The intelligent textile sensors based on fiber(1D)and fabric(2D)are the ideal candidates for wearable devices.Their flexible weaving and unique structure endow them with flexibility,lightweight,good air permeability,a...The intelligent textile sensors based on fiber(1D)and fabric(2D)are the ideal candidates for wearable devices.Their flexible weaving and unique structure endow them with flexibility,lightweight,good air permeability,and feasible integration with garments.In view of the spring-up of novel textile-based strain sensors,the novel materials and fabrication approaches were elaborated from spatial perspectives,i.e.,1D fibers/yarn and 2D fabric.The intrinsic sensing mechanism is the primary fac-tor affecting sensor sensitivity,and the variation trend of the sensing signal is closely related to it.Although existing studies have involved various sensing mechanisms,there is still lacking systematic classification and discussion.Hence,the sensing mechanisms of textile-based sensors were elaborated from spatial perspectives.Considering that strain sensors were mostly based on resistance variation,the sensing mechanisms of resistive textile-based strain sensors were mainly focused,mainly including fiber deformation,tunneling effect,crack propagation,fabric deformation,electrical contact and bridge connec-tion.Meanwhile,the corresponding resistance prediction models,usually used as important data fitting methodology,were also comprehensively discussed,which can reproduce the resistance trend and provide guidance for the sensor performance.Finally,the multifunctionality of textile-based strain sensors was summarized,namely multi-mode signal detection,visual interaction,energy collection,thermal management and medical treatment were discussed.It was expected to provide research insights into the multifunctional integration of textile sensors.展开更多
Inspired by the overlapping structure of snake scales,a reinforced scale-like knitted fabric(R-SLKF)was created in this work.To achieve this,short carbon fibers in an epoxy resin(ER)matrix were incorporated into the s...Inspired by the overlapping structure of snake scales,a reinforced scale-like knitted fabric(R-SLKF)was created in this work.To achieve this,short carbon fibers in an epoxy resin(ER)matrix were incorporated into the scales of an SLKF.The resulting textile is a highly stable protective composite that is flexible,warm,and thermally insulated.In addition,supe-rior stab-resistance is ensured through rigid protective blocks in the R-SLKF,making up a hard overlapping scale region,besides satisfactory flexibility via soft twisted ultra-high-molecular-weight polyethylene yarn-based textiles.The R-SLKF achieves high stab resistance(peak load of approximately 600 N for a single scale thickness of 2 mm),good flexibility(~290 mN cm),and breathability(100 MPa,423 mm/s),coupled with good warmth retention and thermal insulation prop-erties(0.28℃/s),which are superior to previously reported protective composite textiles.From the results,the combination of desirable individual protection,excellent wearability and comfort enables human beings to survive in extremely danger-ous environments.Finite element simulations provided valuable insights into the factors influencing the stab resistance of R-SLKF and elucidated the underlying anti-puncture mechanism in accordance with the experimental findings.This study presents a novel strategy for the facile industrial fabrication of flexible and lightweight protective composite textiles,which is expected to enhance the structure and material design for future innovations and provide advantages for personal protec-tive equipment in various industrial fields.展开更多
Neuromorphic computing systems,which mimic the operation of neurons and synapses in the human brain,are seen as an appealing next-generation computing method due to their strong and efficient computing abilities.Two-d...Neuromorphic computing systems,which mimic the operation of neurons and synapses in the human brain,are seen as an appealing next-generation computing method due to their strong and efficient computing abilities.Two-dimensional (2D) materials with dangling bond-free surfaces and atomic-level thicknesses have emerged as promising candidates for neuromorphic computing hardware.As a result,2D neuromorphic devices may provide an ideal platform for developing multifunctional neuromorphic applications.Here,we review the recent neuromorphic devices based on 2D material and their multifunctional applications.The synthesis and next micro–nano fabrication methods of 2D materials and their heterostructures are first introduced.The recent advances of neuromorphic 2D devices are discussed in detail using different operating principles.More importantly,we present a review of emerging multifunctional neuromorphic applications,including neuromorphic visual,auditory,tactile,and nociceptive systems based on 2D devices.In the end,we discuss the problems and methods for 2D neuromorphic device developments in the future.This paper will give insights into designing 2D neuromorphic devices and applying them to the future neuromorphic systems.展开更多
