This study investigated the influence of graded Zn content on the evolution of precipitated and iron-rich phases and grain struc-ture of the alloys,designed and developed the Al–8.0Zn–1.5Mg–1.5Cu–0.2Fe(wt%)alloy w...This study investigated the influence of graded Zn content on the evolution of precipitated and iron-rich phases and grain struc-ture of the alloys,designed and developed the Al–8.0Zn–1.5Mg–1.5Cu–0.2Fe(wt%)alloy with high strength and formability.With the increase of Zn content,forming the coupling distribution of multiscale precipitates and iron-rich phases with a reasonable matching ratio and dispersion distribution characteristics is easy.This phenomenon induces the formation of cell-like structures with alternate distribu-tion of coarse and fine grains,and the average plasticity–strain ratio(characterizing the formability)of the pre-aged alloy with a high strength is up to 0.708.Results reveal the evolution and influence mechanisms of multiscale second-phase particles and the corresponding high formability mechanism of the alloys.The developed coupling control process exhibits considerable potential,revealing remarkable improvements in the room temperature formability of high-strength Al–Zn–Mg–Cu alloys.展开更多
The microstructures and mechanical properties of a new Mg-6%Zn-1%Mn(mass fraction) wrought magnesium alloy were studied,which could be extruded smoothly at 310-330℃with a complete dynamic recrystallization.After solu...The microstructures and mechanical properties of a new Mg-6%Zn-1%Mn(mass fraction) wrought magnesium alloy were studied,which could be extruded smoothly at 310-330℃with a complete dynamic recrystallization.After solution treatment one and two-step aging techniques were used.All as-aged microstructures contained two types of dispersed phases:β' phases and pureα-Mn particles.The two-step aging had a better strengthening effect than the traditional one-step aging,and the strength value achieved by the two-step aging could reach that of the ZK60 wrought magnesium alloy.The outstanding precipitation strengthening effect of the alloy should be attribute to the GP zones,diffusive solute-rich zones and some metastable phases formed during the first step aging that provide more effective nuclei for Mg-Zn strengthening phases during the second step aging.展开更多
The temperature dependence of critical strain for serrated yielding in high strength A1-Zn-Mg-Cu alloy may be divided into two temperature regions.Their temperature coefficients of critical strain will be negative and...The temperature dependence of critical strain for serrated yielding in high strength A1-Zn-Mg-Cu alloy may be divided into two temperature regions.Their temperature coefficients of critical strain will be negative and positive,respectively.展开更多
As a structural material with low density and high strength, super-highstrength aluminum alloys have a future for wide application. However, its poor stress corrosionresistance (SCC) restricts further development. In ...As a structural material with low density and high strength, super-highstrength aluminum alloys have a future for wide application. However, its poor stress corrosionresistance (SCC) restricts further development. In present, retrogression and re-ageing (RRA)treatment, which can improve both strength and SCCR of 7XXX series alloy, is a best method to solvethis problem. The effect of RRA treatment on the microstructure evolution of a new type lowfrequency electric-magnetic casting Al-9.OZn-2.45Mg-2.2Cu-0.15Zr alloy was investigated using DSCand TEM technologies. The results show that the typical microstructure of the alloy at T6 conditionis characterized by both fine eta' and GP zone homogeneously distributed in the matrix andcontinuous r) particles occurred on the grain-boundary. After RRA treatment, the matrixprecipitations are mainly fine and dispersed eta' and eta phases, being coarser and more stable thanthat from T6 temper. While, the grain-boundary microstructure is very close to that resulting fromT73 temper. High retrogression temperature and long retrogression time leads to a more stablemicrostructure after re-ageing.展开更多
In order to improve the stress corrosion cracking resistance of the weldable Al Zn Mg alloys with medium strength, the near solvus pre precipitation following high temperature solution treatment was performed on LC52 ...In order to improve the stress corrosion cracking resistance of the weldable Al Zn Mg alloys with medium strength, the near solvus pre precipitation following high temperature solution treatment was performed on LC52 and 7039 aluminum alloys. The effect of the pre precipitation on the microstructure, age hardening and stress corrosion cracking of LC52 and 7039 alloy was investigated. The results show that the near solvus pre precipitation can be limited on grain boundary and can enhance the discontinuity of grain boundary precipitates. The stress corrosion cracking resistance of aged Al Zn Mg alloys can be improved with non deteriorated strength and plasticity via pre precipitation.展开更多
