To improve their mechanical and thermal insulation properties, aluminum silicate fibrous materials with in situ synthesized K_2Ti_6O_(13) whiskers were prepared by firing a mixture of short aluminum silicate fibers an...To improve their mechanical and thermal insulation properties, aluminum silicate fibrous materials with in situ synthesized K_2Ti_6O_(13) whiskers were prepared by firing a mixture of short aluminum silicate fibers and gel powders obtained from a sol–gel process. During the preparation process, the fiber surface was coated with K_2Ti_6O_(13) whiskers after the fibers were subjected to a heat treatment carried out at various temperatures. The effects of process parameters on the microstructure, compressive strength, and thermal conductivity were analyzed systematically. The results show that higher treatment temperatures and longer treatment durations promoted the development of K_2Ti_6O_(13) whiskers on the surface of aluminum silicate fibers; in addition, the intersection structure between whiskers modulated the morphology and volume of the multi-aperture structure among fibers, substantially increasing the fibers' compressive strength and reducing their heat conduction and convective heat transfer at high temperatures.展开更多
The zeta potential measurements show that the flotation separation of diaspore from kaolinite, illite and pyrophyllite could be achieved in the range of pH 46.5 with cationic collectors. A special quaternary ammonium ...The zeta potential measurements show that the flotation separation of diaspore from kaolinite, illite and pyrophyllite could be achieved in the range of pH 46.5 with cationic collectors. A special quaternary ammonium salts(DTAL) shows better selectivity than that the dodecyl amine(DDA) does for the flotation of three silicates. The closed circuit flotation results show that the reverse flotation de silicate can be achieved with DTAL as collector, a new inorganic reagent(SFL) as depressant and MIBC as frother to obtain a bauxite concentrate m (Al 2O 3)/ m (SiO 2) >10, Al 2O 3 recovery>86%).展开更多
To improve the crack-resistance of the mould for silica sol bonded quartz based ceramic mould casting,aluminum silicate fibers with the diameter ranging from 5 μm to 25 μm and the length about 1 mm were dispersed in...To improve the crack-resistance of the mould for silica sol bonded quartz based ceramic mould casting,aluminum silicate fibers with the diameter ranging from 5 μm to 25 μm and the length about 1 mm were dispersed in the ceramic mould.The effect of the aluminum silicate fibers on the tensile strength,shrinkage rate and the cracking trend of the ceramic mould were investigated.In the ceramic slurry,quartz sand was applied as ceramic aggregate,silica sol containing 30% silicon dioxide as bonder,and the weight ratio of quartz sand to silica sol was 2.69;the dispersed fibers changed from 0 to 0.24vol.%.The mould samples were formed after the slurry was poured and gelled at room temperature,and then sintered at different temperatures ranging from 100 to 800 ℃ to measure the tensile strength and shrinkage rate.The results show that,with the aluminum silicate fiber addition increasing from 0 to 0.24vol.%,the tensile strength increases linearly from 0.175 MPa to 0.236 MPa,and the shrinkage rate decreases linearly from 1.75% to 1.68% for the ceramic mould sintered at 400 ℃,from 1.37% to 1.31% for the ceramic mould at room temperature.As the sintering temperature was raised from 100 ℃ to 800 ℃,the tensile strength increases,and the shrinkage rate decreases at all temperatures,compared with those without fiber dispersion,but their variation patterns remain the same.Furthermore,the cracking trend of the mould and its decreasing proportion were defined and analyzed quantitatively considering both effects of the fiber dispersion on the strength and shrinkage.The cracking trend appears to decrease linearly with increasing fiber content and to reach the maximum reduction of 28.8% when 0.24vol.% fiber was dispersed.Therefore,the investigation proposes a new method to improve the crack-resistance of the ceramic mould,i.e.,inorganic fiber dispersion into the ceramic mould.展开更多