Flexible electronics offer a multitude of advantages,such as flexibility,lightweight property,portability,and high durability.These unique properties allow for seamless applications to curved and soft surfaces,leading...Flexible electronics offer a multitude of advantages,such as flexibility,lightweight property,portability,and high durability.These unique properties allow for seamless applications to curved and soft surfaces,leading to extensive utilization across a wide range of fields in consumer electronics.These applications,for example,span integrated circuits,solar cells,batteries,wearable devices,bio-implants,soft robotics,and biomimetic applications.Recently,flexible electronic devices have been developed using a variety of materials such as organic,carbon-based,and inorganic semiconducting materials.Silicon(Si)owing to its mature fabrication process,excellent electrical,optical,thermal properties,and cost efficiency,remains a compelling material choice for flexible electronics.Consequently,the research on ultra-thin Si in the context of flexible electronics is studied rigorously nowadays.The thinning of Si is crucially important for flexible electronics as it reduces its bending stiffness and the resultant bending strain,thereby enhancing flexibility while preserving its exceptional properties.This review provides a comprehensive overview of the recent efforts in the fabrication techniques for forming ultra-thin Si using top-down and bottom-up approaches and explores their utilization in flexible electronics and their applications.展开更多
The advancement of integrated circuits has made it easier to reduce the size of increasingly potent wearable electronic devices.However,it is still difficult to seamlessly integrate electronic systems enabling unrestr...The advancement of integrated circuits has made it easier to reduce the size of increasingly potent wearable electronic devices.However,it is still difficult to seamlessly integrate electronic systems enabling unrestricted human behavior into wearable gadgets.The procedure of creating fiber devices by twisting fiber electrodes and incorporating them into textile systems is exhibited in recent work.These textile systems are highly resilient and flexible,which makes them ideal for various wearable applications,i.e.,thread lithium-ion batteries(TLIBs),multi-ply sensing threads(MSTs),and thread electroluminescent devices(TELDs).展开更多
The development of various artificial electronics and machines would explosively increase the amount of information and data,which need to be processed via in-situ remediation.Bioinspired synapse devices can store and...The development of various artificial electronics and machines would explosively increase the amount of information and data,which need to be processed via in-situ remediation.Bioinspired synapse devices can store and process signals in a parallel way,thus improving fault tolerance and decreasing the power consumption of artificial systems.The organic field effect transistor(OFET)is a promising component for bioinspired neuromorphic systems because it is suitable for large-scale integrated circuits and flexible devices.In this review,the organic semiconductor materials,structures and fabrication,and different artificial sensory perception systems functions based on neuromorphic OFET devices are summarized.Subsequently,a summary and challenges of neuromorphic OFET devices are provided.This review presents a detailed introduction to the recent progress of neuromorphic OFET devices from semiconductor materials to perception systems,which would serve as a reference for the development of neuromorphic systems in future bioinspired electronics.展开更多
There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,a...There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,and fexible optoelectronics.Existing direct-lithography methods are difficult to use on fexible,nonplanar,and biocompatible surfaces.Therefore,this fabrication is usually accomplished by nanotransfer printing.However,large-scale integration of multiscale nanostructures with unconventional substrates remains challenging because fabrication yields and quality are often limited by the resolution,uniformity,adhesivity,and integrity of the nanostructures formed by direct transfer.Here,we proposed a resist-based transfer strategy enabled by near-zero adhesion,which was achieved by molecular modification to attain a critical surface energy interval.This approach enabled the intact transfer of wafer-scale,ultrathin-resist nanofilms onto arbitrary substrates with mitigated cracking and wrinkling,thereby facilitating the in situ fabrication of nanostructures for functional devices.Applying this approach,fabrication of three-dimensional-stacked multilayer structures with enhanced functionalities,nanoplasmonic structures with~10 nm resolution,and MoS2-based devices with excellent performance was demonstrated on specific substrates.These results collectively demonstrated the high stability,reliability,and throughput of our strategy for optical and electronic device applications.展开更多
Flexible thermoelectric(TE)materials that convert heat into electricity have been widely used in wearable electronics and other flexible devices.In this work,inorganic TE pillars were combined with thermoplastic polyu...Flexible thermoelectric(TE)materials that convert heat into electricity have been widely used in wearable electronics and other flexible devices.In this work,inorganic TE pillars were combined with thermoplastic polyurethane(TPU)to assemble a flexible string-shaped TE generator(TEG)for the fabrication of the thermoelectric fabric(TEF).Moreover,finite element analysis(FEA)was used to optimize the dimensions of the TE string and evaluate its performance.The FEA results showed that the inter-pillar spacing significantly affected the temperature difference,the output voltage and the internal resistance.A maximum power density of 3.43μW/cm^(2)(temperate gradientΔT=10.5 K)was achieved by the TE string with a diameter of 3.5 mm and an inter-pillar spacing of 2 mm.However,under the experimental condition,the achievable power density of the fabricated three-dimensional(3D)TEF was limited to 29%of the simulation result because of the inclination of the TE string within the fabric concerning heat plate contact and copper wire-TE pillar connections.The actual TE string also demonstrated high flexibility and stable mechanical properties after 450 bending cycles.Thus,the study would provide a foundation for future research in developing more efficient TEFs to offer a comfortable and conformable option for wearable energy harvesting applications.展开更多
