To solve the problems of rock strength increase caused by high in-situ stress,the stress release method with rock slot in the bottom hole by an ultra-high-pressure water jet is proposed.The stress conditions of bottom...To solve the problems of rock strength increase caused by high in-situ stress,the stress release method with rock slot in the bottom hole by an ultra-high-pressure water jet is proposed.The stress conditions of bottom hole rock,before and after slotting are analyzed and the stress release mechanism of slotting is clarified.The results show that the stress release by slotting is due to the coupling of three factors:the relief of horizontal stress,the stress concentration zone distancing away from the cutting face,and the increase of pore pressure caused by rock mass expansion;The stress concentration increases the effective stress of rock along the radial distance from O.6R to 1R(R is the radius of the well),and the presence of groove completely releases the stress,it also allows the stress concentration zone to be pushed away from the cutting face,while significantly lowering the value of stresses in the area the drilling bit acting,the maximum stress release efficiency can reach 80%.The effect of slotting characteristics on release efficiency is obvious when the groove location is near the borehole wall.With the increase of groove depth,the stress release efficiency is significantly increased,and the release range of effective stress is enlarged along the axial direction.Therefore,the stress release method and results of simulations in this paper have a guiding significance for best-improving rock-breaking efficiency and further understanding the technique.展开更多
Taking the Paleogene Shahejie Formation in Nanpu sag of Bohai Bay Basin as an example,this study comprehensively utilizes seismic,mud logging,well logging,physical property analysis and core thin section data to inves...Taking the Paleogene Shahejie Formation in Nanpu sag of Bohai Bay Basin as an example,this study comprehensively utilizes seismic,mud logging,well logging,physical property analysis and core thin section data to investigate the metamorphic reservoir formed by contact metamorphism after igneous rock intrusion.(1)A geological model of the igneous intrusion contact met amorphic system is proposed,which can be divided into five structural layers vertically:the intrusion,upper metamorphic aureole,lower metamorphic aureole,normal sedimentary layers on the roof and floor.(2)The intrusion is characterized by xenoliths indicating intrusive facies at the top,regular changes in rock texture and mineral crystallization from the center to the edge on a microscopic scale,and low-angle oblique penetrations of the intrusion through sedimentary strata on a macroscopic scale.The metamorphic aureole has characteristics such as sedimentary rocks as the host rock,typical palimpsest textures developed,various low-temperature thermal metamorphic minerals developed,and medium-low grade thermal metamorphic rocks as the lithology.(3)The reservoir in contact metamorphic aureole has two types of reservoir spaces:matrix pores and fractures.The matrix pores are secondary"intergranular pores"distributed around metamorphic minerals after thermal metamorphic transformation in metasandstones.The fractures are mainly structural fractures and intrusive compressive fractures in metamudstones.The reservoirs generally have three spatial distribution characteristics:layered,porphyritic and hydrocarbon impregnation along fracture.(4)The distribution of reservoirs in the metamorphic aureole is mainly controlled by the intensity of thermal baking.Furthermore,the distribution of favorable reservoirs is controlled by the coupling of favorable lithofacies and thermal contact metamorphism,intrusive compression and hydrothermal dissolution.The proposal and application of the geological model of the intrusion contact metamorphic system are expected to promote the discovery of exploration targets of contact metamorphic rock in Nanpu sag,and provide a reference for the study and exploration of deep contact metamorphic rock reservoirs in the Bohai Bay Basin.展开更多
Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples ...Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals.These samples included gneisses rocks,monzogranite,and metavolcano-sedimentary rocks for both the Thalbah and Bayda groups.Using the Rf/j and Fry methods,the axial ratios(XZ)range about 2.20 to 7.10 and 1.90 to 9.10,respectively.For various rock units,the strain measurements show moderate to highly deformation.Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain(X).The short axes(Z)based to be subvertical foliation related with a subhorizontal foliation.The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units.It concluded that nappe generation in orogens results from pure shear deformation.展开更多
The Dahongshan Group,situated at the southwestern margin of the Yangtze Block,represents a geological unit characterized by relatively high-grade metamorphism in the region.This paper investigates the garnet-biotite s...The Dahongshan Group,situated at the southwestern margin of the Yangtze Block,represents a geological unit characterized by relatively high-grade metamorphism in the region.This paper investigates the garnet-biotite schist from the Laochanghe Formation of the Dahongshan Group,employing an integrated approach that includes petrological analysis,phase equilibrium modeling,and zircon U-Pb dating.The schist is mainly composed of garnet,biotite,plagioclase,quartz,rutile,and ilmenite.Phase equilibrium modeling revealed the peak metamorphic conditions of 8-9 kbar and 635-675°C.By further integrating the prograde metamorphic profile of garnet and geothermobarometric results,a clockwise P-T metamorphic evolution path is constructed,which includes an increase in temperature and pressure during the prograde stage.LA-ICP-MS zircon U-Pb dating and zircon Ti thermometry constrains the post-peak metamorphic age of 831.2±7.2 Ma.Integrated with previously reported results,it is revealed that the southwestern margin of the Yangtze Block experienced a large-scale regional metamorphism during the Neoproterozoic(890-750 Ma),which is related to the collisional orogenic process.This may be associated with the late-stage assembly of the Rodinia supercontinent or with local compression and subduction processes during the breakup of the Rodinia supercontinent.展开更多
Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of suc...Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future.展开更多
