Study on Extraction of Oolong Tea Assisted by Ultrasonic Wave and 4C Technique and Its Application

[Objectives]The extraction conditions of formula oolong tea were investigated by an orthogonal experiment.[Methods]The technical conditions were optimized by the 4C method,and the application of formula oolong tea extract in cigarettes was studied.[Results]①In the experimental range,the best sensory evaluation effect of formula oolong tea extract was obtained with extraction conditions of 70%ethanol as extraction solvent,extraction time h,extraction temperature 25℃,and ultrasonic frequency 80 kHz,and follow-up low-temperature concentration,low-temperature sedimentation and low-temperature centrifugation.②The effects of different centrifugal speeds on the quality of formula oolong tea extract were explored.The formula oolong tea extract obtained under the conditions of 3000 r/min and centrifugal time of 10 min showed the best evaluation effect with soft and delicate smoke,rich smoke fragrance,good comfort and refreshing mouthfeel.③The effective aroma components in the formula oolong tea extract were qualitatively analyzed by GC-MS.[Conclusions]This study provides high-quality raw materials and a theoretical basis for the research of independent flavor blending in cigarette industry enterprises.

Assessment of flexural properties of different grade dimension lumber by ultrasonic technique

The dimension lumber （45mm×90mm×3700mm） of plantation Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） was graded to four different classes as SS, No. 1, No.2 and No.3, according to national lumber grades authority （NLGA） for structure light framing and structure joists and planks. The properties of apparent density was determined at 15% moisture content, bending strength and stiffness were tested according to American Society for Testing and Materials （ASTM） D198-99, and dynamic modulus of elasticity （Eusw） was measured by ultrasonic technique, for predicting the flexural properties of different grade lumbers. The results showed that Eosw was larger than the static MOE. The relationship between Eusw and static MOE was significant at 0.01 level, and the determination coefficients （R2） of the four grade lumbers followed the sequence as R^2No.2 （0.616）〉 R^2ss （0.567）〉 R^2No1 （0.366）〉 R^2No.3 （0.137）. The R^2 of Fusw and MOR were lower than that of the Etru and MOR for each grade. The Eusw of all the grade lumbers, except No.3-grade, had significant correlation with the static MOE and MOR, thus the bending strengthof those grade lumbers can be estimated by the E The Etru valuesof four grade lumbers followed a sequence as No.2-grade （10.701 GPa） 〉 SS-grade （10.359 GPa） 〉 No.l-grade （9.840 GPa） 〉 No.3-grade （9.554 GPa）. For the same grade dimension lumber, its Eusw value was larger than static MOE. Mean values of MOR for four grade lumbers follow a sequence as No.2-grade （48.67 MPa） 〉 SS-grade （48.16 MPa） 〉 No.3-grade （46.55 MPa） 〉 No. 1-grade （43.39MPa）.

A fast approach to optimize dye loading of photoanode via ultrasonic technique for highly efficient dye-sensitized solar cells

A distinctive method is proposed by simply utilizing ultrasonic technique in Ti02 electrode fabrication in order to improve the optoelectronic performance of dye-sensitized solar cells （DSSCs）. Dye molecules are at random and single molecular state in the ultrasonic field and the ultrasonic wave favors the diffusion and adsorption processes of dye molecules. As a result, the introduction of ultrasonic technique at room temperature leads to faster and more well-distributed dye adsorption on TiO2 as well as higher cell efficiency than regular deposition, thus the fabrication time is markedly reduced. It is found that the device based on 40 kHz ultrasonic （within 1 h） with N719 exhibits a Voc of 789 mV, Jsc of 14.94 mA]cm2 and fill factor （FF） of 69.3, yielding power conversion efficiency （PCE） of 8.16%, which is higher than device regularly dyed for 12 h （PCE = 8.06%）. In addition, the DSSC devices obtain the best efficiency （PCE = 8.68%） when the ultrasonic deposition time increases to 2.5 h. The DSSCs fabricated via ultrasonic technique presents more dye loading, larger photocurrent, less charge recombination and higher photovoltage. The charge extraction and electron impedance spectroscopy （EIS） were performed to understand the influence of ultrasonic technique on the electron recombination and performance of DSSCs.

Ultrasonic wave extraction and simultaneous analysis of polycyclic aromatic hydrocarbons (PAHs) and phthalic esters in soil

A method is developed for detection of polycyclic aromatic hydrocarbons(PAHs) and Phthalic Acid Esters(PAEs) in soil samples. Ultrasonic Wave Extraction under airtight circumstances is adopted to extract the analytes in soil samples with n-hexane–acetone(V:V=1:1) as extraction solvent. This method has several advantages, including high extraction efficiency, short time, convenience and simplicity. It can be used to detect polycyclic aromatic hydrocarbons(PAHs) and Phthalic Acid Esters(PAEs) in soil.