Based on the investigation of the tensile properties of spray formed ultra-high strength Al10.8Zn2.9Mg1.9Cu alloys, the high-cycle fatigue properties under different theoretical stress concentration factors were inves...Based on the investigation of the tensile properties of spray formed ultra-high strength Al10.8Zn2.9Mg1.9Cu alloys, the high-cycle fatigue properties under different theoretical stress concentration factors were investigated, the fatigue fracture surfaces and microstructures were observed, and the fatigue mechanism was discussed. The results indicate that the ultimate tensile strength of spray formed Al10.8Zn2.9Mg1.9Cu alloys can reach up to 730?740 MPa, and the elongation is about 8%?10% under the condition of two-stage aging treatment. For the stress ratio is 0.1, the maximum stress for 107 cycles is over 400 MPa and 120 MPa, when the theoretical stress concentration factor is 1 and 3, respectively.展开更多
The effect of Yb addition on the strength and fracture toughness of Al-Zn-Mg-Cu-Zr aluminum alloy was investigated by measuring tensile properties and fracture toughness.The surface morphology was observed by optical ...The effect of Yb addition on the strength and fracture toughness of Al-Zn-Mg-Cu-Zr aluminum alloy was investigated by measuring tensile properties and fracture toughness.The surface morphology was observed by optical microscopy,scanning electron microscopy and transmission electron microscopy.The results show that Yb addition can produce fine coherent Yb contained dispersoids.Those dispersoids trend to inhibit Al matrix recrystallization and retain the recovery deformed microstructure.Compared with Al-Zn-Mg-Cu-Zr alloy,Yb contained alloy demonstrates mechanical property improvements from 710 MPa to 747 MPa for ultimate strength,from 684 MPa to 725 MPa for yield strength,from 21 MPa.m1/2 to 29 MPa.m1/2 for fracture toughness with T6 treatment.展开更多
The microstructures after various ageing treatments and their relation to the strength, fracture toughness, and corrosion behavior of an Al-Zn-Mg-Cu alloy pre-stretched plate were investigated. The results show that r...The microstructures after various ageing treatments and their relation to the strength, fracture toughness, and corrosion behavior of an Al-Zn-Mg-Cu alloy pre-stretched plate were investigated. The results show that retrogression and reaging (RRA) treatment led to a combination of high strength and stress corrosion cracking (SCC) resistance of the alloy. The TEM microstructure of the RRA-treated alloy is a distribution of very fine precipitates in the aluminum matrix grains, similar to that obtained under T6 condition, and the distribution of coarse η MgZn2 precipitates on the grain boundaries similar to that obtained by T7 temper. SEM observations revealed that most of the intergranular fracture characteristics were present on the fracture surface of both the T6 and RRA-treated specimens. On the contrary, the fractographs of the T7 treated specimens mainly consisted of dimple-type ductile transgranular fracture with minor intergranular cracking.展开更多
The effects of the composition and cooling process on the microstructures and properties of hot-rolled ultra-high strength low alloy (HSLA) steel, complex phase steel and martensite steel were studied in the laborat...The effects of the composition and cooling process on the microstructures and properties of hot-rolled ultra-high strength low alloy (HSLA) steel, complex phase steel and martensite steel were studied in the laboratory. And S700MC and MP1200 ultra-high strength steels were trial produced at the 1 880 mm hot-rolling line of Baosteel. Compared with conventional hot-rolled high strength products,the idea that water is alloy was applied in the newly developed hot-rolled ultra-high strength steel. By the use of the economical composition design and controlled cooling after hot-rolling effectively,ultra-high strength steel of different steel grades can be obtained.展开更多
基金supported by the National Key Research and Development Program of China(No.2021YFE0115900)the National Natural Science Foundation of China(Nos.52371016,51871029,and 51571023)the Opening Project of State Key Laboratory for Advanced Metals and Materials(Nos.2020-ZD02 and No.2022-Z03).