The Longgang Block is one of the most important parts of the eastern North China Craton,characterized by extensive Late Neoarchean(~2.5 Ga)granulite facies metamorphism.However,it remains uncertain whether it was infl...The Longgang Block is one of the most important parts of the eastern North China Craton,characterized by extensive Late Neoarchean(~2.5 Ga)granulite facies metamorphism.However,it remains uncertain whether it was influenced by Paleoproterozoic magmatism-metamorphism.The authors provide a comprehensive analysis of amphibolite in Laojinchang area,southern Jilin Province,through petrographic,geochemical,mineralogical,and zircon dating.The main findings are as follows:The mineral assemblage of amphibolite is Hb+Pl+Cpx+Bi+Kf+Q,characteristic of amphibolite facies;zircon U-Pb dating indicates that the metamorphic age of amphibolite is 1834±33 Ma;the amphibolite has geochemical characteristics of calcium alkaline,with depletion of Nb,Ta,Ti and P.The plagioclase in the amphibolite is oligoclase,belonging to acidic plagioclase.It is speculated that the protolith of the amphibolite is diorite;using geothermobarometer,the peak metamorphic P-T conditions of amphibolite are determined to be 536–593℃/3.4–5.0 kbar,and the post-peak conditions are 429–566℃/1.3–3.1 kbar.The above results indicate that the Paleoproterozoic metamorphism has been superimposed on Longgang Block,linked to a new orogenic event on the northern edge of North China Craton.展开更多
The Jitang metamorphic complex is key to studying the tectonic evolution of the Northern Lancangjiang zone.Through structural-lithological mapping,structural analysis and laboratory testing,the composition of the Jita...The Jitang metamorphic complex is key to studying the tectonic evolution of the Northern Lancangjiang zone.Through structural-lithological mapping,structural analysis and laboratory testing,the composition of the Jitang metamorphic complex was determined.The macro-and microstructural analyses of the ductile detachment shear zone(Guoxuepu ductile shear zone,2–4 km wide)between the metamorphic complex and the overlying sedimentary cap show that the shear sense of the ductile shear zones is top-to-the-southeast.The presence of various deformation features and quartz C-axis electron backscatter diffraction(EBSD)fabric analysis suggests multiple deformation events occurring at different temperatures.The average stress is 25.68 MPa,with the strain rates(έ)ranging from 9.77×10^(−14)s^(−1)to 6.52×10^(−16)s^(−1).The finite strain of the Guoxuepu ductile shear zone indicates an elongated strain pattern.The average kinematic vorticity of the Guoxuepu ductile shear zone is 0.88,implying that the shear zone is dominated by simple shear.The muscovite selected from the protomylonite samples in the Guoxuepu ductile shear zone yields a 40Ar-39Ar age of 60.09±0.38 Ma.It is suggested that,coeval with the initial Indo–Eurasian collision,the development of strike-slip faults led to a weak and unstable crust,upwelling of lower crust magma,then induced the detachment of the Jitang metamorphic complex in the Eocene.展开更多
New monazite U\|Pb geochronological data from the Everest region suggest that 20~25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase m...New monazite U\|Pb geochronological data from the Everest region suggest that 20~25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase metamorphic history, with peak Barrovian metamorphism at (32 2±0 4)Ma and a later high\|temperature, low\|pressure event (620℃, 400MPa) at (22 7±0 2)Ma.. Emplacement and crystallization of the Everest granite subsequently occurred at 20 5~21 3Ma. The monazite crystallization ages that differ by 10Ma are recorded in two structurally adjacent rocks of different lithology, which have the same post collisional p—T history.. Scanning electron microscopy reveals that the younger monazite is elaborately shaped and grew in close association with apatite at grain boundaries and triple junctions, suggesting that growth was stimulated by a change in the fluid regime. The older monazite is euhedral, is not associated with apatite, and is commonly armoured within silicate minerals. During the low\|pressure metamorphic event, the armouring protected the older monazites, and a lack of excess apatite in this sample prevented new growth. Textural relationships suggest that apatite is one of the necessary monazite\|producing reactants, and spots within monazite that are rich in Ca, Fe, Al and Si suggest that allanite acted as a preexisting rare earth element host. We propose a simplified reaction for monazite crystallization based on this evidence.展开更多
In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamo...In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50. 1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54-3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T evolutional path characterized by the near-isothermal decompression. The inclusion assemblage (Hb+Ep+Bi+Pl+Qz) within garnet and other minerals has recorded a pre-peak stage (Mi) epidote amphibole fades metamorphic event. High- and ultrahigh-pressure peak metamorphism (M2) took place at T=750-860℃ and P>2.7 GPa. The symplectitic assemblages after garnet, jadeitic-clinopyroxene and rutile imply a near-isothermal decompression metamorphism (M3, M4) during the rapid exhumation. Several lines of evidence of petrography and metamorphic reactions indicate that both gneisses and eclogites have experienced ultrahigh-pressure metamorphism in the Donghai area. This research may be of great significance for an in-depth study of the metamorphism and tectonic evolution in the Su-Lu ultrahigh-pressure metamorphic belt.展开更多
The east sector of the southern Qinling belt is, lithologically, composed mainly of metapelites, ***qüartzites, marbles and small amount of metabasites and gneisses, whose protoliths are the Silurian, Devonian an...The east sector of the southern Qinling belt is, lithologically, composed mainly of metapelites, ***qüartzites, marbles and small amount of metabasites and gneisses, whose protoliths are the Silurian, Devonian and less commonly the Sinian and Upper Palaeozoic. They have been subjected at least to two epochs of metamorphism. The early epoch belongs to progressive metamorphism which is centered on high amphibolite-granulite fades in the Fuping area and changed outwards into low amphibolite facies (staurolite-kyanite zone), epidote amphibolite facies (garnet zone) and greenschist facies (chlorite and biotite zones), the metamorphic age of which is about 220–260 Ma. This early-epoch metamorphism belongs to different pressure types: the rocks from greenschist to low amphibolite facies belong to the typical medium-pressure type which shows geothermal gradients of about 17–20 ***C/km and was probably produced by a crustal thickening process related to continental collision, and the high amphibolite-granulite facies belongs to the low-pressure type which shows geothermal gradients of about 25–38 ***C/km and was probably affected by some magmatic heats. Based on the basic characteristics of the P-T paths of the different facies calculated from the garnet zonations, it can be deduced that the metamorphism of medium-pressure facies series took place during an imbricated thickening process, rather than during the uplifting process after thickening. The late-epoch metamorphism belongs to dynamic metamorphism of greenschist facies which is overprinted on the early-epoch metamorphic rocks and is Yanshanian or Himalayan in age, probably related to intracontinental orogeny.展开更多