Antiviral effects of a synthetic Aluminum-Magnesium Silicate (AMS) were tested on Fowl Pox Virus (FPV). Five batches of the Nigerian brand of FPV vaccine were used as sources of the virus. The reconstituted vaccines w...Antiviral effects of a synthetic Aluminum-Magnesium Silicate (AMS) were tested on Fowl Pox Virus (FPV). Five batches of the Nigerian brand of FPV vaccine were used as sources of the virus. The reconstituted vaccines were mixed with The Synthetic AMS on equal volume to weight basis and incubated at room temperature for one hour. They were centrifuged for 10 minutes at 2000 revolutions per minute. The incubation and centrifugation were repeated on a portion of each vaccine supernatant. The two sets of supernatants were tested by the Modified Passive Haemagglutination test, for FPV titres. Portions of the vaccines, not incubated with the AMS, were served as controls. Fowl Pox Virus titres of the vaccines increased from a mean of 2.8 ± 1.10 to 11.2 ± 4.38 when incubated with the AMS once. When incubation with the AMS was repeated, the titres reduced (P< 0.05) to zero in each sample.展开更多
Ultra-fine aluminum nitride has been synthesized by the evaporation of aluminum powder at atmospheric-pressure nitrogen plasma in a hot-wall reactor. The average size of aluminum nitride particle is 0.11 μm measured ...Ultra-fine aluminum nitride has been synthesized by the evaporation of aluminum powder at atmospheric-pressure nitrogen plasma in a hot-wall reactor. The average size of aluminum nitride particle is 0.11 μm measured by scanning electric mirror (SEM), and the purity is at least over 90% evaluated by X-Ray diffraction (XRD). The conversion of Al powder to aluminum nitride is strongly depended on the injection of NH3. Typical experimental parameters such as the feed rate of raw material, the flow rate of ammonia and the position of injecting aluminum powder into the reactor are given.展开更多
Viral loads (copies of RNA per ml of plasma) of HIV/AIDS patients, who volunteered for clinical trial of the Medicinal synthetic Aluminum-magnesium silicate, were assessed, before and after they were treated. The trea...Viral loads (copies of RNA per ml of plasma) of HIV/AIDS patients, who volunteered for clinical trial of the Medicinal synthetic Aluminum-magnesium silicate, were assessed, before and after they were treated. The treatment lasted 4 weeks, 8 weeks and 12 weeks respectively. A patient who could not access approved laboratory for viral load test on time, continued the treatment?for 24 weeks. Following treatment with the medicine, mean viral load of HIV/AIDS patients reduced (P < 0.05) from 18875.00 ± 17059.18 to 327.50 ± 226.84. Rates of the viral load reduction were: 86% after 4 weeks, 96% after 8 weeks and 99.71% after 12 weeks. Clinical signs complained of, by the patients during the treatment, included, fever, dermatitis, boils, joint pain, leg edema and sore throat. These clinical signs ceased when they were treated, so that the antiretroviral treatment was completed. The patient who was on the medication for 24 weeks had no adverse drug reaction.展开更多
Experiments were conducted to evaluate the grain refinement and thermal stability of ultra-fine grained Al-4Mgalloy introduced by equal-channel angular pressing (ECAP) at 473 K. The results show that the intensities o...Experiments were conducted to evaluate the grain refinement and thermal stability of ultra-fine grained Al-4Mgalloy introduced by equal-channel angular pressing (ECAP) at 473 K. The results show that the intensities of X-ray(111/222) and (200/400) peaks for the alloy processed by ECAP decrease significantly and the peak widths of halfheight become broadening compared with the corresponding value in the annealed alloy. The microstructure of 2passes ECAPed alloy consists of both elongated and equiaxed subgrains. The residual strain in the alloy increaseswith increasing passes numbers, that appears as increasing dislocation density and lattice constant of matrix. Anequiaxed ultra-fine grained structure of~0.2μm is obtained in the present alloy after 8 passes. The ultra-fine grainsare stable below 523 K, because the alloy retains extremely fine grain size of~1μm after static annealing at 523 Kfor 1 h.展开更多