文摘This study investigated the influence of graded Zn content on the evolution of precipitated and iron-rich phases and grain struc-ture of the alloys,designed and developed the Al–8.0Zn–1.5Mg–1.5Cu–0.2Fe(wt%)alloy with high strength and formability.With the increase of Zn content,forming the coupling distribution of multiscale precipitates and iron-rich phases with a reasonable matching ratio and dispersion distribution characteristics is easy.This phenomenon induces the formation of cell-like structures with alternate distribu-tion of coarse and fine grains,and the average plasticity–strain ratio(characterizing the formability)of the pre-aged alloy with a high strength is up to 0.708.Results reveal the evolution and influence mechanisms of multiscale second-phase particles and the corresponding high formability mechanism of the alloys.The developed coupling control process exhibits considerable potential,revealing remarkable improvements in the room temperature formability of high-strength Al–Zn–Mg–Cu alloys.
基金Projects(2006BAE04B03,2007BAQ00134-04)supported by the National Science and Technology Supporting ProgramProject(2007CB613700)supported hy the"973"National Grand Theoretical Research Program of ChinaProject(50725413)supportedby the National Outstanding Youth Scientific Fund of China
文摘The microstructures and mechanical properties of a new Mg-6%Zn-1%Mn(mass fraction) wrought magnesium alloy were studied,which could be extruded smoothly at 310-330℃with a complete dynamic recrystallization.After solution treatment one and two-step aging techniques were used.All as-aged microstructures contained two types of dispersed phases:β' phases and pureα-Mn particles.The two-step aging had a better strengthening effect than the traditional one-step aging,and the strength value achieved by the two-step aging could reach that of the ZK60 wrought magnesium alloy.The outstanding precipitation strengthening effect of the alloy should be attribute to the GP zones,diffusive solute-rich zones and some metastable phases formed during the first step aging that provide more effective nuclei for Mg-Zn strengthening phases during the second step aging.
文摘The temperature dependence of critical strain for serrated yielding in high strength A1-Zn-Mg-Cu alloy may be divided into two temperature regions.Their temperature coefficients of critical strain will be negative and positive,respectively.
文摘As a structural material with low density and high strength, super-highstrength aluminum alloys have a future for wide application. However, its poor stress corrosionresistance (SCC) restricts further development. In present, retrogression and re-ageing (RRA)treatment, which can improve both strength and SCCR of 7XXX series alloy, is a best method to solvethis problem. The effect of RRA treatment on the microstructure evolution of a new type lowfrequency electric-magnetic casting Al-9.OZn-2.45Mg-2.2Cu-0.15Zr alloy was investigated using DSCand TEM technologies. The results show that the typical microstructure of the alloy at T6 conditionis characterized by both fine eta' and GP zone homogeneously distributed in the matrix andcontinuous r) particles occurred on the grain-boundary. After RRA treatment, the matrixprecipitations are mainly fine and dispersed eta' and eta phases, being coarser and more stable thanthat from T6 temper. While, the grain-boundary microstructure is very close to that resulting fromT73 temper. High retrogression temperature and long retrogression time leads to a more stablemicrostructure after re-ageing.