Based upon fluid effects, retrograde metamorphism of eclogites in the Dabieregion can be divided into the fluid-poor, fluid-bearing and fluid-rich stages. The fluid-poor stageis marked by polymorphic inversion, recrys...Based upon fluid effects, retrograde metamorphism of eclogites in the Dabieregion can be divided into the fluid-poor, fluid-bearing and fluid-rich stages. The fluid-poor stageis marked by polymorphic inversion, recrystallization and exsolution of solid solutions, and isthought to represent eclogite-facies retrograde environments. The fluid-bearing stage is likely tohave occurred at the late stage of ecologite-facies diaphthorosis and is represented by kyaniteporphyroblasts, rutile, and sodic pyroxene in association with high-pressure hydrous minerals suchas phengite and zoisite (clinozoisite) without significant amount of hydrous minerals such asamphibole, epidote and biotite. The fluid-rich stage might have commenced concomitantly with loweramphibolite-facies diaphthoresis and persisted all the way towards the near-surface environment. Theproduct of this stage is characterized by plentiful hydrous and volatile-bearing phases.The dissemination-type rutile mineralizations in eclogites might have formed by preferentialshearing-induced pressure solution of gangue minerals at the fluid-bearing stage. The accompanyingvein rutile was precipitated from fluids of this stage after local transport and concentration, andmay hence represent proximal mobilization of titanium from the eclogite. Therefore, rutile veins canbe used as an exploration indicator for dissemination-type rutile deposits.展开更多
We used illite and chlorite crystaHinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify t...We used illite and chlorite crystaHinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garze orogen along profile Zoige-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. lllite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370℃±21℃ at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.展开更多
The Soursat metamorphic complex (SMC) in northwestern Iran is part of the Sanandaj- Sirjan metamorphic belt. The complex is composed of different metamorphic and plutonic rocks, but is dominated by metapelites compo...The Soursat metamorphic complex (SMC) in northwestern Iran is part of the Sanandaj- Sirjan metamorphic belt. The complex is composed of different metamorphic and plutonic rocks, but is dominated by metapelites composed of garnet, staurolite, kyanite, fibrolite, cordierite, and andalusite. Porphyroblasts in schists have the same fabric, and three stages of schistosity are present. The internal schistosity (Sn) inclusion trails are also offset by conjugate sets of extensional schistosity (Sn+l) and a second (Sn+2) that crenulates (Sn+l). Polyphase metamorphisms are present in the complex. Garnet, staurolite, kyanite, and fibrolite assemblage preserves conditions during the M1 metamorphic event. This assemblage yields a P-t estimate of 645±11℃ and 6.5±0.5 kbar. Other samples of the central part of SMC contain cordierite and andalusite (M2) overgrowth that yields a P- t estimate of 532±33℃ and 2.1±1.1 kbar.展开更多
The paper deals with results of petrological observations of the Precambrian rocks in the Tiya-Olokit metamorphic belt of the Northern Balkal region. Evoluhon of mstamorphic processes from Archean through to Paleozoic...The paper deals with results of petrological observations of the Precambrian rocks in the Tiya-Olokit metamorphic belt of the Northern Balkal region. Evoluhon of mstamorphic processes from Archean through to Paleozoic is characterized. Interrelations of metamorphic and ore formation processes are shown .Various genetic types of metamorphism and their metallogeulc speianzation (pyrihc-polylnetallic, gold-sulphide and others) are established.A great number of previously published analyses of garnets, biohtes, amphiholes, pyroxenes and muscovitde from metamorphic rocks have been made use of. The evoluhon of their compositions under progressive zoned metamorphism and diaphthoresis is revealed.展开更多
The origin, age and evolution of the Precambrian metamorphic basement of southern China provide useful insights into early crustal development. Here, we present new laser ablation-inductively coupled plasma-mass spect...The origin, age and evolution of the Precambrian metamorphic basement of southern China provide useful insights into early crustal development. Here, we present new laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb age data for detrital zircons from five samples of the Precambrian metamorphic basement of the Xiangshan uranium orefield. Two of these samples, from the northern Xiangshan volcanic basin, yielded a total of 140 U-Pb ages that cluster within the Neoproterozoic (773-963 Ma; 79.3% of data points), with the rest being scattered through the Paleoproterozoic and Mesoproterozoic, along with a single Archean age. These ages indicate that this basement material is associated with the Cathaysia Block. In comparison, the 172 concordant ages from the other three samples from the southern part of the Xiangshan volcanic basin cluster within the Neoproterozoic (767-944 Ma; 59.8%) as well as the Proterozoic (37.8%) and the Archean (2502-2712 Ma; 14.5%). These samples are also free of zircons with Grenvillian ages, indicating that these units are associated with the southeastern Yangtze Block. Combining these data with the geochemistry of these units, which suggests that the metamorphosed sedimentary rocks within the northern and southern parts of the Xiangshan basin have a common component from a magmatic island arc that formed during the early Neoproterozoic, we infer that the basin was located along the boundary between the Cathaysian and Yangtze blocks. In addition, the zircons within the samples from the southern and northern parts of the Xiangshan basin show different pre-Neoproterozoic (963 Ma) age populations but similar post- Neoproterozoic zircon populations, indicating that the amalgamation of the Cathaysian and Yangtze blocks occurred after the Neoproterozoic (960 Ma), with magmatism peaking at 830 Ma and rifting starting at -770 Ma, leading to the subsequent deposition (from bottom to top) of the Shenshan, Kuli, and Shangshi formations.展开更多
The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized wi...The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized with the sulphur dioxide formation,and the process chemical mechanism does not depend on the quality of organic matter.The medium-metamorphized coal,capable of turning into a plastic state and cake in the range of investigated temperatures(350~450 ℃),is desulphurized with the greatest difficulty.The chemical mechanism dealing with the transformations of pyritic sulphur present in brown coal differs from similar processes taking place in black coal and anthracite,because FeS2 is converted with hydrogen sulphide formation at desulphurization.展开更多