The precursor with TiC0.7N0.3@WO3-MO3 microspheres were prepared by a novel method from the WO3-MoO3 sol dipping. Subsequently, TiC0.7N0.3@WC-MoC2 core-shell structural microspheres were successfully obtained by carbu...The precursor with TiC0.7N0.3@WO3-MO3 microspheres were prepared by a novel method from the WO3-MoO3 sol dipping. Subsequently, TiC0.7N0.3@WC-MoC2 core-shell structural microspheres were successfully obtained by carburizing the precursor at 900 °C in a flowing mixture of CH4 (20 ml·min-1) and H2 (200 ml·min-1) for 2 h. Then TiC0.7N0.3@WC-MoC2-15Co cermets were prepared utilizing the core-shell powders by spark plasma sintering (SPS). Powders of the precursors with TiC0.7N0.3@WO3-MO3 microspheres, TiC0.7N0.3@WC-MoC2 microspheres and TiC0.7N0.3@WC-MoC2-15Co cermets were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The obtained TiC0.7N0.3@WC-MoC2 microspheres have a dense WC-MoC2 coatings shell. The thickness of the shell could be easily controlled by adjusting the number of sol dipping cycles. It was found that the TiC0.7N0.3@WC-MoC2 microspheres were more beneficial to fabricate the "core-rim" structures by SPS.展开更多
The Janus fabrics designed for personal moisture/thermal regulation have garnered significant attention for their potential to enhance human comfort.However,the development of smart and dynamic fabrics capable of mana...The Janus fabrics designed for personal moisture/thermal regulation have garnered significant attention for their potential to enhance human comfort.However,the development of smart and dynamic fabrics capable of managing personal moisture/thermal comfort in response to changing external environments remains a challenge.Herein,a smart cellulose-based Janus fabric was designed to dynamically manage personal moisture/heat.The cotton fabric was grafted with N-isopropylacrylamide to construct a temperature-stimulated transport channel.Subsequently,hydrophobic ethyl cellulose and hydrophilic cellulose nanofiber were sprayed on the bottom and top sides of the fabric to obtain wettability gradient.The fabric exhibits anti-gravity directional liquid transportation from hydrophobic side to hydrophilic side,and can dynamically and continuously control the transportation time in a wide range of 3–66 s as the temperature increases from 10 to 40℃.This smart fabric can quickly dissipate heat at high temperatures,while at low temperatures,it can slow down the heat dissipation rate and prevent the human from becoming too cold.In addition,the fabric has UV shielding and photodynamic antibacterial properties through depositing graphitic carbon nitride nanosheets on the hydrophilic side.This smart fabric offers an innovative approach to maximizing personal comfort in environments with significant temperature variations.展开更多
In Fused Filament Fabrication(FFF),the state of material flow significantly influences printing outcomes.However,online monitoring of these micro-physical processes within the extruder remains challenging.The flow sta...In Fused Filament Fabrication(FFF),the state of material flow significantly influences printing outcomes.However,online monitoring of these micro-physical processes within the extruder remains challenging.The flow state is affected by multiple parameters,with temperature and volumetric flow rate(VFR)being the most critical.The study explores the stable extrusion of flow with a highly sensitive acoustic emission(AE)sensor so that AE signals generated by the friction in the annular region can reflect the flow state more effectively.Nevertheless,the large volume and broad frequency range of the data present processing challenges.This study proposes a method that initially selects short impact signals and then uses the Fast Kurtogram(FK)to identify the frequency with the highest kurtosis for signal filtration.The results indicate that this approach significantly enhances processing speed and improves feature extraction capabilities.By correlating AE characteristics under various parameters with the quality of extruded raster beads,AE can monitor the real-time state of material flow.This study offers a concise and efficient method for monitoring the state of raster beads and demonstrates the potential of online monitoring of the flow states.展开更多
In the fabrication of Bi nanowire array thermoelectric materials,electrodeposition technology has been used to deposit bismuth into the nanopores of anodic alumina porous films.The experiments show that the temperatur...In the fabrication of Bi nanowire array thermoelectric materials,electrodeposition technology has been used to deposit bismuth into the nanopores of anodic alumina porous films.The experiments show that the temperature significantly affects the electrodepositing process,and the simple form of Bi 3+ in the solutions is helpful to the deposition of metal Bi.The pulse plating technique is necessary for the electrodeposition because of the diffusive difficulty of Bi 3+ into the nanopores of the films.The XRD analysis indicates that Bi nanowire arrays have been manufactured by this technology.展开更多