文摘In order to improve the stress corrosion cracking resistance of the weldable Al Zn Mg alloys with medium strength, the near solvus pre precipitation following high temperature solution treatment was performed on LC52 and 7039 aluminum alloys. The effect of the pre precipitation on the microstructure, age hardening and stress corrosion cracking of LC52 and 7039 alloy was investigated. The results show that the near solvus pre precipitation can be limited on grain boundary and can enhance the discontinuity of grain boundary precipitates. The stress corrosion cracking resistance of aged Al Zn Mg alloys can be improved with non deteriorated strength and plasticity via pre precipitation.
基金Project(2001AA332030) supported by the National High-Tech Research and Development Program of China
文摘Based on the investigation of the tensile properties of spray formed ultra-high strength Al10.8Zn2.9Mg1.9Cu alloys, the high-cycle fatigue properties under different theoretical stress concentration factors were investigated, the fatigue fracture surfaces and microstructures were observed, and the fatigue mechanism was discussed. The results indicate that the ultimate tensile strength of spray formed Al10.8Zn2.9Mg1.9Cu alloys can reach up to 730?740 MPa, and the elongation is about 8%?10% under the condition of two-stage aging treatment. For the stress ratio is 0.1, the maximum stress for 107 cycles is over 400 MPa and 120 MPa, when the theoretical stress concentration factor is 1 and 3, respectively.
基金Project(2005CB623704)supported by the National Basic Research Program of ChinaProject(50721003)supported by the Creative Research Group of National Natural Science Foundation of China
文摘The effect of Yb addition on the strength and fracture toughness of Al-Zn-Mg-Cu-Zr aluminum alloy was investigated by measuring tensile properties and fracture toughness.The surface morphology was observed by optical microscopy,scanning electron microscopy and transmission electron microscopy.The results show that Yb addition can produce fine coherent Yb contained dispersoids.Those dispersoids trend to inhibit Al matrix recrystallization and retain the recovery deformed microstructure.Compared with Al-Zn-Mg-Cu-Zr alloy,Yb contained alloy demonstrates mechanical property improvements from 710 MPa to 747 MPa for ultimate strength,from 684 MPa to 725 MPa for yield strength,from 21 MPa.m1/2 to 29 MPa.m1/2 for fracture toughness with T6 treatment.
基金the financial support from the Fundamental Research Program of Shanxi Province,China(No.202203021211130)the National Natural Science Foundation of China(Nos.51801132,52075359)。
基金financially supported by the National Hi-Tech Research and Development Program of China (No. 2003AA331100)
文摘The microstructures after various ageing treatments and their relation to the strength, fracture toughness, and corrosion behavior of an Al-Zn-Mg-Cu alloy pre-stretched plate were investigated. The results show that retrogression and reaging (RRA) treatment led to a combination of high strength and stress corrosion cracking (SCC) resistance of the alloy. The TEM microstructure of the RRA-treated alloy is a distribution of very fine precipitates in the aluminum matrix grains, similar to that obtained under T6 condition, and the distribution of coarse η MgZn2 precipitates on the grain boundaries similar to that obtained by T7 temper. SEM observations revealed that most of the intergranular fracture characteristics were present on the fracture surface of both the T6 and RRA-treated specimens. On the contrary, the fractographs of the T7 treated specimens mainly consisted of dimple-type ductile transgranular fracture with minor intergranular cracking.
基金supported by the National Natural Science Foundation of China(No.51905215)the Major Scientific and Technological Innovation Project of Shandong Province,China(No.2019JZZY020111)。
文摘The effects of the composition and cooling process on the microstructures and properties of hot-rolled ultra-high strength low alloy (HSLA) steel, complex phase steel and martensite steel were studied in the laboratory. And S700MC and MP1200 ultra-high strength steels were trial produced at the 1 880 mm hot-rolling line of Baosteel. Compared with conventional hot-rolled high strength products,the idea that water is alloy was applied in the newly developed hot-rolled ultra-high strength steel. By the use of the economical composition design and controlled cooling after hot-rolling effectively,ultra-high strength steel of different steel grades can be obtained.