The Chertovo Koryto gold deposit(80 t Au at 1.84 g/t) in the Lena world-class province,Siberia,is hosted in a metamorphosed sequence of the Paleoproterozoic Mikhailovsk Formation that comprises the oldest black shal...The Chertovo Koryto gold deposit(80 t Au at 1.84 g/t) in the Lena world-class province,Siberia,is hosted in a metamorphosed sequence of the Paleoproterozoic Mikhailovsk Formation that comprises the oldest black shale strata of the Baikal-Patom region.The mineralisation is confined to the thrust zone complicated with a conjugate anticline fold,zones of shearing and dislocation.The struaural position of the mineralisation is similar to that at the giant Sukhoi Log deposit in the neighbouring Mama-Bodaibo zone.In the latter,the isotope age data suggest that Khomolkho black shales,hosts to Sukhoi Log mineralisation,are of Ediacaran age and underwent prograde metamorphism during early Paleozoic.The geochemical composition of the terrigenous rocks that host Sukhoi Log,Chertovo Koryto,and a number of other deposits at the various stratigraphic levels throughout the Proterozoic sequence have much in common.They do not show elevated metal contents above the common black shale abundances,except for Au and As,which is at variance with the accepted view on diagenetic enrichment of black shales in the Lena province.The occurrence of sagenitic rutile in quartz and chlorite pseudomorphs after biotite and other petrographic observations provide evidence on a retrograde nature of the metamorphic mineral assemblages in the Mikhailovsk rocks.The sulphides are pyrrhotite and arsenopyrite with very minor pyrite at Chertovo Koryto,whereas pyrite is the predominant sulphide in the Sukhoi Log ore.Fluid inclusion data on both deposits emphasise a high-temperature nature of the mineralisation albeit revealing great contrast in the fluid composition.Sukhoi Log mineralisation was formed at mixing between low-salinity aqueous solutions and dense gaseous carbonic fluids,which facilitated effective gold scavenging and precipitation,as demonstrated by thermodynamic simulation.The precursory devolatilisation of the Mikhailovsk sediments at the prograde stage results in the paucity of gaseous carbonic fluid during retrograde metamorphism and mineralisation.The similarity in the styles and chemical parameters of mineralisation,and the predominant structural control of ore localisation within the same Precambrian regional tectonic unit support an idea that orogenic gold mineralisation in the Lena province was produced during a single early Paleozoic event.展开更多
The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones ...The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones surrounding the core of the Luotian dome, and the separation of the UHP, HP and epidote blueschist units by the detachment zones, which form the vertically stacking sheet like slices of the HP and UHP metamorphic rocks. From the core outwards, exist the HP and UHP rock barren Dabie complex, UHP unit, HP unit and epidote blueschist unit. The extension tectonics of post HP and UHP metamorphic event constrain the distribution and present configuration of the HP and UHP metamorphic rocks, and the extensional tectonic framework bears some similarities to the Cordillera metamorphic core complex. It is suggested that partial melting happened in the Dabie gneiss complex (DGC) and UHP unit contemporaneously with the extrusion of UHP metamorphic rocks into the lower-middle crust. The formation and emplacement of the migmatite and granites are the response to the change in thermal state, facilitating the transfer from the compressive regime to extensional regime in the crust. The large scale crustal extension and uplift and the accompanying anatexis in Dabieshan are probably related to the delamination and magmatic underplating in the mantle and the lower crust.展开更多
Successions of FIAs(foliation inflection/intersection axes preserved within porphyroblasts) provide a relative time scale for deformation and metamorphism.In-situ dating of monazite grains preserved as inclusions wi...Successions of FIAs(foliation inflection/intersection axes preserved within porphyroblasts) provide a relative time scale for deformation and metamorphism.In-situ dating of monazite grains preserved as inclusions within garnet and staurolite porphyroblasts within the foliations defining each FIA from such successions provides a rigorous approach to grouping ages that formed over extended periods of deformation and metamorphism.Matching age and FIA progressions confirms the suitability of this approach plus provides access to lengthy histories that cannot otherwise be determined.Tectonism in the Big Thompson region of the Colorado Rocky Mountains,USA began about a SW-NE trending axis defined by FIA set 1 at around 1761±13 Ma.Subsequent periods of tectonism occurred around 1712±25 and 1672±21 Ma about W-E and NW-SE trending FIAs 2 and 3, respectively.Tectonism in the Balcooma Metamorphic Group NW of Greenvale in NE Queensland, Australia began around 470 Ma with the growth of garnet porphyroblasts about a W-E trending axis defined by FIA set 1.No monazite grains were preserved as inclusions in this mineral phase but they were in subsequently grown staurolite.Tectonism then occurred around 443.2±3.8,424±4 and 408.9±8.9 Ma about NNW-SSE,SSW-NNE and W-E trending FIAs 2,3 and 4,respectively.This test of a FIA based approach to monazite dating in tectonic regimes in different parts of the world and with dramatically different ages suggests it can be used in all orogens containing porphyroblasts preserving inclusion trails.展开更多
This study uses illite crystallinity,chlorite crystallinity,illite polytypes,the b0 cell-dimension of K-white mica,clay mineral assemblages and mineral geothermo-geobarometers to investigate the overprint of diagenesi...This study uses illite crystallinity,chlorite crystallinity,illite polytypes,the b0 cell-dimension of K-white mica,clay mineral assemblages and mineral geothermo-geobarometers to investigate the overprint of diagenesis and metamorphism on the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang in northeastern Hunan Province,China.Illite crystallinity Kbler index(KI) of the 〈2μm fractions ranges from 0.225 to 0.485°Δ2θ while chlorite crystallinity Arkai index(AI) ranges from 0.244 to 1.500°Δ2θ.This indicates that the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang were overprinted with diagenesis and anchi- to epimetamorphism.Peak metamorphic temperature is estimated with the IV site chlorite geothermometer roughly at 360℃.The b0 cell dimension values of illites(K-mica) range from 0.9002 to 0.9054 nm and,on average,at 0.9030 nm for the Meso-Neoproterozoic.Based on cumulative frequency curves of illite(K-mica) b0 cell dimension,the peak metamorphic pressure of the MesoNeoproterozoic along the profile Yueyang-Linxiang is derived of an intermediate pressure type.Most illites occur in the 2M1 polytype and some of them in a mixture of 2M1+1M types especially those in the Paleozoic.This result partly agrees with the conclusion of the lower greenschist and greenschist facies of the Lengjiaxi and Banxi Groups.However,it is not agreed with the sedimentary cover from the Sinian to the Lower Paleozoic or from the Banxi Group to the Lower Paleozoic.Crustal thickening due to "collision" between the Yangtze and Cathaysia blocks led to an increase in the thickness of the Meso-Neoproterozoic to ca.14 km and resulted in a temperature increase in those rocks due to burial.The very low grade to low grade metamorphism overprinting the Meso-Neoproterozoic implies that the so called "Chiangnania or Jiangnan orogen" was no relative with the "Grenvillian orogeney;instead,it might be a continuous amalgamation product between the Yangtze and Cathaysia blocks.展开更多
基金support of the National Key Research and Development Program of China(2021YFE0111400)the Shandong provincial natural science foundation(No.ZR2019MEE120)the horizon programme of the EU's funding of the ORCH YD project,EU-H2020(101006752-ORCHYD).