随着区块链技术应用的普及,联盟链Hyperledger Fabric(简称Fabric)已成为知名区块链开源平台,并得到广泛关注.然而Fabric仍受困于并发事务间冲突问题,冲突发生时会引发大量无效交易上链,导致吞吐量下降,阻碍其发展.对于该问题,现有面向...随着区块链技术应用的普及,联盟链Hyperledger Fabric(简称Fabric)已成为知名区块链开源平台,并得到广泛关注.然而Fabric仍受困于并发事务间冲突问题,冲突发生时会引发大量无效交易上链,导致吞吐量下降,阻碍其发展.对于该问题,现有面向块内冲突的方案缺乏高效的冲突检测和避免方法,同时现有研究往往忽略区块间冲突对吞吐量的不利影响.提出了一种Fabric的优化方案Fabric-HT(fabric with high throughput),从区块内和区块间2方面入手,有效降低事务间并发冲突和提高系统吞吐量.针对区块内事务冲突,提出了一种事务调度机制,根据块内冲突事务集定义了一种高效数据结构——依赖关系链,识别具有“危险结构”的事务并提前中止,合理调度事务和消除冲突;针对区块间事务冲突,将冲突事务检测提前至排序节点完成,建立以“推送-匹配”为核心的冲突事务早期避免机制.在多场景下开展大量实验,结果表明Fabric-HT在吞吐量、事务中止率、事务平均执行时间、无效事务空间占用率等方面均优于对比方案.Fabric-HT吞吐量最高可达Fabric的9.51倍,是最新优化方案FabricSharp的1.18倍;空间利用率上相比FabricSharp提升了14%.此外,Fabric-HT也表现出较好的鲁棒性和抗攻击能力.展开更多
Linkers were assembled on a glass surface based on the hydrolysis and condensation of 3-glycidoxy ̄propyltrimethoxysilane (GPS). After the assembly of GPS, four approaches were tried to open the ending epoxide group o...Linkers were assembled on a glass surface based on the hydrolysis and condensation of 3-glycidoxy ̄propyltrimethoxysilane (GPS). After the assembly of GPS, four approaches were tried to open the ending epoxide group of GPS or to further elongate the linkers. The effect of these approaches on DNA in situ synthesis and hybridization was investigated. For the spacing of the synthesis initiation sites, the wettability of the support and the length of the linking group that attaches the initiation site to the surface have direct influences on the yield of coupling reactions and the subsequent hybridization events. X-ray photoelectron spectroscopy (XPS) and mean contact angles of deionized water of the above slides were measured to assess the linker's characteristics in each procedure. It was proved that the glass slides were successfully modified and became excellent supports for the oligonucleotides synthesis. In addition, it proved best for the in situ oligonucleotides synthesis that a glass slide was in turn treated with ethylenediamine, glutaradehyde, ethanolamine and sodium borohydride solution at ambient temperature after silanized with GPS.展开更多
Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics w...Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics was investigated. The results indicated that micro-honeycomb ceramics made from pore-forming agent cloth fabric with fibre diameter of 100 μm and slurry with 45% (mass fraction) moisture content have the porosity of 65% (volume fraction), bending strength of 24.3 MPa, pore size of about 100 μm, cell wall thickness of about 50 μm and porosity of 1131 pore/cm2. It was suggested that the pore size and the porosity could be adjusted using the pore-forming agent and moisture content of the slurry respectively.展开更多
As an excellent giant-magnetostrictive material, Tb-Dy-Fe alloys(based on Tb0.27-0.30Dy0.73-0.70Fe1.9-2Laves compound) can be applied in many engineering fields, such as sonar transducer systems, sensors, and micro-ac...As an excellent giant-magnetostrictive material, Tb-Dy-Fe alloys(based on Tb0.27-0.30Dy0.73-0.70Fe1.9-2Laves compound) can be applied in many engineering fields, such as sonar transducer systems, sensors, and micro-actuators. However, the cost of the rare earth elements Tb and Dy is too high to be widely applied for the materials. Nowadays, there are two different ways to substitute for these alloying elements. One is to partially replace Tb or Dy by cheaper rare earth elements, such as Pr, Nd, Sm and Ho; and the other is to use non-rare earth elements, such as Co, Al, Mn, Si, Ce, B, Be and C, to substitute Fe to form single MgCu_2-type Laves phase and a certain amount of Re-rich phase, which can reduce the brittleness and improve the corrosion resistance of the alloy. This paper systemically introduces the development, the fabrication methods and the corresponding preferred growth directions of Tb-Dy-Fe alloys. In addition, the effects of alloying elements and heat treatment on magnetostrictive and mechanical properties of Tb-Dy-Fe alloys are also reviewed, respectively. Finally, some possible applications of Tb-Dy-Fe alloys are presented.展开更多
Reduced activation ferritic/martensitic steel (RAFM) is recognized as the primary candidate structural material for ITER's test blanket module (TBM). To provide a material and property database for the design and...Reduced activation ferritic/martensitic steel (RAFM) is recognized as the primary candidate structural material for ITER's test blanket module (TBM). To provide a material and property database for the design and fabrication of the Chinese helium cooled ceramic breeding TBM (CN HCCB TBM), a type of RAFM steel named CLF-1 was developed and chaxacter^zed at the Southwestern Institute of Physics (SWIP), China. In this paper, the R&D status of CLF-1 steel and the technical issues in using CLF-1 steel to manufacture CN HCCB TBM were reviewed, including the steel manufacture and different welding technologies. Several kinds of property data have been obtained for its application to the design of the ITER TBM.展开更多
A new type heat storage concrete material used in solar thermal power was fabricated by using aluminates cement to be the gelatinizer, and using high heat capacity materials, such as basalt and bauxite, as aggregate, ...A new type heat storage concrete material used in solar thermal power was fabricated by using aluminates cement to be the gelatinizer, and using high heat capacity materials, such as basalt and bauxite, as aggregate, and adding high heat conductivity graphite and high efficient water reducing agent. The experimental results show the addition of graphite can improve the thermal conductivity of the concrete, the value of thermal conductivity is about 2.34 W/mK which means the obtained concrete storage material has excellent thermal properties, and it is expected to be a good heat storage material used in solar power.展开更多
基金supported by the major project of the National Natural Science Foundation of China(52090033/52090030).