The crystallinity of lithium aluminosilicate(LAS) glass after crystallization were studied at different temperatures by X-ray diffractometry and the crystallinity of the standard glass ceramic with known crystal and g...The crystallinity of lithium aluminosilicate(LAS) glass after crystallization were studied at different temperatures by X-ray diffractometry and the crystallinity of the standard glass ceramic with known crystal and glass phases was examined. The crystallization mechanism of LAS glass was analyzed by the crystallinity, with a formula relating the crystallinity (X) and temperature (T). The results show that the calculated crystallinity of LAS glass by XRD increases with the crystallization temperature, in the range of 40%?50%, which is close to the calculated ones of standard samples with spodumene quartz ratio of 40%?70%. The activation energy of LAS glass is different within different temperature ranges; nEc is 125.44 kJ/mol at 710?810 ℃ and nEc is 17.42 kJ/mol at 810?980 ℃, which indicates different crystallization mechanisms. It has been proved that the required energy for crystallization of glass in the lower temperature range includes the interfacial energy between glass and crystalline phase and the free energy difference of atoms in structures of glass and crystal, and in the higher temperature ranges only the interfacial energy between glass and crystalline phase is considered.展开更多
Effects of aluminum on water distribution system and human health mainly attribute to its speciation in drinking water. Laboratory experiments were performed to investigate factors that may influence aluminum speciati...Effects of aluminum on water distribution system and human health mainly attribute to its speciation in drinking water. Laboratory experiments were performed to investigate factors that may influence aluminum speciation in water supply system. The concentration of soluble aluminum and its transformation among other aluminum species were mainly controlled by kinetics processes of related reactions. Total aluminum concentration had a notable effect on the concentrations of mononuclear and soluble aluminum in the first 4 day; then its effect became weak. At pH above 7.50, both fluoride and orthophosphate had little effect on aluminum speciation; while, when the solution pH was below 7.50, the concentrations of mononuclear and soluble aluminum were proportional to the concentration of fluoride and inversely proportional to the concentration of orthophosphate. Both mononuclear and polynuclear silicic acids could complex with mononuclear aluminum by forming soluble aluminosilicates. In addition, the adding sequence of orthophosphate and aluminum into drinking water would also affect the distribution of aluminum species in the first 4 day. In order to minimize aluminum bioavailability in drinking water, it was suggested that orthophosphate should be added prior to coagulant process, and that the concentrations of fluoride and silicic acids should be controlled below 2.0 and 25 mg/L, respectively, prior to the treatment. The solution pH in coagulation and filtration processes should be controlled in the range of 6.50-7.50.展开更多
Using cetyl trimethylammonium bromide (CTAB) as collector, the flotation de-silicating from diasporic-bauxite was investigated. And the Zeta potentials and contact-angles of silicate minerals and diaspore were also ...Using cetyl trimethylammonium bromide (CTAB) as collector, the flotation de-silicating from diasporic-bauxite was investigated. And the Zeta potentials and contact-angles of silicate minerals and diaspore were also stu-(died.)The results show that in the presence of 2×10-4 mol·L-1CTAB, the surface charges of pyrophyllite, kaolinite and illite become more positive, and the contact angles of these three silicates also increase evidently in the pH range of 2-8, but the Zeta potentials and contact angles of diaspore change little. So, the floatability of the four minerals is in the following order: pyrophyllite>kaolinite≈illite>diaspore. The open-circuit flotation results also show that a bauxite concentrate with m(Al2O3)/m(SiO2) over 9.3 and Al2O3 recovery over 76% can be obtained from diasporic-bauxite ore. The result of XRD of the bauxite concentrate shows that pyrophyllite is easier to be removed from diasporic-bauxite than illite and kaolinite due to its better floatability.展开更多