文摘To solve the problems of rock strength increase caused by high in-situ stress,the stress release method with rock slot in the bottom hole by an ultra-high-pressure water jet is proposed.The stress conditions of bottom hole rock,before and after slotting are analyzed and the stress release mechanism of slotting is clarified.The results show that the stress release by slotting is due to the coupling of three factors:the relief of horizontal stress,the stress concentration zone distancing away from the cutting face,and the increase of pore pressure caused by rock mass expansion;The stress concentration increases the effective stress of rock along the radial distance from O.6R to 1R(R is the radius of the well),and the presence of groove completely releases the stress,it also allows the stress concentration zone to be pushed away from the cutting face,while significantly lowering the value of stresses in the area the drilling bit acting,the maximum stress release efficiency can reach 80%.The effect of slotting characteristics on release efficiency is obvious when the groove location is near the borehole wall.With the increase of groove depth,the stress release efficiency is significantly increased,and the release range of effective stress is enlarged along the axial direction.Therefore,the stress release method and results of simulations in this paper have a guiding significance for best-improving rock-breaking efficiency and further understanding the technique.
基金Supported by the Basic Science Research Fund Project of PetroChina Affiliated Institute(2020D-5008-06)。
文摘Taking the Paleogene Shahejie Formation in Nanpu sag of Bohai Bay Basin as an example,this study comprehensively utilizes seismic,mud logging,well logging,physical property analysis and core thin section data to investigate the metamorphic reservoir formed by contact metamorphism after igneous rock intrusion.(1)A geological model of the igneous intrusion contact met amorphic system is proposed,which can be divided into five structural layers vertically:the intrusion,upper metamorphic aureole,lower metamorphic aureole,normal sedimentary layers on the roof and floor.(2)The intrusion is characterized by xenoliths indicating intrusive facies at the top,regular changes in rock texture and mineral crystallization from the center to the edge on a microscopic scale,and low-angle oblique penetrations of the intrusion through sedimentary strata on a macroscopic scale.The metamorphic aureole has characteristics such as sedimentary rocks as the host rock,typical palimpsest textures developed,various low-temperature thermal metamorphic minerals developed,and medium-low grade thermal metamorphic rocks as the lithology.(3)The reservoir in contact metamorphic aureole has two types of reservoir spaces:matrix pores and fractures.The matrix pores are secondary"intergranular pores"distributed around metamorphic minerals after thermal metamorphic transformation in metasandstones.The fractures are mainly structural fractures and intrusive compressive fractures in metamudstones.The reservoirs generally have three spatial distribution characteristics:layered,porphyritic and hydrocarbon impregnation along fracture.(4)The distribution of reservoirs in the metamorphic aureole is mainly controlled by the intensity of thermal baking.Furthermore,the distribution of favorable reservoirs is controlled by the coupling of favorable lithofacies and thermal contact metamorphism,intrusive compression and hydrothermal dissolution.The proposal and application of the geological model of the intrusion contact metamorphic system are expected to promote the discovery of exploration targets of contact metamorphic rock in Nanpu sag,and provide a reference for the study and exploration of deep contact metamorphic rock reservoirs in the Bohai Bay Basin.
基金supported and funded by the Researchers Supporting Project(Project No.RSPD2024R781),King Saud University,Riyadh,Saudi Arabia。
文摘Identifying deformational mechanisms and associated structures at various scales,ranging from regional-scale structures to microscopic fabric,is crucial for the assessment of tectonic development.Thirty-three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals.These samples included gneisses rocks,monzogranite,and metavolcano-sedimentary rocks for both the Thalbah and Bayda groups.Using the Rf/j and Fry methods,the axial ratios(XZ)range about 2.20 to 7.10 and 1.90 to 9.10,respectively.For various rock units,the strain measurements show moderate to highly deformation.Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain(X).The short axes(Z)based to be subvertical foliation related with a subhorizontal foliation.The results demonstrate that contacts generated at semi-brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units.It concluded that nappe generation in orogens results from pure shear deformation.
基金supported by the National Natural Science Foundation of China(Grant Nos.42162012,42072094)the Key Laboratory of Sanjiang Metallogeny and Resource Exploration and Utilization,Ministry of Natural Resources(Project No.ZRZYBSJSYS2022001).
文摘The Dahongshan Group,situated at the southwestern margin of the Yangtze Block,represents a geological unit characterized by relatively high-grade metamorphism in the region.This paper investigates the garnet-biotite schist from the Laochanghe Formation of the Dahongshan Group,employing an integrated approach that includes petrological analysis,phase equilibrium modeling,and zircon U-Pb dating.The schist is mainly composed of garnet,biotite,plagioclase,quartz,rutile,and ilmenite.Phase equilibrium modeling revealed the peak metamorphic conditions of 8-9 kbar and 635-675°C.By further integrating the prograde metamorphic profile of garnet and geothermobarometric results,a clockwise P-T metamorphic evolution path is constructed,which includes an increase in temperature and pressure during the prograde stage.LA-ICP-MS zircon U-Pb dating and zircon Ti thermometry constrains the post-peak metamorphic age of 831.2±7.2 Ma.Integrated with previously reported results,it is revealed that the southwestern margin of the Yangtze Block experienced a large-scale regional metamorphism during the Neoproterozoic(890-750 Ma),which is related to the collisional orogenic process.This may be associated with the late-stage assembly of the Rodinia supercontinent or with local compression and subduction processes during the breakup of the Rodinia supercontinent.
基金funded by Science and Technology Major Project of China National Offshore Oil Corporation(CNOOC-KJ 135 ZDXM36 TJ 08TJ).
文摘Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future.
