The ultra-long electromagnetic wave remote sensing technique developed by Peking University is one of new future techniques, which can detect the submarine geological information from the depth of 20 to 10000 m below ...The ultra-long electromagnetic wave remote sensing technique developed by Peking University is one of new future techniques, which can detect the submarine geological information from the depth of 20 to 10000 m below the surface by receiving natural ultra-long electromagnetic waves (n Hz to n 100 Hz). The new remote sensor is composed of three parts: a main instrument with a portable computer, an antenna with an amplifier and an external power.展开更多
A stability of a nonlinear ultra-long wave and its solution are discussed in this paper by employing Burger model which is subject to heat resource. It is of interest noted that the wave solution can be described by a...A stability of a nonlinear ultra-long wave and its solution are discussed in this paper by employing Burger model which is subject to heat resource. It is of interest noted that the wave solution can be described by an equation of KDV or MKDV and that conditions for the existence of the solution are related to characteristic divergences. In addition, a wave velocity expression for nonlinear ultra-long waves and some diagnostic correlations among wave parameters have been obtained.展开更多
We develop a new electrospinning method to prepare ultra-long ordered La1-xSrxMnO3 （LSMO） nanowires. The length is up to several centimeters and is only limited by the size of the collector. The well-ordered straigh...We develop a new electrospinning method to prepare ultra-long ordered La1-xSrxMnO3 （LSMO） nanowires. The length is up to several centimeters and is only limited by the size of the collector. The well-ordered straight-line structure ensures the transport measurement, which is impossible to be carried out for the random nanowires fabricated by the traditional electrospinning method. Magnetic and transport measurements indicate that the physical properties of the LSMO nanowires depend sensitively on the doping concentration. At the optimum doping, the LSMO wires are ferromagnetic at room temperature with a metal-insulator transition temperature close to room temperature. Magnetic force microscopy studies are also performed to provide a microscopic view of these ultra-long nanowires.展开更多
Recently, an effective exciton diffusion length L exceeding 100μm has been reported for organic- inorganic halide perovskites owing to both the high mobility and ultra-long lifetime of the excitons; however, the orig...Recently, an effective exciton diffusion length L exceeding 100μm has been reported for organic- inorganic halide perovskites owing to both the high mobility and ultra-long lifetime of the excitons; however, the origin of ultra-long L is still unclear in nature. In some photoelectric materials, reverse intersystem crossing （RISC） from the triplet to the singlet state can enhance the quantum yield of pho- toluminescence greatly. In this study, our theoretical investigation indicated that the energy difference △E_st between the singlet state and the triplet state of CH_3NH_3Pbl_3 was less than 0.1 eV, which represents one crucial prerequisite for the occurrence of RISC. Meanwhile, the experimental results showed that the photoluminescence lifetime increased with the increasing temperature, a typical feature of RISC. Based on this study, we put forward the hypothesis that the ultra-long lifetime of excitons in organic-inorganic halide perovskite might be caused by the RISC process. This may provide a new insight into the important photophysical properties of such novel photovoltaic materials.展开更多
Carbon nitrides with two-dimensional layered structures and high theoretical capacities are attractive as anode materials for sodium-ion batteries while their low crystallinity and insufficient structural stability st...Carbon nitrides with two-dimensional layered structures and high theoretical capacities are attractive as anode materials for sodium-ion batteries while their low crystallinity and insufficient structural stability strongly restrict their practical applications.Coupling carbon nitrides with conductive carbon may relieve these issues.However,little is known about the influence of nitrogen(N)configurations on the interactions between carbon and C_(3)N_(4),which is fundamentally critical for guiding the precise design of advanced C_(3)N_(4)-related electrodes.Herein,highly crystalline C_(3)N_(4)(poly(triazine imide),PTI)based all-carbon composites were developed by molten salt strategy.More importantly,the vital role of pyrrolic-N for enhancing charge transfer and boosting Na+storage of C_(3)N_(4)-based composites,which was confirmed by both theoretical and experimental evidence,was spot-highlighted for the first time.By elaborately controlling the salt composition,the composite with high pyrrolic-N and minimized graphitic-N content was obtained.Profiting from the formation of highly crystalline PTI and electrochemically favorable pyrrolic-N configurations,the composite delivered an unusual reverse growth and record-level cycling stability even after 5000 cycles along with high reversible capacity and outstanding full-cell capacity retention.This work broadens the energy storage applications of C_(3)N_(4) and provides new prospects for the design of advanced all-carbon electrodes.展开更多
文摘The ultra-long electromagnetic wave remote sensing technique developed by Peking University is one of new future techniques, which can detect the submarine geological information from the depth of 20 to 10000 m below the surface by receiving natural ultra-long electromagnetic waves (n Hz to n 100 Hz). The new remote sensor is composed of three parts: a main instrument with a portable computer, an antenna with an amplifier and an external power.