文摘The intelligent textile sensors based on fiber(1D)and fabric(2D)are the ideal candidates for wearable devices.Their flexible weaving and unique structure endow them with flexibility,lightweight,good air permeability,and feasible integration with garments.In view of the spring-up of novel textile-based strain sensors,the novel materials and fabrication approaches were elaborated from spatial perspectives,i.e.,1D fibers/yarn and 2D fabric.The intrinsic sensing mechanism is the primary fac-tor affecting sensor sensitivity,and the variation trend of the sensing signal is closely related to it.Although existing studies have involved various sensing mechanisms,there is still lacking systematic classification and discussion.Hence,the sensing mechanisms of textile-based sensors were elaborated from spatial perspectives.Considering that strain sensors were mostly based on resistance variation,the sensing mechanisms of resistive textile-based strain sensors were mainly focused,mainly including fiber deformation,tunneling effect,crack propagation,fabric deformation,electrical contact and bridge connec-tion.Meanwhile,the corresponding resistance prediction models,usually used as important data fitting methodology,were also comprehensively discussed,which can reproduce the resistance trend and provide guidance for the sensor performance.Finally,the multifunctionality of textile-based strain sensors was summarized,namely multi-mode signal detection,visual interaction,energy collection,thermal management and medical treatment were discussed.It was expected to provide research insights into the multifunctional integration of textile sensors.
基金supported by the National Natural Science Funds of China(52373085 and 11972172)Natural Science Foundation of Hubei Province(2023AFB828)+5 种基金Innovative Team Program of Natural Science Foundation of Hubei Province(2023AFA027)the Fundamental Research Funds for the Central Universities(JUSRP22026)a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAP)Open Fund for Hubei Key Laboratory of Digital Textile EquipmentWuhan Textile University(No.DTL 2023022)National Local Joint Laboratory for Advanced Textile Processing and Clean Production(17).
文摘Inspired by the overlapping structure of snake scales,a reinforced scale-like knitted fabric(R-SLKF)was created in this work.To achieve this,short carbon fibers in an epoxy resin(ER)matrix were incorporated into the scales of an SLKF.The resulting textile is a highly stable protective composite that is flexible,warm,and thermally insulated.In addition,supe-rior stab-resistance is ensured through rigid protective blocks in the R-SLKF,making up a hard overlapping scale region,besides satisfactory flexibility via soft twisted ultra-high-molecular-weight polyethylene yarn-based textiles.The R-SLKF achieves high stab resistance(peak load of approximately 600 N for a single scale thickness of 2 mm),good flexibility(~290 mN cm),and breathability(100 MPa,423 mm/s),coupled with good warmth retention and thermal insulation prop-erties(0.28℃/s),which are superior to previously reported protective composite textiles.From the results,the combination of desirable individual protection,excellent wearability and comfort enables human beings to survive in extremely danger-ous environments.Finite element simulations provided valuable insights into the factors influencing the stab resistance of R-SLKF and elucidated the underlying anti-puncture mechanism in accordance with the experimental findings.This study presents a novel strategy for the facile industrial fabrication of flexible and lightweight protective composite textiles,which is expected to enhance the structure and material design for future innovations and provide advantages for personal protec-tive equipment in various industrial fields.
基金supported by the Hunan Science Fund for Distinguished Young Scholars (2023JJ10069)the National Natural Science Foundation of China (52172169)。
文摘Neuromorphic computing systems,which mimic the operation of neurons and synapses in the human brain,are seen as an appealing next-generation computing method due to their strong and efficient computing abilities.Two-dimensional (2D) materials with dangling bond-free surfaces and atomic-level thicknesses have emerged as promising candidates for neuromorphic computing hardware.As a result,2D neuromorphic devices may provide an ideal platform for developing multifunctional neuromorphic applications.Here,we review the recent neuromorphic devices based on 2D material and their multifunctional applications.The synthesis and next micro–nano fabrication methods of 2D materials and their heterostructures are first introduced.The recent advances of neuromorphic 2D devices are discussed in detail using different operating principles.More importantly,we present a review of emerging multifunctional neuromorphic applications,including neuromorphic visual,auditory,tactile,and nociceptive systems based on 2D devices.In the end,we discuss the problems and methods for 2D neuromorphic device developments in the future.This paper will give insights into designing 2D neuromorphic devices and applying them to the future neuromorphic systems.