基金Supported by projects of the National Natural Science Foundation of China(Nos.42172213,42372255).
文摘The Longgang Block is one of the most important parts of the eastern North China Craton,characterized by extensive Late Neoarchean(~2.5 Ga)granulite facies metamorphism.However,it remains uncertain whether it was influenced by Paleoproterozoic magmatism-metamorphism.The authors provide a comprehensive analysis of amphibolite in Laojinchang area,southern Jilin Province,through petrographic,geochemical,mineralogical,and zircon dating.The main findings are as follows:The mineral assemblage of amphibolite is Hb+Pl+Cpx+Bi+Kf+Q,characteristic of amphibolite facies;zircon U-Pb dating indicates that the metamorphic age of amphibolite is 1834±33 Ma;the amphibolite has geochemical characteristics of calcium alkaline,with depletion of Nb,Ta,Ti and P.The plagioclase in the amphibolite is oligoclase,belonging to acidic plagioclase.It is speculated that the protolith of the amphibolite is diorite;using geothermobarometer,the peak metamorphic P-T conditions of amphibolite are determined to be 536–593℃/3.4–5.0 kbar,and the post-peak conditions are 429–566℃/1.3–3.1 kbar.The above results indicate that the Paleoproterozoic metamorphism has been superimposed on Longgang Block,linked to a new orogenic event on the northern edge of North China Craton.
基金financially supported by the China Geological Survey Scientific Research Project(Grant Nos.DD20190167 and DD20190053)the National Natural Science Foundation of China(Grant No.42172259).
文摘The Jitang metamorphic complex is key to studying the tectonic evolution of the Northern Lancangjiang zone.Through structural-lithological mapping,structural analysis and laboratory testing,the composition of the Jitang metamorphic complex was determined.The macro-and microstructural analyses of the ductile detachment shear zone(Guoxuepu ductile shear zone,2–4 km wide)between the metamorphic complex and the overlying sedimentary cap show that the shear sense of the ductile shear zones is top-to-the-southeast.The presence of various deformation features and quartz C-axis electron backscatter diffraction(EBSD)fabric analysis suggests multiple deformation events occurring at different temperatures.The average stress is 25.68 MPa,with the strain rates(έ)ranging from 9.77×10^(−14)s^(−1)to 6.52×10^(−16)s^(−1).The finite strain of the Guoxuepu ductile shear zone indicates an elongated strain pattern.The average kinematic vorticity of the Guoxuepu ductile shear zone is 0.88,implying that the shear zone is dominated by simple shear.The muscovite selected from the protomylonite samples in the Guoxuepu ductile shear zone yields a 40Ar-39Ar age of 60.09±0.38 Ma.It is suggested that,coeval with the initial Indo–Eurasian collision,the development of strike-slip faults led to a weak and unstable crust,upwelling of lower crust magma,then induced the detachment of the Jitang metamorphic complex in the Eocene.
文摘New monazite U\|Pb geochronological data from the Everest region suggest that 20~25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase metamorphic history, with peak Barrovian metamorphism at (32 2±0 4)Ma and a later high\|temperature, low\|pressure event (620℃, 400MPa) at (22 7±0 2)Ma.. Emplacement and crystallization of the Everest granite subsequently occurred at 20 5~21 3Ma. The monazite crystallization ages that differ by 10Ma are recorded in two structurally adjacent rocks of different lithology, which have the same post collisional p—T history.. Scanning electron microscopy reveals that the younger monazite is elaborately shaped and grew in close association with apatite at grain boundaries and triple junctions, suggesting that growth was stimulated by a change in the fluid regime. The older monazite is euhedral, is not associated with apatite, and is commonly armoured within silicate minerals. During the low\|pressure metamorphic event, the armouring protected the older monazites, and a lack of excess apatite in this sample prevented new growth. Textural relationships suggest that apatite is one of the necessary monazite\|producing reactants, and spots within monazite that are rich in Ca, Fe, Al and Si suggest that allanite acted as a preexisting rare earth element host. We propose a simplified reaction for monazite crystallization based on this evidence.
文摘In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50. 1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54-3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T evolutional path characterized by the near-isothermal decompression. The inclusion assemblage (Hb+Ep+Bi+Pl+Qz) within garnet and other minerals has recorded a pre-peak stage (Mi) epidote amphibole fades metamorphic event. High- and ultrahigh-pressure peak metamorphism (M2) took place at T=750-860℃ and P>2.7 GPa. The symplectitic assemblages after garnet, jadeitic-clinopyroxene and rutile imply a near-isothermal decompression metamorphism (M3, M4) during the rapid exhumation. Several lines of evidence of petrography and metamorphic reactions indicate that both gneisses and eclogites have experienced ultrahigh-pressure metamorphism in the Donghai area. This research may be of great significance for an in-depth study of the metamorphism and tectonic evolution in the Su-Lu ultrahigh-pressure metamorphic belt.
文摘The east sector of the southern Qinling belt is, lithologically, composed mainly of metapelites, ***qüartzites, marbles and small amount of metabasites and gneisses, whose protoliths are the Silurian, Devonian and less commonly the Sinian and Upper Palaeozoic. They have been subjected at least to two epochs of metamorphism. The early epoch belongs to progressive metamorphism which is centered on high amphibolite-granulite fades in the Fuping area and changed outwards into low amphibolite facies (staurolite-kyanite zone), epidote amphibolite facies (garnet zone) and greenschist facies (chlorite and biotite zones), the metamorphic age of which is about 220–260 Ma. This early-epoch metamorphism belongs to different pressure types: the rocks from greenschist to low amphibolite facies belong to the typical medium-pressure type which shows geothermal gradients of about 17–20 ***C/km and was probably produced by a crustal thickening process related to continental collision, and the high amphibolite-granulite facies belongs to the low-pressure type which shows geothermal gradients of about 25–38 ***C/km and was probably affected by some magmatic heats. Based on the basic characteristics of the P-T paths of the different facies calculated from the garnet zonations, it can be deduced that the metamorphism of medium-pressure facies series took place during an imbricated thickening process, rather than during the uplifting process after thickening. The late-epoch metamorphism belongs to dynamic metamorphism of greenschist facies which is overprinted on the early-epoch metamorphic rocks and is Yanshanian or Himalayan in age, probably related to intracontinental orogeny.