Application of subband adaptive filtering techniques to ultrasonic detection in multilayers

The ultrasonic testing for the defects of complete disbond in multi-layered structure with lower acoustic impedance beneath a high acoustic impedance overburden is one of the difficult problems in ultrasonic nondestructive testing field. A model of a multi-layered steel-rubber composite plate is depicted. Because the acoustic impedance of the steel differs far from that of the couplant water and the rubber, the energy of the signal reflected from the debonded rubber layers is very weak. More over, the flaw echoes are masked by the strong echoes reverberated in the steel plate. It's nearly impossible to identify the debonding echoes directly. The subband adaptive filtering method is discussed in the paper, where the subband decomposition is performed by mutual wavelet packets decomposition on the criterion of maximizing the cross-correlation between the signals. The simulations on both synthetic and real signals are presented. The echoes from the delaminated flaw at the depth of 5 mm in the rubber from the calculated signal, and echoes from the flaw at the depth of 3 mm from the real signal are extracted successfully.

Preparation of transparent conducting ZnO:Al films on glass substrates by ultrasonic spray technique

Transparent conductive Al doped ZnO thin films were deposited by ultrasonic spray technique.Conditions of preparation have been optimized to get good quality.A set of aluminum（Al） doped ZnO（between 0 and 5 wt%） thin films were grown on glass substrate at 350℃.Nanocrystalline films with a hexagonal wurtzite structure show a strong（002） preferred orientation.The maximum value of grain size G = 32.05 nm is attained of Al doped ZnO film with 3 wt%.All the films have low absorbance in the visible region,thus the films are transparent in the visible region;the band gap energy increased from 3.10 to 3.26 eV when Al concentration increased from 0 to 3 wt%.The electrical conductivity of the films increased from 7.5 to 15.2（Ω·cm）^（-1）.So the best results are achieved in Al doped ZnO film with 3 wt%.

Correlation between electrical conductivity–optical band gap energy and precursor molarities ultrasonic spray deposition of ZnO thin films

ZnO thin films were deposited using the simple, flexible and cost-effective spray ultrasonic technique at different precursor molarities values. The films were deposited on a glass substrate at 350℃. This paper is to present a new approach to the description of correlation between electrical conductivity and optical gap energy with precursor molarity of ZnO thin films. The ZnO films exhibit higher electrical n-type semiconductors, whose band gap energy increased from 3.08 to 3.37 eV with an increasing of precursor molarity of 0.05 to 0.1 M. The maximum value of electrical conductivity of the films is 7.96 （S2.cm）-1 obtained in the ZnO thin film for precursor molarity 0.125 M. The correlation between the electrical and the optical properties with the precursor molarity suggests that the electrical conductivity of the films is predominantly influenced by the band gap energy and the precursor molarity. The measurement of the electrical conductivity of the films with correlation is equal to the experimental with the error is about 1% in the higher conductivity.

Preparation of Functionalized Porous Silica by Ultrasonic Technique for the Methylation Reaction of Phenol with Dimethyl Carbonate

Porous silica modified with -（CH2）3NH2 （primary amine）, -（CH2）3NHCH2CH2NH2 （secondary/primary amine） and -（CH2）3N-cycl-（CH2）4 （tertiary amine） were synthesized by ultrasonic technique under mild conditions. The samples were characterized by BET, elemental analysis and TG, showing that the organosilane moieties were grafted onto the surface of porous silica by covalent bond. The structure of the organosilane moieties and ultrasonic treatment time were all significant for the quantities of grafted amino groups. The samples exhibited promising catalytic properties towards the methylation reaction of phenol with dimethyl carbonate （DMC）. The methylation reaction with the modified samples featured high selectivity at high conversion. The samples were subjected to utilization for a few recycles without obvious loss of activity to indicate that ultrasonic technique was effective for the preparation of organically modified porous silica catalysts.

Ultrasonic spray pyrolysis deposition of SnSe and SnSe_2 using a single spray solution

Thin films of SnSe and SnSe2 have been deposited using the ultrasonic spray pyrolysis（USP） technique.To the best of our knowledge this is the first report of the deposition of SnSe and SnSe2 thin films using a single spray solution.The use of a single spray solution for obtaining both a p-type material,SnSe,and an n-type material,SnSe2,simplifies the deposition technique.The SnSe2 thin films have a bandgap of 1.1 eV and the SnSe thin films have a band gap of 0.9 eV.The Hall measurements were used to determine the resistivity of the thin films.The SnSe2 thin films show a resistivity of 36.73 Ωcm and n-type conductivity while the SnSe thin films show a resistivity of 180 Ωcm and p-type conductivity.