基金supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. RS-2024-00353768)the Yonsei Fellowship, funded by Lee Youn Jae. This study was funded by the KIST Institutional Program Project No. 2E31603-22-140 (K J Y). S M W acknowledges the support by National Research Foundation of Korea (NRF) grant funded by the Korea government (Grant Nos. NRF-2021R1C1C1009410, NRF2022R1A4A3032913 and RS-2024-00411904)
文摘Flexible electronics offer a multitude of advantages,such as flexibility,lightweight property,portability,and high durability.These unique properties allow for seamless applications to curved and soft surfaces,leading to extensive utilization across a wide range of fields in consumer electronics.These applications,for example,span integrated circuits,solar cells,batteries,wearable devices,bio-implants,soft robotics,and biomimetic applications.Recently,flexible electronic devices have been developed using a variety of materials such as organic,carbon-based,and inorganic semiconducting materials.Silicon(Si)owing to its mature fabrication process,excellent electrical,optical,thermal properties,and cost efficiency,remains a compelling material choice for flexible electronics.Consequently,the research on ultra-thin Si in the context of flexible electronics is studied rigorously nowadays.The thinning of Si is crucially important for flexible electronics as it reduces its bending stiffness and the resultant bending strain,thereby enhancing flexibility while preserving its exceptional properties.This review provides a comprehensive overview of the recent efforts in the fabrication techniques for forming ultra-thin Si using top-down and bottom-up approaches and explores their utilization in flexible electronics and their applications.
基金supported by the Hunan Provincial Natural Science Foundation of China(No.2021JJ40519)the Outstanding Youth Project of Hunan Education Department(No.21B0750).
文摘The advancement of integrated circuits has made it easier to reduce the size of increasingly potent wearable electronic devices.However,it is still difficult to seamlessly integrate electronic systems enabling unrestricted human behavior into wearable gadgets.The procedure of creating fiber devices by twisting fiber electrodes and incorporating them into textile systems is exhibited in recent work.These textile systems are highly resilient and flexible,which makes them ideal for various wearable applications,i.e.,thread lithium-ion batteries(TLIBs),multi-ply sensing threads(MSTs),and thread electroluminescent devices(TELDs).
基金the National Natural Science Foundation of China(U21A20497)Singapore National Research Foundation Investigatorship(Grant No.NRF-NRFI08-2022-0009)。
文摘The development of various artificial electronics and machines would explosively increase the amount of information and data,which need to be processed via in-situ remediation.Bioinspired synapse devices can store and process signals in a parallel way,thus improving fault tolerance and decreasing the power consumption of artificial systems.The organic field effect transistor(OFET)is a promising component for bioinspired neuromorphic systems because it is suitable for large-scale integrated circuits and flexible devices.In this review,the organic semiconductor materials,structures and fabrication,and different artificial sensory perception systems functions based on neuromorphic OFET devices are summarized.Subsequently,a summary and challenges of neuromorphic OFET devices are provided.This review presents a detailed introduction to the recent progress of neuromorphic OFET devices from semiconductor materials to perception systems,which would serve as a reference for the development of neuromorphic systems in future bioinspired electronics.
基金supported by the National Key Research and Development Program of China(No.2022YFB4602600)the National Natural Science Foundation of China(No.52221001)Hunan Provincial Innovation Foundation for Postgraduate(No.CX20220406)。
文摘There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,and fexible optoelectronics.Existing direct-lithography methods are difficult to use on fexible,nonplanar,and biocompatible surfaces.Therefore,this fabrication is usually accomplished by nanotransfer printing.However,large-scale integration of multiscale nanostructures with unconventional substrates remains challenging because fabrication yields and quality are often limited by the resolution,uniformity,adhesivity,and integrity of the nanostructures formed by direct transfer.Here,we proposed a resist-based transfer strategy enabled by near-zero adhesion,which was achieved by molecular modification to attain a critical surface energy interval.This approach enabled the intact transfer of wafer-scale,ultrathin-resist nanofilms onto arbitrary substrates with mitigated cracking and wrinkling,thereby facilitating the in situ fabrication of nanostructures for functional devices.Applying this approach,fabrication of three-dimensional-stacked multilayer structures with enhanced functionalities,nanoplasmonic structures with~10 nm resolution,and MoS2-based devices with excellent performance was demonstrated on specific substrates.These results collectively demonstrated the high stability,reliability,and throughput of our strategy for optical and electronic device applications.
基金National Natural Science Foundation of China(No.51973034)Natural Science Foundation of Shanghai,China(No.23ZR1402500)Fundamental Research Funds for the Central Universities,China(Nos.2232022G01 and 19D110106)。
文摘Flexible thermoelectric(TE)materials that convert heat into electricity have been widely used in wearable electronics and other flexible devices.In this work,inorganic TE pillars were combined with thermoplastic polyurethane(TPU)to assemble a flexible string-shaped TE generator(TEG)for the fabrication of the thermoelectric fabric(TEF).Moreover,finite element analysis(FEA)was used to optimize the dimensions of the TE string and evaluate its performance.The FEA results showed that the inter-pillar spacing significantly affected the temperature difference,the output voltage and the internal resistance.A maximum power density of 3.43μW/cm^(2)(temperate gradientΔT=10.5 K)was achieved by the TE string with a diameter of 3.5 mm and an inter-pillar spacing of 2 mm.However,under the experimental condition,the achievable power density of the fabricated three-dimensional(3D)TEF was limited to 29%of the simulation result because of the inclination of the TE string within the fabric concerning heat plate contact and copper wire-TE pillar connections.The actual TE string also demonstrated high flexibility and stable mechanical properties after 450 bending cycles.Thus,the study would provide a foundation for future research in developing more efficient TEFs to offer a comfortable and conformable option for wearable energy harvesting applications.