An open-cell aluminum foam filled with silicate rubber (AFFSR) was fabricated by infiltration of the liquid silicate rubber into the open-cell aluminum foam. The experiments were carried out to investigate the compres...An open-cell aluminum foam filled with silicate rubber (AFFSR) was fabricated by infiltration of the liquid silicate rubber into the open-cell aluminum foam. The experiments were carried out to investigate the compressive behavior and energy absorption characteristics of the material. It is found that the stress—strain response of the AFFSR exhibits five regions including two plateau regimes, which is quite different from the stress—strain curves of many unfilled metallic foams that usually exhibit three distinct regions. The plastic deformation of the AFFSR is prolonged because of the filled silicate rubber, compared with the aluminum foam without such a filler. The AFFSR also exhibits a higher energy capacity than the aluminum foam without filler. Additionally, for the prolonged plateau region in the stress—strain curve, the energy absorption efficiency of the AFFSR maintains a high level (above 0.6) over a wide strain range from 3% to 60%.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51474166 and 51672195)the Program for Innovative Teams of Out-standing Young and Middle-aged Researchers in the Higher Education Institutions of Hubei Province (No. T201602)
文摘To improve their mechanical and thermal insulation properties, aluminum silicate fibrous materials with in situ synthesized K_2Ti_6O_(13) whiskers were prepared by firing a mixture of short aluminum silicate fibers and gel powders obtained from a sol–gel process. During the preparation process, the fiber surface was coated with K_2Ti_6O_(13) whiskers after the fibers were subjected to a heat treatment carried out at various temperatures. The effects of process parameters on the microstructure, compressive strength, and thermal conductivity were analyzed systematically. The results show that higher treatment temperatures and longer treatment durations promoted the development of K_2Ti_6O_(13) whiskers on the surface of aluminum silicate fibers; in addition, the intersection structure between whiskers modulated the morphology and volume of the multi-aperture structure among fibers, substantially increasing the fibers' compressive strength and reducing their heat conduction and convective heat transfer at high temperatures.
文摘The zeta potential measurements show that the flotation separation of diaspore from kaolinite, illite and pyrophyllite could be achieved in the range of pH 46.5 with cationic collectors. A special quaternary ammonium salts(DTAL) shows better selectivity than that the dodecyl amine(DDA) does for the flotation of three silicates. The closed circuit flotation results show that the reverse flotation de silicate can be achieved with DTAL as collector, a new inorganic reagent(SFL) as depressant and MIBC as frother to obtain a bauxite concentrate m (Al 2O 3)/ m (SiO 2) >10, Al 2O 3 recovery>86%).
文摘To improve the crack-resistance of the mould for silica sol bonded quartz based ceramic mould casting,aluminum silicate fibers with the diameter ranging from 5 μm to 25 μm and the length about 1 mm were dispersed in the ceramic mould.The effect of the aluminum silicate fibers on the tensile strength,shrinkage rate and the cracking trend of the ceramic mould were investigated.In the ceramic slurry,quartz sand was applied as ceramic aggregate,silica sol containing 30% silicon dioxide as bonder,and the weight ratio of quartz sand to silica sol was 2.69;the dispersed fibers changed from 0 to 0.24vol.%.The mould samples were formed after the slurry was poured and gelled at room temperature,and then sintered at different temperatures ranging from 100 to 800 ℃ to measure the tensile strength and shrinkage rate.The results show that,with the aluminum silicate fiber addition increasing from 0 to 0.24vol.%,the tensile strength increases linearly from 0.175 MPa to 0.236 MPa,and the shrinkage rate decreases linearly from 1.75% to 1.68% for the ceramic mould sintered at 400 ℃,from 1.37% to 1.31% for the ceramic mould at room temperature.As the sintering temperature was raised from 100 ℃ to 800 ℃,the tensile strength increases,and the shrinkage rate decreases at all temperatures,compared with those without fiber dispersion,but their variation patterns remain the same.Furthermore,the cracking trend of the mould and its decreasing proportion were defined and analyzed quantitatively considering both effects of the fiber dispersion on the strength and shrinkage.The cracking trend appears to decrease linearly with increasing fiber content and to reach the maximum reduction of 28.8% when 0.24vol.% fiber was dispersed.Therefore,the investigation proposes a new method to improve the crack-resistance of the ceramic mould,i.e.,inorganic fiber dispersion into the ceramic mould.
