,glacier-derived chemical components are subjected to future changes in weathering types and intensity. 展开更多
关键词 Arctic glacial meltwater WEATHERING major ions trace metals
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Trace elements in magmatic and hydrothermal quartz:Implications on the genesis of the Xingluokeng Tungsten Deposit,South China
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作者 Qing-Qing Zhang You-Wei Chen Jian-Feng Gao 《Acta Geochimica》 EI CAS CSCD 2024年第3期441-458,共18页
The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,and... The Xingluokeng deposit is the largest gran-ite-related tungsten deposit within the Wuyi metallogenic belt in South China.The Xingluokeng intrusion primarily consists of porphyritic biotite granite,biotite granite,andfine-grained granite.The deposit is represented by veinlet-disseminated mineralization with K-feldspathization and biotitization,alongside quartz-vein mineralization with gre-isenization and sericitization.This study investigates in-situ analyses of quartz compositions from both the intrusion and hydrothermal veinlets and veins.Trace element correlations indicate that trivalent Al^(3+)and Fe^(3+)replace Si^(4+)within the quartz lattice,with monovalent cations(such as Li^(+),Na^(+),and K^(+))primarily serving as charge compensators.Low Ge/Al ratios(<0.013)of quartz from granites suggest a mag-matic origin.The low Al/Ti and Ge/Ti ratios,accompanied by high Ti contents in quartz,suggest that the porphyritic biotite granite and biotite granite are characterized by rela-tively low levels of differentiation and high crystallization temperatures.In contrast,thefine-grained granite exhibits a higher degree of fractionation,lower crystallization tem-peratures,and a closer association with tungsten miner-alization.Ti contents in quartz from quartz veins indicate Qz-Ⅰformed at temperatures above 400°C,while Qz-Ⅱto Qz-Ⅴformed at temperatures below 350°C.Variations in different generations of quartz,as indicated by Al content and(Al+Fe)/(Li+Na+K)ratio,suggest that Qz-Ⅰprecipi-tated from a less acidicfluid with a stable pH,whereas Qz-Ⅱto Qz-Ⅴoriginated from a more acidicfluid with notable pH variations.Consequently,alkaline alteration and acidic alteration supplied the essential Ca and Fe for the precipita-tion of scheelite and wolframite,respectively,highlighting a critical mechanism in tungsten mineralization at the Xin-gluokeng deposit. 展开更多
关键词 QUARTZ Xingluokeng Tungsten deposit Trace elements South China
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Distribution, health and ecological risk assessments of trace elements in Nigerian oil sands
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作者 Odunayo T.Ore Festus M.Adebiyi 《Acta Geochimica》 EI CAS CSCD 2024年第1期59-71,共13页
The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. I... The Nigerian oil sands represent the largest oil sand deposit in Africa, yet there is little published information on the distribution and potential health and ecological risks of trace elements in the oil resource. In the present study, we investigated the distribution pattern of 18trace elements(including biophile and chalcophile elements) as well as the estimated risks associated with exposure to these elements. The results of the study indicated that Fe was the most abundant element, with a mean concentration of 22,131 mg/kg while Br had the lowest mean concentration of 48 mg/kg. The high occurrence of Fe and Ti suggested a possible occurrence of ilmenite(Fe TiO_(3)) in the oil sands. Source apportionment using positive matrix factorization showed that the possible sources of detected elements in the oil sands were geogenic, metal production, and crustal. The contamination factor, geo-accumulation index, modified degree of contamination, pollution load index, and Nemerow pollution index indicated that the oil sands are heavily polluted by the elements. Health risk assessment showed that children were relatively more susceptible to the potentially toxic elements in the oil sands principally via ingestion exposure route(HQ > 1E-04). Cancer risks from inhalation are unlikely due to CR < 1E-06 but ingestion and dermal contact pose severe risks(CR > 1E-04). The high concentrations of the elements pose serious threats due to the potential for atmospheric transport, bioaccessibility, and bioavailability. 展开更多
关键词 Biophile Chalcophile Oil sand Risk assessment Trace element
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面向数智化异构学习环境的学习者交互多层网络分析——基于Traces分析框架的应用与展望
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作者 王志军 苏晨予 余新宇 《远程教育杂志》 CSSCI 北大核心 2024年第6期73-82,91,共11页