文摘Based upon fluid effects, retrograde metamorphism of eclogites in the Dabieregion can be divided into the fluid-poor, fluid-bearing and fluid-rich stages. The fluid-poor stageis marked by polymorphic inversion, recrystallization and exsolution of solid solutions, and isthought to represent eclogite-facies retrograde environments. The fluid-bearing stage is likely tohave occurred at the late stage of ecologite-facies diaphthorosis and is represented by kyaniteporphyroblasts, rutile, and sodic pyroxene in association with high-pressure hydrous minerals suchas phengite and zoisite (clinozoisite) without significant amount of hydrous minerals such asamphibole, epidote and biotite. The fluid-rich stage might have commenced concomitantly with loweramphibolite-facies diaphthoresis and persisted all the way towards the near-surface environment. Theproduct of this stage is characterized by plentiful hydrous and volatile-bearing phases.The dissemination-type rutile mineralizations in eclogites might have formed by preferentialshearing-induced pressure solution of gangue minerals at the fluid-bearing stage. The accompanyingvein rutile was precipitated from fluids of this stage after local transport and concentration, andmay hence represent proximal mobilization of titanium from the eclogite. Therefore, rutile veins canbe used as an exploration indicator for dissemination-type rutile deposits.
基金This study was supported by the National Natural Science Foundation of China (Grant No. 40572032);the open fund of the central laboratory of Peking University (No. 14 and 15).
文摘We used illite and chlorite crystaHinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garze orogen along profile Zoige-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. lllite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370℃±21℃ at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.
基金supported by the Research Vice Chancellor of Tarbiat Moallem University(Tehran,I.R of Iran)
文摘The Soursat metamorphic complex (SMC) in northwestern Iran is part of the Sanandaj- Sirjan metamorphic belt. The complex is composed of different metamorphic and plutonic rocks, but is dominated by metapelites composed of garnet, staurolite, kyanite, fibrolite, cordierite, and andalusite. Porphyroblasts in schists have the same fabric, and three stages of schistosity are present. The internal schistosity (Sn) inclusion trails are also offset by conjugate sets of extensional schistosity (Sn+l) and a second (Sn+2) that crenulates (Sn+l). Polyphase metamorphisms are present in the complex. Garnet, staurolite, kyanite, and fibrolite assemblage preserves conditions during the M1 metamorphic event. This assemblage yields a P-t estimate of 645±11℃ and 6.5±0.5 kbar. Other samples of the central part of SMC contain cordierite and andalusite (M2) overgrowth that yields a P- t estimate of 532±33℃ and 2.1±1.1 kbar.
文摘The paper deals with results of petrological observations of the Precambrian rocks in the Tiya-Olokit metamorphic belt of the Northern Balkal region. Evoluhon of mstamorphic processes from Archean through to Paleozoic is characterized. Interrelations of metamorphic and ore formation processes are shown .Various genetic types of metamorphism and their metallogeulc speianzation (pyrihc-polylnetallic, gold-sulphide and others) are established.A great number of previously published analyses of garnets, biohtes, amphiholes, pyroxenes and muscovitde from metamorphic rocks have been made use of. The evoluhon of their compositions under progressive zoned metamorphism and diaphthoresis is revealed.
基金financially supported by the National Natural Science Foundation of China(Grant No.41602069 and 41572185)the Fundamental Science on Radioactive Geology and Exploration Technology Laboratory(Grant No.RGET1402)+1 种基金the Natural Science Foundation of Jiangxi Province(Grant No.20171BAB213026)Science and technology research projectfrom the Education Department of Jiangxi Province(Grant No.GJJ150554)
文摘The origin, age and evolution of the Precambrian metamorphic basement of southern China provide useful insights into early crustal development. Here, we present new laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb age data for detrital zircons from five samples of the Precambrian metamorphic basement of the Xiangshan uranium orefield. Two of these samples, from the northern Xiangshan volcanic basin, yielded a total of 140 U-Pb ages that cluster within the Neoproterozoic (773-963 Ma; 79.3% of data points), with the rest being scattered through the Paleoproterozoic and Mesoproterozoic, along with a single Archean age. These ages indicate that this basement material is associated with the Cathaysia Block. In comparison, the 172 concordant ages from the other three samples from the southern part of the Xiangshan volcanic basin cluster within the Neoproterozoic (767-944 Ma; 59.8%) as well as the Proterozoic (37.8%) and the Archean (2502-2712 Ma; 14.5%). These samples are also free of zircons with Grenvillian ages, indicating that these units are associated with the southeastern Yangtze Block. Combining these data with the geochemistry of these units, which suggests that the metamorphosed sedimentary rocks within the northern and southern parts of the Xiangshan basin have a common component from a magmatic island arc that formed during the early Neoproterozoic, we infer that the basin was located along the boundary between the Cathaysian and Yangtze blocks. In addition, the zircons within the samples from the southern and northern parts of the Xiangshan basin show different pre-Neoproterozoic (963 Ma) age populations but similar post- Neoproterozoic zircon populations, indicating that the amalgamation of the Cathaysian and Yangtze blocks occurred after the Neoproterozoic (960 Ma), with magmatism peaking at 830 Ma and rifting starting at -770 Ma, leading to the subsequent deposition (from bottom to top) of the Shenshan, Kuli, and Shangshi formations.
文摘The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized with the sulphur dioxide formation,and the process chemical mechanism does not depend on the quality of organic matter.The medium-metamorphized coal,capable of turning into a plastic state and cake in the range of investigated temperatures(350~450 ℃),is desulphurized with the greatest difficulty.The chemical mechanism dealing with the transformations of pyritic sulphur present in brown coal differs from similar processes taking place in black coal and anthracite,because FeS2 is converted with hydrogen sulphide formation at desulphurization.