文摘Antiviral effects of a synthetic Aluminum-Magnesium Silicate (AMS) were tested on Fowl Pox Virus (FPV). Five batches of the Nigerian brand of FPV vaccine were used as sources of the virus. The reconstituted vaccines were mixed with The Synthetic AMS on equal volume to weight basis and incubated at room temperature for one hour. They were centrifuged for 10 minutes at 2000 revolutions per minute. The incubation and centrifugation were repeated on a portion of each vaccine supernatant. The two sets of supernatants were tested by the Modified Passive Haemagglutination test, for FPV titres. Portions of the vaccines, not incubated with the AMS, were served as controls. Fowl Pox Virus titres of the vaccines increased from a mean of 2.8 ± 1.10 to 11.2 ± 4.38 when incubated with the AMS once. When incubation with the AMS was repeated, the titres reduced (P< 0.05) to zero in each sample.
基金This work was supported by Science and Technology Innovation Fund of Middle-Minor Enterprises from Ministy of Science and Technology.
文摘Ultra-fine aluminum nitride has been synthesized by the evaporation of aluminum powder at atmospheric-pressure nitrogen plasma in a hot-wall reactor. The average size of aluminum nitride particle is 0.11 μm measured by scanning electric mirror (SEM), and the purity is at least over 90% evaluated by X-Ray diffraction (XRD). The conversion of Al powder to aluminum nitride is strongly depended on the injection of NH3. Typical experimental parameters such as the feed rate of raw material, the flow rate of ammonia and the position of injecting aluminum powder into the reactor are given.
文摘Viral loads (copies of RNA per ml of plasma) of HIV/AIDS patients, who volunteered for clinical trial of the Medicinal synthetic Aluminum-magnesium silicate, were assessed, before and after they were treated. The treatment lasted 4 weeks, 8 weeks and 12 weeks respectively. A patient who could not access approved laboratory for viral load test on time, continued the treatment?for 24 weeks. Following treatment with the medicine, mean viral load of HIV/AIDS patients reduced (P < 0.05) from 18875.00 ± 17059.18 to 327.50 ± 226.84. Rates of the viral load reduction were: 86% after 4 weeks, 96% after 8 weeks and 99.71% after 12 weeks. Clinical signs complained of, by the patients during the treatment, included, fever, dermatitis, boils, joint pain, leg edema and sore throat. These clinical signs ceased when they were treated, so that the antiretroviral treatment was completed. The patient who was on the medication for 24 weeks had no adverse drug reaction.
文摘Experiments were conducted to evaluate the grain refinement and thermal stability of ultra-fine grained Al-4Mgalloy introduced by equal-channel angular pressing (ECAP) at 473 K. The results show that the intensities of X-ray(111/222) and (200/400) peaks for the alloy processed by ECAP decrease significantly and the peak widths of halfheight become broadening compared with the corresponding value in the annealed alloy. The microstructure of 2passes ECAPed alloy consists of both elongated and equiaxed subgrains. The residual strain in the alloy increaseswith increasing passes numbers, that appears as increasing dislocation density and lattice constant of matrix. Anequiaxed ultra-fine grained structure of~0.2μm is obtained in the present alloy after 8 passes. The ultra-fine grainsare stable below 523 K, because the alloy retains extremely fine grain size of~1μm after static annealing at 523 Kfor 1 h.