The effect of the film thickness and doping content of SnO2:F thin films prepared by the ultrasonic spray method

This paper reports on the effects of film thickness and doping content on the optical and electrical properties of fluorine-doped tin oxide. Tin （Ⅱ） chloride dehydrate, ammonium fluoride dehydrate, ethanol and HC1 were used as the starting materials, dopant source, solvent and stabilizer, respectively. The doped films were deposited on a glass substrate at different concentrations varying between 0 and 5 wt% using an ultrasonic spray technique. The SnO2：F thin films were deposited at a 350 ℃ pending time （5, 15, 60 and 90 s）. The average transmission was about 80%, and the films were thus transparent in the visible region. The optical energy gap of the doped films with 2.5 wt% F was found to increase from 3.47 to 3.89 eV with increasing film thickness, and increased after doping at 5 wt%. The decrease in the Urbach energy of the SnO2：F thin films indicated a decrease in the defects. The increase in the electrical conductivity of the films reached maximum values of 278.9 and 281.9 （Ω.cm）-1 for 2.5 and 5 wt% F, respectively, indicating that the films exhibited an n-type semiconducting nature. A systematic study on the influence of film thickness and doping content on the properties of SnO2：F thin films deposited by ultrasonic spray was reported.

Application of the digital matched-filter technique to ultrasonic non-destructive testing

Acoustic-pulse compression is obtained in systems with different timebandwidth products by applying the digital matched-filter technique to ultrasonic non-destructive testing. The signal is linearly frequency -modulated (LFM) pulse and the digitized electrical-excitation signal itself is used as a digital matched filter. Experimental results are in good agreement with theory. Suppressions of side lobes achieve -41.9 dB and -41.5 dB for the Hamming and Gaussian weighted signals respectively. It shows that the application of the digital matched-filter technique improves the performances of a ultrasonic testing system explicitly.

Influence of growth time on crystalline structure,conductivity and optical properties of ZnO thin films

This paper examines the growth of ZnO thin films on glass substrate at 350 ℃ using an ultrasonic spray technique. We have investigated the influence of growth time ranging from 1 to 4 min on structural, optical and electrical properties of ZnO thin films. The as-grown films exhibit a hexagonal structure wurtzite and are （002） oriented. The maximum value of grain size G = 63.99 nm is attained for ZnO films grown at 2 min. The average transmittance is about 80%, thus the films are transparent in the visible region. The optical gap energy is found to increase from 3.26 to 3.37 eV with growth time increased from 1 to 2 min. The minimum value of electrical resistivity of the films is 0.13 Ω.cm obtained at 2 min. A systematic study on the influence of growth time on the properties of ZnO thin films deposited by ultrasonic spray at 350 ℃ has been reported.

MEASUREMENT AND ANALYSIS OF LASER GENERATED RAYLEIGH AND LAMB WAVES CONSIDERING ITS PULSE DURATION

In this article, laser generated Rayleigh and Lamb waves are studied by taking into account its pulse duration. The physical model and theoretical solution are presented to predict the corresponding waveforms for aluminum samples under the ablation generation regime. The waveforms of the excited Rayleigh and Lamb waves by laser with selected pulse duration were measured by laser interferometer and analyzed theoretically, and the agreement between measurement and analysis is demonstrated for the validation of the theoretical model and solution. The broadening of the Rayleigh wave and the disappearing of high order Lamb wave modes can be found with the increase of the pulse duration by the laser ultrasonic technique.

Preparation of n-type semiconductor SnO_2 thin films

We studied fluorine-doped tin oxide on a glass substrate at 350℃using an ultrasonic spray technique. Tin（Ⅱ） chloride dehydrate,ammonium fluoride dehydrate,ethanol and NaOH were used as the starting material, dopant source,solvent and stabilizer,respectively.The SnO_2：F thin films were deposited at 350℃and a pending time of 60 and 90 s.The as-grown films exhibit a hexagonal wurtzite structure and have（101） orientation.The G = 31.82 nm value of the grain size is attained from SnO_2：F film grown at 90 s,and the transmittance is greater than 80%in the visible region.The optical gap energy is found to measure 4.05 eV for the film prepared at 90 s, and the increase in the electrical conductivity of the film with the temperature of the sample is up to a maximum value of 265.58（Ω·cm）^（-1）,with the maximum activation energy value of the films being found to measure 22.85 meV,indicating that the films exhibit an n-type semiconducting nature.