基金Funded by the National High-tech Research and Development Program of China (2008AA031103)the Scientific and Technical Project of Sichuan Province (07GG002-006)
文摘The precursor with TiC0.7N0.3@WO3-MO3 microspheres were prepared by a novel method from the WO3-MoO3 sol dipping. Subsequently, TiC0.7N0.3@WC-MoC2 core-shell structural microspheres were successfully obtained by carburizing the precursor at 900 °C in a flowing mixture of CH4 (20 ml·min-1) and H2 (200 ml·min-1) for 2 h. Then TiC0.7N0.3@WC-MoC2-15Co cermets were prepared utilizing the core-shell powders by spark plasma sintering (SPS). Powders of the precursors with TiC0.7N0.3@WO3-MO3 microspheres, TiC0.7N0.3@WC-MoC2 microspheres and TiC0.7N0.3@WC-MoC2-15Co cermets were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The obtained TiC0.7N0.3@WC-MoC2 microspheres have a dense WC-MoC2 coatings shell. The thickness of the shell could be easily controlled by adjusting the number of sol dipping cycles. It was found that the TiC0.7N0.3@WC-MoC2 microspheres were more beneficial to fabricate the "core-rim" structures by SPS.
基金support of this work by National Key Research and Development Program of China(2019YFC19059003)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(23KJB430024)+1 种基金Jiangsu Funding Program for Excellent Postdoctoral Talent(2023ZB680)Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)are gratefully acknowledged.
文摘The Janus fabrics designed for personal moisture/thermal regulation have garnered significant attention for their potential to enhance human comfort.However,the development of smart and dynamic fabrics capable of managing personal moisture/thermal comfort in response to changing external environments remains a challenge.Herein,a smart cellulose-based Janus fabric was designed to dynamically manage personal moisture/heat.The cotton fabric was grafted with N-isopropylacrylamide to construct a temperature-stimulated transport channel.Subsequently,hydrophobic ethyl cellulose and hydrophilic cellulose nanofiber were sprayed on the bottom and top sides of the fabric to obtain wettability gradient.The fabric exhibits anti-gravity directional liquid transportation from hydrophobic side to hydrophilic side,and can dynamically and continuously control the transportation time in a wide range of 3–66 s as the temperature increases from 10 to 40℃.This smart fabric can quickly dissipate heat at high temperatures,while at low temperatures,it can slow down the heat dissipation rate and prevent the human from becoming too cold.In addition,the fabric has UV shielding and photodynamic antibacterial properties through depositing graphitic carbon nitride nanosheets on the hydrophilic side.This smart fabric offers an innovative approach to maximizing personal comfort in environments with significant temperature variations.
文摘In Fused Filament Fabrication(FFF),the state of material flow significantly influences printing outcomes.However,online monitoring of these micro-physical processes within the extruder remains challenging.The flow state is affected by multiple parameters,with temperature and volumetric flow rate(VFR)being the most critical.The study explores the stable extrusion of flow with a highly sensitive acoustic emission(AE)sensor so that AE signals generated by the friction in the annular region can reflect the flow state more effectively.Nevertheless,the large volume and broad frequency range of the data present processing challenges.This study proposes a method that initially selects short impact signals and then uses the Fast Kurtogram(FK)to identify the frequency with the highest kurtosis for signal filtration.The results indicate that this approach significantly enhances processing speed and improves feature extraction capabilities.By correlating AE characteristics under various parameters with the quality of extruded raster beads,AE can monitor the real-time state of material flow.This study offers a concise and efficient method for monitoring the state of raster beads and demonstrates the potential of online monitoring of the flow states.
基金the National Natural Science Foundation of China(No.50 0 71 0 4 0 )
文摘In the fabrication of Bi nanowire array thermoelectric materials,electrodeposition technology has been used to deposit bismuth into the nanopores of anodic alumina porous films.The experiments show that the temperature significantly affects the electrodepositing process,and the simple form of Bi 3+ in the solutions is helpful to the deposition of metal Bi.The pulse plating technique is necessary for the electrodeposition because of the diffusive difficulty of Bi 3+ into the nanopores of the films.The XRD analysis indicates that Bi nanowire arrays have been manufactured by this technology.