基金Project(2003C11030) supported by the High Science & Technique Brainstorm of Zhejiang Province, China
文摘The crystallinity of lithium aluminosilicate(LAS) glass after crystallization were studied at different temperatures by X-ray diffractometry and the crystallinity of the standard glass ceramic with known crystal and glass phases was examined. The crystallization mechanism of LAS glass was analyzed by the crystallinity, with a formula relating the crystallinity (X) and temperature (T). The results show that the calculated crystallinity of LAS glass by XRD increases with the crystallization temperature, in the range of 40%?50%, which is close to the calculated ones of standard samples with spodumene quartz ratio of 40%?70%. The activation energy of LAS glass is different within different temperature ranges; nEc is 125.44 kJ/mol at 710?810 ℃ and nEc is 17.42 kJ/mol at 810?980 ℃, which indicates different crystallization mechanisms. It has been proved that the required energy for crystallization of glass in the lower temperature range includes the interfacial energy between glass and crystalline phase and the free energy difference of atoms in structures of glass and crystal, and in the higher temperature ranges only the interfacial energy between glass and crystalline phase is considered.
基金supported by the National Natural Science Foundation of China (No.50238020)the American Aluminum Foundation
文摘Effects of aluminum on water distribution system and human health mainly attribute to its speciation in drinking water. Laboratory experiments were performed to investigate factors that may influence aluminum speciation in water supply system. The concentration of soluble aluminum and its transformation among other aluminum species were mainly controlled by kinetics processes of related reactions. Total aluminum concentration had a notable effect on the concentrations of mononuclear and soluble aluminum in the first 4 day; then its effect became weak. At pH above 7.50, both fluoride and orthophosphate had little effect on aluminum speciation; while, when the solution pH was below 7.50, the concentrations of mononuclear and soluble aluminum were proportional to the concentration of fluoride and inversely proportional to the concentration of orthophosphate. Both mononuclear and polynuclear silicic acids could complex with mononuclear aluminum by forming soluble aluminosilicates. In addition, the adding sequence of orthophosphate and aluminum into drinking water would also affect the distribution of aluminum species in the first 4 day. In order to minimize aluminum bioavailability in drinking water, it was suggested that orthophosphate should be added prior to coagulant process, and that the concentrations of fluoride and silicic acids should be controlled below 2.0 and 25 mg/L, respectively, prior to the treatment. The solution pH in coagulation and filtration processes should be controlled in the range of 6.50-7.50.
文摘Using cetyl trimethylammonium bromide (CTAB) as collector, the flotation de-silicating from diasporic-bauxite was investigated. And the Zeta potentials and contact-angles of silicate minerals and diaspore were also stu-(died.)The results show that in the presence of 2×10-4 mol·L-1CTAB, the surface charges of pyrophyllite, kaolinite and illite become more positive, and the contact angles of these three silicates also increase evidently in the pH range of 2-8, but the Zeta potentials and contact angles of diaspore change little. So, the floatability of the four minerals is in the following order: pyrophyllite>kaolinite≈illite>diaspore. The open-circuit flotation results also show that a bauxite concentrate with m(Al2O3)/m(SiO2) over 9.3 and Al2O3 recovery over 76% can be obtained from diasporic-bauxite ore. The result of XRD of the bauxite concentrate shows that pyrophyllite is easier to be removed from diasporic-bauxite than illite and kaolinite due to its better floatability.
文摘An open-cell aluminum foam filled with silicate rubber (AFFSR) was fabricated by infiltration of the liquid silicate rubber into the open-cell aluminum foam. The experiments were carried out to investigate the compressive behavior and energy absorption characteristics of the material. It is found that the stress—strain response of the AFFSR exhibits five regions including two plateau regimes, which is quite different from the stress—strain curves of many unfilled metallic foams that usually exhibit three distinct regions. The plastic deformation of the AFFSR is prolonged because of the filled silicate rubber, compared with the aluminum foam without such a filler. The AFFSR also exhibits a higher energy capacity than the aluminum foam without filler. Additionally, for the prolonged plateau region in the stress—strain curve, the energy absorption efficiency of the AFFSR maintains a high level (above 0.6) over a wide strain range from 3% to 60%.