在数智时代,学习逐渐呈现出学习空间开放多元、学习过程复杂非线性的特点,学习的社会化、智能化、情境化、网络化特征愈发显著,学习发生的情境是一个复杂系统。连续的学习行为数据以不同粒度分散在多个异构学习环境中,关联这些环境中的... 在数智时代,学习逐渐呈现出学习空间开放多元、学习过程复杂非线性的特点,学习的社会化、智能化、情境化、网络化特征愈发显著,学习发生的情境是一个复杂系统。连续的学习行为数据以不同粒度分散在多个异构学习环境中,关联这些环境中的数据是对复杂学习行为形成连续认识、系统深入把握数智化学习规律的关键,而如何对粒度不一且分散的交互数据进行关联和分析是学习分析研究中必须解决的问题。为此,研究指出基于多层网络分析法——Traces分析框架是应对这一问题的解决方案,并系统梳理了Traces分析框架的特征、核心概念、各个层级的分析过程及支持方法,进而通过案例展示了该方法既可以整体应用于识别交互会话及关键参与者、识别学习者群组(社区)、分析参与者之间的关系以及参与情况随时间的演变态势,又可以局部应用于微观层面的数据分析。研究表明,Traces分析框架能跨越多个数智化异构学习环境,从多个层次有效融合线程分析法、社会网络分析等多种方法,突破单一维度和还原论分析法的局限,关注行动者之间的复杂关系并扩展了分析对象,有助于研究者形成对复杂学习行为的连续性认识,堪称人类迈向“数据海洋”的数智时代教育研究新范式。该方法为全面地理解数智化异构学习环境中的交互规律,从整体和系统层面深度把握数智时代学习的复杂规律提供了新思路。 展开更多
关键词 多层网络分析 Traces分析框架 数智化学习环境 关联数据 学习分析 复杂系统 人工智能 数据海洋
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Mobility of Major and Trace Elements during the Bauxitization Processes in Ngaoundal Area (Adamawa Cameroon): Implication on Mining Perspectives
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作者 André Sini Harouna Boukari +4 位作者 Ondoa Augustin Désiré Balla Djetenbe Beral Salomon Wangmené Awé Simon Djakba Basga Jean Pierre Nguetnkam 《Open Journal of Geology》 CAS 2024年第1期81-100,共20页
This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical ... This study was focused to assess major and trace elements in bauxitic duricrusts from Ngaoundal and its surroundings in order to establish their mining interest. To this end, fieldworks, mineralogical and geochemical analyses were carried out. Four facies of duricrust were identified and characterized from the summit to the top of the slope of the Ngaoundal mountain: scoriaceous, pisolitic, nodular and massive. Mineralogical and geochemical analyses performed on 16 samples, revealed a significant concentration of Al<sub>2</sub>O<sub>3</sub> mainly in the scoriaceous facies (over 45% in grade), moderate in Fe<sub>2</sub>O<sub>3</sub> (averaging 23.69%) and SiO<sub>2</sub> (averaging 21.7%). Trace elements were generally low, excluding Cr (421 ppm on average), Zr (327 ppm on average and V (213 ppm on average). In addition, the limited quantities of alkalis (Na<sub>2</sub>O, K<sub>2</sub>O) and alkaline earths metals (MgO, CaO) coupled with the very high values of Chemical Index of Alteration (CIA) and Mineralogical Index of Alteration (MIA), (more than 99%) attest to the intense weathering of the studied materials. Allitization and monosiallitization constituted the crystallochemical phenomena that have led to the development of bauxitic minerals. More than 90% of gibbsite in scoriaceous facies, 52.21% - 76.01% of kaolinite in pisolitic facies and more than 40% of hematite in nodular facies were quantified. The relationships between the constitutive components indicated their interdependency during the bauxitization phenomenon. The mineralogical and geochemical properties highlighted the mining interest of the studied duricrusts to be valorized. 展开更多
关键词 Duricrust Bauxitization Phenomenon Mineralogical and Geochemical Characterization Major and Trace Elements Mining Potential
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Environmental characteristics of trace metals in seawater from the Ninety East Ridge in the Indian Ocean
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作者 Jingxi LI Di ZHANG +3 位作者 Fenghua JIANG Hong CHEN Wei CAO Chengjun SUN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第4期1119-1129,共11页
The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East ... The Ninety East Ridge in the Indian Ocean has complex and unique characteristics.The concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East Ridge in the Indian Ocean were investigated.Results show that the average concentrations of different trace metals in all the collected seawater samples were 1.134μg/L for V,0.158μg/L for Cr,0.489μg/L for Mn,0.427μg/L for Fe,0.011μg/L for Co,0.395μg/L for Ni,0.403μg/L for Cu,0.097μg/L for Cd,0.139μg/L for Pb,and 3.470μg/L for U.Differences in the horizontal and vertical distributions of all measured trace metals were revealed,and the occurrence of high concentrations was nonuniform.In addition,the significant differences in the concentration distribution of different trace metals in seawater on both sides of the Ninety East Ridge present regional segmentation in the area for various trace metals in deep sea water.This study provided basic data for future investigations on the environmental and ecological impact of trace metals in the Indian Ocean and the potential water mass transport mechanism. 展开更多
关键词 trace metal environmental characteristic Ninety East Ridge seawater Indian Ocean
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