基金partly supported by the Russian Scientific Foundation(Grant 14-17-00693)
文摘The Chertovo Koryto gold deposit(80 t Au at 1.84 g/t) in the Lena world-class province,Siberia,is hosted in a metamorphosed sequence of the Paleoproterozoic Mikhailovsk Formation that comprises the oldest black shale strata of the Baikal-Patom region.The mineralisation is confined to the thrust zone complicated with a conjugate anticline fold,zones of shearing and dislocation.The struaural position of the mineralisation is similar to that at the giant Sukhoi Log deposit in the neighbouring Mama-Bodaibo zone.In the latter,the isotope age data suggest that Khomolkho black shales,hosts to Sukhoi Log mineralisation,are of Ediacaran age and underwent prograde metamorphism during early Paleozoic.The geochemical composition of the terrigenous rocks that host Sukhoi Log,Chertovo Koryto,and a number of other deposits at the various stratigraphic levels throughout the Proterozoic sequence have much in common.They do not show elevated metal contents above the common black shale abundances,except for Au and As,which is at variance with the accepted view on diagenetic enrichment of black shales in the Lena province.The occurrence of sagenitic rutile in quartz and chlorite pseudomorphs after biotite and other petrographic observations provide evidence on a retrograde nature of the metamorphic mineral assemblages in the Mikhailovsk rocks.The sulphides are pyrrhotite and arsenopyrite with very minor pyrite at Chertovo Koryto,whereas pyrite is the predominant sulphide in the Sukhoi Log ore.Fluid inclusion data on both deposits emphasise a high-temperature nature of the mineralisation albeit revealing great contrast in the fluid composition.Sukhoi Log mineralisation was formed at mixing between low-salinity aqueous solutions and dense gaseous carbonic fluids,which facilitated effective gold scavenging and precipitation,as demonstrated by thermodynamic simulation.The precursory devolatilisation of the Mikhailovsk sediments at the prograde stage results in the paucity of gaseous carbonic fluid during retrograde metamorphism and mineralisation.The similarity in the styles and chemical parameters of mineralisation,and the predominant structural control of ore localisation within the same Precambrian regional tectonic unit support an idea that orogenic gold mineralisation in the Lena province was produced during a single early Paleozoic event.
文摘The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones surrounding the core of the Luotian dome, and the separation of the UHP, HP and epidote blueschist units by the detachment zones, which form the vertically stacking sheet like slices of the HP and UHP metamorphic rocks. From the core outwards, exist the HP and UHP rock barren Dabie complex, UHP unit, HP unit and epidote blueschist unit. The extension tectonics of post HP and UHP metamorphic event constrain the distribution and present configuration of the HP and UHP metamorphic rocks, and the extensional tectonic framework bears some similarities to the Cordillera metamorphic core complex. It is suggested that partial melting happened in the Dabie gneiss complex (DGC) and UHP unit contemporaneously with the extrusion of UHP metamorphic rocks into the lower-middle crust. The formation and emplacement of the migmatite and granites are the response to the change in thermal state, facilitating the transfer from the compressive regime to extensional regime in the crust. The large scale crustal extension and uplift and the accompanying anatexis in Dabieshan are probably related to the delamination and magmatic underplating in the mantle and the lower crust.
文摘Successions of FIAs(foliation inflection/intersection axes preserved within porphyroblasts) provide a relative time scale for deformation and metamorphism.In-situ dating of monazite grains preserved as inclusions within garnet and staurolite porphyroblasts within the foliations defining each FIA from such successions provides a rigorous approach to grouping ages that formed over extended periods of deformation and metamorphism.Matching age and FIA progressions confirms the suitability of this approach plus provides access to lengthy histories that cannot otherwise be determined.Tectonism in the Big Thompson region of the Colorado Rocky Mountains,USA began about a SW-NE trending axis defined by FIA set 1 at around 1761±13 Ma.Subsequent periods of tectonism occurred around 1712±25 and 1672±21 Ma about W-E and NW-SE trending FIAs 2 and 3, respectively.Tectonism in the Balcooma Metamorphic Group NW of Greenvale in NE Queensland, Australia began around 470 Ma with the growth of garnet porphyroblasts about a W-E trending axis defined by FIA set 1.No monazite grains were preserved as inclusions in this mineral phase but they were in subsequently grown staurolite.Tectonism then occurred around 443.2±3.8,424±4 and 408.9±8.9 Ma about NNW-SSE,SSW-NNE and W-E trending FIAs 2,3 and 4,respectively.This test of a FIA based approach to monazite dating in tectonic regimes in different parts of the world and with dramatically different ages suggests it can be used in all orogens containing porphyroblasts preserving inclusion trails.
基金supported by the National Natural Science Foundation of China(Grant No 41372061 and 40821002)
文摘This study uses illite crystallinity,chlorite crystallinity,illite polytypes,the b0 cell-dimension of K-white mica,clay mineral assemblages and mineral geothermo-geobarometers to investigate the overprint of diagenesis and metamorphism on the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang in northeastern Hunan Province,China.Illite crystallinity Kbler index(KI) of the 〈2μm fractions ranges from 0.225 to 0.485°Δ2θ while chlorite crystallinity Arkai index(AI) ranges from 0.244 to 1.500°Δ2θ.This indicates that the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang were overprinted with diagenesis and anchi- to epimetamorphism.Peak metamorphic temperature is estimated with the IV site chlorite geothermometer roughly at 360℃.The b0 cell dimension values of illites(K-mica) range from 0.9002 to 0.9054 nm and,on average,at 0.9030 nm for the Meso-Neoproterozoic.Based on cumulative frequency curves of illite(K-mica) b0 cell dimension,the peak metamorphic pressure of the MesoNeoproterozoic along the profile Yueyang-Linxiang is derived of an intermediate pressure type.Most illites occur in the 2M1 polytype and some of them in a mixture of 2M1+1M types especially those in the Paleozoic.This result partly agrees with the conclusion of the lower greenschist and greenschist facies of the Lengjiaxi and Banxi Groups.However,it is not agreed with the sedimentary cover from the Sinian to the Lower Paleozoic or from the Banxi Group to the Lower Paleozoic.Crustal thickening due to "collision" between the Yangtze and Cathaysia blocks led to an increase in the thickness of the Meso-Neoproterozoic to ca.14 km and resulted in a temperature increase in those rocks due to burial.The very low grade to low grade metamorphism overprinting the Meso-Neoproterozoic implies that the so called "Chiangnania or Jiangnan orogen" was no relative with the "Grenvillian orogeney;instead,it might be a continuous amalgamation product between the Yangtze and Cathaysia blocks.