文摘随着区块链技术应用的普及,联盟链Hyperledger Fabric(简称Fabric)已成为知名区块链开源平台,并得到广泛关注.然而Fabric仍受困于并发事务间冲突问题,冲突发生时会引发大量无效交易上链,导致吞吐量下降,阻碍其发展.对于该问题,现有面向块内冲突的方案缺乏高效的冲突检测和避免方法,同时现有研究往往忽略区块间冲突对吞吐量的不利影响.提出了一种Fabric的优化方案Fabric-HT(fabric with high throughput),从区块内和区块间2方面入手,有效降低事务间并发冲突和提高系统吞吐量.针对区块内事务冲突,提出了一种事务调度机制,根据块内冲突事务集定义了一种高效数据结构——依赖关系链,识别具有“危险结构”的事务并提前中止,合理调度事务和消除冲突;针对区块间事务冲突,将冲突事务检测提前至排序节点完成,建立以“推送-匹配”为核心的冲突事务早期避免机制.在多场景下开展大量实验,结果表明Fabric-HT在吞吐量、事务中止率、事务平均执行时间、无效事务空间占用率等方面均优于对比方案.Fabric-HT吞吐量最高可达Fabric的9.51倍,是最新优化方案FabricSharp的1.18倍;空间利用率上相比FabricSharp提升了14%.此外,Fabric-HT也表现出较好的鲁棒性和抗攻击能力.
文摘Linkers were assembled on a glass surface based on the hydrolysis and condensation of 3-glycidoxy ̄propyltrimethoxysilane (GPS). After the assembly of GPS, four approaches were tried to open the ending epoxide group of GPS or to further elongate the linkers. The effect of these approaches on DNA in situ synthesis and hybridization was investigated. For the spacing of the synthesis initiation sites, the wettability of the support and the length of the linking group that attaches the initiation site to the surface have direct influences on the yield of coupling reactions and the subsequent hybridization events. X-ray photoelectron spectroscopy (XPS) and mean contact angles of deionized water of the above slides were measured to assess the linker's characteristics in each procedure. It was proved that the glass slides were successfully modified and became excellent supports for the oligonucleotides synthesis. In addition, it proved best for the in situ oligonucleotides synthesis that a glass slide was in turn treated with ethylenediamine, glutaradehyde, ethanolamine and sodium borohydride solution at ambient temperature after silanized with GPS.
基金Project (2011WK4013) supported by the Basic Research Program of Hunan Provincial Science and Technology Department, ChinaProject (K1003031-11) supported by the Major Program for the Fundamental Research of Changsha Science and Technology Bureau, China
文摘Micro-honeycomb ceramics were successfully fabricated through brush-coating with cloth fabric as pore-forming agent. The influence of pore-forming agent and slurry’s moisture content on the micro-honeycomb ceramics was investigated. The results indicated that micro-honeycomb ceramics made from pore-forming agent cloth fabric with fibre diameter of 100 μm and slurry with 45% (mass fraction) moisture content have the porosity of 65% (volume fraction), bending strength of 24.3 MPa, pore size of about 100 μm, cell wall thickness of about 50 μm and porosity of 1131 pore/cm2. It was suggested that the pore size and the porosity could be adjusted using the pore-forming agent and moisture content of the slurry respectively.
文摘As an excellent giant-magnetostrictive material, Tb-Dy-Fe alloys(based on Tb0.27-0.30Dy0.73-0.70Fe1.9-2Laves compound) can be applied in many engineering fields, such as sonar transducer systems, sensors, and micro-actuators. However, the cost of the rare earth elements Tb and Dy is too high to be widely applied for the materials. Nowadays, there are two different ways to substitute for these alloying elements. One is to partially replace Tb or Dy by cheaper rare earth elements, such as Pr, Nd, Sm and Ho; and the other is to use non-rare earth elements, such as Co, Al, Mn, Si, Ce, B, Be and C, to substitute Fe to form single MgCu_2-type Laves phase and a certain amount of Re-rich phase, which can reduce the brittleness and improve the corrosion resistance of the alloy. This paper systemically introduces the development, the fabrication methods and the corresponding preferred growth directions of Tb-Dy-Fe alloys. In addition, the effects of alloying elements and heat treatment on magnetostrictive and mechanical properties of Tb-Dy-Fe alloys are also reviewed, respectively. Finally, some possible applications of Tb-Dy-Fe alloys are presented.
基金supported by the China Nuclear Energy Development Program (No. H6603100)
文摘Reduced activation ferritic/martensitic steel (RAFM) is recognized as the primary candidate structural material for ITER's test blanket module (TBM). To provide a material and property database for the design and fabrication of the Chinese helium cooled ceramic breeding TBM (CN HCCB TBM), a type of RAFM steel named CLF-1 was developed and chaxacter^zed at the Southwestern Institute of Physics (SWIP), China. In this paper, the R&D status of CLF-1 steel and the technical issues in using CLF-1 steel to manufacture CN HCCB TBM were reviewed, including the steel manufacture and different welding technologies. Several kinds of property data have been obtained for its application to the design of the ITER TBM.
基金Funded by the National ‘973’ Program (No. 2010CB227105)the Na-tional ‘863’ Program (No.2007AA05Z459)
文摘A new type heat storage concrete material used in solar thermal power was fabricated by using aluminates cement to be the gelatinizer, and using high heat capacity materials, such as basalt and bauxite, as aggregate, and adding high heat conductivity graphite and high efficient water reducing agent. The experimental results show the addition of graphite can improve the thermal conductivity of the concrete, the value of thermal conductivity is about 2.34 W/mK which means the obtained concrete storage material has excellent thermal properties, and it is expected to be a good heat storage material used in solar power.