文摘A stability of a nonlinear ultra-long wave and its solution are discussed in this paper by employing Burger model which is subject to heat resource. It is of interest noted that the wave solution can be described by an equation of KDV or MKDV and that conditions for the existence of the solution are related to characteristic divergences. In addition, a wave velocity expression for nonlinear ultra-long waves and some diagnostic correlations among wave parameters have been obtained.
基金Supported by the National Basic Research Program of China under Grant Nos 2016YFA0300700,2013CB932901 and2014CB921104the National Natural Science Foundation of China under Grant Nos 11274071 and 11504053the Shanghai Municipal Natural Science Foundation under Grant No 11ZR140260
文摘We develop a new electrospinning method to prepare ultra-long ordered La1-xSrxMnO3 （LSMO） nanowires. The length is up to several centimeters and is only limited by the size of the collector. The well-ordered straight-line structure ensures the transport measurement, which is impossible to be carried out for the random nanowires fabricated by the traditional electrospinning method. Magnetic and transport measurements indicate that the physical properties of the LSMO nanowires depend sensitively on the doping concentration. At the optimum doping, the LSMO wires are ferromagnetic at room temperature with a metal-insulator transition temperature close to room temperature. Magnetic force microscopy studies are also performed to provide a microscopic view of these ultra-long nanowires.
基金The financial supports of the National Natural Science Foundation of China (grant nos. 21373042, 21677029 and 51402036)the Fundamental Research Funds for the Central Universities (grant no. DUT15YQ109)
文摘Recently, an effective exciton diffusion length L exceeding 100μm has been reported for organic- inorganic halide perovskites owing to both the high mobility and ultra-long lifetime of the excitons; however, the origin of ultra-long L is still unclear in nature. In some photoelectric materials, reverse intersystem crossing （RISC） from the triplet to the singlet state can enhance the quantum yield of pho- toluminescence greatly. In this study, our theoretical investigation indicated that the energy difference △E_st between the singlet state and the triplet state of CH_3NH_3Pbl_3 was less than 0.1 eV, which represents one crucial prerequisite for the occurrence of RISC. Meanwhile, the experimental results showed that the photoluminescence lifetime increased with the increasing temperature, a typical feature of RISC. Based on this study, we put forward the hypothesis that the ultra-long lifetime of excitons in organic-inorganic halide perovskite might be caused by the RISC process. This may provide a new insight into the important photophysical properties of such novel photovoltaic materials.
基金supported by the National Natural Science Foundation of China(51904059)Applied Basic Research Program of Liaoning(2022JH2/101300200)+1 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515140188)Fundamental Research Funds for the Central Universities(N_(2)002005,N_(2)125004,N_(2)225044)。
文摘Carbon nitrides with two-dimensional layered structures and high theoretical capacities are attractive as anode materials for sodium-ion batteries while their low crystallinity and insufficient structural stability strongly restrict their practical applications.Coupling carbon nitrides with conductive carbon may relieve these issues.However,little is known about the influence of nitrogen(N)configurations on the interactions between carbon and C_(3)N_(4),which is fundamentally critical for guiding the precise design of advanced C_(3)N_(4)-related electrodes.Herein,highly crystalline C_(3)N_(4)(poly(triazine imide),PTI)based all-carbon composites were developed by molten salt strategy.More importantly,the vital role of pyrrolic-N for enhancing charge transfer and boosting Na+storage of C_(3)N_(4)-based composites,which was confirmed by both theoretical and experimental evidence,was spot-highlighted for the first time.By elaborately controlling the salt composition,the composite with high pyrrolic-N and minimized graphitic-N content was obtained.Profiting from the formation of highly crystalline PTI and electrochemically favorable pyrrolic-N configurations,the composite delivered an unusual reverse growth and record-level cycling stability even after 5000 cycles along with high reversible capacity and outstanding full-cell capacity retention.This work broadens the energy storage applications of C_(3)N_(4) and provides new prospects for the design of advanced all-carbon electrodes.
